CN100575439C - Environment friendly heat resistant adhesive for energy saving lamp holder - Google Patents
Environment friendly heat resistant adhesive for energy saving lamp holder Download PDFInfo
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- CN100575439C CN100575439C CN200610043621A CN200610043621A CN100575439C CN 100575439 C CN100575439 C CN 100575439C CN 200610043621 A CN200610043621 A CN 200610043621A CN 200610043621 A CN200610043621 A CN 200610043621A CN 100575439 C CN100575439 C CN 100575439C
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- lamp holder
- emulsion
- saving lamp
- tackiness agent
- energy
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- 239000000853 adhesive Substances 0.000 title claims description 9
- 230000001070 adhesive effect Effects 0.000 title claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 48
- 239000000839 emulsion Substances 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002612 dispersion medium Substances 0.000 claims abstract description 17
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000011521 glass Substances 0.000 claims description 14
- 229920003023 plastic Polymers 0.000 claims description 11
- 239000004033 plastic Substances 0.000 claims description 11
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- 238000007334 copolymerization reaction Methods 0.000 claims description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 7
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical compound C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 239000010433 feldspar Substances 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- 239000011863 silicon-based powder Substances 0.000 claims description 5
- 230000002087 whitening effect Effects 0.000 claims description 5
- 239000010456 wollastonite Substances 0.000 claims description 5
- 229910052882 wollastonite Inorganic materials 0.000 claims description 5
- 230000003712 anti-aging effect Effects 0.000 claims description 4
- 239000011256 inorganic filler Substances 0.000 claims description 4
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 4
- 239000012764 mineral filler Substances 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 230000007704 transition Effects 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 239000010458 rotten stone Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 3
- 235000010234 sodium benzoate Nutrition 0.000 claims description 3
- 239000004299 sodium benzoate Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000003292 glue Substances 0.000 abstract description 20
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 238000004880 explosion Methods 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000011160 research Methods 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 description 20
- 239000000463 material Substances 0.000 description 15
- 230000009970 fire resistant effect Effects 0.000 description 10
- 230000032683 aging Effects 0.000 description 5
- 238000007599 discharging Methods 0.000 description 4
- 238000005286 illumination Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000013464 silicone adhesive Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
Abstract
The present invention relates to a kind of tackiness agent, relate in particular to and a kind ofly be the emulsion such as benzene emulsion, Vinyl Acetate Copolymer-vac emulsion and Vinyl Acetate Copolymer of dispersion medium in order to water and add multiple filler and produced high temperature resistant, the environment-friendly type energy-saving lamp lamp holder of additive glueds joint the tackiness agent that uses.The present invention adopts up-to-date theory and on the basis of research practice for many years, and it is not only high temperature resistant but also can prevent effectively that the energy-saving lamp holder glue of explosion from appearring in fluorescent tube to develop a series of not only environmental protection.This glue has following characteristics: tackiness agent is dispersion medium with water.Starting material are easy to get, manufacturing process simple, use technology easy, and cost is very low.Be but that heating curable is placed under the room temperature again and carried out cold-curing.This glue is emitted in curing and use unharmful substance simultaneously, can fully satisfy environment friendly and pollution-free requirement.
Description
Technical field
The present invention relates to a kind of tackiness agent, relating in particular to a kind of is that produced high temperature resistant, the environment-friendly type energy-saving lamp lamp holder of the emulsion of dispersion medium, multiple filler and additive glueds joint the tackiness agent that uses in order to water.
Background technology
Along with the develop rapidly of human society and science and technology, energy-conservationly more and more be subjected to people and extensively pay attention to, electricity-saving lamp arises at the historic moment.At present, the world's annual production electricity-saving lamp is about more than 1,000,000,000, and its main place of production is in China.Connection between energy-saving lamp holder and the fluorescent tube is mainly gluedd joint by lamp holder glue.In recent years, the lamp holder glue that each electricity-saving lamp manufacturer of China adopts mainly contains that chloroprene rubber-toluene solution adds the inorganic filler type tackiness agent, polyvinyl acetate emulsion adds inorganic filler type tackiness agent, the filled type tackiness agent of heat-reactive phenolic resin, the filled type tackiness agent of thermosetting epoxy resin and silicone adhesive etc., have that environmental pollution is big, resistance toheat is poor, be prone to the problem of aspects such as fluorescent tube explosion in production and the use, can not satisfy far away country to the quality of environmental protection, electricity-saving lamp and work-ing life the aspect requirement.
Summary of the invention
Order of the present invention be solve current existing lamp holder glue technical feature can not satisfy country to the quality of environmental protection, electricity-saving lamp and work-ing life the aspect the common problem of existence of requirement.
The present invention adopts up-to-date theory and on the basis of research practice for many years, and it is not only high temperature resistant but also can prevent effectively that the energy-saving lamp holder glue of explosion from appearring in fluorescent tube to develop a series of not only environmental protection.This glue has following characteristics: tackiness agent is dispersion medium with water.Starting material are easy to get, manufacturing process simple, use technology easy, and cost is very low.Be but that heating curable is placed under the room temperature again and carried out cold-curing.This glue is emitted in curing and use unharmful substance simultaneously, can fully satisfy environment friendly and pollution-free requirement.Non-scale, not bulge after this adhesive curing can not cause the fluorescent tube explosion.This glue Joint strength height, can for a long time anti-160 ℃ of high temperature and thermal ageing, 250 ℃ under do not decompose.The energy-conservation lamp holder glue of present several kinds has formed batch process, and the man factory of number is used for the production of electricity-saving lamp in the supplier, is subjected to extensive favorable comment.
The technical problem to be solved in the present invention realizes (containing the right that will advocate) by following technological approaches:
It is a kind of white paste adhesive of being made by additives such as latex 100 mass parts that are dispersion medium, high temperature resistant inorganic filler 50～300 mass parts, whitening agent 0～20 mass parts, anti-aging agent 0～10 mass parts, anti-mildew agent 0～10 mass parts, 0～20 part of drying aid and water with water that a kind of single component is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination (hereinafter to be referred as lamp holder glue).
Wherein, adoptable is that the latex of dispersion medium is mainly benzene emulsion, Vinyl Acetate Copolymer-ethylene copolymerization emulsions (being the VAE emulsion) and Vinyl Acetate Copolymer (PVAc) emulsion with water.
Adoptable is the benzene emulsion of dispersion medium with water, and its solid content is 40%～65%, is preferably 45%～55%; Viscosity is 400mPas～1500mPas, is preferably 500mPas～1000mPas; Second-order transition temperature Tg is 5～25 ℃, is preferably 5～15 ℃; Residual monomer quantity≤1%.
Adoptable is the VAE emulsion of dispersion medium with water, and its solid content is 45%～60%, is preferably 50%～55%; Viscosity is 400mPas～1500mPas, is preferably 500mPas～1000mPas; Second-order transition temperature Tg is-5～15 ℃, is preferably-3～7 ℃; Residual monomer quantity≤1%.
Adoptable is the PVAc emulsion of dispersion medium with water, and its solid content is 40%～65%; Viscosity is 4.0～7.0Pas, is preferably 5Pas～6Pas; Ash content≤3%; Residual VAc quantity≤1%.
Adoptable mineral filler mainly contains silicon powder, wollastonite powder, Feldspar Powder, talcum powder, silica powder, tripoli, aluminum oxide powder and lightweight, heavy calcium carbonate.
In the silicon powder, SiO
2Content 〉=90%, be preferably 〉=95%; Fineness should reach 200 orders～1000 orders; Moisture content≤1%.
SiO in the wollastonite powder
2Content 〉=40%, be preferably 〉=75%; Calcium oxide content is 〉=40%, be preferably 〉=45%; Fineness should reach 200 orders～1000 orders; Moisture content≤1% is preferably moisture content≤0.5%.
SiO in the Feldspar Powder
2Content 〉=70%, be preferably 〉=75%; The content of aluminium sesquioxide 〉=10%, be preferably 〉=11%; Calcium oxide content is≤1.4%; The content of ferric oxide≤1.4%; Fineness reaches more than 200 orders;
Talcum powder should be pure white or silvery white; SiO
2Content 〉=55%, be preferably 〉=58%; Content of magnesia 〉=27%, be preferably 〉=29%; Fineness 45 μ m sieve percent of pass 〉=90%; Moisture content≤1%.
Other adoptable filler silica powders, tripoli, aluminum oxide powder and lightweight, heavy calcium carbonate, fineness should reach 200 orders～1000 orders, moisture content≤1.0%
Adoptable whitening agent is a titanium dioxide, content of titanium dioxide 〉=94%, 105 ℃ fugitive constituent≤0.5% wherein, fineness 45 μ m screenings≤0.3%, the content of ferric oxide≤1.4%; Insolubles in the water≤0.5%.
Adoptable anti-aging agent is an antioxidant DOD, i.e. xenol, fusing point 〉=275 ℃.
Anti-mildew agent is sodium pentachlorophenate or Sodium Benzoate, first fusing point 〉=175 of sodium pentachlorophenate ℃, insolubles content in the water≤1%.
Drying aid is terra alba (CaSO
42H
2O), granularity≤100 orders.
Formula optimization is: latex (be mainly benzene emulsion, Vinyl Acetate Copolymer-ethylene copolymerization emulsions is VAE emulsion and Vinyl Acetate Copolymer (PVAc) emulsion) 100 mass parts that with water are dispersion medium; Mineral filler (being mainly silicon powder, wollastonite powder, Feldspar Powder and talcum powder) 100～250 mass parts, whitening agent titanium dioxide 1～5 mass parts, antioxidant DOD are that 0.1～0.5 mass parts, anti-mildew agent sodium pentachlorophenate are that 0.05～0.10 mass parts, drying aid terra alba 0.1～2.0 mass parts, water are 0～20 mass parts.
The used raw material of the present invention all can be bought from market and obtain, and its specification is a commercial grade.
Dominant mechanism of the present invention
1. why the present invention is referred to as environmental-protection type adhesive, its major cause is because to have adopted be that the copolymer emulsion of dispersion medium is a cohesive material with water, only there is small amount of moisture to disengage in its curing and the use, discharge without any hazardous and noxious substances, can not cause any harm, so be referred to as environmental-protection type adhesive to environment or human body
2. why to be referred to as its dominant mechanism of heat resistant adhesive be that the polymer copolymerization emulsions that adopts has good thermotolerance in the present invention, molecular chain has internal plasticization mechanism, the characteristics such as migration, infiltration and volatilization that simple plasticizer produces have been avoided adding, make tackiness agent have the characteristic of stronger oxytolerant, ozone, light, heat and ultraviolet ray etc., high temperature resistantly reach 250 ℃ and do not decompose.
3. why fire resistant environment-friendly lamp holder tackiness agent of the present invention can not produce the cracked of glass fluorescent tube in its curing and use, its dominant mechanism is that the present invention adopted is that the Vinyl Acetate Copolymer-ethylene copolymerization emulsions or the benzene emulsion of dispersion medium is cohesive material with water, all introduced intramolecularly plasticising mechanism to some extent in the polymer copolymerization emulsions that adopts, its minimum drying and forming-film temperature only is-3～10 ℃, its glass transition temp Tg only is-3～7 ℃ after this adhesive curing, that is to say, in top temperature (50～200 ℃) scope that the closing condition temperature (10～35 ℃) and the electricity-saving lamp energising of the solidification value (100 ℃) of energy-saving lamp holder glue and electricity-saving lamp are used, lamp holder glue is in the elastic region of material all the time, can not produce destructive racking stress to the bigger glass lamp of thermal expansivity.
4. fire resistant environment-friendly lamp holder tackiness agent of the present invention why its solidify and use in can not produce the glass fluorescent tube cracked be granularity and the filling ratio that has adopted suitable filler and Synergist S-421 95, the best.
Embodiment
[embodiment 1]
1.JTX-658 the type energy-saving lamp holder preparation of fire resistant environment-friendly tackiness agent
Under room temperature, in planetary pair of oar stirring tank of 450 liters, 707-Vinyl Acetate Copolymer-ethylene copolymer the breast that adds 100kg earlier, then add 10kg water, start stirring, add the 1kg granularity after 10 minutes according to the order of sequence less than 250 purpose titanium dioxide dry powder, the 300g antioxidant DOD, 100g sodium pentachlorophenate and 0.5kg terra alba, restir 30 minutes, treat that the even back of mixing of materials is 800 purpose silicon powder 220kg do not stop to add granularity under the condition of stirring in batches, after all material added, continuously stirring was 2～3 hours again, treats that material is a white paste thick liquid, when reaching 60～170Pas, can stop to stir and discharging and packing with rotational viscosimeter test viscosity.
2.JTX-658 the type energy-saving lamp holder performance test of fire resistant environment-friendly tackiness agent
The energy-saving lamp holder glue that above method is made is coated on respectively and is used for fixing fluorescent tube and following seat board in 100 double-H groove welds and the three U type energy-saving lamp holders, and the Amount of spread of every lamp holder is 4～8g.Lamp holder glue is completely solidified after the baking in following 40 minutes of 100～120 ℃ of temperature.Joint strength 〉=5MPa (glass-PET); Fluorescent tube does not have cracked generation; Light fixture is under 160 ℃ of conditions, and illumination and the thermal ageing of switching on continuously through 8000 hours fluorescent tube do not occur and become flexible, break and the fluorescent tube obscission.
Detect through Hong Kong SGS company, this glue meets the requirement of European Union relevant electricity-saving lamp tackiness agent green technology standard aspect fully.
[embodiment 2]
1.JTX-678 the type energy-saving lamp holder preparation of fire resistant environment-friendly tackiness agent
In the planetary three oar stirring tanks of 250 liters, the TR-217 phenylpropyl alcohol copolymerization breast that adds 100kg earlier, stir and add 0.5kg titanium dioxide dry powder, 200g antioxidant DOD, 100g Sodium Benzoate and 0.5kg terra alba after 10 minutes according to the order of sequence, restir 10 minutes, treat do not stopping to add 800 order wollastonite powder 240kg under the condition of stirring after mixing of materials evenly in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste thick liquid, reach 60～170Pas with rotational viscosimeter test viscosity, can stop to stir and discharging and packing.
2.JTX-678 the type energy-saving lamp holder performance test of fire resistant environment-friendly tackiness agent
The energy-saving lamp holder glue that above method is made is coated on respectively and is used for fixing fluorescent tube and following seat board in 100 double-H groove welds and the three U type energy-saving lamp holders, and the Amount of spread of every lamp holder is 5～8g.Lamp holder after following 40 minutes of 100～120 ℃ of temperature are solidified, completely solidified.Joint strength 〉=5MPa (glass-PET); Fluorescent tube does not have cracked generation; Light fixture is under 160 ℃ of conditions, and illumination and the thermal ageing of switching on continuously through 8000 hours fluorescent tube do not occur and break, become flexible and the fluorescent tube obscission
[embodiment 3]
1.JTX-688 the type energy-saving lamp holder preparation of fire resistant environment-friendly tackiness agent
In the planetary three oar stirring tanks of 250 liters, the polyvinyl acetate emulsion that adds 100kg earlier, then add the 10kg tap water, stir and add 0.5kg titanium dioxide dry powder after 10 minutes according to the order of sequence, the 200g antioxidant 264,100g sodium pentachlorophenate and 0.5kg terra alba, behind the restir 10 minutes, treat do not stopping to add the 280kg talcum powder under the condition of stirring after mixing of materials evenly in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste, thick liquid, reach 60～170Pas with rotational viscosimeter test viscosity, can stop to stir and discharging and packing.
2.JTX-688 the type energy-saving lamp holder performance test of fire resistant environment-friendly tackiness agent
The energy-saving lamp holder glue that above method is made is coated on respectively and is used for fixing fluorescent tube and following seat board in 100 double-H groove welds and the three U type energy-saving lamp holders, and the Amount of spread of every lamp holder is 5～8g.Lamp holder after following 40 minutes of 100～120 ℃ of temperature are solidified, completely solidified.Joint strength 〉=5MPa (glass-PET); Fluorescent tube does not have cracked generation; Light fixture is under 160 ℃ of conditions, and illumination and the thermal ageing of switching on continuously through 8000 hours fluorescent tube do not occur and break, become flexible and the fluorescent tube obscission.
[embodiment 4]
1.JTX-698 the type energy-saving lamp holder preparation of fire resistant environment-friendly tackiness agent
In the planetary three oar stirring tanks of 250 liters, Vinyl Acetate Copolymer-the vac emulsion that adds 100kg earlier, then add the 10kg tap water, stir and add 0.5kg titanium dioxide dry powder after 10 minutes according to the order of sequence, the 200g antioxidant 264,100g sodium pentachlorophenate and 0.5kg terra alba, behind the restir 10 minutes, treat do not stopping to add the 250kg Feldspar Powder under the condition of stirring after mixing of materials evenly in batches, after all material adds, continuously stirring is 2～3 hours again, treat that material is a white paste thick liquid, reach 60～170Pas with rotational viscosimeter test viscosity, can stop to stir and discharging and packing.
2.JTX-698 the type energy-saving lamp holder performance test of fire resistant environment-friendly tackiness agent
The energy-saving lamp holder glue that above method is made is coated on respectively and is used for fixing fluorescent tube and following seat board in 100 double-H groove welds and the three U type energy-saving lamp holders, and the Amount of spread of every lamp holder is 5～8g.Lamp holder after following 40 minutes of 100～120 ℃ of temperature are solidified, completely solidified.Joint strength 〉=5MPa (glass-PET); Fluorescent tube does not have cracked generation; Light fixture is under 160 ℃ of conditions, and illumination and the thermal ageing of switching on continuously through 8000 hours fluorescent tube do not occur and break, become flexible and the fluorescent tube obscission.
Claims (10)
1, a kind of single component is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, be by latex 100 mass parts that are dispersion medium with water, the following a kind of white paste adhesive made from, 50～300 parts of high temperature resistant inorganic fillers, 0～20 part in whitening agent, 0～10 part in anti-aging agent, 0～10 part of anti-mildew agent, 0～20 part of drying aid and water, described is that the latex of dispersion medium is benzene emulsion or Vinyl Acetate Copolymer-ethylene copolymerization emulsions (being the VAE emulsion) or Vinyl Acetate Copolymer (PVAc) emulsion with water.
2, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, and what it is characterized in that adopting is the benzene emulsion of dispersion medium with water, and its solid content is 40%～65%; Viscosity is 400mPas～1500mPas; Second-order transition temperature Tg is 5～25 ℃; Residual monomer quantity≤1%.
3, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, what it is characterized in that described employing is the Vinyl Acetate Copolymer-ethylene copolymerization emulsions (VAE emulsion) of dispersion medium with water, and its solid content is 45%～60%; Viscosity is 400mPas～1500mPas; Second-order transition temperature Tg is-5～15 ℃; Residual monomer quantity≤1%.
4, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, what it is characterized in that adopting is Vinyl Acetate Copolymer (PVAc) emulsion of dispersion medium with water, and its solid content is 40%～65%; Viscosity is 4.0～7.0Pas, ash content≤3%; Residual VAc quantity≤1%.
5, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, it is characterized in that the mineral filler of adopting is silicon powder or wollastonite powder, Feldspar Powder or talcum powder or silica powder or tripoli or aluminum oxide powder or lightweight, heavy calcium carbonate, the filler fineness is the 50-1200 order, its consumption is 100 mass parts with respect to copolymer emulsion, and the amount ranges of mineral filler is 50～300 mass parts.
6, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, it is characterized in that the whitening agent that adopts is a titanium dioxide, and consumption is 100 parts with respect to emulsion, and titanium dioxide is 0～20 part.
7, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, it is characterized in that the anti-aging agent that adopts is an antioxidant DOD, consumption is 100 parts with respect to emulsion, and antioxidant DOD is 0～10 part.
8, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, it is characterized in that the anti-mildew agent that adopts is an xenol, consumption is 100 parts with respect to emulsion, and xenol is 0～10 mass parts.
9, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, it is characterized in that the anti-mildew agent that adopts is sodium pentachlorophenate or Sodium Benzoate, consumption is that 100 parts of mould inhibitors are 0～10 part with respect to emulsion.
10, a kind of single component according to claim 1 is used for cementitious tackiness agent between energy-saving lamp holder lower cover plastic component and glass lamp termination, it is characterized in that the drying aid that adopts is a terra alba, and consumption is 100 parts with respect to emulsion, and drying aid is 0～20 part.
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| CN200610043621A CN100575439C (en) | 2006-04-17 | 2006-04-17 | Environment friendly heat resistant adhesive for energy saving lamp holder |
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| Application Number | Priority Date | Filing Date | Title |
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| CN200610043621A CN100575439C (en) | 2006-04-17 | 2006-04-17 | Environment friendly heat resistant adhesive for energy saving lamp holder |
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| CN1944562A CN1944562A (en) | 2007-04-11 |
| CN100575439C true CN100575439C (en) | 2009-12-30 |
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Families Citing this family (17)
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| CN101108955B (en) * | 2007-08-17 | 2010-04-07 | 张恩天 | Adhesion agent for bonding energy conserving lamp glass ball bulb and lamp cap plastic member and method of manufacturing the same |
| CN101979453B (en) * | 2010-11-17 | 2012-02-15 | 湖南神力铃胶粘剂制造有限公司 | Display shell spreading-ball sealing glue and preparation method thereof |
| CN102433089B (en) * | 2011-09-13 | 2013-09-18 | 杭州电子科技大学 | Preparation method for adhesive for energy-saving lamp |
| CN102352203B (en) * | 2011-09-13 | 2012-11-07 | 杭州电子科技大学 | Preparation method of novel adhesive for energy-saving lamps |
| CN102352204B (en) * | 2011-09-13 | 2012-11-07 | 杭州电子科技大学 | Preparation method for bonding material for energy-saving lamp |
| CN102352202B (en) * | 2011-09-13 | 2012-11-07 | 杭州电子科技大学 | Method for preparing bonding material |
| CN102304335B (en) * | 2011-09-17 | 2016-08-17 | 烟台恒迪克能源科技有限公司 | A kind of clay water-base lampshade foamed shell rubber and preparation method thereof |
| CN102504724A (en) * | 2011-09-17 | 2012-06-20 | 党庆风 | Silicon-containing nano water-based lampshade glue and preparation method thereof |
| CN102408851A (en) * | 2011-10-12 | 2012-04-11 | 厦门市金泰祥新科技有限公司 | Environment-friendly adhesive for energy-saving lamp holder |
| CN102408852A (en) * | 2011-10-12 | 2012-04-11 | 厦门市金泰祥新科技有限公司 | Multicomponent environment-friendly high temperature resistant adhesive used for energy saving lamp caps |
| CN102504729A (en) * | 2011-10-12 | 2012-06-20 | 厦门市金泰祥新科技有限公司 | Multi-component adhesive for energy saving lamp |
| CN102367369A (en) * | 2011-10-12 | 2012-03-07 | 厦门市金泰祥新科技有限公司 | Environment-friendly heat-resistant adhesive for energy saving lamp-cap |
| CN102516901B (en) * | 2011-11-29 | 2013-09-11 | 宁波蓝鼎电子科技有限公司 | Adhesive for environment-friendly energy-saving lamp and preparation method thereof |
| CN102719204A (en) * | 2012-07-10 | 2012-10-10 | 镇江智鹰照明光源有限公司 | Carbon fiber-reinforced adhesive for energy-saving lamp and preparation method thereof |
| CN103571399B (en) * | 2012-08-07 | 2015-06-03 | 厦门诺瑞特实业有限公司 | Anti-yellowing energy-saving lamp adhesive and preparation method thereof |
| CN104099042B (en) * | 2013-04-07 | 2016-04-20 | 福建云冶电子科技有限公司 | A kind of high-performance energy saving lamp head sticks with glue agent |
| CN111925752B (en) * | 2020-07-07 | 2021-11-05 | 林俊贤 | Adhesive for high-temperature photoelectric semiconductor material and preparation method thereof |
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2006
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Assignee: Xiamen Jintaixiang New Technology Co.,Ltd. Assignor: Zhang Entian|Duan Caiyi Contract fulfillment period: 2009.7.1 to 2026.4.16 Contract record no.: 2009351000047 Denomination of invention: Environment friendly heat resistant adhesive for energy saving lamp holder License type: Exclusive license Record date: 20090720 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.7.1 TO 2026.4.16; CHANGE OF CONTRACT Name of requester: XIAMEN CITY JINTAI XIANGXIN TECHNOLOGY CO., LTD. Effective date: 20090720 |
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Commission number: 4W100319 Conclusion of examination: Claim No. 200610043621.3 of the invention No. 8 shall be void and shall continue to be valid on the basis of claim 1-7 and 9-10. Decision date of declaring invalidation: 20110706 Decision number of declaring invalidation: 16877 Denomination of invention: Environment friendly heat resistant adhesive for energy saving lamp holder Granted publication date: 20091230 Patentee: Zhang Entian|Duan Caiyi |
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Effective date of registration: 20220214 Address after: 361026 unit 101-301, building 18, Pingcheng West Road, Haicang street, Haicang District, Xiamen City, Fujian Province Patentee after: XIAMEN JINTAIXIANG NEW TECHNOLOGY Co.,Ltd. Address before: 150040 No. 164, Harbin Power District, Heilongjiang, Zhongshan Road Patentee before: Zhang Entian Patentee before: Duan Caiyi |
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