CN101096398A - New-type inner-outer wall coating water-proof antimicrobial latex - Google Patents
New-type inner-outer wall coating water-proof antimicrobial latex Download PDFInfo
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- CN101096398A CN101096398A CNA200610014510XA CN200610014510A CN101096398A CN 101096398 A CN101096398 A CN 101096398A CN A200610014510X A CNA200610014510X A CN A200610014510XA CN 200610014510 A CN200610014510 A CN 200610014510A CN 101096398 A CN101096398 A CN 101096398A
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Abstract
The invention discloses a water resistance antibiotic emulsion of new inner or exterior wall paint. The preparing method comprises the following steps: dissolving sodium carbonate decahydrate in the deionized water; dissolving the ammonium peroxodisulfate with the water; dispersing ZnO, TIO2 with the water; dissolving the tert-butyl hydroperoxide with the water; dissolving sodium formaldehyde sulfoxylate in the water; adding the emulsifier in the deionized water; getting preemulsion by adding butyl acrylate, phenylethene, acroleic acid and N-methylol acrylamide and mixing; adding the rest deionized water in the chiller, agitator and heat indicator bottle; adding the nanometer material after mixing the rest emulsifier and sodium carbonate decahydrate solution; heating; adding the preemulsion and initiating agent solution; dropping the rest preemulsion and initiating agent solution after reacting; reducing the temperature; adding tert-butyl hydroperoxide solution; mixing by adding water; adding formaldehyde sodium sulphoxylate solution; proceeding with the secondary initiation reaction; reducing the temperature and adding AMP-95; adjusting pH value of emulsion; stopping mixing; getting the material by filtering. The invention has the water resistance, the pollution resistibility, the age resistance and the antibiosis.
Description
Technical field
The present invention relates to a kind of New-type inner-outer wall coating water-proof antimicrobial latex.
Background technology
Present used emulsion in the confecting inner-outer wall coating, its oily emulsion waterproof, resistance to soiling are good, but not environmental protection.The water-based emulsion feature of environmental protection is good, but the waterproof resistance to deterioration is poor, and is more not antibiotic.
Summary of the invention
The objective of the invention is to overcome above-mentioned shortcoming, a kind of New-type inner-outer wall coating water-proof antimicrobial latex is provided.
Technical scheme of the present invention is: a kind of New-type inner-outer wall coating water-proof antimicrobial latex is characterized in that: the deionized water with 42%, 24.4% Butyl acrylate, 24% benzene second are rare, 1.8% nonionic emulsifier, 1.8% nano-ZnO, 1.2% nano-TiO
2, 1% anionic emulsifier, 1%N-methylol propylene phthalein amine, 0.8% vinylformic acid, 0.6% tertbutyl peroxide, 0.6% rongalite, 0.4% ammonium persulphate, 0.2% sodium bicarbonate, 0.2% multifunctional assistant, carry out pre-emulsification, stirring, dropping, high temperature polymerization by weight and form.
The present invention has the following advantages: have waterproof, resistant, anti-aging function, have antibiotic, photocatalysis.
Embodiment
Embodiment: a kind of New-type inner-outer wall coating water-proof antimicrobial latex, sodium bicarbonate is added molten opening in the deionized water, 1 part of sodium bicarbonate is converted 10 parts of water, 1 part of initiator ammonium persulfate is converted 15 parts of water-soluble opening, nano-ZnO, nanometer TIO
2Powder respectively with 1 convert 10 parts of hydrominings with 3000-4000 rev/min high speed dispersion 1-2 hour, 1 part of tertbutyl peroxide is converted 10 parts of water-soluble opening, 1 part of rongalite is dissolved in 10 parts of water, above material prepares stand-by by weight, the various emulsifying agents that account for total amount 2/3rds join 45% deionized water for stirring evenly after, successively lentamente Butyl acrylate, benzene second is rare, vinylformic acid, N-methylol propylene phthalein amine, add and wherein stir, make pre-emulsion, condenser is being housed, agitator, add the residue deionized water in the four-hole bottles such as thermometer, after stirring, residual emulsifier and saleratus solution add nano pulp, be warming up to 88 ℃, the pre-emulsion of adding 5% and 1/3 initiator solution, react after 30 minutes and to drip remaining pre-emulsion and initiator solution and dripped off temperature in three hours synchronously and be controlled at 88-90 ℃, after being incubated 1 hour again, when being cooled to 65 ℃, add tertbutyl peroxide solution, 1 part of tertbutyl peroxide is converted 10 parts of water and is stirred, react and add rongalite solution again after 10 minutes, 1 part of rongalite is converted 10 parts of water-soluble opening, carry out the initiation reaction second time, the pH value that adds AMP-95 accent emulsion of lowering the temperature again 40 ℃ is that 7-9 stops to stir, and filters discharging and gets final product.
Claims (1)
1, a kind of New-type inner-outer wall coating water-proof antimicrobial latex is characterized in that: the deionized water with 42%, 24.4% Butyl acrylate, 24% benzene second are rare, 1.8% nonionic emulsifier, 1.8% nano-ZnO, 1.2% nano-TiO
2, 1% anionic emulsifier, 1%N-methylol propylene phthalein amine, 0.8% vinylformic acid, 0.6% tertbutyl peroxide, 0.6% rongalite, 0.4% ammonium persulphate, 0.2% sodium bicarbonate, 0.2% multifunctional assistant, carry out pre-emulsification, stirring, dropping, high temperature polymerization by weight and form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200610014510XA CN101096398A (en) | 2006-06-30 | 2006-06-30 | New-type inner-outer wall coating water-proof antimicrobial latex |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200610014510XA CN101096398A (en) | 2006-06-30 | 2006-06-30 | New-type inner-outer wall coating water-proof antimicrobial latex |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101096398A true CN101096398A (en) | 2008-01-02 |
Family
ID=39010501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200610014510XA Withdrawn CN101096398A (en) | 2006-06-30 | 2006-06-30 | New-type inner-outer wall coating water-proof antimicrobial latex |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101096398A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717593B (en) * | 2010-01-14 | 2012-03-21 | 邯郸市森弛木业有限公司 | Wear-resistant coating of wood floor |
| CN104312350A (en) * | 2014-11-11 | 2015-01-28 | 合肥不老传奇保健科技有限公司 | Composite silicon-acrylic acid exterior wall coating material with high solid content and high stability and preparation method thereof |
| CN104312241A (en) * | 2014-11-11 | 2015-01-28 | 合肥不老传奇保健科技有限公司 | Sterilizing, anti-algae and anti-aging water-based exterior wall coating and preparation method thereof |
| CN104530840A (en) * | 2014-11-28 | 2015-04-22 | 高峰 | Coating |
-
2006
- 2006-06-30 CN CNA200610014510XA patent/CN101096398A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101717593B (en) * | 2010-01-14 | 2012-03-21 | 邯郸市森弛木业有限公司 | Wear-resistant coating of wood floor |
| CN104312350A (en) * | 2014-11-11 | 2015-01-28 | 合肥不老传奇保健科技有限公司 | Composite silicon-acrylic acid exterior wall coating material with high solid content and high stability and preparation method thereof |
| CN104312241A (en) * | 2014-11-11 | 2015-01-28 | 合肥不老传奇保健科技有限公司 | Sterilizing, anti-algae and anti-aging water-based exterior wall coating and preparation method thereof |
| CN104530840A (en) * | 2014-11-28 | 2015-04-22 | 高峰 | Coating |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C04 | Withdrawal of patent application after publication (patent law 2001) | ||
| WW01 | Invention patent application withdrawn after publication |