CN104530840A - Coating - Google Patents

Coating Download PDF

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Publication number
CN104530840A
CN104530840A CN201410702076.9A CN201410702076A CN104530840A CN 104530840 A CN104530840 A CN 104530840A CN 201410702076 A CN201410702076 A CN 201410702076A CN 104530840 A CN104530840 A CN 104530840A
Authority
CN
China
Prior art keywords
coating
reactor
parts
potassium persulphate
sodium laurylsulfonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410702076.9A
Other languages
Chinese (zh)
Inventor
高峰
Original Assignee
高峰
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 高峰 filed Critical 高峰
Priority to CN201410702076.9A priority Critical patent/CN104530840A/en
Publication of CN104530840A publication Critical patent/CN104530840A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/10Silicon-containing compounds
    • C08K7/12Asbestos
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc

Abstract

The invention relates to a coating. The coating compriss a styrene acrylic emulsion, titanium dioxide, sodium dodecyl sulfonate, potassium persulfate, zinc oxide, mica powder and asbestos staple fibers. The coating has very good adhesion performance; the asbestos staple fibers are used to enhance the strength of the coating, so the service time of the coating is prolonged; and the coating does not release toxic gases, and is safe and environmentally-friendly.

Description

A kind of coating
Technical field
The invention belongs to paint field, be specifically related to a kind of coating.
Background technology
Coating is applied to body surface can be formed and have protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprises oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating as one of the main material of house decoration, the large percentage accounted in decorations, but many times during paint spay-coating, adhesiving effect is bad, and the wear resistance of coating is poor, and volatile toxic substance content is higher, is harmful to health.
Summary of the invention
The object of this invention is to provide a kind of coating, not containing volatility toxic gas, and the adhesion of coating is good, difficult drop-off.
The present invention is achieved through the following technical solutions:
A kind of coating, comprise: vinylbenzene 30-50 part, butyl acrylate 40-50 part, titanium dioxide 10-15 part, sodium laurylsulfonate 3-8 part, Potassium Persulphate 0.2-1 part, zinc oxide 1-2 part, mica powder 25-40 part, asbestos short fiber 10-15 part, prepared by use following methods: (1), vinylbenzene 30-50 part, butyl acrylate 40-50 part are mixed with 400 parts of water, obtains mixture; (2), get 1/10 of said mixture and add reactor, in reactor, then add sodium laurylsulfonate 0.02-0.1 part, Potassium Persulphate 0.02-0.1 part, carry out pre-polymerization under stirring at 60-65 DEG C, stirring velocity is 220-260r/min; (3), remaining mixed solution, sodium laurylsulfonate, Potassium Persulphate are mixed and add funnel, with 10ml/min to titration in reactor, in maintenance reactor, temperature is at 78 DEG C, after titration completes, titanium dioxide, zinc oxide, mica powder and asbestos short fiber is added in reactor, under agitation continue reaction 1-2h, obtain finished product.
The short fiber of described asbestos short fiber to be length be 0.1-0.5mm.
Beneficial effect of the present invention: paint-flow provided by the invention is good, is easy to spraying, has good adhesion property, and use asbestos short fiber to strengthen, make intensity enhancing and the wear resistance of coating, improve duration of service, and can not poisonous gas be discharged, safety and environmental protection.
Embodiment
Embodiment 1
A kind of coating, comprise: vinylbenzene 45 parts, butyl acrylate 50 parts, titanium dioxide 12 parts, sodium laurylsulfonate 5 parts, Potassium Persulphate 0.5 part, 1 part, zinc oxide, mica powder 30 parts, asbestos short fiber 12 parts, prepared by use following methods: (1), vinylbenzene 45 parts, butyl acrylate 50 parts are mixed with 400 parts of water, obtains mixture; (2), get 1/10 of said mixture and add reactor, in reactor, then add sodium laurylsulfonate 0.1 part, Potassium Persulphate 0.1 part, carry out pre-polymerization under stirring at 60-65 DEG C, stirring velocity is 220r/min; (3), remaining mixed solution, sodium laurylsulfonate, Potassium Persulphate are mixed and add funnel, with 10ml/min to titration in reactor, in maintenance reactor, temperature is at 78 DEG C, after titration completes, titanium dioxide, zinc oxide, mica powder and asbestos short fiber is added in reactor, under agitation continue reaction 2h, obtain finished product.
The conventional coating of the paint adhesion force rate that present method obtains is strong by 10%, and erosion resistance liquid also has greatly improved, and the crocking resistance of material promotes 25%.
Embodiment 2
Comprise: vinylbenzene 45 parts, butyl acrylate 45 parts, titanium dioxide 12 parts, sodium laurylsulfonate 8 parts, Potassium Persulphate 0.6 part, 2 parts, zinc oxide, mica powder 35 parts, asbestos short fiber 14 parts.

Claims (1)

1. a coating, it is characterized in that, comprise: vinylbenzene 30-50 part, butyl acrylate 40-50 part, titanium dioxide 10-15 part, sodium laurylsulfonate 3-8 part, Potassium Persulphate 0.2-1 part, zinc oxide 1-2 part, mica powder 25-40 part, asbestos short fiber 10-15 part, prepared by use following methods: (1), vinylbenzene 30-50 part, butyl acrylate 40-50 part are mixed with 400 parts of water, obtains mixture; (2), get 1/10 of said mixture and add reactor, in reactor, then add sodium laurylsulfonate 0.02-0.1 part, Potassium Persulphate 0.02-0.1 part, carry out pre-polymerization under stirring at 60-65 DEG C, stirring velocity is 220-260r/min; (3), remaining mixed solution, sodium laurylsulfonate, Potassium Persulphate are mixed and add funnel, with 10ml/min to titration in reactor, in maintenance reactor, temperature is at 78 DEG C, after titration completes, titanium dioxide, zinc oxide, mica powder and asbestos short fiber is added in reactor, under agitation continue reaction 1-2h, obtain finished product.
CN201410702076.9A 2014-11-28 2014-11-28 Coating Pending CN104530840A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410702076.9A CN104530840A (en) 2014-11-28 2014-11-28 Coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410702076.9A CN104530840A (en) 2014-11-28 2014-11-28 Coating

Publications (1)

Publication Number Publication Date
CN104530840A true CN104530840A (en) 2015-04-22

Family

ID=52846483

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410702076.9A Pending CN104530840A (en) 2014-11-28 2014-11-28 Coating

Country Status (1)

Country Link
CN (1) CN104530840A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003192993A (en) * 2001-12-26 2003-07-09 Nippon Zeon Co Ltd Coating agent for dip-molded article and dip-molded article
CN1844270A (en) * 2006-05-17 2006-10-11 河北科技大学 Nano antibacterial powdered paint and its micro-suspension one-step preparation therefor
CN101096398A (en) * 2006-06-30 2008-01-02 天津市振东涂料有限公司 New-type inner-outer wall coating water-proof antimicrobial latex
CN102304316A (en) * 2011-07-22 2012-01-04 陕西科技大学 Polyacrylate/nanometer ZnO composite finishing agent and preparation method thereof
CN102993883A (en) * 2012-10-12 2013-03-27 张家港市永法涂料有限公司 Acrylic ester waterproof paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003192993A (en) * 2001-12-26 2003-07-09 Nippon Zeon Co Ltd Coating agent for dip-molded article and dip-molded article
CN1844270A (en) * 2006-05-17 2006-10-11 河北科技大学 Nano antibacterial powdered paint and its micro-suspension one-step preparation therefor
CN101096398A (en) * 2006-06-30 2008-01-02 天津市振东涂料有限公司 New-type inner-outer wall coating water-proof antimicrobial latex
CN102304316A (en) * 2011-07-22 2012-01-04 陕西科技大学 Polyacrylate/nanometer ZnO composite finishing agent and preparation method thereof
CN102993883A (en) * 2012-10-12 2013-03-27 张家港市永法涂料有限公司 Acrylic ester waterproof paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李东光: "《实用化工产品配方与制备》", 31 August 2013 *

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SE01 Entry into force of request for substantive examination
C10 Entry into substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150422

WD01 Invention patent application deemed withdrawn after publication