CN101091020A - Process for producing rugged fabric - Google Patents

Process for producing rugged fabric Download PDF

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Publication number
CN101091020A
CN101091020A CNA2006800016037A CN200680001603A CN101091020A CN 101091020 A CN101091020 A CN 101091020A CN A2006800016037 A CNA2006800016037 A CN A2006800016037A CN 200680001603 A CN200680001603 A CN 200680001603A CN 101091020 A CN101091020 A CN 101091020A
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CN
China
Prior art keywords
fiber
silk
cloth
china ink
painted
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Granted
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CNA2006800016037A
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Chinese (zh)
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CN100585066C (en
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宫川惠司
柳克彦
高坂贵浩
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Seiren Co Ltd
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Seiren Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C23/00—Making patterns or designs on fabrics
    • D06C23/04—Making patterns or designs on fabrics by shrinking, embossing, moiréing, or crêping
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/30—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
    • D03D15/33—Ultrafine fibres, e.g. microfibres or nanofibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8214—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing ester and amide groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/02—Producing patterns by locally destroying or modifying the fibres of a web by chemical actions, e.g. making translucent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/08—Decorating textiles by fixation of mechanical effects, e.g. calendering, embossing or Chintz effects, using chemical means
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/12—Physical properties biodegradable
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel

Abstract

A process for producing a rugged fabric which is excellent in the sharpness of the rugged part and in the smoothness of the recessed parts and which has a three-dimensional pattern with a wide variation. The process for rugged-fabric production comprises the step of giving a fiber decomposer by an ink-jet technique to a fabric comprising 20-75 wt.% nylon fibers having a single-yarn fineness of 4 dtex or less and a total fineness of 110 dtex or less and 25-80 wt.% polyester fibers having a single-yarn fineness of 3 dtex or less and a total fineness of 170 dtex or less.

Description

The manufacture method of rugged fabric
Technical field
The present invention relates to manufacture method by 2 kinds of different fibroplastic rugged fabrics, more particularly, relate to by the clear-cut of the part of concavo-convex processing and recess flatness excellence, formed the manufacture method of the rugged fabric of changeful space pattern.In addition, also relate to the manufacture method that also can show the rugged fabric of chromatic pattern to recess.
Background technology
In recent years, developed cloth and silk with high functionality, in the utilization in the built-in material of automobile and building field and motion or fashion field in continuous expansion.High functionality cloth and silk, what is called have the cloth and silk of space pattern, and be concavo-convex owing to having formed on the surface of cloth and silk, therefore receives publicity as the cloth and silk with third dimension, feeling of high class or refrigerant sense.
As the method that on cloth and silk, forms such space pattern, study so far, adopted from physics and form concavo-convex method and from chemically forming concavo-convex method.
The method of the former physics aspect is included under the heat and adopts engraved roll to carry out the embossing processing of pressing mold and Schreiner finish etc.But because the cloth and silk insertion is heavily added between the warm-up mill of depressing, there are the following problems: the sclerosis of feel, the flattening of cloth and silk become very big, and produce the metallic luster that hot-rolling causes sometimes, perhaps produce thermo-color, can not be at recess face performance chromatic pattern.
As the method for the latter's chemical aspect, as shown in the public clear 47-23709 communique of spy, when carrying out stamp, the medicament that makes filament contraction or decrement is mixed into stamp sticks with paste and handle.When using naphthol derivative as medicament, owing to be insoluble in water, exist when therefore being coated with to form uneven problem easily, when using amine, alkali metal hydroxide, exist to produce stench, perhaps harmfulness, dangerous high problem.In order to address this problem, to open the spy and to have proposed in the 2000-96439 communique that the mixed carbonic acid guanidine uses as medicament in stamp is stuck with paste.Though this method requires alkali resistance to the paste that uses, and has the shortcoming that defines spendable paste, but still thinks the method for concavo-convex repeatability, environment and secure context excellence.
But all need aspect time and cost, there be the problem of a spot of processing of extremely difficult reply in the method for having stated so far from the modeling starting of hot-rolling, stamp silk screen.In addition, stick with paste and to be high viscosity owing to mixed the stamp of medicament, therefore low to the impregnability of cloth and silk, when the long piloerection cloth and silk of villus length was used, medicament can't enter into fine hair inside, had the tendency of concavo-convex insufficient, concave surface flatness shortcoming.In addition, want recess is carried out when painted, be mixed with filament contraction agent etc. by manufacturing and stick with paste, its stamp is carried out, but aspect operation, being colored as single look is the limit that it is extremely difficult freely showing chromatic pattern with the look of dyestuff.
In order to solve such problem, receive publicity thereby adopt ink-jetting style to give the method that filament contraction agent etc. forms space patterns in recent years to cloth and silk.
For ink-jetting style, owing to do not need the modeling of hot-rolling, stamp silk screen, thus can give cloth and silk with medicament by the medicament that the part of necessity is sprayed necessary amount, therefore in economic aspect, secure context excellence.In addition, resulting space pattern is the ultimate attainment close space pattern that adopts mode in the past to make, and is therefore very useful.
As the formation method of the space pattern that adopts ink-jetting style, for example, thereby there is the spy to open the disclosed method that fine hair is shunk from the agent of nozzle ejection filament contraction in the flat 10-298863 communique.In this case, used the full-bodied like this China ink of 100～200cps, but the ink-jet printing apparatus of popularizing uses the China ink of the low viscosity type about 1～10cps, therefore the printing equipment that needs new high viscous ink to use.In addition, because China ink is full-bodied, be easy to generate nozzle blockage.In addition, because the filament contraction agent is low to the impregnability of cloth and silk, when therefore the long piloerection cloth and silk of villus length being used, exist medicament can't enter into fine hair inside, the concavo-convex inadequate tendency that becomes.In addition, be easy to generate the fluctuation of filament contraction agent to the impregnability of fine hair, concave surface flatness shortcoming is in order when same position gives painted China ink, to produce problems such as feint decorative pattern to the painted chromatic pattern of concave surface.
Therefore, as the space pattern formation method on the cloth and silk, ink-jetting style is considered to very useful method, but does not find as yet to access recess flatness excellence, and can carry out the manufacture method of the painted rugged fabric of chromatic pattern to recess.
Summary of the invention
The object of the present invention is to provide by the clear-cut of the part of concavo-convex processing and recess flatness excellence, formed the manufacture method of the rugged fabric of changeful space pattern.In addition, also provide the recess also manufacture method of the rugged fabric of painted chromatic pattern freely.
Promptly, the present invention relates to the manufacture method of rugged fabric, it comprises with ink-jetting style and gives the operation of fiber distintegrant to cloth and silk that it is that 4dtex is following, total fiber number is following nylon fiber 20～75 weight % of 110dtex and filament number is that 3dtex is following, total fiber number is following polyester fiber 25～80 weight % of 170dtex that described cloth and silk comprises filament number.
Preferably when giving above-mentioned fiber distintegrant, give to make the painted China ink of polyester fiber and/or can make the painted China ink of nylon fiber.
Preferred above-mentioned fiber distintegrant is the guanidine salt of weak acid.
Preferred above-mentioned guanidine salt of weak acid is a guanidine carbonate.
Preferred above-mentioned cloth and silk is two-sided braided fabric.
Plaiting (plating) gimmick of preferred above-mentioned two-sided braided fabric employing garden tube knitting (circular knitting) forms.
In addition, the present invention relates to adopt above-mentioned manufacture method and the rugged fabric that obtains.
The specific embodiment
The cloth and silk that uses among the present invention comprise filament number as below the 4dtex, total fiber number as 20～75 weight % of the nylon fiber below the 110dtex and filament number as below the 3dtex, total fiber number is 25～80 weight % of the polyester fiber below the 170dtex.
Polyester fiber is owing to intensity, weatherability and chemical-resistant excellence, and the rugged fabric of the present invention that therefore contains this polyester fiber can use in various uses such as motion dress material, fashion dress material, interior dress material, automobile inside material and advertisement curtain.
The nylon fiber that uses among the present invention is nylon 6 fiber and nylon 66 fiber etc.Wherein, in the occasion of desired strengths such as motion dress material usefulness, preferred nylon 66 fiber.
In addition, the filament number of above-mentioned nylon fiber is below the 4dtex, to be preferably below the 3dtex.As lower limit, be preferably 1dtex.If filament number surpasses 4dtex, the thickness of cloth and silk increases, and therefore might produce fluctuation, bad in the decomposition of polyester fiber.On the other hand, if filament number less than 1dtex, might can not get high concentration when painted.In addition, as total fiber number, below 110dtex, be preferably below the 78dtex.As lower limit, be preferably 11dtex, more preferably 33dtex.If total fiber number surpasses 110dtex, the thickness of cloth and silk increases, and with above-mentioned same, the decomposition to polyester fiber exerts an influence thus.On the other hand, if total fiber number less than 11dtex, the intensity of cloth and silk is low, recess might rupture.
The polyester fiber that uses among the present invention comprises the polyester fiber that formed by polyethylene terephthalate etc. and the cationic dyeable polyester fiber of normal pressure type or high-pressure type.Wherein, from the repeatability and the excellent aspect of colorfastness of look, the cationic dyeable polyester fiber of preferred high-pressure type.
In addition, the filament number of above-mentioned polyester fiber below 3dtex, is preferably below the 2dtex.As lower limit, be preferably 0.1dtex, more preferably 0.7dtex.If filament number surpasses 3dtex, decompose fully sometimes and remove the difficulty that becomes, visually, on the sense of touch or have problems on the function.On the other hand, if filament number less than 0.1dtex, might can not get high concentration when painted.In addition, as total fiber number, below 170dtex, be preferably below the 110dtex.As lower limit, be preferably 22dtex, more preferably 56dtex.If total fiber number surpasses 170dtex, the thickness of cloth and silk increases, and with above-mentioned same, the decomposition of polyester fiber is exerted an influence.In addition, the total fiber number of polyester fiber is preferably set to 1～3 times of total fiber number of nylon fiber, more preferably is set at 1.2～2.5 times.If be this scope, can also form distinct space pattern, in addition, polyester fiber is carried out can obtaining distinct chromatic pattern when painted under situation the about color of nylon fiber not being adjusted.
The total fiber number of above-mentioned nylon fiber and polyester fiber can be according to the purposes decision of cloth and silk of the present invention.For example, when being used for the lining shirt, preferred nylon fiber is below the 60dtex, polyester fiber is 30～60dtex, and when being used for about match, golf shirt and other easily broken classes (カ Star ト ソ one) cloth and silk, preferred nylon fiber is below the 90dtex, polyester fiber is 55～170dtex, be used to race and warm-up time spent of tennis, preferred nylon fiber is below the 80dtex, and polyester fiber is 30～170dtex.
These nylon fibers and polyester fiber are preferably processed to the Taslan yarn or cladded yarn uses.Adopt these processing, can give cloth and silk and change, can be fit for various uses and use.
As above-mentioned cladded yarn, with nylon fiber as heart yarn, polyester fiber is used as the sheath yarn.At this moment, be preferably below the 110dtex as the total fiber number of the nylon fiber of heart yarn, more preferably below the 78dtex.As lower limit, be preferably 22dtex.If the total fiber number of heart yarn surpasses 110dtex, the thickness of cloth and silk increases, and with above-mentioned same, might produce harmful effect to the decomposition of polyester fiber.When using polyester fiber as the sheath yarn, its filament number is preferably below the 2.5dtex, more preferably below the 1.5dtex.As lower limit, be preferably 0.1dtex.If filament number surpasses 2.5dtex, there is the tendency that extremely descends in the decomposability of polyester fiber.Total fiber number is preferably 30～170dtex.If total fiber number is less than 30dtex, in order to suppress to expose as the pinprick of the nylon fiber of heart yarn, the number of times of Bao Xin increases, and the feel of cloth and silk is tended to hardening, if surpass 170dtex, there is the tendency that can not well carry out in the decomposition of polyester fiber.
In the cloth and silk that uses among the present invention, nylon fiber is 20～75 weight %, and polyester fiber is 25～80 weight %, and preferred nylon fiber is 30～70 weight %, and polyester fiber is 30～70 weight %.If nylon fiber is more than 75 weight %, promptly polyester fiber lacks than 25 weight %, and space pattern can not show clearly, if nylon fiber lacks than 20 weight %, be that polyester fiber surpasses 80 weight %, the intensity of the part that polyester fiber is decomposed reduces significantly, can not keep cloth and silk.
Moreover nylon fiber that uses among the present invention and polyester fiber can adopt blending, mix fibre, hand over combination such as the method for twisting with the fingers, interweave or hand over volume.Moreover, the cloth and silk that uses among the present invention preferably constitutes by 2 kinds of nylon fiber and polyester fiber, but as long as in the scope that does not hinder effect of the present invention, effect, also can contain polyurethanes fiber beyond the nylon fiber, acrylic fiber etc. not because of giving the fiber that the fiber distintegrant decomposes.
As the cloth and silk that uses among the present invention, can enumerate braided fabric, fabric and nonwoven fabric etc., but be not particularly limited.As fabric, can enumerate for example plain cloth, TWILL CLOTH, SATIN AND SATEEN CLOTH etc.As braided fabric, can enumerate for example weft-knitted fabrics such as plain weave thing, ribbed knitting thing and pearl knitting thing, section's braided fabric in the spy, through the suede braided fabric, through compiling tricots such as satin weave thing, chain type braided fabric and liner braided fabric.
Wherein, from forming changeful space pattern aspect, a preferred face that mainly constitutes cloth and silk, the main two-sided braided fabric that constitutes the another side of cloth and silk by Undec fiber by the polyester fiber that decomposes.That is, be layer that forms by polyester fiber and the braided fabric that layer constitutes that forms by nylon fiber.For the gimmick that forms two-sided braided fabric, can be known method, be not particularly limited, wherein tube knitting plaiting gimmick (being also referred to as plating-knitted) in garden is because intensity keeps excellent, and the balling-up that washing waits abrasion to produce is few, and is therefore preferred.In addition, as the shape of base cloth, from the aspect of good hand touch, preferred raised fabric having.So-called raised fabric having is meant that the substrate tissue is made of braided fabric or nonwoven fabric, has the cloth and silk of pilomotor fibers.Moreover, owing to also piloerection is called fine hair, so raised fabric having is also referred to as Pile cloth.
Its thickness is preferably below the 5mm, more preferably below the 3mm.As lower limit, be preferably 0.5mm, more preferably 1mm.If thickness surpasses 5mm, be easy to generate the fluctuation of impregnability of the China ink of decomposing polyester fibrid described later, the decomposition of polyester fiber is removed and is had the inadequate tendency that becomes.If thinner than 0.5mm, exist be difficult to visually with sense of touch on clearly performance implemented the tendency of the part of space pattern.
Manufacture method of the present invention comprises the operation that above-mentioned cloth and silk is given the fiber distintegrant with ink-jetting style.
As above-mentioned fiber distintegrant, can enumerate guanidine salt of weak acid, phenols, alcohols, alkali metal hydroxide and alkaline-earth metal hydroxide etc.Wherein, big from the concave-convex effect that obtains, setting out preferred guanidine salt of weak acid aspect environment and the safe face excellence.Wherein, comparing with other highly basic such as caustic soda, reach 10～13 because the pH of the aqueous solution is low, sets out in operational security, the device aspect that is difficult for being corroded, and fiber is carried out when painted being set out in the little aspect of influence of the pigment that uses etc., especially preferably guanidine carbonate.As adopting this guanidine carbonate, think that by inference in the heat treatment step that carries out, guanidine carbonate is broken down into urea and ammonia, thereby becomes highly basic after giving guanidine carbonate with the reason that polyester fiber decomposes.
As the administered dose of above-mentioned fiber distintegrant, preferred 1～50g/m 2Scope, more preferably 5～30g/m 2If administered dose compares 1g/m 2Few, there is the tendency that is difficult to obtain sufficient concave-convex effect, if the opposite 50g/m that surpasses 2,, therefore exist to become expensive tendency owing to be necessary above amount.
In addition, from stablizing the ejection aspect for a long time, preferably above-mentioned fiber distintegrant is carried out water-soluble and use.In this case, as the concentration of fiber distintegrant, the scope of preferred 10～35 weight %, the more preferably scope of 15～30 weight %.If lack than 10 weight %, existence can not obtain the tendency of sufficient concave-convex effect, if surpass 35 weight %, because near the solubility limit of fiber distintegrant in water, therefore become the reason of spray nozzle clogging such as precipitate generation, existence can not be stablized the tendency of ejection for a long time.
Contain the viscosity of the China ink (hereinafter referred to as fiber decomposability China ink) of above-mentioned fiber distintegrant, under 25 ℃, be preferably 1～10cps, more preferably 1～5cps.If less than 1cps, there is the tendency of the clear-cut difference of space pattern in the ink droplet of ejection in the middle division of circling in the air, if surpass 10cps, because the viscosity height, so exist from the tendency of the black difficulty that becomes of nozzle ejection.
The fiber distintegrant carried out water-soluble and when using,, preferably make it contain urea in order stably to be dissolved in water.Because to little as the important viscosity of inkjet, ink, capillary influence, urea is the most suitable.As content of urea, the scope of preferred 0.1～10 weight %, the more preferably scope of 0.5～5 weight %.If urea lacks than 0.1 weight %, lack effect as lytic agent, there is the tendency of the reason that becomes nozzle blockage, if surpass 10 weight %, there is space pattern as the cloth and silk of the original purpose inadequate tendency that becomes.
And then, from preventing nozzle air obstruction aspect, preferably make it contain at least a kind in the surfactant of oxirane that has been selected from polyalcohol, polyol derivative and addition.As its content, the scope of preferred 0.1～10 weight %, the more preferably scope of 0.5～5 weight %.If lack than 0.1 weight %, the air bound of nozzle prevents that effect from reducing, and has the tendency that becomes the China ink that causes air bound easily, if surpass 10 weight %, China ink becomes high viscosity, has the tendency that sprays the difficulty that becomes from nozzle.
As operable polyalcohol or polyol derivative among the present invention, can enumerate for example glycerine, diethylene glycol (DEG), diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, triethylene glycol, triglyme, triethylene glycol monomethyl ether, propylene glycol, propylene glycol monomethyl ether, dipropylene glycol, tripropylene glycol, 1, ammediol, polyethylene glycol, Polyethylene glycol dimethyl ether etc.
As operable surfactant among the present invention, the ethylene oxide adduct of preferred nonionic and cationic surfactant.Reason is, the anionic surfactant might be in existing problems aspect the compatibility of fiber distintegrant and foaming characteristic.
As addition the nonionic surfactant of oxirane, can enumerate ester type nonionic surfactants such as Etheric ester type nonionic surfactant, cithrols such as ether type nonionic surfactant, poly(ethylene oxide) fatty acid glyceride such as polyethylene oxide alkyl ethers etc.
In addition, as addition the cationic surfactant of oxirane, can enumerate the ethylene oxide adduct of aliphatic amine salt, aliphatic quaternary ammonium salt etc.
Wherein, from the excellent in safety aspect of operation, more preferably propylene glycol.In addition, from the stable high aspect alkaline aqueous solution, the more preferably ethylene oxide adduct of aliphatic quaternary ammonium salt.
In addition, above-mentioned surfactant, special preferred number average molecular weight is the low viscous surfactant below 5000.If number-average molecular weight is more than 5000, the viscosity of China ink raises, and has the tendency of the ejection stability that lacks China ink.
In above-mentioned fiber decomposability China ink, can add other dryings as required and prevent agent, preservative agent and water colo(u)r etc.
Adopt ink-jetting style to give above-mentioned cloth and silk with above-mentioned fiber decomposability China ink.By using ink-jetting style, can freely regulate the concavo-convex degree of depth, width.In addition, do not have the restriction of the such decorative pattern of stamp type yet, can freely show the space pattern of the densification of 1 pixel level.And then, owing to can change the concavo-convex degree of depth at leisure, except can expression range, can also show the iridescence decorative pattern of concavo-convex generation with the mode of in the past employing roller, silk screen.In addition, except the time goes up, on the cost and the operation, does not produce a large amount of drainings, therefore aspect environment also than in the past mode excellence.
The ink-jet printed device that uses among the present invention, in order to prevent that the fiber distintegrant is because of thermogenetic decomposition with using chemically-reactive dyes as the painted hydrolysis that the response gene heating of chemically-reactive dyes produces during with China ink described later, so long as the mode that China ink is heated not then is not particularly limited.Can use for example continuation modes such as electric charge modulation system, charged spray regime, little point mode and ink mist mode, piezoelectric transduction mode and electrostatic attraction mode etc. are any way such as mode as required.Wherein, from the stability and the excellence of ejection property continuously of black spray volume, can set out preferred piezoelectricity mode to carry out manufacture view at a low price.
Wherein, before adopting ink-jetting style to give the operation of fiber distintegrant, preferably be contained in the operation that forms black receptive layer on the above-mentioned cloth and silk to above-mentioned cloth and silk.The black receptive layer of Xing Chenging is owing to accept and stop moderately it to be kept fiber decomposability China ink from nozzle ejection instantaneously like this, can prevent that therefore spreading and sinking in of fiber decomposability China ink from oozing.
Above-mentioned black receptive layer is accepted agent by the China ink that with the water soluble polymer is main component usually and is formed.As water soluble polymer, can enumerate for example sodium alginate, methylcellulose, Carboxymethyl Cellulose, carboxymethyl cellulose, starch, heal sore glue, polyvinyl alcohol and polyacrylic acid etc.These can be used in combination more than 2 kinds.Wherein, preferred alkali resistance excellence, price is low and the carboxymethyl cellulose of mobile excellence.In black receptive layer, can contain anti-reducing agent, surfactant, preservative agent, fast light improving agent etc. as required.
Convert with solid constituent, preferably give 1～20g/m 2Above-mentioned China ink is accepted agent, more preferably 2～10g/m 2If administered dose compares 1g/m 2Few, because black competence power is poor, so the existence China ink is spread and sunk in or the tendency of ink bleed, if surpass 20g/m 2, because the cloth and silk hardening, therefore the conveying that exists in the ink-jet printer becomes bad, is held the tendency that agent comes off from cloth and silk easily when perhaps operating.
In addition, it gives method and can enumerate dip-nip method, rotary screen method, scraper rubbing method, touch roll rubbing method and gravure roll rubbing method etc.Wherein,, China ink can be subjected to hold layer and give cloth and silk integral body, can make the cloth and silk aspect of black competence power excellence and set out, preferred dip-nip method from cloth and silk surface not only.
Preferably when giving above-mentioned fiber distintegrant, give the China ink (hereinafter referred to as the painted China ink of polyester fiber) that can make polyester fiber painted and/or can make the painted China ink of nylon fiber (hereinafter referred to as the painted China ink of nylon fiber).That is, the preferred device for ink of preparing to possess above-mentioned fiber decomposability China ink, the painted China ink of polyester fiber and the painted China ink of nylon fiber according to the form and aspect and the concentration of the decorative pattern that no concave-convex, recess and protuberance are arranged, suitably selects China ink to carry out stamp.Can think painted chromatic pattern on the concave surface of difficulty on the same cloth and silk thus in the past, can only carry out simultaneously the painted processing of concavo-convex processing, concavo-convex processing and recess, the only painted processing of polyester fiber and the various processing such as painted processing of nylon fiber and polyester fiber.
More particularly, when on cloth and silk, showing space pattern, select fiber decomposability China ink, carry out stamp.In addition, when its recess performance chromatic pattern, select the painted China ink of nylon fiber, stamp is carried out in the position identical with fiber decomposability China ink.In addition, when not needing space pattern, only polyester fiber when painted, is selected the painted China ink of polyester fiber, carry out stamp.When painted nylon fiber only, select the painted China ink of nylon fiber, carry out stamp.According to the cloth and silk that uses, when only any fiber being carried out when painted, the chromatic pattern that obtains sometimes produces that pinprick exposes, light color is fuzzy etc., and it is bad to become on the quality.In this case, on same position, use painted China ink separately to carry out stamp, carry out painted to polyester fiber and nylon fiber simultaneously.
As the painted China ink of above-mentioned polyester fiber, the DISPERSE DYES aqueous dispersion of fastness, distinctiveness and color emissivity excellence can mainly be used and the China ink that obtains.In addition, the China ink that the pigment aqueous dispersion is obtained can be used, perhaps when using cationic-dyeable type polyester fiber, the China ink that cation dyes water-soluble or aqueous dispersion are obtained can be used.
As the painted China ink of above-mentioned nylon fiber, can use chemically-reactive dyes, ACID DYES or metal complex salt type dye water-soluble and the China ink that obtains.The kind of chemically-reactive dyes preferably has at least 1 a kind of chemically-reactive dyes as reactive group that is selected from a chlorotriazine base, a Cyanuric trifluoride base, difluoro one chlorine pyrimidine radicals and the trichloropyrimidine base etc.Chemically-reactive dyes with other reactive groups is easy to generate hydrolysis under alkali atmosphere, when mixing on cloth and silk with the China ink of fibre-bearing distintegrant, reactive group decomposes, on nylon fiber the possibility height that reduces of colour saturation.
As a chlorotriazine type chemically-reactive dyes, can enumerate for example Kayacion (Japanese chemical drug (strain) system), Cibacron (Ciba Specialty Chemicals system), Drimarene P (Clariant system), Procion P (DyStar society system) and KP CION (recording and chemical industry (strain) system) etc.As a Cyanuric trifluoride type chemically-reactive dyes, can enumerate for example CIBACRON F (Ciba Specialty Chemicals system) etc.As difluoro one chlorine pyrimidine Type chemically-reactive dyes, can enumerate for example Levafix E-A (DyStar system) etc.As trichloropyrimidine type chemically-reactive dyes, for example commercially available with Drimarene X trade names such as (Clariant systems).
Above-mentioned painted China ink is the combination that is dissolved or dispersed in the China ink that obtains in the water with the various concentration levels of various looks, suitably selects to use according to form and aspect, the concentration of decorative pattern portion.Therefore, color is not particularly limited.General is has added black in yellow, pinkish red, blue or green this 3 primary colors and has possessed the China ink of at least 4 looks, but is not limited thereto.Equally, painted content with pigment also is not particularly limited, if but consider practicality, storage stability and ejection stability, with respect to painted China ink, be preferably 0.1～25 weight %.If pigment content is lower than 0.1 weight %, because of the difference of base coat colour concentration, the concentration of painted China ink is crossed low and is not had meaning.If surpass 25 weight %, because China ink becomes high viscosity, perhaps dissolubility becomes bad etc., therefore has the tendency of ejection poor stability.
Its administered dose also is not particularly limited, preferred 1～50g/m 2, more preferably 5～30g/m 2If administered dose compares 1g/m 2The tendency few, that the possibility that exists the shortcoming of style of calligraphy characterized by hollow strokes shape to produce increases is if surpass 50g/m 2, exist producing spreads and sinks in oozes, the image feint tendency that becomes.
In addition, above-mentioned painted China ink all can contain drying as required and prevent agent, preservative agent, viscosity modifier and ultra-violet absorber etc.
After adopting ink-jetting style to give fiber decomposability China ink and painted China ink as required, heat-treat.By heat-treating, fiber is decomposed, concavo-convex manifesting, when giving painted China ink, carry out painted to fiber.
As heat treated condition, preferably handled about about 10 minutes down at 160～190 ℃.If lower, there be the decomposition of the polyester fiber inadequate tendency that becomes, and particularly have the painted inadequate tendency that also becomes polyester fiber than 160 ℃.If surpass 190 ℃, the painted of nylon fiber become insufficient on the contrary, perhaps be easy to generate fiber and burn and phenomenons such as flavescence.Heat treatment can be any of dry heat treatment or humid heat treatment.Wherein, from become good aspect and carry out at the same time obtaining good aspects such as color emissivity simultaneously when painted of the concaveconvex shape that forms, more preferably adopt damp and hot processing.
And then, carried out after the heat treatment, for make black receptive layer residual on the cloth and silk, the analyte of fixation reaction dyestuff and fiber does not come off from cloth and silk, preferably carries out carrying out washing treatment.For this method for washing and processing, can use common enforcement use the reduction washing etc. of bisulfites, surfactant and soda ash etc.
In addition, preferably when washing, above-mentioned reduction also carries out decrement treatment.
By carrying out decrement treatment,, can be removed when the inadequate part of decomposition of fiber is arranged when residual, and then can form distinct concavo-convex.
Condition as decrement treatment is not particularly limited, and for example, can use reduction promoter 1～5g/L and caustic soda (particle) 2～15g/L, handles 10～60 minutes down for 70～90 ℃ in treatment temperature.
As reduction promoter, can use quaternary cationics, aromatic series quaternary cationics and the heterocyclic quaternary ammonium salt cation surfactant etc. of aliphatic amine salt cationic surfactant, aliphatic amine salt.
Like this, after cloth and silk being given fiber decomposability China ink, heat-treat and carrying out washing treatment, can fully decompose and remove polyester fiber.
Manufacturing method according to the invention can make by the cloth and silk of the clear-cut of the part of concavo-convex processing and recess flatness excellence.In addition, by giving painted China ink simultaneously, can be to having implemented the part performance chromatic pattern of concavo-convex processing, can access recess protuberance decorative pattern part separately distinctiveness and heavy colour excellence, have the jet recorded matter on fabric of high-grade space pattern.In addition, owing to adopt ink-jetting style to give China ink, so economy and environment adaptability are also excellent.
In addition, the rugged fabric that adopts manufacture method of the present invention to obtain, have because of giving the cloth and silk that the fiber distintegrant decomposes fiber of removing (polyester fiber) and the fiber (nylon fiber) that does not make its decomposition owing to used with specific ratio combination, the interface of male and fomale(M﹠F) is very distinct.In addition, owing to adopt ink-jetting style to give above-mentioned fiber distintegrant, therefore not only merely give difference of height as in the past, and can obtain clear-cut and the more excellent space pattern of recess flatness.In addition, because physics performances such as flexible poor, intensity difference, venting quality difference also become possibility, so can access more changeful space pattern.
Embodiment
Below enumerate embodiments of the invention and comparative example, the present invention is specifically described, but the present invention is not limited by following embodiment." % " expression " weight % " in embodiment, the comparative example should be described.
Production Example 1
(making of cloth and silk A)
Use the cationic dyeable polyester fiber (east beautiful (strain) system, filament number 1.2dtex, 84dtex/72f) of nylon 66 fiber (east beautiful (strain) system, filament number 1.4dtex, 36dtex/26f) and high-pressure type, two-sided (plain weave half full cardigan fabric) tissue by through compiling obtains the compound cloth and silk of being made up of nylon fiber 43.0 weight %, polyester fiber 57.0 weight % (thick 1mm).Moreover a face of the cloth and silk that obtains is made of polyester fiber, and another side mainly is made of nylon fiber, and the giving of China ink described later carried out the face that is made of polyester fiber.
Then, adopting the dip-nip method to give treatment fluid to the compound cloth and silk that obtains makes to convert by solid constituent and reaches 2g/m 2, described treatment fluid passes through following composition is mixed, and the use homogenizer stirred 1 hour and obtained, and drying is 2 minutes under 170 ℃, has obtained forming the compound cloth and silk A of black receptive layer.
Treatment fluid
DKSファィンガム(fine gum)HEL-1 2％
(the first industrial pharmacy (strain) system, etherificate carboxymethyl cellulose)
MS liquid 5%
(bright one-tenth chemical industry (strain) system, nitrobenzene-sulfonic acid salt, anti-reducing agent, active ingredient 30%)
Water 93%
Production Example 2
(making of cloth and silk B)
Use nylon 6 fiber (east beautiful (strain) system, filament number 3.3dtex, 78dtex/24f) and polyester fiber (east beautiful (strain) system, filament number 0.46dtex, 66dtex/144f), by the deer point pattern tissue of the knitting plaiting gimmick of employing garden tube, obtain the compound cloth and silk of forming by nylon fiber 49.4 weight %, polyester fiber 50.6 weight % (thick 2mm).Moreover a face of the cloth and silk that obtains is made of polyester fiber, and another side is made of nylon fiber, and the giving of China ink described later carried out for the face that is made of polyester fiber.
Similarly on the cloth and silk that obtains, form black receptive layer with Production Example 1, obtain compound cloth and silk B.
Production Example 3
(making of cloth and silk C)
Except making polyester fiber is the 100 weight %, obtains cloth and silk similarly to Example 1.Similarly on the cloth and silk that obtains, form black receptive layer with Production Example 1, obtain cloth and silk C.
Production Example 4
(making of cloth and silk D)
Use cotton fiber (day clear weaving (strain) system, 40 numbers) and polyester fiber (Supreme Being people's (strain) system, filament number 2.3dtex, 84dtex/36f), two-sided (plain weave half full cardigan fabric) tissue by through compiling obtains the compound cloth and silk of being made up of cotton fiber 63 weight %, polyester fiber 37 weight % (thick 2mm).Moreover a face of the cloth and silk that obtains is made of polyester fiber, and another side is made of cotton fiber, and the giving of China ink described later carried out for the face that is made of polyester fiber.
Similarly on the cloth and silk that obtains, form black receptive layer with Production Example 1, obtain compound cloth and silk D.
Production Example 5
(making of cloth and silk E)
Use the cationic dyeable polyester fiber (east beautiful (strain) system, filament number 1.2dtex, 84dtex/72f) of nylon 6 fiber (east beautiful (strain) system, filament number 3.1dtex, 22dtex/7f) and high-pressure type, two-sided (chain stitch) tissue by through compiling obtains the compound cloth and silk of being made up of nylon fiber 40.0 weight %, polyester fiber 60.0 weight % (thick 1.2mm).Moreover a face of the cloth and silk that obtains is made of polyester fiber, and another side mainly is made of nylon fiber, and the giving of China ink described later carried out the face that is made of polyester fiber.
Similarly on the cloth and silk that obtains, form black receptive layer with Production Example 1, obtain compound cloth and silk E.
Production Example 6
(modulation of fiber decomposability China ink a)
Following composition is mixed, use agitator to stir after 1 hour, behind ADVANTEC high-purity filter paper No.5A (Japan's filter paper (strain) system) filtration under diminished pressure, carry out vacuum outgas and handle, obtain fiber decomposability China ink a.Moreover the viscosity under 25 ℃ is 3cps.
Fiber decomposability China ink a
Guanidine carbonate (fiber distintegrant) 20%
Urea (steady dissolution agent) 5%
Diethylene glycol (DEG) (anti-drying dose) 5%
Water 70%
Production Example 7
(modulation of fiber decomposability China ink b)
Following composition is mixed, use agitator to stir after 1 hour, behind ADVANTEC high-purity filter paper No.5A (Japan's filter paper (strain) system) filtration under diminished pressure, carry out vacuum outgas and handle, obtain fiber decomposability China ink b.Moreover the viscosity under 25 ℃ is 2cps.
Fiber decomposability China ink b
NaOH (fiber distintegrant) 10%
Urea 5%
Water 85%
Production Example 8
(modulation of the painted 3 primary colors China ink of polyester fiber combination I)
Following composition is mixed, use homogenizer to stir after 1 hour, behind ADVANTEC high-purity filter paper No.5A (Japan's filter paper (strain) system) filtration under diminished pressure, carry out vacuum outgas and handle, obtain the painted 3 primary colors China ink of polyester fiber combination I.
The painted 3 primary colors China ink of polyester fiber combination I
(Lan Mo)
Kiwalon Polyester Blue BGF 10％
(discipline and chemical industry (strain) system, DISPERSE DYES, C.I. disperse blue 73)
Disper TL 2％
(bright one-tenth chemical industry (strain) system, anionic species surfactant)
Diethylene glycol (DEG) 5%
Water 83%
(red China ink)
Kiwalon Polyester Red BFL 10％
(discipline and chemical industry (strain) system, DISPERSE DYES, C.I. disperse red 92)
Disper TL 2％
Diethylene glycol (DEG) 5%
Water 83%
(Huang Mo)
Kiwalon Polyester Yellow 6GF 10％
(discipline and chemical industry (strain) system, DISPERSE DYES, C.I. disperse yellow 114)
Disper TL 2％
Diethylene glycol (DEG) 5%
Water 83%
Production Example 9
(modulation of the painted 3 primary colors China ink of nylon fiber combination II)
Following composition is mixed, use agitator to stir after 1 hour, behind ADVANTEC high-purity filter paper No.5A (Japan's filter paper (strain) system) filtration under diminished pressure, carry out vacuum outgas and handle, obtain the painted 3 primary colors China ink of nylon fiber combination II.
The painted 3 primary colors China ink of nylon fiber combination II
(Lan Mo)
Cibacron Blue P-3R liq.40％ 40％
(CibaSC society system, C.I. reactive blue 49, a chlorotriazine type chemically-reactive dyes)
Urea (steady dissolution agent) 5%
Water 55%
(red China ink)
Kayacion Red P-4BN liq.33％ 50％
(Japanese chemical drug (strain) system, C.I. reactive red 3: 1, a chlorotriazine type chemically-reactive dyes)
Urea 5%
Water 45%
(Huang Mo)
Cibacron Yellow P-6GS liq.33％ 50％
(CibaSC society system, C.I. reactive yellow 95, a chlorotriazine type chemically-reactive dyes)
Urea 5%
Water 55%
Production Example 10
(modulation of the mixing 3 primary colors China ink combination III that polyester fiber is used and nylon fiber is used)
On the level of the cohesion that does not produce DISPERSE DYES, sedimentation, following composition is mixed, after using homogenizer to stir at 1 o'clock, behind ADVANTEC high-purity filter paper No.5A (Japan's filter paper (strain) system) filtration under diminished pressure, carry out vacuum outgas and handle, obtain the mixing 3 primary colors China ink combination III that polyester fiber is used and nylon fiber is used.
Mix 3 primary colors China ink combination III
(Lan Mo)
Kiwalon Polyester Blue BGF 5％
Cibacron Blue P-3R liq.40％ 10％
Disper TL 2％
Diethylene glycol (DEG) 5%
Water 78%
(red China ink)
Kiwalon Polyester Red BFL 5％
Kayacion Red P-4BN liq.33％ 10％
Disper TL 2％
Diethylene glycol (DEG) 5%
Water 78%
(Huang Mo)
Kiwalon Polyester Yellow 6GF 5％
Cibacron Yellow P-6GS liq.33％ 10％
Disper TL 2％
Diethylene glycol (DEG) 5%
Water 78%
Embodiment 1～5 and comparative example 1～2
On the cloth and silk A～E that in Production Example 1～5, makes, press the combination shown in the table 1, adopt ink-jetting style fiber decomposability China ink a, the b, the China ink combination I～III stamp that obtain in the Production Example 6～10.In stamp portion,, implement the painted processing of painted processing, polyester fiber and nylon fiber of painted processing, the nylon fiber of concavo-convex processing, the painted concavo-convex processing of recess, polyester fiber according to the combination of printing ink.
Table 1
Embodiment Comparative example
1 2 3 4 5 1 2
Cloth and silk A B A B E C D
Fiber decomposability China ink a a b a a b b
The China ink combination I、 II I、 II I、 II III I、 II I III
Ink-jet printed condition is as described below.
Ink-jet printed condition
Printing device: the ink-jet printed device of mode serial scan type as required
Nozzle diameter: 50 μ m
Driving voltage: 100V
Frequency: 5kHz
Resolution: 360dpi
The stamp amount:
(1) the concavo-convex Ministry of worker that adds
Fiber decomposability China ink 40g/m 2
(2) the painted concavo-convex Ministry of worker that adds of recess chromatic pattern
Fiber decomposability China ink 40g/m 2
Nylon fiber painted 3 primary colors China ink combination II 15g/m of all kinds 2
(3) the painted portion of polyester fiber chromatic pattern
Polyester fiber painted 3 primary colors China ink combination I 15g/m of all kinds 2
(4) the painted portion of nylon fiber chromatic pattern
Nylon fiber painted 3 primary colors China ink combination II 15g/m of all kinds 2
(5) the painted portion of the chromatic pattern of polyester fiber and nylon fiber
Mix 3 primary colors China ink combination III 15g/m of all kinds 2
After the cloth and silk drying, use the HT steam generator under 175 ℃, to carry out humid heat treatment 10 minutes.And then in soaping of the bisulfites of the soda ash that contains the ト ラ ィ Port one Le TK of 2g/L (the first industrial pharmacy (strain) system, non-ionic surface active agent), 2g/L, 1g/L bathed, 80 ℃ handled 10 minutes down and after the washing, wash, dry and obtain jet recorded matter on fabric.
Decorative pattern portion for obtaining jet recorded matter on fabric in the foregoing description 1～5 and the comparative example 1～2 estimates following project.Show the result in the table.
(1) concavo-convex clear-cut, concave surface flatness
Use magnifying glass, according to the clear-cut and the concave surface flatness at the concavo-convex interface of the visual judgement of following benchmark.
Zero concavo-convex interface distinctness, concave surface flatness are also excellent
The concavo-convex interface of △ distinctness, but convex-concave appears in concave surface
* concavo-convex interface is not distinct, and convex-concave also appears in concave surface
(2) distinctiveness, the heavy colour of the chromatic pattern portion of concave surface
The distinctiveness of chromatic pattern adopts visual, and heavy colour use Macbeth RD918 (Gretag Macbeth system) measures anti-body concentration, comprehensively judges according to following benchmark.
Showed chromatic pattern zero distinctness and heavy colour
That △ is coloured to is slightly not distinct, concentration is slightly bad
* not distinct, concentration is bad terrifically
(3) distinctiveness, the heavy colour of the chromatic pattern portion of convex surface
The distinctiveness of chromatic pattern adopts visual, and heavy colour use Macbeth RD918 (Gretag Macbeth system) measures reflection density, comprehensively judges according to following benchmark.
Zero no pinprick exposes, and has showed chromatic pattern distinctness and heavy colour
△ finds that pinprick exposes, but distinctness and heavy colour showed chromatic pattern
* find that pinprick exposes, become performance not distinct and that concentration is bad
Table 2
Example Comparative example
1 2 3 4 5 1 2
(1) concavo-convex clear-cut, concave surface flatness ○ △ △ △ △ × △
(2) distinctiveness, the heavy colour of the chromatic pattern portion of concave surface ○ ○ △ △ ○ × ×
(3) distinctiveness, the heavy colour of the chromatic pattern portion of convex surface ○ △ ○ △ △ ○ ×
According to the present invention, can provide by the clear-cut of the part of concavo-convex processing and recess flatness excellence, form the manufacture method of the rugged fabric of changeful space pattern.In addition, can also provide the recess also manufacture method of the rugged fabric of painted chromatic pattern freely.

Claims (7)

1. the manufacture method of a rugged fabric, it comprises with ink-jetting style and gives the operation of fiber distintegrant to cloth and silk that it is that 4dtex is following, total fiber number is following nylon fiber 20～75 weight % of 110dtex and filament number is that 3dtex is following, total fiber number is following polyester fiber 25～80 weight % of 170dtex that described cloth and silk comprises filament number.
2. the manufacture method of rugged fabric according to claim 1 wherein, when giving above-mentioned fiber distintegrant, gives to make the painted China ink of polyester fiber and/or can make the painted China ink of nylon fiber.
3. the manufacture method of rugged fabric according to claim 1 and 2, wherein, above-mentioned fiber distintegrant is the guanidine salt of weak acid.
4. the manufacture method of rugged fabric according to claim 3, wherein, above-mentioned guanidine salt of weak acid is a guanidine carbonate.
5. according to the manufacture method of claim 1,2,3 or 4 described rugged fabrics, wherein, above-mentioned cloth and silk is two-sided braided fabric.
6. the manufacture method of rugged fabric according to claim 5, wherein, the above-mentioned two-sided braided fabric employing garden knitting plaiting gimmick of tube forms.
7. rugged fabric that adopts claim 1,2,3,4,5 or 6 described manufacture methods and obtain.
CN200680001603A 2005-01-14 2006-01-12 Process for producing rugged fabric Expired - Fee Related CN100585066C (en)

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CN102926226A (en) * 2012-10-31 2013-02-13 浙江港龙织造科技有限公司 Printing process for elastic fiber fabric
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CN102926226A (en) * 2012-10-31 2013-02-13 浙江港龙织造科技有限公司 Printing process for elastic fiber fabric
CN102926228A (en) * 2012-10-31 2013-02-13 浙江港龙织造科技有限公司 Treating fluid for elastic fiber fabric
CN102926226B (en) * 2012-10-31 2014-07-23 浙江港龙织造科技有限公司 Printing process for elastic fiber fabric
CN102926228B (en) * 2012-10-31 2014-07-23 浙江港龙织造科技有限公司 Treating fluid for elastic fiber fabric
CN102912657B (en) * 2012-10-31 2014-09-17 浙江港龙织造科技有限公司 Embossed elastic fiber fabric
CN115354438A (en) * 2018-05-11 2022-11-18 耐克创新有限合伙公司 Textile comprising yarns having different material compositions at different areas of the textile surface

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