CN101085876A - Solid pigment preparations - Google Patents
Solid pigment preparations Download PDFInfo
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- CN101085876A CN101085876A CNA2007101102534A CN200710110253A CN101085876A CN 101085876 A CN101085876 A CN 101085876A CN A2007101102534 A CNA2007101102534 A CN A2007101102534A CN 200710110253 A CN200710110253 A CN 200710110253A CN 101085876 A CN101085876 A CN 101085876A
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- ketone
- pigment
- pigment preparation
- solid pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0092—Dyes in solid form
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/006—Preparation of organic pigments
- C09B67/0063—Preparation of organic pigments of organic pigments with only macromolecular substances
Abstract
The invention relates to solid pigment preparations consisting of at least one pigment and a resin, to their production processes and to their use in paints, varnishes, adhesives or inks.
Description
Technical field
The present invention relates to the solid pigment preparation formed by at least a pigment and resin, its preparation method and its application in colorant, paint vehicle, tackiness agent, ink or printing-ink.
Background technology
These solid pigment preparations are applied in the coating, and for example colorant, paint vehicle, tackiness agent, ink or printing-ink for example are used for the coating by metal and the made article of plastics.These coating substance compositions are suitable for all conventional application methodes, and it can be used in modern washing industry and plastic coat industry and the printing-ink industry, in for example spraying, electrostatic spraying and the printing by the different printing method.
Typically by preparing pigment preparation earlier, then the mode with former lacquer (Stammlack) coating (auflacken) prepares Color paint.
In liquid medium, disperse filler and pigment during the preparation pigment preparation.This adopts dispersion agent to implement usually, thereby makes solid effectively disperse the mechanical shear stress of needs with reduction, realizes high as far as possible fill level simultaneously.Dispersion agent has promoted the decomposition of aggregate, and surface wetting as surface active cpd and/or that dispersed particle is treated in coating, makes these particle-stabilisedization to avoid disadvantageous reagglomeration.
In the production of colorant and paint vehicle, wetting agent and dispersion agent have promoted the introducing of pigment and filler, and it has determined the visual appearance and the physicochemical property of coating substantially as important recipe ingredient.For realizing its best applications, these solids must be dispersed in paint vehicle and the colorant on the one hand, in case dispersed obtains then must be stable on the other hand.In many cases, the function of stabilization component also can realize by binder ingredients.Because this class tackiness agent is to the contribution of faster drying and the increase of film former hardness, they also are the important component of coating.
For solvent-laden coating, serve as the solvent-laden pigment preparation of basis preparation with various wetting agents and dispersion agent usually, itself and the various former lacquer of solvent that contains apply.For water-borne coatings, serve as basis preparation aqueous pigment preparations also usually with various wetting agents and dispersion agent, it applies with the former lacquer of different water-baseds.
For fear of since a large amount of pigment preparations that preparation and storage produced was expensive, developed have with the general consistency of tackiness agent and in organic solvent deliquescent pigment preparation.This for example record to some extent in DE4404809 of pigment preparation based on ketone resin.The polyalkylene oxide that EP1078946 discloses block copolymerization is used in the universal pigment preparation as dispersion agent, and it can be adjusted to both moisture, contains solvent again.Disclosed universal pigment ingredients preparation in DE102005012316, it is based on the polyalkylene oxide that contains Styrene oxide 98min. of block copolymerization and the combination of ketone resin, and it has extensive consistency and the solvability in used organic solvent and water with adhesive therefor equally.In addition, suppressing foam in aqueous pigment preparations forms.
Except water, organic solvent and dispersion agent, all these liquid pigment preparations generally can contain other auxiliary agents, for example anti-drying dose, rheologic additive, anti-peeling agent, biocide or improve the preparation of frost resistance.For fear of the operability of these auxiliary agents and the colo(u)rant dispersion of consumes energy and time, developed solid pigment preparation, it can be incorporated in the solution of water or organic solvent by simple agitation.EP702055 discloses colo(u)rant dispersion in the high-molecular weight organic binder bond, and promptly so-called stir-in pigment is in order to prepare the painted coatings volatile organic compounds that contains.But this pigment is unsettled for reagglomeration, thereby for example can not avoid interference reliably owing to form fritter.
In EP702062 disclosed pigment preparation through the conditioning.But, for the structure (Textur) of improving pigment, can use the inorganic salt of Gum Rosin, it can be distributed in the pigment preparation on the one hand and can cause interference in organic coating.On the other hand, dispersion agent is not best, thereby when using phthalocyanine pigment, it is wet-milling repeatedly.
The vinyl pyrrolidone homopolymer or the multipolymer that are used to prepare the stir-in pigment preparation are disclosed in EP902061.This pigment preparation is particularly suitable for carrying out painted to aqueous industrial paint vehicle or solvent-free plastics.
DE10256416 discloses solid pigment preparation, and it is by pigment dyestuff, functionalized pigment derivative and be selected from nonionic polyoxyalkylene or the water-soluble surface-active additives of its special derivative is formed.But these additives are different with the additive that uses in pigment preparation of the present invention.
US6734231 discloses the method that is used to prepare color compositions, and it is by hybrid pigment and urea-formaldehyde resin or urea ketone resin and extrude subsequently and prepare.But this resin is different with the resin that uses in pigment preparation of the present invention.
EP432480 discloses the masterbatch that mixes three kinds of basic ingredient preparations: a) acrylate resin, ketone resin or urea formaldehyde, b) citrate, acetyl citrate or tartrate and c) dyestuff and/or pigment and additive.But the use of citrate, acetyl citrate or tartrate can throw into question when ground pigment.
WO2004/078852 discloses a kind of pigment preparation, and wherein, organic pigment particle in small, broken bits combines with inorganic pigment granules, and in addition, these particles have the organic macromolecule coating.
Summary of the invention
The present invention based on task be to find such solid pigment preparation, it is formed simple as far as possible and owing to be easy to disperse to be distributed in the dissimilar employing media especially, especially is distributed in the liquid medium of employing by simple agitation (admixing).By in containing solvent or solvent-free application, using solid pigment preparation, can demonstrate high colour intensity and flocculation stability.
Astoundingly, the present invention based on task can be resolved by using at least a not carbonyl hydrogenated ketone resin and/or not carbonyl hydrogenated ketone/urea formaldehyde to combine with at least a pigment.
Be surprisingly found out that this solid pigment preparation can be sneaked into easily and be contained solvent or solventless coatings.It is easy to be dissolved in organic solvent or the adhesive melt.It demonstrates the consistency with multiple tackiness agent.Gained coating has extraordinary flowability (Verlauf).
Theme of the present invention is a solid pigment preparation, and it consists essentially of:
A) at least a pigment of 40-99 weight %,
B) at least a not carbonyl hydrogenated ketone resin and/or the not carbonyl hydrogenated ketone/urea formaldehyde of 1-60 weight %,
C) at least a mineral filler of 0-50 weight %,
Component A), B) and C) the weight amount summation be 100 weight %.
As component A) can use organic or inorganic pigment and carbon black.
Admissible pigment dyestuff is an azo pigment for example, azomethine pigment, metal complex pigments, anthraquinone pigment, phthalocyanine pigment encircles pigment more, thioindigo particularly, quinacridone, two piperazines, pyrrolo-, naphthalene tetracarboxylic acid ， perylene, indanthrone, Isoamidolin (on), isoindolinone, flavanthrone, many rings pigment of pyranthrone or isoviolanthrone series.The mixture of these pigment or Solid solution also are feasible.Particularly suitable pigment is selected from azo, two piperazines, pyrrolo-(particularly diketopyrrolo-pyrrole pigment), quinacridone, phthalocyanine, indanthrone or isoindolinone pigment.Fit closely pigment dyestuff is those that put down in writing in Color Index.Comprise, for example, C.I. Pigment red 202, C.I. pigment red 122, C.I. Pigment red 144, C.I. Pigment red 170, C.I. Pigment red 177, C.I. Pigment red 179, C.I. Pigment red 254, C.I. Pigment red 255, C.I. Pigment red 264, C.I. pigment brown 23, C.I. pigment yellow 13, C.I. Pigment Yellow 73 74, C.I. pigment yellow 83, C.I. Pigment Yellow 73 109, C.I. Pigment Yellow 73 110, C.I. pigment yellow 147, C.I. Pigment Yellow 73 191.1, C.I. pigment orange 48, C.I. pigment orange 49, C.I. pigment orange 61, C.I. pigment orange 71, C.I. pigment Blue 15, C.I. pigment blue 60, C.I. pigment violet 19, C.I. pigment Violet 23, C.I. pigment violet 37, C.I. pigment Green 7, C.I. pigment green 36.
The example of suitable mineral dye is independent or form of mixtures, metal oxide, blended metal oxide, merimee's yellow, lead chromate, the chromium sulphate lead plumbate, lead molybdate, ultramarine, cobalt blue, manganese indigo plant, chromoxide green, transparent vert emeraude, cobalt green, metallic sulfide, cadmium sulfoselenide, zinc ferrite or pucherite.
As carbon black, independent or form of mixtures is used channel black, flame black or furnace black.In addition, these carbon blacks can be by rear oxidation and/or granulating.
Also can use organic and mineral dye and/or sooty any mixture.
All not carbonyl hydrogenated ketone resins and/or not carbonyl hydrogenated ketone/urea formaldehyde are adapted in the solid pigment preparation as B component in principle) use.
All ketone is suitable as the ketone of preparation ketone resin and ketone/urea formaldehyde, acetone particularly independent or form of mixtures, methyl phenyl ketone, methylethylketone, tertiary butyl methyl ketone, 2-heptanone, propione, methyl iso-butyl ketone (MIBK), cyclopentanone, cyclododecanone, 2,2,4-and 2,4, the mixture of 4-trimethylammonium cyclopentanone, suberone and cyclooctanone, pimelinketone and all have the alkyl substituted cyclohexanone that one or more total carbon atom numbers are the alkyl of 1-8.The example of the alkyl substituted cyclohexanone that can mention comprises 4-tert-pentyl pimelinketone, 2-sec.-butylcyclohexanone, 2-tertiary butyl pimelinketone, 4-tertiary butyl pimelinketone, 2-methylcyclohexanone and 3,3,5-trimethylcyclohexanone.
But, use the institute ketone resin that is useful on and the ketone/urea formaldehyde synthetic ketone described in the document usually, generally be that all C-H-acid ketone is as suitable described ketone.Preferably based on the ketone/urea formaldehyde of following ketone, independent or with the methyl phenyl ketone of form of mixtures, pimelinketone, 4-tertiary butyl pimelinketone, 3,3, the ketone resin of 5-trimethylcyclohexanone and suberone and pimelinketone.
The aldehyde component that is suitable as ketone/urea formaldehyde is aldehyde branching or nonbranched in principle, as formaldehyde, and acetaldehyde, butyraldehyde-n, isobutyric aldehyde, valeral and lauric aldehyde.Usually, the ketone resin synthetic aldehyde that is useful on described in the document all is suitable as described aldehyde.Yet preferred the use separately or the formaldehyde of form of mixtures.
Required formaldehyde is general to be used as the water that is about 20-40 weight % or alcohol (for example methyl alcohol or butanols) solution.Other types of service of formaldehyde, for example Paraformaldehyde 96 or three alkane are feasible equally.Can also with the mixture of formaldehyde in contain aromatic aldehyde, as phenyl aldehyde.
Especially preferably as B component) starting compound be to use separately or with the methyl phenyl ketone of the form of mixtures of formaldehyde, pimelinketone, 4-tertiary butyl pimelinketone, 3,3,5-trimethylcyclohexanone and heptanone.
This ketone-urea formaldehyde is at for example DD12433, DD123481, and DE1256898, DE1300256 is described among DE2831613 and the DE4404809.
Having described molecular weight among the EP902061 is vinyl pyrrolidone homopolymer or the multipolymer of 5000-300000g/mol.Because molecular weight is less than 3000g/mol, ketone resin used in the present invention or ketone/urea formaldehyde have obviously lower molecular weight.
This filler mainly obtains by decomposing, make with extra care, grind the natural generation material that also is classified to particle fraction subsequently.Yet if relate to degree of cleaning (brightness) or degree particularly in small, broken bits, so for example the sintetics of vitriol or carbonate also can be used as filler.Be different from pigment, filler has low opaqueness usually.Except that increasing volume (reducing cost), it also plays very special effect in film, for example reflectivity, surface tissue, wearability or anti-rubble impact.Their use is decided by its particle size, particle size distribution, particle form, grain pattern, hardness, density, color, wettability, abradability, surface adsorption, specific refractory power, chemical constitution, purity, stability and price.
The suitable filler that is adapted at using in the solid pigment preparation of the present invention for example is based on kaolin, talcum, mica, other silicate, quartz, cristobalite, wollastonite, perlite, diatomite, fibrous packing, aluminium hydroxide, those of barium sulfate and/or lime carbonate.
Theme of the present invention also is to prepare the method for solid pigment preparation, and described solid pigment preparation consists essentially of:
A) at least a pigment of 40-99 weight %,
B) at least a not carbonyl hydrogenated ketone resin and/or the not carbonyl hydrogenated ketone/urea formaldehyde of 1-60 weight %,
C) at least a mineral filler of 0-50 weight %,
Component A), B) and C) the weight amount summation be 100 weight %,
Wherein in organic solvent and/or water by pigment A), ketone resin or ketone/urea formaldehyde B) and mineral filler C optionally) prepare suspension, in suitable device, disperse this suspension, the separate solid pigment preparation.
Can consider ball mill especially as diverting device, have the agitating ball mill of level or arranged vertical, perhaps radially stir mill.But also can use for example decollator, Skandex mixing tank, Red Devil, single roller pulverizer, three roller pulverizer or ball mills.The separation of this solid pigment preparation can be carried out with the conventional drying device usually, and for example at fluidized-bed, spray-drier is in belt drying machine or the Vacuumdrier.Prepare the de-agglomerate in the solid pigment preparation scope that wherein contains agglomerate of the present invention, by for example hammer grinding machine, needle mill, impact grinding or classification grinding machine carry out, but also can be for example be incorporated in the drying process with the form of mill-drying.
Therefore, theme of the present invention also is solid pigment at colorant, paint vehicle, and tackiness agent, the application in ink or the printing-ink, described solid pigment preparation consists essentially of:
A) at least a pigment of 40-99 weight %,
B) at least a not carbonyl hydrogenated ketone resin and/or the not carbonyl hydrogenated ketone/urea formaldehyde of 1-60 weight %,
C) at least a mineral filler of 0-50 weight %,
Component A), B) and C) the weight amount summation be 100 weight %.
Solid pigment preparation of the present invention can be incorporated into all well known by persons skilled in the art containing in solvent and the solvent-free coating system, for example paint vehicle, colorant, tackiness agent, ink or printing-inks.These systems can be for example by physical dryness in 1K-or 2K japanning, oxidation drying or with other approach reacting drying.
There is a large amount of physical dryness resins, nitrocotton for example, polyvinyl butyral acetal, VC multipolymer, acrylate, methacrylic ester, cellulose ester, ether of cellulose, hydrocarbon resin, resol, Gum Rosin, maleic acid resin, polystyrene resin, silicone resin, coating resins base rubber is thermoprene for example, chlorinated rubber, chlorinatedpolyolefins or low polyhutadiene, polyolefine, polyvinylesters, polyvinyl alcohol, polyvinylacetal, epoxide, aminoresin, acyl ammonia resin and vibrin.The example of the coating of oxidation drying is a Synolac.1K coating is based on for example (methyl) acrylate resin, Resins, epoxy, polyvinyl acetate resins, vibrin or urethane resin.These resins also can be undersaturated, promptly contain the two keys of acrylate or methacrylic ester, for example, (methyl) acrylic (methyl) acrylate resin, epoxy (methyl) acrylate resin, polyester (methyl) acrylate resin, polyethers (methyl) acrylate resin, or urethane (methyl) acrylate resin.1K coating also is with melamine resin or the block polyisocyanate resin coating based on polypropylene provided with hydroxyl group acid ester resin or vibrin as linking agent.2K coating is for example to be the coating based on epoxide system or polypropylene provided with hydroxyl group acid esters or vibrin of linking agent with unblocked polyisocyanate resin.
In coating system, can use all auxiliary agents well known by persons skilled in the art and additive.Mention for example defoamer at this, air release agent, auxiliary rheological agents can influence for example oilness, anti-scratch property, anti-caking effect, mobile and glossy surface additive, base material moistening additive, siccative, stablizer or microbicide.
Solid pigment preparation of the present invention is with Powdered, the solid matter that preferred micropowder exists.It is characterized in that being dispersed in especially easily in the dissimilar working mediums, especially be dispersed in the liquid working medium by simple stirring (admixing).By the use of this solid pigment preparation in containing solvent or solvent-free application,, can obtain to have the coating system of high colouring intensity and high glossiness as the use in the powder paint vehicle.
Embodiment
The purpose of following examples is further to set forth the present invention, but unrestricted its range of application:
Embodiment
1) preparation of ketone/urea formaldehyde (non-the present invention)
Insert in advance 176.7g 4-tertiary butyl pimelinketone, 481.7g 3,3, the 30 weight % formalin solutions of 5-trimethylcyclohexanone, 112.4g pimelinketone and 373.1g, and be heated to 60 ℃.Afterwards, in 15 minutes, drip the 50 weight % sodium hydroxide solutions of 114.5g, and with this mixture heating up to 80 ℃.Then, in 90 minutes, drip the 200.0g formalin solution, and under 85 ℃ of reflux conditionss, kept 4 hours.Water neutralising flush gained resin behind the adding Glacial acetic acid.After the distillation, obtain softening temperature and be 85 ℃ light yellow brittle resin.
2) preparation of solid pigment preparation of the present invention
380g Spezialschwarz 4 (the C.I. Pigment black 7 of Degussa AG) is stirred into moisture filter cake with 520g water.In the container that separates, with 467g ketone/urea formaldehyde 1) be dissolved in the 467g ethanol, and add 76.5g ULTRA Talc 609 (from Barretts Minerals Inc.).Add talcum/resin compound to pigment filter cake, and in dissolver, disperse.Dried pigment dispersion liquid and make its micronization in loft drier.
3) contain the preparation (non-the present invention) of solvent pigment preparation
Making 280g Spezialschwarz 4 and 520g ketone/urea formaldehyde 1) 50% solution and 187gDisperbyk 163 (from Byk-Chemie) in acetic acid methoxyl group propyl ester mix mutually, adds the granulated glass sphere of 1mm at 1: 1 with volume ratio.In Dispermat CV, under 3000 commentaries on classics per minute conditions, disperse this mixture to reach 80 minutes.
4) contain the preparation (non-the present invention) of the former lacquer of solvent
Listed addition material in Dispermat CV, stirred 20 minutes under 2400 commentaries on classics per minutes and 25 ℃ of bushing temperature conditions under the 2mm granulated glass sphere helps in the table.Then, at room temperature drying should reach 24 hours by white medium oil alkyd resin paint vehicle.Tackiness agent (solid) is 1: 0.8 with the ratio of white pigment.
Table 1: former lacquer is formed
| Addition material | Consumption (weight %) |
| Alkydal F 49 (55% form) | 61.92 |
| Kronos 2310 | 27.24 |
| Ca siccative (5%Ca) | 0.77 |
| Co siccative (10%Co) | 0.53 |
| Zr siccative (12%Zr) | 0.18 |
| Mn siccative (10%Mn) | 0.10 |
| Octa-Soligen VP 033 | 0.26 |
| Dimethylbenzene | 4.5 |
| Acetate methoxyl group propyl ester | 2.1 |
| Petroleum solvent | 2.1 |
| Borchinox M2 | 0.3 |
| Amount to | 100.0 |
5) preparation of coating composition of the present invention
In order to prepare coating, insert pigment preparation 2 in advance) and 3), and under agitation condition, add a white former lacquer 4 in each case by part).Table 2 provides coating composition and character thereof.
Table 2: coating substance composition
| Prescription | Embodiment | Comparative Examples |
| 4) white paint vehicle | 150.0g | 150.0g |
| 2) black solid pigment preparation | 3.2g | - |
| 3) black pigment preparation | - | 4.2g |
| Butyleneglycol | 3.0g | 3.0g |
| Hydropalat 535 N | 2.3g | 2.3g |
| Based on white pigment, the % of black pigment | 3.2 | 3.2 |
| Coating technology character on the common iron | ||
| Coat-thickness (μ m) | 25 | 25 |
| K nig pendulum hardness after 28 days | 69 | 67 |
| Lattice are drawn test (Glitterschnitt) after 28 days | 0-1 | 0-1 |
| Erichsen drawing test (mm) after 28 days | 6.5 | 6.5 |
| 20 °/60 ° glossiness after 28 days | 77/88 | 76/88 |
| Mist degree after 28 days (Glanzschleier) | 45-49 | 50-52 |
| Δ E rubs off (rub out) | 1.02 | 1.08 |
The exemplary coating composition based on solid pigment preparation of the present invention and solvent-laden white Synolac paint vehicle that illustrates has mechanical properties and the color attributes that high glossiness is become reconciled.These character can with compare based on the coating composition that contains the solvent pigment preparation.
Claims (17)
1, solid pigment preparation, it contains basically:
A) 40-99 weight % at least-kind of pigment,
B) at least a not carbonyl hydrogenated ketone resin and/or the not carbonyl hydrogenated ketone/urea formaldehyde of 1-60 weight %,
C) at least a mineral filler of 0-50 weight %,
Component A wherein), B) and weight amount summation C) be 100 weight %.
2, the solid pigment preparation of claim 1 is characterized in that, as component A) comprise separately or the organic or inorganic pigment or the carbon black of form of mixtures.
3, the solid pigment preparation of at least one of aforementioned claim, it is characterized in that, comprise separately or the azo pigment of form of mixtures as pigment dyestuff, azomethine pigment, metal complex pigment, anthraquinone pigment, phthalocyanine pigment, thioindigo-, quinacridone-, two piperazines-, pyrrolo--, naphthalene tetracarboxylic acid-, perylenes-, indanthrone-, Isoamidolin (on)-, isoindolinone-, flavanthrone-, pyranthrone-or many rings pigment of isoviolanthrone series.
4, the solid pigment preparation of at least one of aforementioned claim is characterized in that, comprises separately or the metal oxide of form of mixtures as mineral dye, the blended metal oxide, merimee's yellow, lead chromate, the chromium sulphate lead plumbate, lead molybdate, ultramarine, cobalt blue, manganese indigo plant, chromoxide green, transparent vert emeraude, cobalt green, metallic sulfide, cadmium sulfoselenide, zinc ferrite or pucherite.
5, the solid pigment preparation of at least one of aforementioned claim is characterized in that, comprises channel black as carbon black, flame black and/or furnace black.
6, the solid pigment preparation of at least one of aforementioned claim is characterized in that, in B component) ketone resin and ketone/urea formaldehyde in contain C-H-acid ketone.
7, the solid pigment preparation of at least one of aforementioned claim, it is characterized in that, in B component) ketone resin and ketone/urea formaldehyde in contain the following ketone that is selected from of independent or form of mixtures: acetone, methyl phenyl ketone, methylethylketone, tertiary butyl methyl ketone, 2-heptanone, propione, methyl iso-butyl ketone (MIBK), cyclopentanone, cyclododecanone, 2,2,4-trimethylammonium cyclopentanone and 2,4, the mixture of 4-trimethylammonium cyclopentanone, suberone, cyclooctanone, pimelinketone and have the alkyl substituted cyclohexanone that one or more total carbon atom numbers are the alkyl of 1-8.
8, the solid pigment preparation of at least one of aforementioned claim, it is characterized in that, in B component) ketone resin and ketone/urea formaldehyde in contain separately or the 4-tert-pentyl pimelinketone of form of mixtures, 2-sec.-butylcyclohexanone, 2-tertiary butyl pimelinketone, 4-tertiary butyl pimelinketone, 2-methylcyclohexanone or 3,3, the 5-trimethylcyclohexanone.
9, the solid pigment preparation of at least one of aforementioned claim is characterized in that, in B component) ketone resin and ketone/urea formaldehyde in contain separately or the methyl phenyl ketone of form of mixtures pimelinketone, 4-tertiary butyl pimelinketone, 3,3,5-trimethylcyclohexanone or heptanone.
10, the solid pigment preparation of at least one of aforementioned claim is characterized in that, comprises separately or formaldehyde, acetaldehyde, butyraldehyde-n, isobutyric aldehyde, valeral and the lauric aldehyde of form of mixtures as aldehyde.
11, the solid pigment preparation of at least one of aforementioned claim is characterized in that, comprises formaldehyde.
12, the solid pigment preparation of at least one of aforementioned claim is characterized in that, as component C) comprise and be selected from following compound: kaolin, talcum, mica, other silicate, quartzy, cristobalite, wollastonite, perlite, diatomite, fibrous packing, aluminium hydroxide, barium sulfate and/or lime carbonate.
13, be used to prepare the method for solid pigment preparation, described solid pigment preparation consists essentially of:
A) at least a pigment of 40-99 weight %,
B) at least a not carbonyl hydrogenated ketone resin and/or the not carbonyl hydrogenated ketone/urea formaldehyde of 1-60 weight %,
C) at least a mineral filler of 0-50 weight %,
Component A), B) and C) the weight amount summation be 100 weight %,
Wherein in organic solvent and/or water by pigment A), ketone resin or ketone/urea formaldehyde B) and mineral filler C optionally) prepare suspension, in suitable device, disperse this suspension, and separate this solid pigment preparation.
14, the method that is used to prepare solid pigment preparation of claim 13 is characterized in that, suspension is at ball mill, and agitating ball mill radially stirs mill, decollator, and the Skandex mixing tank, Red Devil, single roller pulverizer disperses in three roller pulverizers or the ball mill.
15, at least one the method that is used to prepare solid pigment preparation in the claim 13 to 14 is characterized in that, solid pigment preparation is at fluidized-bed, and spray-drier separates in belt drying machine or the Vacuumdrier.
16, at least one the method that is used to prepare solid pigment preparation in the claim 13 to 15 is characterized in that, solid pigment preparation at after separating at the hammer grinding machine, needle mill, de-agglomerate in impact grinding or the classification grinding machine.
17, the application of solid pigment preparation in colorant, paint vehicle, tackiness agent, ink or printing-ink, described solid pigment preparation consists essentially of:
A) at least a pigment of 40-99 weight %,
B) at least a not carbonyl hydrogenated ketone resin and/or the not carbonyl hydrogenated ketone/urea formaldehyde of 1-60 weight %,
C) at least a mineral filler of 0-50 weight %,
Component A wherein), B) and C) the weight amount summation be 100 weight %.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006026762.1 | 2006-06-09 | ||
| DE200610026762 DE102006026762A1 (en) | 2006-06-09 | 2006-06-09 | Solid pigment preparations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101085876A true CN101085876A (en) | 2007-12-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101102534A Pending CN101085876A (en) | 2006-06-09 | 2007-06-08 | Solid pigment preparations |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN101085876A (en) |
| DE (1) | DE102006026762A1 (en) |
| WO (1) | WO2007141090A1 (en) |
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| CN102652158A (en) * | 2009-12-10 | 2012-08-29 | 株式会社御牧工程 | Ink |
| CN109054705A (en) * | 2018-06-22 | 2018-12-21 | 安徽索亚装饰材料有限公司 | A kind of wallpaper adhesive with good wet performance |
| CN113617493A (en) * | 2021-06-29 | 2021-11-09 | 南京信彩科技有限公司 | Raw material grinding method for preparing color ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004020740A1 (en) | 2004-04-27 | 2005-11-24 | Degussa Ag | Polymer compositions of carbonyl-hydrogenated ketone-aldehyde resins and polyisocyanates in reactive solvents |
| CN106192556B (en) * | 2016-07-13 | 2017-09-12 | 太原理工大学 | Crushed crude pearlite is used as paper grade (stock) filler/pigment and method |
| CN107955398A (en) * | 2017-12-17 | 2018-04-24 | 李巧珍 | A kind of preparation method of surface cladding phthalocyanine blue composite pigment |
| CN114907704A (en) * | 2022-06-30 | 2022-08-16 | 宇虹颜料股份有限公司 | Method for preparing superfine pigment preparation for ink or solvent-based coating |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4404809A1 (en) * | 1994-02-16 | 1995-08-17 | Huels Chemische Werke Ag | Wide compatibility ketone-aldehyde resins, process for their preparation and their use |
| DE19813394A1 (en) * | 1998-03-26 | 1999-09-30 | Merck Patent Gmbh | Pigment preparation |
| EP1277808B1 (en) * | 2001-07-09 | 2004-12-15 | Ciba SC Holding AG | Easily distributable pigment compositions |
| IT1364636B (en) * | 2005-02-07 | 2009-07-31 | Achille Bardelli | COATING OF ORGANIC AND INORGANIC PIGMENTS WITH ALDEHYDIC AND KETONIC RESINS |
-
2006
- 2006-06-09 DE DE200610026762 patent/DE102006026762A1/en not_active Withdrawn
-
2007
- 2007-04-24 WO PCT/EP2007/053982 patent/WO2007141090A1/en active Application Filing
- 2007-06-08 CN CNA2007101102534A patent/CN101085876A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102652158A (en) * | 2009-12-10 | 2012-08-29 | 株式会社御牧工程 | Ink |
| CN102652158B (en) * | 2009-12-10 | 2016-02-03 | 株式会社御牧工程 | Ink |
| CN109054705A (en) * | 2018-06-22 | 2018-12-21 | 安徽索亚装饰材料有限公司 | A kind of wallpaper adhesive with good wet performance |
| CN113617493A (en) * | 2021-06-29 | 2021-11-09 | 南京信彩科技有限公司 | Raw material grinding method for preparing color ink |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007141090A1 (en) | 2007-12-13 |
| DE102006026762A1 (en) | 2008-01-10 |
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