CN101085850A - Degradable water soluble packaging film - Google Patents
Degradable water soluble packaging film Download PDFInfo
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- CN101085850A CN101085850A CN 200610083699 CN200610083699A CN101085850A CN 101085850 A CN101085850 A CN 101085850A CN 200610083699 CN200610083699 CN 200610083699 CN 200610083699 A CN200610083699 A CN 200610083699A CN 101085850 A CN101085850 A CN 101085850A
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- film
- water
- weight part
- water soluble
- soluble package
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- 239000012785 packaging film Substances 0.000 title description 3
- 229920006280 packaging film Polymers 0.000 title description 3
- 238000009463 water soluble packaging Methods 0.000 title description 3
- 239000000463 material Substances 0.000 claims abstract description 33
- 238000012856 packing Methods 0.000 claims abstract description 13
- 239000004902 Softening Agent Substances 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- -1 Polyoxyethylene Polymers 0.000 claims description 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 18
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 16
- 230000000694 effects Effects 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 150000003333 secondary alcohols Chemical class 0.000 claims description 9
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 8
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims description 7
- 239000013543 active substance Substances 0.000 claims description 7
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims description 7
- 229920002101 Chitin Polymers 0.000 claims description 6
- 229920000881 Modified starch Polymers 0.000 claims description 6
- 230000007613 environmental effect Effects 0.000 claims description 6
- 239000008108 microcrystalline cellulose Substances 0.000 claims description 6
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 6
- 235000019426 modified starch Nutrition 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 6
- 239000004368 Modified starch Substances 0.000 claims description 5
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 5
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000005022 packaging material Substances 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 108090000790 Enzymes Proteins 0.000 claims description 4
- 102000004190 Enzymes Human genes 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 238000004806 packaging method and process Methods 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000005194 fractionation Methods 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000003094 microcapsule Substances 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 2
- 235000011089 carbon dioxide Nutrition 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 239000010408 film Substances 0.000 claims 21
- 238000005538 encapsulation Methods 0.000 claims 1
- 230000000704 physical effect Effects 0.000 claims 1
- 239000010409 thin film Substances 0.000 claims 1
- 231100000331 toxic Toxicity 0.000 abstract description 3
- 230000002588 toxic effect Effects 0.000 abstract description 3
- 239000012528 membrane Substances 0.000 abstract description 2
- 239000012190 activator Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 9
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 230000002950 deficient Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229920001661 Chitosan Polymers 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 238000006136 alcoholysis reaction Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000941 radioactive substance Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 101001099470 Bos taurus Lactoperoxidase Proteins 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- ZBAFFZBKCMWUHM-UHFFFAOYSA-N propiram Chemical compound C=1C=CC=NC=1N(C(=O)CC)C(C)CN1CCCCC1 ZBAFFZBKCMWUHM-UHFFFAOYSA-N 0.000 description 1
- 229950003779 propiram Drugs 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000006049 ring expansion reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention provides a new degradable water- soluble packing membrane, which is a new green packimg material, and can be used to pack corrosive or toxic material. It employs water- soluble high molecular material as filming raw material, takes complex dispersing, plasticizing agent, softening agent, surface activator and antisticking agent as auxiliary material, and applies special filming process.
Description
Technical field
The present invention relates to a kind of degradable water soluble packaging film, is novel environmentally friendly packing material, can be used for the packing that chemical has materials such as corrodibility or toxic.Degradable water solvability packing film adopt can be in water rapidly the dissolved water-soluble high-molecular material as becoming membrane matrix, subsidiary material such as composite dispersing agent, softening agent, softening agent, tensio-active agent and antisticking agent are made by specific film-forming process.
Background technology
Before the present invention proposes, be used to have the container that various plastics, glass or metallic substance etc. are made that mostly is of corrodibility and toxic chemical substance packing.This class material is durable in use, uses back residual various corrodibility of depleted packing material and radioactive substance to be present in the environment, and environment is polluted, and is made his usefulness by people's mistake easily simultaneously, and humans and animals is damaged.
For these reasons; a kind of new packaging material that can pack chemical corrosivity and radioactive substance is proposed; this new packaging material not with the material generation chemical reaction of packaging; can prevent effectively that these materials from leaking and pollution; can in environment, disperse naturally after packing is used, disintegrate and degraded; and the final material that environment is safe from harm that in environment, becomes; to protection environment and human health and safety; embodiment is attached most importance to environment, and advanced society's theory that people-oriented has positive function and significance.
The present invention just is based on the formula combination and the making method of a kind of environment amenable safe new packaging material of above-mentioned requirements proposition.
Before the present invention proposed, existing abroad water-soluble film mainly adopted complete alcoholysis type polyvinyl alcohol or partial alcoholysis type polyvinyl alcohol as film forming material, and usually, its polymerization degree is between 1700-3000.This class water soluble package film, because film forming material is single, the inherent physico-chemical property of film forming material own makes its diaphragm that becomes that certain defective be arranged.These defect maps are present:
1, nearly all polyvinyl alcohol all has stronger water absorbability, especially when its during as the main film forming material of water-soluble film, add softening agent for example behind the glycerine according to film forming needs, more strengthened the water absorbability of polyvinyl alcohol, the moisture in its absorbing environmental can reach more than a times of quality own; When being used to pack, can produce film blocking and leakage phenomenon.
When 2, existing water-soluble film is dissolved in the water of normal temperature, can not promptly spread apart, form cotton-shaped heavy-gravity object and swim in the water,, can influence the degree of uniformity of pesticide spraying with this film packaging agricultural chemicals.
Though 3, existing employing polyvinyl alcohol is single film forming material water-soluble film has good gas-insulated property, and is all very high to the transmitance of ammonia and water vapor, can influence the stability of some packaged materials and active.
4, in the technology in the past, other adopt the film forming water-soluble film of single-material, have many defectives too, easily form bubble as Mierocrystalline cellulose diaphragm surface, and solubility property is bad fast; Starch diaphragm tensile strength is weak etc.
The degradable water soluble package film that the present invention proposes has overcome the defective of product in the past, has solved the above-mentioned problem of enumerating well.
Technology contents
The object of the invention is to provide a kind of good isolated property that has, and can replace common plastics, metal and glass packaging, and dispersing and dissolving fast in water can be degraded into the new packaging material of environmental sound material after the dissolving.
The present invention is combined with each other with one or more water-soluble high-molecular materials, as water soluble package film film forming substrate material, compound suitable manufacturing methods, softening agent, tensio-active agent, dispersion agent and antisticking agent are made film by special film-forming apparatus, and branch is cut to the size that is fit to automatic packing machine packing bag simultaneously, the rolling packing, standby.The water-soluble film that the present invention makes has overcome the defective of water-soluble film in the past.
The present invention is achieved through the following technical solutions:
Get: polyoxyethylene 100-400 weight part
Modified polyvinyl alcohol 100-400 weight part
Oleic acid triglyceride 20-60 weight part
Nonoxynolum 20-60 weight part
Cocamidopropyl betaine 20-200 weight part
Secondary alcohol reaction oxydase 1-10 weight part
Chitin 1-10 weight part
Microcrystalline Cellulose 1-20 weight part
Polyvinylpyrrolidone 20-120 weight part
Modified starch 20-120 weight part
Deionized water residuals weight part
Film forming component main separation polyoxyethylene and modified polyvinyl alcohol that the present invention selects for use, they as required the chemical property of packing material carry out proportioning in accordance with the appropriate ratio, its relative proportion scope is 1: 99-99: between 1, only ratio is 50: 50.Polyoxyethylene is the well-regulated macromolecular material that is dissolved in water fully of line style that is formed by epoxyethane ring-expansion polymerization, has good film-forming properties, the film softness, the thermoplasticity that are become are strong, be processed into bag, it is good to seal the heat seal performance, the more important thing is that polyoxyethylene does not absorb water substantially, use polyoxyethylene can guarantee the film that become not can produce, use and the preservation process in the moisture absorption adhesion phenomenon takes place.Modified polyvinyl alcohol is a kind of novel material that is used to make the polyvinyl alcohol of water-soluble film different from the past, carry out modification by adding starch hydrolyzates polysaccharide Propiram, make the polymerization degree of modified polyvinyl alcohol be lower than 600, thereby had the water-soluble and the dispersiveness that more are better than polyvinyl alcohol, can in water, not form flocculent substance, and the isolated property to all gases has improved twice, and ammonia and water vapour also can be effectively isolated in addition, enlarged the use range of water soluble package film.The pure and mild polyoxyethylene of modified poly ethylene can be miscible mutually preferably, two kinds of water-soluble high-molecular materials mix use in accordance with the appropriate ratio, leakage phenomenon can not stick together by the agent of low hygroscopicity assurance film of polyoxyethylene, guarantee the good heat seal of film, simultaneously modified polyvinyl alcohol can guarantee the organic solvent-resistant and the greasy performance of the film that become, and polyoxyethylene has also overcome the not defective of anti-amide solvent of polyvinyl alcohol.Polyoxyethylene and modified polyvinyl alcohol performance are complementary in the present invention.The pure and mild polyoxyethylene of modified poly ethylene mixes use, and the stability of polyoxyethylene is greatly improved.
The present invention selects for use the oleic acid triglyceride as softening agent, its effect is for flexibility that improves film and plasticity, why select the oleic acid triglyceride for use, be because the oleic acid triglyceride is good softening agent for the selected film forming material of the present invention, and do not have the strong water absorbability of glycerine.
The present invention selects for use nonoxynolum as the Film Fractionation dispersion agent.Nonoxynolum is a kind of nonionogenic tenside, and surface wettability is preferably arranged, and can when Film Fractionation it be spread apart rapidly in water, and it is cotton-shaped to prevent that film from forming.The consumption of nonoxynolum should be controlled in 3 percent, surpasses 3 percent, can produce certain foam.
The present invention selects for use cocamidopropyl betaine as tensio-active agent, this composition can be in film making processes, reduce the gelating soln surface tension, prevent that the shrinkage cavity phenomenon from appearring in film in solidification process, can ensure that film can more easily strip down smoothly simultaneously from the coated panel of film former, guarantee the film uniformity, there is not pore, equally, the consumption of tensio-active agent can not be too high, and usually usage quantity is not higher than 10.
The effect of the secondary alcohol oxidizing reaction enzyme that the present invention selects for use is, because secondary alcohol reacts oxidasic existence, can make film after using dissolving to enter environment, can the main chain of the pure and mild polyoxyethylene of modified poly ethylene be cut off, some extraordinary floras are degraded into film forming material the material of environmental sound in the cooperation environment, wherein, modified polyvinyl alcohol is degraded into carbonic acid gas and water, and polyoxyethylene is degraded into the dme and the water of environmental sound.
The present invention selects for use the effect of degradable water-soluble high-molecular material chitin to be to utilize chitin coating effect, in 1% lactic acid aqueous solution of 2% chitosan, add secondary alcohol reaction Bovinelactoperoxidase active substance, through stirring fast, chitosan and above-mentioned substance form oil-in-water structure, regulator solution is neutral alkali partially, chitosan is coating these protein-active materials and is flocculating, form microcapsule, make mentioned component at the making processes of film and product between effective service life, remain higher activity, fully improve its availability, bring into play its degraded promoter action fully, simultaneously, because the raising of the availability of active substance descends the cost of product significantly.
The present invention selects for use the effect of Microcrystalline Cellulose to be that Microcrystalline Cellulose has been widely used in the production of capsule product as the antiblocking composition in pharmaceutical production, Microcrystalline Cellulose will further reduce the water absorbability of modified polyvinyl alcohol in the present invention, prevent product moisture absorption adhesion.
The present invention selects for use the effect of polyvinylpyrrolidone and modified starch to be to utilize polyvinylpyrrolidone to improve the Shore hardness and the tear strength of film, utilizes modified starch to reduce the percentage of elongation of film.The Shore hardness of existing film is lower than 10, and this draws intensity low excessively, and percentage of elongation is excessive, and this will make film cut in production technique with rolling and can not realize well, can not use automatic packing machine technology simultaneously.
Owing to adopted the scientific combination of above material, made water soluble package film at normal temperatures, be soft translucent laminar, the diaphragm physical behavior is good, outward appearance is beautiful, good to the isolated property of chemical substance with corrodibility and toxic, all gases transmitance in the environment is lower than almost nil, film has better water solubility.Be under 1: 1 the condition, also can dissolve preferably in the quality of diaphragm and water.Film after the dissolving is degraded substantially in 5 days in environment, and COD detection limit on the 5th is one of initial percentage.
Experimental example:
Physics that film should be had jointly according to general-purpose plastics film and water-soluble film and the chemical property gained the results list of testing is as follows
| Project | Describe in detail and operative norm | The result |
| Outward appearance | The water white transparency flexible film | Qualified |
| Thickness | GB/T6672，0.03-0.05mm | 0.05mm |
| Tensile strength | GB/T13022， 100-300kg/cm 2 | 280kg/cm 2 |
| Extensibility | GB/T1040，10-600％ | 160％ |
| Hardness | GB/T1040, GB/T1039 Shore hardness＜20 | 9＜Shore hardness＜20 |
| Heat resisting temperature | GB1035-70，＞140℃ | ＞140℃ |
| Dissolution rate | -4 ℃--35 ℃, dissolving in 1 minute | 4 ℃/1 minute |
| Security | LD50＞10000/mgkg -1Non-stimulated " disinfection technology standard " | Qualified |
| Biological oxygen demand (BOD) on the 5th | GB 8978-1996，＜1％ | Qualified |
| Ventilation property | GB1038-70， 0 | 0 |
| Stability | ＞60 ℃, 14 days, relative humidity was greater than 70%, uviolizing | The These parameters no change |
Embodiment:
Chitin 10 gram is dissolved in makes viscous solution A in 100 milliliter of 1% lactic acid aqueous solution and get the above-mentioned solution of 10 grams and be diluted to 95 milliliters with 1% lactic acid solution, add secondary alcohol reaction oxydase composition 5 grams, stirred 30 minutes fast, use 1% sodium hydrate regulator solution to neutral alkali partially simultaneously, make chitosan and secondary alcohol reaction oxydase form microcapsule solution B; 600 ml waters are heated to 70 degree, get each 250 gram of the pure and mild polyoxyethylene of modified poly ethylene and add, fully stirring and dissolving is made translucent solution C, filters; 80 gram modified starches, 20 gram Microcrystalline Celluloses and 50 gram polyvinylpyrrolidones are added in 500 ml waters successively, and heating is until dissolving.Add each 50 gram of cocamidopropyl betaine, oleic acid triglyceride and nonoxynolum, fully stir, make solution D; Above-mentioned four kinds of solution are mixed, stir, stand-by; The thickness of above-mentioned solution with 0.10 millimeter is uniformly coated on the Stainless Steel Band of film machine, and heating, drying can obtain thickness and be 0.05 millimeter flexible film.Film is taken off from Stainless Steel Band, cut, pack and make finished product.
Claims (10)
1, water soluble package film of the present invention is characterized in that it being a kind of good isolated property that has, can replace common plastics, metal and glass packaging, quick dispersing and dissolving in water can be degraded into the new packaging material of environmental sound material after the dissolving.
2, water soluble package film according to claim 1 is characterized in that being grouped into by following one-tenth:
Polyoxyethylene 100-400 weight part
Modified polyvinyl alcohol 100-400 weight part
Oleic acid triglyceride 20-60 weight part
Nonoxynolum 20-60 weight part
Cocamidopropyl betaine 20-200 weight part
Secondary alcohol oxidizing reaction enzyme 1-10 weight part
Chitin 1-10 weight part
Microcrystalline Cellulose 1-20 weight part
Polyvinylpyrrolidone 20-120 weight part
Modified starch 20-120 weight part
Deionized water residuals weight part
3, water soluble package film according to claim 2 is characterized in that polyoxyethylene and modified polyvinyl alcohol are the film forming main components, two kinds of film forming components are according to 99: 1--1: 99 proportional range makes up, film forming effectively, prevent the moisture absorption adhesion, have good isolated property, thermotolerance, heat seal and, organic solvent resistance and water-soluble.
4, water soluble package film according to claim 2 is characterized in that softening agent is the oleic acid triglyceride, and the oleic acid triglyceride does not produce hygroscopic effect in the effect of playing softening agent.
5, water soluble package film according to claim 2 is characterized in that used nonoxynolum is a kind of dispersion agent, plays the dissolved thin film composition is dispersed in effect in the water fast.
6, water soluble package film according to claim 2 is characterized in that used cocamidopropyl betaine is a kind of tensio-active agent, reduces the surface tension of solution in the making processes of film, film uniformity that assurance becomes.
7, water soluble package film according to claim 2 is characterized in that used secondary alcohol oxidizing reaction enzyme its role is to after Film Fractionation is in environment, and the degradable film film forming component makes it to become the carbonic acid gas of environmental sound and water etc.
8, water soluble package film according to claim 2 is characterized in that used chitin is a kind of microcapsule, and its effect is that secondary alcohol oxidizing reaction enzyme is protected through micro encapsulation, keeps its activity.
9, water soluble package film according to claim 2 is characterized in that used Microcrystalline Cellulose is a kind of antiblocking agent, and its effect is the water absorbability that reduces film.
10, water soluble package film according to claim 2 is characterized in that used modified starch and polyvinylpyrrolidone its role is to improve the hardness of film, extensibility and tear strength, makes that the physical property of film is more suitable for that automatization is cut, rolling and packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100836998A CN101085850B (en) | 2006-06-05 | 2006-06-05 | Degradable water soluble packaging film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100836998A CN101085850B (en) | 2006-06-05 | 2006-06-05 | Degradable water soluble packaging film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101085850A true CN101085850A (en) | 2007-12-12 |
| CN101085850B CN101085850B (en) | 2011-03-16 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100836998A Expired - Fee Related CN101085850B (en) | 2006-06-05 | 2006-06-05 | Degradable water soluble packaging film |
Country Status (1)
| Country | Link |
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| CN (1) | CN101085850B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102391530A (en) * | 2011-06-29 | 2012-03-28 | 郝喜海 | Method for manufacturing polyvinyl alcohol slow/controlled release film |
| CN102617046A (en) * | 2012-04-11 | 2012-08-01 | 林嘉宏 | Glass containing protective coating layer |
| CN103172912A (en) * | 2013-03-14 | 2013-06-26 | 南京林业大学 | Preparation method of modified microcrystalline cellulose enhanced starch plastic |
| CN104830000A (en) * | 2015-04-29 | 2015-08-12 | 安徽松泰包装材料有限公司 | Production method of food package material |
| CN105885174A (en) * | 2016-05-31 | 2016-08-24 | 蚌埠天成包装科技股份有限公司 | Anti-fog moisture-absorption film for fresh product packaging |
| CN106496894A (en) * | 2016-10-31 | 2017-03-15 | 安徽鼎正高分子材料科技有限责任公司 | A kind of low-temperature water-soluble pesticides packaging film and preparation method thereof |
| CN106566150A (en) * | 2016-10-31 | 2017-04-19 | 安徽鼎正高分子材料科技有限责任公司 | Water-soluble single seed packaging film prepared through impregnation method |
| CN107286547A (en) * | 2017-07-31 | 2017-10-24 | 海南大学 | A kind of preparation method of chitin liquefaction products/polyvinyl alcohol blending film |
| WO2018041262A1 (en) * | 2016-09-05 | 2018-03-08 | 广东聚益新材有限公司 | Water-soluble shopping bag and preparation method therefor |
| CN108314891A (en) * | 2018-03-21 | 2018-07-24 | 安徽江淮汽车集团股份有限公司 | A kind of PEO composite material and preparation methods |
| CN109181179A (en) * | 2018-07-03 | 2019-01-11 | 海南大学 | A kind of crust liquefied substance/degradation plastic blend film and preparation method thereof |
| WO2024097921A1 (en) * | 2022-11-04 | 2024-05-10 | H.J. Heinz Company Brands Llc | Degradation of polyvinyl alcohol and derivatives thereof using an enzymatic cascade |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1142264C (en) * | 2002-01-15 | 2004-03-17 | 北京博恒新材料研究有限责任公司 | Completely water-soluble hand-washing film |
-
2006
- 2006-06-05 CN CN2006100836998A patent/CN101085850B/en not_active Expired - Fee Related
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102391530A (en) * | 2011-06-29 | 2012-03-28 | 郝喜海 | Method for manufacturing polyvinyl alcohol slow/controlled release film |
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| CN107286547A (en) * | 2017-07-31 | 2017-10-24 | 海南大学 | A kind of preparation method of chitin liquefaction products/polyvinyl alcohol blending film |
| CN108314891A (en) * | 2018-03-21 | 2018-07-24 | 安徽江淮汽车集团股份有限公司 | A kind of PEO composite material and preparation methods |
| CN109181179A (en) * | 2018-07-03 | 2019-01-11 | 海南大学 | A kind of crust liquefied substance/degradation plastic blend film and preparation method thereof |
| CN109181179B (en) * | 2018-07-03 | 2021-05-11 | 海南大学 | Chitin liquefiable matter/degradable plastic blending film and preparation method thereof |
| WO2024097921A1 (en) * | 2022-11-04 | 2024-05-10 | H.J. Heinz Company Brands Llc | Degradation of polyvinyl alcohol and derivatives thereof using an enzymatic cascade |
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