CN101101240A - Low voltage dipole terrestrial electricity extraction method - Google Patents

Low voltage dipole terrestrial electricity extraction method Download PDF

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Publication number
CN101101240A
CN101101240A CNA2007101289663A CN200710128966A CN101101240A CN 101101240 A CN101101240 A CN 101101240A CN A2007101289663 A CNA2007101289663 A CN A2007101289663A CN 200710128966 A CN200710128966 A CN 200710128966A CN 101101240 A CN101101240 A CN 101101240A
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China
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low voltage
soil
electrode
extract
extraction method
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CNA2007101289663A
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Chinese (zh)
Inventor
罗先熔
欧阳菲
胡云沪
文美兰
王葆华
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Guilin University of Technology
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Guilin University of Technology
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Priority to CNA2007101289663A priority Critical patent/CN101101240A/en
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  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

The invention discloses a method of extraction low voltage dipole.Building a manpower electric field, which is made up of electric source (1), lead(2), extraction pole(3). Digging the two earth pit at the instrument station, dig into the soil bottom (5), putting the after dunking extraction pole(3)in the extracting solution into the center of the two pole, filling the soil, pouring the disposal well extracting solution into the soil with filling, trampling solid after filling. At last, connecting the two lead(2) of extraction pole(3) with electric source (1) positive negative pole respectively. After energizing 20-48 hours, taking out the extraction pole (3), making the adsorbing matter to airing, numbering and sample detection. The invention simplicity of operation, taking easily, low cost, high work efficiency and operation easily, it adapts to search insidiousness metal mine body and t developing prospect for forecasting in the heavy layer broken product overlay region, heavy layer basic rock overlay region, gobi overlay region and heavy layer wash, accumulation, proluvial deposit overlay region.

Description

Low voltage dipole terrestrial electricity extraction method
Technical field
The present invention relates to geochemistry and seek nonferrous metal ore, particularly utilize earth electrochemical principle to seek the low voltage dipole terrestrial electricity extraction method of latent mineral metal products.
Background technology
Because commercial production is to the heavy demand of nonferrous metal ore resource, the mineral resources of the face of land and superficial part are reconnoitred totally, both at home and abroad the method and technology of seeking latent mineral metal products resource are more and more paid attention to.The conventional geochemical method of seeking mineral metal products at present has protofaint method, secondary halo method, dispersion train method, biomass geochemistry method etc.These methods are composed the form of depositing and the emphasis difference cuts both ways at metallic element is different.For example, the protofaint method takes the basement rock sample to come analytical element content, and this has just required a large amount of basement rock exposures.And the secondary halo method is taked pedotheque analytical element content, but soil is the synthesis result of multiple weathering, and wherein element is through to a certain degree differentiation, and is so close not as protofaint with the relation of ore body; And be subjected to the influence of ground surface environment easily, make the anti-interference and extraneous contamination of this method ability a little less than.This several method is better to seeking the depth of burial little face of land or superficial part ore body effect, and the latent metal ore body of seeking the deep is then loseed effect.
Summary of the invention
The invention provides a kind of utilization and add artificial electric field and extract metallic element in the soil, by analyzing the low voltage dipole terrestrial electricity extraction method that the metal element content that is extracted carries out deep prospecting.
The present invention is achieved in that and sets up an artificial electric field, extracts electrode by power supply, lead, negative and positive and forms.Dig out two heatable adobe sleeping platforms at survey station, dig the soil bottom, negative and positive are extracted put into two after electrode soaks respectively cheat bottom centre in extract, extract is that concentration is a kind of in nitric acid, sulfuric acid and the hydrochloric acid of 10%-40%, and consumption is 500-1500mL.Fill out the soil that digs out when digging pit, the extract that configures is poured in the soil uniformly, bury the back soil is treaded while filling out.To connect the both positive and negative polarity that two leads that extract electrodes are connected with the mains respectively at last.Switch on after 20-48 hour, just can extract electrode and take out, wherein sorbing material dry, numbering and sample presentation chemically examine.
Requiring of each building block of the present invention is as follows: power supply adopts dry cell, and lead is thin copper core metal lead.The step of extracting the electrode making is such: get a graphite carbon rod, end at graphite carbon rod carves a sulculus, by sulculus plain conductor is linked to each other with graphite carbon rod, and seal with the paraffin place that plain conductor is exposed, and the joint of wrapping plain conductor with the waterproof insulation adhesive plaster.Wrap the sorbing material (being generally the height bubble sponge or the absorbent cotton of strong adsorbability) of process respective handling in the outside of graphite carbon rod, wrap filter paper in the outside of sorbing material then, and twine with cotton thread.Should note when making graphite electrode following some: 1) resistance between plain conductor (and power supply join that end) and the graphite carbon rod bottom is about 0.1 Ω, and maximum can not surpass 0.2 Ω, with the assurance excellent conducting performance.2) sorbing material must soak 6-30 hour through the mixed solution with 15%-25% hydrochloric acid and 0.5%-15% thiocarbamide.Its objective is and make original metallic element background uniform contentization in the sorbing material.4) center of extraction electrode is that the square section is circular graphite carbon rod.5) outermost filter paper is that general high speed filter paper gets final product.Its objective is to stop big solid soil particle to enter sorbing material,, influence the prospecting result of this method in case soil particle mixes mutually with the metallic element or the metallic ion of extraction.
In using process of the present invention, should also be noted that following problem:
1) laying of measuring point: the distance between each measuring point can be a distance with 20 meters generally with reference to the geochemical exploration standard for manual sampling of corresponding proportion chi, can encrypt 10 meters some distances during complicated geologic conditions.Interval of survey line is 100M.
2) spacing between the cathode and anode of extraction electrode is: 40-100CM.
3) extract: a kind of in nitric acid, sulfuric acid and the hydrochloric acid of concentration 10%-40%, consumption is 500-1500mL.Can suitably strengthen consumption under the special soil condition, as in the serious soil of the salinization of soil of northwest desert.
4) extraction time is to be conduction time 20-48 hour.
The present invention extract to compose the activity part that has the metallic element among the soil by extra electric field, and this part material is from ore body, and is closely related with ore-forming element or mineralization.These materials are moved to the face of land from the deep under the driving of the electrochemical field specifically that ore body self forms, and under face of land precipitation, enrichment, it is unusual to have formed local geo-electrochemistry.Because its occurrence patterns is comparatively active, be not subjected to obducent shielding of thick-layer and interference, therefore, even under the situation of the big degree of depth, also can have the preferred metal constituent content unusual, this be routine look for the ore deposit can not accomplish.
The present invention is simple to operate, easy to carry, cost is low, high efficiency, easy to operate, seek compared with routinizing and to look for the concealed orebody method that remarkable advantages is arranged, can seek concealed orebody at thick areal coverage, predict in the ore deposit of looking for that is included in external drift load areal coverage such as thick-layer alluvial deposits, deposit, proluvium, predict in the ore deposit of looking at the residual cliff debris areal coverage of thick-layer, and seeks latent mineral metal products at thick-layer basement rock areal coverage.
Description of drawings
Fig. 1 is a low voltage dipole terrestrial electricity extraction element synoptic diagram of the present invention.
Fig. 2 extracts electrode structural chart for the present invention.
Fig. 3 is the embodiment of the invention and secondary halo method prospecting result comparison diagram.
Mark among the figure: the 1-power supply, the 2-lead, 3-extracts electrode, 4-humus layer, 5-soil bottom, 6-graphite carbon rod, 7-sorbing material, 8-filter paper.
Embodiment
Embodiment
With the mining area, Hunan is example, has carried out ore prospecting test research above known ore body.
The point of survey line is 20m apart from (distance between the measuring point), and the pass point distance is 10m above main ore body, total long 500m of survey line, and 26 of survey stations, numbering is followed successively by 0 point-25 point.
As shown in Figure 1, set up an artificial electric field, form by power supply (1), lead (2), extraction electrode (3).Power supply (1) adopts the 9V dry cell, and lead (2) is thin copper core metal lead.Extract structure such as Fig. 2 of electrode (3), the step of its making is such: the graphite carbon rod (6) of getting a long 15CM diameter 1.5CM, carve the sulculus of a 3mm at an end of graphite carbon rod (6), plain conductor (2) is linked to each other with graphite carbon rod (6), seal up the exposed section of plain conductor (2) with paraffin, and twined the joint with the waterproof insulation adhesive plaster.Sorbing material (7) is soaked processing in 24 hours through the mixed solution of 20% hydrochloric acid and 0.5% thiocarbamide, and dry.Wrap the promptly high bubble sponge of sorbing material (7) after treatment in the outside of graphite carbon rod (6), wrap filter paper (8) in the outside of sorbing material (7) then, and twine with cotton thread.Resistance between plain conductor (2) and graphite carbon rod (6) bottom requires less than 0.2 Ω.The specification of sorbing material (7) is that 12CM is long, 8CM is wide, 2CM is thick.Graphite carbon rod (6) 15CM, diameter 1.5CM.Outermost filter paper (8) size is that 15CM is long, 15CM is wide.
Bury the dark 50CM of heatable adobe sleeping platform that extracts electrode (3) underground, the distance between two heatable adobe sleeping platform centers is 1M.Dig soil bottom (5), put into the hole extracting after electrode (3) (each one of cathode and anode) soaks in extract, extract is 15% nitric acid, consumption 1000mL; The cathode and anode of extracting electrode (3) is placed on the bottom centre in two holes respectively, fills out the soil that digs out when digging pit, while banket the extract (concentration is 15% nitric acid) that configures is poured in the soil uniformly, buries the back soil is treaded.To connect connect with the mains the respectively both positive and negative polarity of (1) of two leads (2) that extract electrodes (3) at last.Switch on after 24 hours, will extract electrode (3) and take out, wherein sorbing material (7) dry, numbering and sample presentation chemically examine.
As shown in Figure 3, manually arranged a survey line above the known ore body in this mining area, the below of figure is the ore body geologic feature of this survey line, and the top is the content correlation curve of electricity extraction of the present invention ground and secondary halo method.
Ore-forming element W has been carried out chemical spectrum analysis.Secondary halo intensity of anomaly maximum be to be positioned at No. 20 points in section the right.Its abnormal morphology is more random, i.e. the Non Apparent Abnormality feature.And the present invention's ground electricity extracts and contains discharge curve and present tangible off-note: the W constituent content between the 4-17 point is obviously higher, is up to 450ppb, exceeds 2.9 times than mean value 156ppb.And high anomalous concentration has reflected the position that ore-forming element is concentrated at the coincidence position of two main ore bodies, has reflected one-tenth ore deposit feature effectively.

Claims (6)

1. low voltage dipole terrestrial electricity extraction method, it is characterized in that: set up an artificial electric field, form by power supply (1), lead (2), extraction electrode (3), dig out two heatable adobe sleeping platforms at survey station, dig soil bottom (5), in extract, soak the bottom centre that the later cathode and anode that will extract electrode (3) is respectively put into two heatable adobe sleeping platforms respectively, fill out the soil that digs out when digging pit extracting electrode (3), while filling out the extract that configures is poured in the soil uniformly, buried the back soil is treaded; Link to each other with negative pole, the positive pole of power supply (1) respectively extracting electrode (3) at last; Switch on after 20-48 hour, will extract electrode (3) and take out, wherein sorbing material (7) dry, numbering and sample presentation chemically examine.
2. low voltage dipole terrestrial electricity extraction method according to claim 1 is characterized in that described power supply (1) is a dry cell, and its voltage is 4.5-24V.
3. low voltage dipole terrestrial electricity extraction method according to claim 1 is characterized in that described extract is a kind of in nitric acid, sulfuric acid and the hydrochloric acid of concentration 10%-40%, and consumption is 500-1500mL.
4, low voltage dipole terrestrial electricity extraction method according to claim 1, the center that it is characterized in that described extraction electrode (3) is graphite carbon rod (6), be surrounded by sorbing material (7) in the outside of graphite carbon rod (6), the outside of sorbing material (7) is surrounded by filter paper (8).
5,, it is characterized in that described sorbing material (7) soaks height bubble sponge or absorbent cotton after 6-30 hour for the hydrochloric acid of concentration 15%-25% and concentration 0.2%-10% thiocarbamide mixed solution according to claim 1 or require 5 described low voltage dipole terrestrial electricity extraction methods.
6, low voltage dipole terrestrial electricity extraction method according to claim 1 is characterized in that the distance of described extraction electrode (3) when burying underground between the cathode and anode is 40-100CM.
CNA2007101289663A 2007-07-27 2007-07-27 Low voltage dipole terrestrial electricity extraction method Pending CN101101240A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104536050A (en) * 2014-11-27 2015-04-22 核工业北京地质研究院 Geo-electrochemical method and geo-electrochemical device for sandstone-type uranium deposit exploration
WO2022213433A1 (en) * 2021-04-08 2022-10-13 桂林理工大学 Encapsulated geoelectric extraction electrode and use method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104536050A (en) * 2014-11-27 2015-04-22 核工业北京地质研究院 Geo-electrochemical method and geo-electrochemical device for sandstone-type uranium deposit exploration
WO2022213433A1 (en) * 2021-04-08 2022-10-13 桂林理工大学 Encapsulated geoelectric extraction electrode and use method thereof

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Open date: 20080109