CN101092293A - Powder enhanced type grinding aids - Google Patents

Powder enhanced type grinding aids Download PDF

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Publication number
CN101092293A
CN101092293A CNA200710055678XA CN200710055678A CN101092293A CN 101092293 A CN101092293 A CN 101092293A CN A200710055678X A CNA200710055678X A CN A200710055678XA CN 200710055678 A CN200710055678 A CN 200710055678A CN 101092293 A CN101092293 A CN 101092293A
Authority
CN
China
Prior art keywords
trolamine
enhanced type
type grinding
grinding aid
grinding aids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA200710055678XA
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Chinese (zh)
Other versions
CN100503500C (en
Inventor
陈云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jilin Yatai Cememts Co Ltd
Original Assignee
Jilin Yatai Cememts Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jilin Yatai Cememts Co Ltd filed Critical Jilin Yatai Cememts Co Ltd
Priority to CNB200710055678XA priority Critical patent/CN100503500C/en
Publication of CN101092293A publication Critical patent/CN101092293A/en
Application granted granted Critical
Publication of CN100503500C publication Critical patent/CN100503500C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/52—Grinding aids; Additives added during grinding
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Disintegrating Or Milling (AREA)

Abstract

This invention discloses a modified powder grinding aid. The grinding aid utilizes furnace slag as the carrier, and the doping amount is decreased to 0.2% from present 0.8% doping amount. It is proven that the grinding aid can increase the doping amount of mixed materials in composite cement by more than 10%, and increase drilling meters per hour by 10%. Besides, the doping cost of the grinding aid per ton cement is only 1.5 yen, and Cl- content in cement is much lower than 0.06%.

Description

Powder enhanced type grinding aids
Technical field
The present invention is a kind of novel powder enhanced type grinding aids that adds in cement pulverizing course
Technical background
As everyone knows, cement is the high a kind of product of energy consumption, and grog coal consumption, cement grinding power consumption are two the highest key links of energy consumption in the manufacture of cement.Therefore reducing the grog volume and improve the cement grinding mill unit-hour output in cement pulverizing course is the key technique that reduces the cement products energy consumption index.Country will use grinding aid to classify the major technique measure that cement industry cuts down the consumption of energy as in cement, and domestic most cement production enterprises have added grinding aid in process of production.The grinding aid product that has powder and two kinds of forms of liquid in the market.Wherein powder does not have the grinding aid effect basically based on enhancing, and addition content is basically about 0.8%; Liquid is based on grinding aid, and volume is about 0.035%.No matter mixing cost, spares which kind of its ton of grinding aid cement more than 3 yuan.
How with grinding aid with strengthen two kinds of usefulness and effectively combine, improve grinding aid to greatest extent and mix effect, reduce the ton cement grinding aid and add a cost, the economical effectiveness that improves to greatest extent after grinding aid mixes is that institute of each enterprise must consideration.
Summary of the invention
The present invention is the advantage in conjunction with solid and two kinds of grinding aids of liquid, and through various components are screened, the component of will being correlated with carries out heated compounded reaction, improves the component activity, strengthens stimulation effect.Reach and improve grinding aid, reinforced effects, reduce the purpose of grinding aid volume.
The present invention carries out on the basis of test analysis present grinding aid composition and result of use, adopts organic and inorganics to carry out compound raising component activity.Four kinds of selected components are respectively: trolamine, Industrial Salt, unslaked lime, sintering gypsum are carrier with slag or stone flour.Proportioning between the material and complex reaction determine that through a large amount of test compare of analysis the final weight ratio is: trolamine: Industrial Salt: cream during sintering: unslaked lime: slag (stone flour)=(2-3): (20-30): (0-10): (0-5): (55-65)
Produce and realize technology mode: according to various feature of raw material, need not fragmentation in process of production, various materials are adding fashionable must the adding in proportion through metering.Industrial Salt and unslaked lime and trolamine carry out compound tense will control pH value, temperature and reaction times, and the finished product are granular, slightly moist, various materials distribution uniform in product.
By using, this product addition content average out to about 0.2% in the powder process, compare with blank, blended material improves 10%, every performance index of cement all blank improve a lot, the cement grinding process situation is stable, through the cement performance that adds grinding aid is detected, the result is stable, meets product standard, and quality fluctuation is less.
The following advantage of tool of the present invention:
1. adopt organic and inorganic combining in the prescription, raw material need not be broken, and production worker technology is simple relatively, production efficiency height and constant product quality.
2. incorporation is few, reduces the ton cement grinding aid and mixes cost.
3. by using, the grinding aid reinforced effects of this grinding aid will surpass the grinding aid that the patent No.: ZL98110360.X produces.
4. cement production enterprise uses the unit-hour output that not only improves cement grinding mill, and reduces the grog consumption, improves the incorporation of " three wastes " blended material, reaches the tax-free requirement of country.Reduce the product energy consumption index, meet national circular economy policy.
5. this powder grinding aid volume is broken through the volume restriction of conventional powder grinding aid 0.8%, and according to a large amount of production data statistics, this grinding aid add-on in cement pulverizing course is about 0.2%.
When using this product cement quality be mixed with the patent No. (ZL98110360.X) and do not mix grinding aid at cement grinding mill production effect comparison cartogram.
Grinding aid Volume Blended material Fineness Resistance to compression in 3 days Resistance to compression in 28 days The cement grinding mill platform produces
Blank 0 21.32 2.5 19.6 41.9 118t/h
This grinding aid 0.2 32.73 3.8 22.6 42.2 128t/h
ZL98110360.X 0.3 31.70 3.5 21.0 39.1 125/h
As can be seen from the above table, this grinding aid will surpass the patent No. to grinding aid, the reinforced effects of cement: the ZL98110360.X grinding aid.
Embodiment
This product is apparent to be granular product, and being different from general is the powder grinding aid of carrier with flyash, the feature close according to raw material particle size, and the raw material of selecting for use need not fragmentation, just can enter to mix in the mixer through metering to get final product.
Production stage is earlier the quantitative Industrial Salt of part to be added in the gauge water, the heated and stirred dissolving also is warming up to about 90 degree, add quantitative three ethanol of part and unslaked lime, stir and temperature is remained on 90 degree, be incubated, display to transfer to about 3 hours in another bucket and mix with quantitative trolamine.
Remaining Industrial Salt, sintering gypsum, slag (stone flour) are fed mixer after metering and stir.Compound liquid is measured by volume pump, evenly feeds in the mixer continuously, and each component stirs and is finished product after handling equipment enters finished bin.

Claims (4)

1. powder enhanced type grinding aids, it is characterized in that: containing effective enhancing grinding aid composition of trolamine, Industrial Salt, sintering gypsum, unslaked lime and mixture thereof, is carrier with slag or stone flour.Weight proportion is: trolamine: 2-3; Industrial Salt: 20-30; Sintering gypsum: 0-10; Unslaked lime: 0-5; Slag or stone flour: 55-65.Production craft step: raw material need not fragmentation through metering, the part Industrial Salt is added in the entry dissolving back add partly that trolamine heats up, and unslaked lime added adjust pH value in the liquid and carry out complex reaction, and insulation is displayed, and excites material activity in the component.Complex reaction liquid is added mixing behind the part trolamine again, through the volume pump metering continuously evenly in the feeding mixer, be delivered to finished bin after guaranteeing to mix with other component.
2. according to the described powder enhanced type grinding aids of claim 1, it is characterized in that: powder enhanced type grinding aids selects for use material proportion to be: trolamine: Industrial Salt: cream during sintering: unslaked lime: slag (stone flour)=(2-3): (20-30): (0-10): (0-5): (55-65).
3. according to the described powder enhanced type grinding aids of claim 1, it is characterized in that: raw material need not fragmentation.
4. according to the described powder enhanced type grinding aids of claim 1, it is characterized in that: employing Industrial Salt, trolamine and unslaked lime are adjusted pH value and are heated and carry out complex reaction under liquid state, improve the material activity.
CNB200710055678XA 2007-05-25 2007-05-25 Powder enhanced type grinding aids Expired - Fee Related CN100503500C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB200710055678XA CN100503500C (en) 2007-05-25 2007-05-25 Powder enhanced type grinding aids

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB200710055678XA CN100503500C (en) 2007-05-25 2007-05-25 Powder enhanced type grinding aids

Publications (2)

Publication Number Publication Date
CN101092293A true CN101092293A (en) 2007-12-26
CN100503500C CN100503500C (en) 2009-06-24

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNB200710055678XA Expired - Fee Related CN100503500C (en) 2007-05-25 2007-05-25 Powder enhanced type grinding aids

Country Status (1)

Country Link
CN (1) CN100503500C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101269928B (en) * 2008-05-06 2010-06-02 沂源县辰通建材有限公司 Concrete grinding aid and preparation method thereof
CN101618955B (en) * 2009-07-30 2012-02-15 葫芦岛市辽西混凝土外加剂有限公司 High efficiency cement composite grinding additive and preparation method thereof
CN103011656A (en) * 2012-12-20 2013-04-03 山东三特水泥助磨剂有限公司 Powdered cement grinding aid fortifier
CN109250933A (en) * 2018-09-29 2019-01-22 浙江长盈建材科技有限公司 Corrosion protection steel-making slag powder grinding aid and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101269928B (en) * 2008-05-06 2010-06-02 沂源县辰通建材有限公司 Concrete grinding aid and preparation method thereof
CN101618955B (en) * 2009-07-30 2012-02-15 葫芦岛市辽西混凝土外加剂有限公司 High efficiency cement composite grinding additive and preparation method thereof
CN103011656A (en) * 2012-12-20 2013-04-03 山东三特水泥助磨剂有限公司 Powdered cement grinding aid fortifier
CN103011656B (en) * 2012-12-20 2014-09-10 山东三特水泥助磨剂有限公司 Powdered cement grinding aid fortifier
CN109250933A (en) * 2018-09-29 2019-01-22 浙江长盈建材科技有限公司 Corrosion protection steel-making slag powder grinding aid and preparation method thereof

Also Published As

Publication number Publication date
CN100503500C (en) 2009-06-24

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Granted publication date: 20090624

Termination date: 20100525