CN101108955B - Adhesion agent for bonding energy conserving lamp glass ball bulb and lamp cap plastic member and method of manufacturing the same - Google Patents
Adhesion agent for bonding energy conserving lamp glass ball bulb and lamp cap plastic member and method of manufacturing the same Download PDFInfo
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- CN101108955B CN101108955B CN2007101452148A CN200710145214A CN101108955B CN 101108955 B CN101108955 B CN 101108955B CN 2007101452148 A CN2007101452148 A CN 2007101452148A CN 200710145214 A CN200710145214 A CN 200710145214A CN 101108955 B CN101108955 B CN 101108955B
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Abstract
The invention discloses a tackiness agent between adhesive bonding energy saving lamps crystal bulbs and lamp cap plastic parts and the preparation method and application. The tackiness agent consists of the following components of parts of weight: 100 latex using water as the disperse medium, 30 to 300 inorganic fillers, 1 to 20 brightening agents, 0.1 to 10 aging inhibitors, 0.05 to 10 anti-mildew agents, 0.1 to 10 silane coupling agent and 0 to 30 water. The tackiness agent of the invention can not only be heated for curing but also can be put under the room temperature for cold curing, has low heat dilating rate and good resistance to cold and hot alternating performance and is not easy to cause the burst of crystal bulb mouths under the condition of being heated or getting cold during curing and using, and has no toxic substances discharging and can fully meet the requirements of environment protection and no pollution. Because the burst and falling off do not occur to the crystal bulb mouths through interval thermal ageing for 200h under the temperature of 130 DEG C., the tackiness agent can replace the adhesive materials with high thermal expansion rate in high elastic state for the adhesive bonding of energy saving lamps crystal bulbs mouths.
Description
Technical field
The present invention relates to a kind of tackiness agent, relate in particular to the environmental-protection type adhesive that glueds joint usefulness between a kind of glass ball bulb of electricity-saving lamp and the lamp cap plastic parts, the invention still further relates to the preparation method and the using method of this tackiness agent, belong to chemical field.
Background technology
Along with the develop rapidly of human society and science and technology, environment protection and energy-conservationly more and more be subjected to people and pay attention to, electricity-saving lamp promote the use of a vital measure that becomes in the economize on electricity field.At present, annual nearly 10,000,000,000 of the electricity-saving lamp of producing in the world, the main place of production is in China.What be connected between the glass ball bulb that is used for protecting energy-saving lamp tube and the lamp cap plastic parts mainly glueds joint by tackiness agent (calling the bubble chewing-gum in the following text).In recent years, the bubble chewing-gum that each electricity-saving lamp manufacturer of China adopts is main: the filled type tackiness agent of heat-reactive phenolic resin is arranged, the filled type tackiness agent of single, double component thermosetting epoxy resin, single, double component polyurethane adhesive and single, double component silicone cross-linked rubber stick etc., the manufacturing process complexity that has environmental pollution, has, cost height that these glue have, nearly all exist produce and use in be prone to the problem of aspects such as glass ball bulb explosion, can not satisfy national to environmental protection, safety, electricity-saving lamp quality and work-ing life the aspect requirement.Thereby urgent need is developed the environment-friendly type energy-saving bulb chewing-gum that cost of new generation is low, do not occur the explosion of glass sphere bubble mouth in production and use at present.
Summary of the invention
The present invention's technical problem at first to be solved is that the tackiness agent that overcomes between existing splicing electricity-saving lamp glass ball bulb and the lamp cap plastic parts easily causes glass ball bulb cracked in production and use, solidifying and use has harmful substances and defective such as emits, a kind of new environmental protection is provided, tackiness agent between resistant to elevated temperatures splicing electricity-saving lamp glass ball bulb and the lamp cap plastic parts, this tackiness agent can not cause glass ball bulb cracked in production and use, can reduce the production cost of bubble chewing-gum effectively, can not discharge objectionable impurities in curing and use yet, can prevent to steep chewing-gum effectively and be prone to environmental pollution problems in production and use, its performance satisfies the quality of country to the electricity-saving lamp product fully, environmental protection and work-ing life etc. the aspect requirement.
The present invention's technical problem at first to be solved realizes by following technological approaches:
A kind of tackiness agent that glueds joint between electricity-saving lamp glass ball bulb and the lamp cap plastic parts, mainly form by the component of following weight part:
With water is latex 100 heavy parts of dispersion medium, 30～300 parts of high temperature resistant inorganic fillers, 1～20 part in whitening agent, 0.1～10 part in anti-aging agent, 0.05～10 part of anti-mildew agent, 0～30 part in 0.1～10 part of silane coupling agent and water;
Preferably, be outside the latex of dispersion medium divided by water, the weight part of all the other each components is:
100～250 parts of high temperature resistant inorganic fillers, 1～10 part in whitening agent, 0.1～2 part in anti-aging agent, 0.05～5 part of anti-mildew agent, 0.1～2 part of silane coupling agent, 0～20 part in water;
Preferred, the weight part of each component is:
100～200 parts of high temperature resistant inorganic fillers, 1～2 part in whitening agent, 0.1～1 part in anti-aging agent, 0.05～1 part of anti-mildew agent, 0.1～1 part of silane coupling agent, 0～10 part in water.
Wherein, described is that the latex (comprising the dry powder made from emulsion) of dispersion medium is preferably from benzene emulsion, organosilicon crylic acid latex or pure-acrylic emulsion with water.
Described is the benzene emulsion of dispersion medium with water, and its solid content is 30%～65%, is preferably 45%～55%; Viscosity is 400mPas～2000mPas, is preferably 500mPas～1000mPas; Second-order transition temperature Tg is 15 ℃～30 ℃, is preferably 20 ℃～25 ℃; Residual monomer quantity≤1%.
Described is the pure-acrylic emulsion of dispersion medium with water, and its solid content is 30%～60%, is preferably 45%～55%; Viscosity is 300mPas～2000mPas, is preferably 500mPas～1500mPas; Second-order transition temperature Tg is-30 ℃～30 ℃, is preferably 10 ℃～20 ℃; The pH value is 7.5～10, residual monomer quantity≤1%.
Described is the organosilicon crylic acid latex of dispersion medium with water, and its solid content is 30%～60%, is preferably 45%～55%; The pH value is 7.5～10, is preferably 8～9.5, and viscosity is 200mPas～2000mPas, is preferably 300mPas～900mPas; Second-order transition temperature Tg is 10 ℃～30 ℃, is preferably 12 ℃～18 ℃; Residual monomer quantity≤1%.
Described high temperature resistant inorganic filler is preferably from silicon powder, wollastonite powder, Feldspar Powder, talcum powder, silica powder, tripoli, aluminum oxide powder, lightweight, heavy calcium carbonate, zinc sulfide white, ground barium sulfate, mica powder, potter's clay powder or kaolin powder etc.
Wherein, for silicon powder, its SiO
2Content 〉=90%, be preferably 〉=99%; The content of ferric oxide≤1%, best≤0.1%; Fineness should reach 50 orders～1200 orders; Moisture content≤1%.
For wollastonite powder, its SiO
2Content 〉=40%, be preferably 〉=75%; Calcium oxide content is 〉=40%, be preferably 〉=45%; Fineness should reach 200 orders～1200 orders; Moisture content≤1% is preferably moisture content≤0.5%.
For Feldspar Powder, its SiO
2Content 〉=70%, be preferably 〉=75%; The content of aluminium sesquioxide 〉=10%, be preferably 〉=11%; Calcium oxide content is≤1.4%; The content of ferric oxide≤1.4%; Fineness reaches more than 50 orders;
For talcum powder, its outward appearance should be pure white or silvery white; SiO
2Content 〉=55%, be preferably 〉=58%; Content of magnesia 〉=27%, be preferably 〉=29%; Fineness 45 μ m sieve percent of pass 〉=90%; Moisture content≤1%.
For silica powder, its SiO
2Content 〉=90%, be preferably 〉=99%; The content of ferric oxide≤1%, be preferably≤0.1%; Fineness should reach 50 orders～1200 orders; Moisture content≤1%.
Other adoptable other filler such as tripoli, aluminum oxide powder and lightweight, heavy calcium carbonate, zinc sulfide white, ground barium sulfate, mica powder, potter's clay powder or kaolin powder, fineness should reach 50 orders～1200 orders, moisture content≤1.0%
Described whitening agent is preferably titanium dioxide, content of titanium dioxide 〉=94%, 105 ℃ fugitive constituent≤0.5% wherein, fineness 45 μ m screenings≤0.3%, the content of ferric oxide≤1.4%;
Described anti-aging agent is preferably antioxidant DOD, i.e. xenol, fusing point 〉=275 ℃.
Described anti-mildew agent is preferably sodium pentachlorophenate, magnesiumcarbonate or Sodium Benzoate, first fusing point 〉=175 of sodium pentachlorophenate ℃, insolubles content in the water≤1%.
Described silane coupling agent is preferably the γ aminopropyl triethoxysilane, its purity 〉=90%.
The used raw material of the present invention all can buy from market, and its specification is three grades of chemical reagent or commercial grade.
Another technical problem to be solved by this invention provides a kind of method for preparing tackiness agent between above-mentioned splicing electricity-saving lamp glass ball bulb and the lamp cap plastic parts.
A kind of method for preparing tackiness agent between above-mentioned splicing electricity-saving lamp glass ball bulb and the lamp cap plastic parts comprises:
(1) take by weighing each component by following weight part: with water 100 parts of the latexes of dispersion medium, 30～300 parts of high temperature resistant inorganic fillers, 1～20 part in whitening agent, 0.1～10 part in anti-aging agent, 0.05～10 part of anti-mildew agent, 0～30 part in 0.1～10 part of silane coupling agent and water;
(2) at first will be with water the latex of dispersion medium join stir 5-20 minute (being preferably 10 minutes) in the stirring tank after, add whitening agent successively, anti-aging agent, anti-mildew agent and silane coupling agent, restir 5-20 minute (being preferably 10 minutes), treat mixing of materials evenly the back under continuous condition of stirring in batches (as for a minute several batches, those skilled in the art can depend on the circumstances, do not constitute any influence for enforcement of the present invention or effect) the adding mineral filler, after all material adds, continuously stirring is 2～3 hours again, treat that material is the paste thick liquid, viscosity reaches 1～10Pas, stops to stir and discharging, promptly.
The present invention is used to glued joint the using method between electricity-saving lamp glass ball bulb and the lamp cap plastic parts: prepared tackiness agent is coated in the groove of energy-saving lamp holder and is used to glued joint glass ball bulb and lamp cap plastic parts, the Amount of spread of each lamp holder is 2g～3g, the bubble chewing-gum through completely solidified after the baking of following 40 minutes of 120 ℃ of temperature (perhaps relative humidity less than 60%, envrionment temperature be to hang one day under 20 ℃～30 ℃ conditions after completely solidified).
Tackiness agent of the present invention has following characteristics: tackiness agent is a dispersion medium with water, and starting material are easy to get, and manufacturing process is simple, use technology is easy; Cost is very low; Not only heating curable but also can under room temperature, place and carry out cold-curing; This glue is emitted in curing and use unharmful substance, can fully satisfy the requirement of environment friendly and pollution-free aspect; Can bulging in this glue assimilation process, the coefficient of thermal expansion of cured glue matter is very low, cold-resistant hot alternation thus in use can be owing to the sizing material expanded by heating, meet cold contraction and cause the cracked of glass sphere bubble mouth; This glue Joint strength height can for a long time anti-130 ℃ of high temperature and thermal ageing, does not decompose under 200 ℃.
It is that the copolymer emulsion of dispersion medium is a cohesive material with water that the present invention has adopted, only there is small amount of moisture to disengage in its curing and the use, do not have hazardous and noxious substances to discharge, can not work the mischief environment or human body, so tackiness agent of the present invention is a kind of tackiness agent of environment-friendly type.
The emulsion high-molecular copolymer that the present invention adopts has good thermotolerance and molecular chain has intrinsic toughening mechanism, the bad phenomenon such as migration, infiltration and volatilization of having avoided additional plasticizer to produce, make tackiness agent have characteristics such as stronger resistance to oxidation, anti-ozone, fast light, heat-resisting and UV resistant, so tackiness agent of the present invention is a heat resistant adhesive
Tackiness agent of the present invention its solidify and use in can not cause cracked that the glass ball steeps: it is that the emulsion high-molecular copolymer of dispersion medium is all to contain the linear polymeric material in the cohesive material to some extent and have internal plasticization mechanism with water that the present invention has adopted, its minimum drying and forming-film temperature is lower than 10 ℃, its glass transition temp Tg only is-3 ℃～10 ℃ after this adhesive curing, that is to say, in top temperature (50 ℃～130 ℃) scope that the closing condition temperature (10 ℃～35 ℃) and the electricity-saving lamp energising of the solidification value (100 ℃～150 ℃) of energy-saving bulb chewing-gum and electricity-saving lamp are used, the bubble chewing-gum is in the plastic zone of material all the time, can not produce destructive racking stress to the bigger glass ball bulb of thermal expansivity.
Tackiness agent of the present invention its solidify and use in can not produce glass ball bubble cracked Another reason be to have adopted the granularity and the filling ratio of suitable mineral filler and Synergist S-421 95, the best.Hang down the adding of thermal expansion ratio filler, greatly reduce the thermal expansion ratio of bulb glue, the thermal stresses that the bubble chewing-gum is produced under heating status can not cause the cracked of glass ball bubble port.
Embodiment
Further describe the present invention by the following examples, it should be understood that these embodiment only are used for the purpose of illustration, never limit protection scope of the present invention.
Embodiment 1
1. the preparation of tackiness agent
In 250 liter XJII type planetary stirring machines (manufacturing of highland city three river chemicals), TR-217 styrene-acrylic emulsion (the Fujian Province's Yong'an City that adds 50kg earlier, Fu Wei Fine Chemical Co., Ltd produces), stir and add 0.5kg titanium dioxide dry powder after 10 minutes according to the order of sequence, 0.15kg antioxidant DOD, 0.10kg Sodium Benzoate and 0.3kg silane coupling agent, restir 10 minutes, treat that mixing of materials is evenly constantly adding 600 orders～800 order wollastonite powder 100kg under the condition of stirring in the back in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste thick liquid, reach 2～10Pas with rotational viscosimeter test viscosity, can stop to stir and discharging and packing.
2. the performance of tackiness agent and application test
The tackiness agent that above method is made is coated on respectively in the groove of 100 double-H groove welds or three U type energy-saving lamp holders and is used to glued joint glass ball bulb and lamp cap plastic parts, and the Amount of spread of each lamp holder is 2g～3g.The bubble chewing-gum is completely solidified after the baking in following 40 minutes of 120 ℃ of temperature.
After testing: Joint strength 〉=5MPa (glass-PBT); Light fixture does not occur behind 200 hours thermal ageings and 20 alternating hot and colds that the ball bull pine moves, breaks, obscission under 130 ℃ of conditions.
Detect through Hong Kong SGS company, this glue meets the requirement of European Union relevant green technology standard aspect.
Embodiment 2
1. the preparation of tackiness agent
TR-217 styrene-acrylic emulsion (the Fujian Province's Yong'an City that in 250 liter XJII type planetary stirring machines (manufacturing of highland city three river chemicals), adds 50kg earlier, Fu Wei Fine Chemical Co., Ltd produces), stir and add 0.5kg titanium dioxide dry powder after 10 minutes according to the order of sequence, 0.15kg antioxidant DOD, 0.025kg Sodium Benzoate and 0.05kg silane coupling agent, restir 10 minutes, treat that mixing of materials is evenly constantly adding 50 orders～1200 order silicon powder 15kg under the condition of stirring in the back in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste thick liquid, reach 0.2～2Pas with rotational viscosimeter test viscosity, can stop to stir and discharging and packing;
2. the performance of tackiness agent and application test
The tackiness agent that above method is made is coated on respectively in the groove of 100 double-H groove welds or three U type energy-saving lamp holders and is used to glued joint glass ball bulb and lamp cap plastic parts, and the Amount of spread of each lamp holder is 2g～3g.The bubble chewing-gum is completely solidified after the baking in following 40 minutes of 120 ℃ of temperature.
After testing: Joint strength 〉=5MPa (glass-PBT); Light fixture does not occur behind 200 hours thermal ageings and 20 alternating hot and colds that the ball bull pine moves, breaks, obscission under 130 ℃ of conditions.
Detect through Hong Kong SGS company, this glue meets the requirement of European Union relevant green technology standard aspect.
Embodiment 3
1. the preparation of tackiness agent
In 250 liter XJII type planetary stirring machines (manufacturing of highland city three river chemicals), the FA120 elasticity pure-acrylic emulsion (production of Jiangsu Province three lignify worker limited-liability company) that adds 50kg earlier, then add the 5kg tap water, stir and add 15kg titanium dioxide dry powder after 10 minutes according to the order of sequence, 0.5kg antioxidant 264,0.5kg sodium pentachlorophenate and 1.0kg silane coupling agent, behind the restir 10 minutes, treat that mixing of materials is evenly constantly adding granularity 600 order silica powder 150kg under the condition of stirring in the back in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste thick liquid, reach 5～10Pas with rotational viscosimeter test viscosity, can stop to stir and discharging and packing;
2. the performance of tackiness agent and application test
The energy-saving bulb chewing-gum that above method is made is coated on respectively in the groove of 100 double-H groove welds or three U type energy-saving lamp holders and is used to glued joint glass ball bulb and lamp cap plastic parts, and the Amount of spread of each lamp holder is 2g～3g.The bubble chewing-gum is completely solidified after the baking in following 40 minutes of 120 ℃～130 ℃ temperature.Joint strength 〉=5MPa (glass-PBT); Light fixture does not occur after the thermal ageing through 200 hours that the ball bull pine moves, breaks, obscission under 130 ℃ of conditions.
Or the energy-saving bulb chewing-gum that above method is made is coated on respectively in the groove of 100 double-H groove welds or three U type energy-saving lamp holders and is used to glued joint glass ball bulb and lamp cap plastic parts, the Amount of spread of each lamp holder is 2g～3g.The bubble chewing-gum relative humidity less than 60%, envrionment temperature be to hang one day under 20 ℃～30 ℃ conditions after completely solidified.Joint strength 〉=3MPa (glass-PBT); Light fixture does not occur behind 200 hours thermal ageings and 20 alternating hot and colds that the ball bull pine moves, breaks, obscission under 130 ℃ of conditions.
Detect through Hong Kong SGS company, this glue meets the requirement of European Union relevant green technology standard aspect.
Embodiment 4
1. the preparation of tackiness agent
In 250 liter XJII type planetary stirring machines (manufacturing of highland city three river chemicals), the FA120 elasticity pure-acrylic emulsion (production of Jiangsu Province three lignify worker limited-liability company) that adds 50kg earlier, then add the 2kg tap water, stir and add 0.5kg titanium dioxide dry powder after 10 minutes according to the order of sequence, 0.15kg antioxidant 264,0.05kg sodium pentachlorophenate and 0.4kg silane coupling agent, behind the restir 10 minutes, treat that mixing of materials is evenly constantly adding granularity 600 order silica powder 60kg under the condition of stirring in the back in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste thick liquid, reach 0.2～2Pas with rotational viscosimeter test viscosity, can stop to stir and discharging and packing;
2. the performance of tackiness agent and application test
The energy-saving bulb chewing-gum that above method is made is coated on respectively in the groove of 100 double-H groove welds or three U type energy-saving lamp holders and is used to glued joint glass ball bulb and lamp cap plastic parts, and the Amount of spread of each lamp holder is 2g～3g.The bubble chewing-gum is completely solidified after the baking in following 40 minutes of 120 ℃～130 ℃ temperature.Joint strength 〉=5MPa (glass-PBT); Light fixture does not occur after the thermal ageing through 200 hours that the ball bull pine moves, breaks, obscission under 130 ℃ of conditions.
Or the energy-saving bulb chewing-gum that above method is made is coated on respectively in the groove of 100 double-H groove welds or three U type energy-saving lamp holders and is used to glued joint glass ball bulb and lamp cap plastic parts, the Amount of spread of each lamp holder is 2g～3g.The bubble chewing-gum relative humidity less than 60%, envrionment temperature be to hang one day under 20 ℃～30 ℃ conditions after completely solidified.Joint strength 〉=3MPa (glass-PBT); Light fixture does not occur behind 200 hours thermal ageings and 20 alternating hot and colds that the ball bull pine moves, breaks, obscission under 130 ℃ of conditions.
Detect through Hong Kong SGS company, this glue meet European Union relevant green technology standard side and requirement.Embodiment 5
1. the preparation of tackiness agent
In 500 liter XJII type planetary stirring machines (manufacturing of Rugao City three river chemicals), LD-8308 silicon third copolymer emulsion (production of Jiangsu Province Li Wenjia chemical industry company limited) that adds 100kg earlier, then add 10kg water, start stirring, add the 1kg granularity after 10 minutes according to the order of sequence less than 250 purpose titanium dioxide dry powder, 0.30kg antioxidant DOD, 0.10kg the KH-550 silane coupling agent of sodium pentachlorophenate and 0.5kg, restir 10 minutes, treat that add granularity after mixing of materials evenly under continuous condition of stirring is 600 purpose silicon powder 200kg in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste thick liquid, when reaching 5～10Pas, can stop to stir and discharging and packing with rotational viscosimeter test viscosity.
2. the performance of tackiness agent and application test
The energy-saving bulb chewing-gum that above method is made is coated on respectively in the groove of 100 double-H groove welds or three U type energy-saving lamp holders and is used to glued joint glass ball bulb and lamp cap plastic parts, and the Amount of spread of each lamp holder is 2g～3g.The bubble chewing-gum is completely solidified after the baking in following 40 minutes of 120 ℃ of temperature.Joint strength 〉=5MPa (glass-PBT); Light fixture does not occur behind 200 hours thermal ageings and 20 alternating hot and colds that the ball bull pine moves, breaks, obscission under 130 ℃ of conditions.
Detect through Hong Kong SGS company, this glue meets the requirement of European Union relevant green technology standard aspect.
Embodiment 6
1. the preparation of tackiness agent
In 500 liter XJII type planetary stirring machines (manufacturing of Rugao City three river chemicals), LD-8308 silicon third copolymer emulsion (production of Jiangsu Province Li Wenjia chemical industry company limited) that adds 100kg earlier, then add 10kg water, start stirring, add the 1kg granularity after 10 minutes according to the order of sequence less than 250 purpose titanium dioxide dry powder, 0.30kg antioxidant DOD, 0.10kg the KH-550 silane coupling agent of sodium pentachlorophenate and 0.5kg, restir 10 minutes, treat that add granularity after mixing of materials evenly under continuous condition of stirring is 600 purpose silicon powder 60kg in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste thick liquid, when reaching 0.2～2Pas, can stop to stir and discharging and packing with rotational viscosimeter test viscosity.
2. the performance of tackiness agent and application test
The energy-saving bulb chewing-gum that above method is made is coated on respectively in the groove of 100 double-H groove welds or three U type energy-saving lamp holders and is used to glued joint glass ball bulb and lamp cap plastic parts, and the Amount of spread of each lamp holder is 2g～3g.The bubble chewing-gum is completely solidified after the baking in following 40 minutes of 120 ℃ of temperature.Joint strength 〉=5MPa (glass-PBT); Light fixture does not occur behind 200 hours thermal ageings and 20 alternating hot and colds that the ball bull pine moves, breaks, obscission under 130 ℃ of conditions.
Detect through Hong Kong SGS company, this glue meets the requirement of European Union relevant green technology standard aspect.
Claims (9)
1. tackiness agent that glueds joint between electricity-saving lamp glass ball bulb and the lamp cap plastic parts, mainly form: 100 parts of latexes that with water are dispersion medium by the component of following weight part, 30～300 parts of high temperature resistant inorganic fillers, 1～20 part in whitening agent, 0.1～10 part in anti-aging agent, 0.05～10 part of anti-mildew agent, 0～30 part in 0.1～10 part of silane coupling agent and water; Described is that the latex of dispersion medium is selected from benzene emulsion, organosilicon crylic acid latex or pure-acrylic emulsion with water; Described high temperature resistant inorganic filler is selected from silicon powder, wollastonite powder, Feldspar Powder, talcum powder, silica powder, tripoli, aluminum oxide powder, light calcium carbonate powder, heavy calcium carbonate, zinc sulfide white, ground barium sulfate, mica powder, potter's clay powder or kaolin powder; Described whitening agent is a titanium dioxide; Described anti-aging agent is an xenol; Described anti-mildew agent is selected from sodium pentachlorophenate, magnesiumcarbonate or Sodium Benzoate; Described silane coupling agent is a γ-An Bingjisanyiyangjiguiwan.
2. according to the tackiness agent of claim 1, it is characterized in that, divided by water is outside the latex of dispersion medium, the weight part of all the other each components is: 100～250 parts of high temperature resistant inorganic fillers, 1～10 part in whitening agent, 0.1～2 part in anti-aging agent, 0.05～5 part of anti-mildew agent, 0.1～2 part of silane coupling agent, 0～20 part in water.
3. according to the tackiness agent of claim 2, it is characterized in that the weight part of each component is:
100～200 parts of high temperature resistant inorganic fillers, 1～2 part in whitening agent, 0.1～1 part in anti-aging agent, 0.05～1 part of anti-mildew agent, 0.1～1 part of silane coupling agent, 0～10 part in water.
4. according to the tackiness agent of claim 1, it is characterized in that:
Described benzene emulsion, its solid content are 30%～65%; Viscosity is 400mPas～2000mPas; Second-order transition temperature Tg is 15 ℃～30 ℃; Residual monomer quantity≤1%;
Described pure-acrylic emulsion, its solid content are 30%～60%; Viscosity is 300mPas～2000mPas; Second-order transition temperature Tg is-30 ℃～30 ℃; The pH value is 7.5～10, residual monomer quantity≤1%;
Described organosilicon crylic acid latex, its solid content are 30%～60%; The pH value is 7.5～10; Viscosity is 200mPas～2000mPas; Second-order transition temperature Tg is 10 ℃～30 ℃; Residual monomer quantity≤1%;
Described silicon powder, its SiO
2Content 〉=90%; The content of ferric oxide≤1%; Fineness is 50 orders～1200 orders; Moisture content≤1%;
Described wollastonite powder, its SiO
2Content 〉=40%; Calcium oxide content is 〉=40%; Fineness is 200 orders～1200 orders; Moisture content≤1%;
Described Feldspar Powder, its SiO
2Content 〉=70%; The content of aluminium sesquioxide 〉=10%; Calcium oxide content is≤1.4%; The content of ferric oxide≤1.4%; Fineness is more than 50 orders;
Described talcum powder, its SiO
2Content 〉=55%; Content of magnesia 〉=27%; Fineness 45 μ m sieve percent of pass 〉=90%; Moisture content≤1%;
Described silica powder, its SiO
2Content 〉=90%; The content of ferric oxide≤1%; Fineness is 50 orders～1200 orders; Moisture content≤1%;
Described tripoli, aluminum oxide powder, light calcium carbonate powder, heavy calcium carbonate, zinc sulfide white, ground barium sulfate, mica powder, potter's clay powder or kaolin powder, its fineness are 50 orders～1200 orders, moisture content≤1.0%.
5. according to the tackiness agent of claim 4, it is characterized in that: described benzene emulsion, its solid content are 45%～55%; Viscosity is 500mPas～1000mPas; Second-order transition temperature Tg is 20 ℃～25 ℃;
Described pure-acrylic emulsion, its solid content are 45%～55%; Viscosity is 500mPas～1500mPas; Second-order transition temperature Tg is 10 ℃～20 ℃;
Described organosilicon crylic acid latex, its solid content 45%～55%; The pH value is 8～9.5, and viscosity is 300mPas～900mPas; 12 ℃～18 ℃ of second-order transition temperature Tg; Residual monomer quantity≤1%.
6. according to the tackiness agent of claim 4, it is characterized in that:
Described silicon powder, its SiO
2Content 〉=99%, the content of ferric oxide≤0.1%;
Described wollastonite powder, its SiO
2Content 〉=75%; Calcium oxide content 〉=45%; Moisture content≤0.5%;
Described Feldspar Powder, its SiO
2Content 〉=75%; The content of aluminium sesquioxide 〉=11%;
Described talcum powder, its SiO
2Content 〉=58%; Content of magnesia 〉=29%;
Described silica powder, its SiO
2Content 〉=99%; The content of ferric oxide≤O.1%.
7. according to the tackiness agent of claim 1, it is characterized in that: described whitening agent titanium dioxide, content of titanium dioxide 〉=94%, 105 ℃ fugitive constituent≤0.5% wherein, fineness 45 μ m, screenings≤0.3%, the content of ferric oxide≤1.4%;
Described anti-aging agent xenol, its fusing point 〉=275 ℃;
First fusing point 〉=175 of described anti-mildew agent sodium pentachlorophenate ℃, insolubles content in the water≤1%;
The purity of described silane coupling agent γ-An Bingjisanyiyangjiguiwan 〉=90%.
8. method for preparing the described tackiness agent of claim 1 comprises:
(1) take by weighing each component by following weight part: with water 100 parts of the latexes of dispersion medium, 30～300 parts of high temperature resistant inorganic fillers, 1～20 part in whitening agent, 0.1～10 part in anti-aging agent, 0.05～10 part of anti-mildew agent, 0～30 part in 0.1～10 part of silane coupling agent and water;
(2) at first will be that the latex of dispersion medium joins and stirs after 5-20 minute in the stirring tank with water, add whitening agent, anti-aging agent, anti-mildew agent and silane coupling agent successively, restir 5-20 minute, treat that mixing of materials is evenly constantly adding mineral filler under the condition of stirring in the back in batches, after all material added, continuously stirring was 2～3 hours again, treat that material is the paste thick liquid, viscosity reaches 1～10Pas, stops to stir and discharging, promptly.
9. any one tackiness agent of claim 1-7 is in the application of glueing joint electricity-saving lamp glass ball bulb and lamp cap plastic parts, comprise: any one tackiness agent of claim 1-7 is coated in the groove of energy-saving lamp holder and is used to glued joint glass ball bulb and lamp cap plastic parts, the Amount of spread of each lamp holder is 2g～3g, the bubble chewing-gum through completely solidified after the baking of following 40 minutes of 120 ℃ of temperature or relative humidity less than 60%, envrionment temperature be to hang one day under 20 ℃～30 ℃ conditions after completely solidified.
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| CN2007101452148A CN101108955B (en) | 2007-08-17 | 2007-08-17 | Adhesion agent for bonding energy conserving lamp glass ball bulb and lamp cap plastic member and method of manufacturing the same |
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| CN2007101452148A CN101108955B (en) | 2007-08-17 | 2007-08-17 | Adhesion agent for bonding energy conserving lamp glass ball bulb and lamp cap plastic member and method of manufacturing the same |
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| CN101108955A CN101108955A (en) | 2008-01-23 |
| CN101108955B true CN101108955B (en) | 2010-04-07 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273682A (en) * | 2015-11-27 | 2016-01-27 | 绵阳惠利电子材料有限公司 | Anti-explosion addition type silica gel composition for LED glass bulb lamp |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408852A (en) * | 2011-10-12 | 2012-04-11 | 厦门市金泰祥新科技有限公司 | Multicomponent environment-friendly high temperature resistant adhesive used for energy saving lamp caps |
| CN103939855A (en) * | 2014-03-21 | 2014-07-23 | 浙江晨丰灯头有限公司 | Connection method for glass bulb and lamp cap |
| CN112300750B (en) * | 2020-11-18 | 2021-06-29 | 广州市高士实业有限公司 | Panel lamp glue |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1077210A (en) * | 1992-04-09 | 1993-10-13 | 航空航天工业部南方动力机械公司 | Organic adhesion agent |
| US6300400B1 (en) * | 1997-04-18 | 2001-10-09 | Illinois Tool Works Inc. | Wallboard adhesive |
| CN1322784A (en) * | 2001-06-04 | 2001-11-21 | 广州市海珠区宏泰建筑材料厂 | Stone imitation building paint and its prepn |
| CN1371886A (en) * | 2001-02-23 | 2002-10-02 | 北京四元特种防护技术开发公司 | Electrostatic resistant crushed stone and cobble for building and making method thereof |
| CN1944562A (en) * | 2006-04-17 | 2007-04-11 | 张恩天 | Environment friendly heat resistant adhesive for energy saving lamp holder |
-
2007
- 2007-08-17 CN CN2007101452148A patent/CN101108955B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1077210A (en) * | 1992-04-09 | 1993-10-13 | 航空航天工业部南方动力机械公司 | Organic adhesion agent |
| US6300400B1 (en) * | 1997-04-18 | 2001-10-09 | Illinois Tool Works Inc. | Wallboard adhesive |
| CN1371886A (en) * | 2001-02-23 | 2002-10-02 | 北京四元特种防护技术开发公司 | Electrostatic resistant crushed stone and cobble for building and making method thereof |
| CN1322784A (en) * | 2001-06-04 | 2001-11-21 | 广州市海珠区宏泰建筑材料厂 | Stone imitation building paint and its prepn |
| CN1944562A (en) * | 2006-04-17 | 2007-04-11 | 张恩天 | Environment friendly heat resistant adhesive for energy saving lamp holder |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2004-123943A 2004.04.22 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273682A (en) * | 2015-11-27 | 2016-01-27 | 绵阳惠利电子材料有限公司 | Anti-explosion addition type silica gel composition for LED glass bulb lamp |
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| CN101108955A (en) | 2008-01-23 |
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Application publication date: 20080123 Assignee: Xiamen Jintaixiang New Technology Co.,Ltd. Assignor: Zhang Entian Contract record no.: 2012350000114 Denomination of invention: Adhesion agent for bonding energy conserving lamp glass ball bulb and lamp cap plastic member and method of manufacturing the same Granted publication date: 20100407 License type: Exclusive License Record date: 20121009 |
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