CN101073960A - Silk ink-jetting printing paper and its production - Google Patents
Silk ink-jetting printing paper and its production Download PDFInfo
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- CN101073960A CN101073960A CN 200610035565 CN200610035565A CN101073960A CN 101073960 A CN101073960 A CN 101073960A CN 200610035565 CN200610035565 CN 200610035565 CN 200610035565 A CN200610035565 A CN 200610035565A CN 101073960 A CN101073960 A CN 101073960A
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Abstract
The invention is concerned with the mercerizative inking printing paper, especially the inking printing paper with art printing paper effect, the characteristics is: adds nanometer grade silicon dioxide that the grain diameter is 5nm to 30nm and the micron grade silicon dioxide that the grain diameter is 1um to 15um, produces the mercerizative inking printing paper that the printing effect is the artprinting paper effect and precedes highlight printing paper and sub-photochromic printing paper by assorting soften calendering dressing technics and adjusting the proportion of the nanometer grade and micron grade silicon dioxide.
Description
Technical field
The present invention relates to a kind of Alhue paper and preparation method thereof, particularly a kind of phase chip level silk ink-jetting printing paper.
Background technology
At present, printing house, all layout works of advertising company all need print, print the sample manuscript link through examination, promptly the picture proof works need through making base stock → plate-making → printing, often for one, two sample manuscript, will finish a whole set of program, its unit cost is tens times or a hundred times of final products.In recent years, though released phase chip level Alhue paper (being commonly called as digital photo paper) on the market, but only limit to two kinds of high light and inferior machine-glazed papers, high machine-glazed paper is equivalent to the used glass paperboard in printing house, and inferior machine-glazed paper then is equivalent to wood-free paper, owing to the reason of the material that is adopted in the high machine-glazed paper ink absorbing layer, granularity and preparation method thereof, the glossiness of the high machine-glazed paper of making is too high, the brightness of image that prints is too big, and color is nature inadequately, and image is true to nature inadequately; And inferior machine-glazed paper ink absorbing layer surface is because particle is too thick, cause light towards scattering all around, low in glossiness, image is intensely dark, these two kinds of paper do not have the effect of art paper, what whole world printing consumption maximum and effect were best then is art paper, yet the domestic market is not met the Alhue paper that this copperplate effect is arranged as yet at present, and market is strong day by day to the demand of this printing paper, for this reason, the inventor constantly studies for many years always and explores, and has obtained following achievement.
Summary of the invention
At Gao Guang, the limitation that inferior light phase chip level Alhue paper exists, for filling up the vacancy of domestic market, the purpose of this invention is to provide a kind of silk ink-jetting printing paper with copperplate paper effect, with this silk ink-jetting printing paper printed design original text, its printing effect approaches the printing effect that comes out with halftone paper printing fully, so just, solved the complicated procedures of the traditional printing sample manuscript of printing house and advertising company, greatly reduce cost, saved the time, for developing Gao Guang rapidly on the market at home at present, inferior light phase chip level printing paper provides new kind, allows the consumer that wider selective category and more choice are arranged.
The present invention is that the achieve the above object technical scheme that adopted is as follows:
A kind of silk ink-jetting printing paper comprises base material and the ink absorbing layer of coating on the substrate surface, it is characterized in that containing in the above-mentioned ink absorbing layer nano level silica and micron-sized silica and adhesive.
The particle diameter of such scheme nanometer grade silica is 5-30nm, and the particle diameter of micron silica is 1-15um, and its ratio is a nanometer grade silica: micron silica=1: 1～1: 4.
The adhesive of such scheme is the copolymer emulsion of polyvinyl alcohol and cinnamic acrylic ester, and its ratio is a polyvinyl alcohol: cinnamic acrylic ester emulsion=1: 1～5: 1.
Also contain curing agent, dispersant, brightening agent, plasticizer in the ink absorbing layer of such scheme.
Such scheme ink absorbing layer coating fluid prescription is as follows:
Coating fluid is formed percentage by weight (wt%)
Nanometer grade silica 10-20
Micron silica 5-10
Polyvinyl alcohol 1.5-3.0
Cinnamic acrylic ester emulsion 0.5-1.7
Color-fixing agent (P105G) 2-5
Brightening agent (VBL) 0.1-0.2
Polyethylene of dispersing agent pyrrolidones 0.1-0.3
Plasticizer glycerine 0.1-0.5
Defoamer butanols 0.1-0.3
Deionized water 70-80
A kind of preparation method of silk ink-jetting printing paper, it is characterized in that each material that will constitute ink absorbing layer coating earlier mix → stir → coating that generates behind the froth breaking → adopt wave current extrusion or air knife method to be coated with → to enter the multiple pressure district on base material carries out soft calendaring.
The preparation method of above-mentioned silk ink-jetting printing paper is:
(1), coating fluid preparation
At first polyvinyl alcohol is dissolved down for 90 ℃ in temperature, standby.By prescription deionized water is dropped in the container, under high-speed stirred, add polyvinylpyrrolidone and glycerine, add nanometer grade silica and micron silica then, drop into polyvinyl alcohol, cinnamic acrylic ester emulsion, brightening agent (VBL), color-fixing agent (P105G) and plasticizer glycerine successively after fully disperseing, after stirring is finished, slowly add the defoamer butanols again.
(2), coating, calendaring technology
The viscosity of above-mentioned coating is transferred to 300-800mpa.s, on base material, be coated with wave current extrusion or air knife method, heated-air drying under 100 ℃ of temperature, control base material moisture content is 10-15%, enter the press polish district then, carry out soft calendaring, press polish district process conditions are: the temperature of a nip felt wrapped roll is 110-130 ℃, linear pressure is 50-80kg/cm, the temperature of two nip felt wrapped rolls is 80-100 ℃, linear pressure is 110-150kg/cm, adopts the recirculated cooling water water temperature in the three nip felt wrapped rolls, and linear pressure is 50-80kg/cm.
The present invention is for achieving the above object, nanometer grade silica and micron silica have been adopted in the ink absorbing layer, because the particle diameter of nanometer grade silica is minimum, can pay in the higher glossiness of coating, and the particle diameter of micron silica is relatively large, this powder has unique sponge characteristic in addition, its porosity is 1.2ml/g, and therefore, the adding of this powder has certain photoextinction, thereby regulated the glossiness of Alhue paper effectively, strengthened the print quality of silk ink-jetting printing paper.During use, both combination principle is particle diameter big nanometer grade silica and the little silica combination of particle diameter, particle diameter little nanometer grade silica and the big micron silica combination of particle diameter.The combinations of particle sizes of nanoscale and micron silica is adjusted according to the different demands in market in coating fluid prescription that the present invention adopts and the prescription.
The invention has the beneficial effects as follows:
1, silk ink-jetting printing paper of the present invention, owing to adopted reasonable combination and proportioning between nanometer grade silica and the micron silica, controlled the particle diameter state of pigment in the coating effectively, adopt multi-region soft calendaring paper finishing technology simultaneously, so obtained satisfied glossiness, because the specific area of used pigment is big, gap between particles forms its porous, and therefore it can also eliminate China ink dropping to minimum the drying time of printing ink, hydration and and pigment ooze mutually, this silk ink-jetting printing paper is with respect to high light and inferior light Alhue paper, better glossiness is arranged, and print image is more clear beautiful, and color rendition is more true to nature.
2, use silk ink-jetting printing paper printed design original text of the present invention, its printing effect approaches the printing effect that comes out with halftone paper printing fully, so just, solved the complicated procedures of the traditional printing sample manuscript of printing house and advertising company, and greatly reduced cost and saved the time.
3, silk ink-jetting printing paper of the present invention has been opened up the new varieties of digital photo paper, allows the consumer that wider choice is arranged.
The specific embodiment
The present invention is further described below in conjunction with embodiment.
Embodiment 1
(1) coating fluid is formed percentage by weight (wt%)
Nanometer grade silica 13
Micron silica 6
Polyvinyl alcohol 2
Cinnamic acrylic ester emulsion 1.2
Color-fixing agent (P105G) 4
Brightening agent (VBL) 0.1
Polyethylene of dispersing agent pyrrolidones 0.2
Plasticizer glycerine 0.3
Defoamer butanols 0.2
Deionized water 73
(2) coating process
Coating fluid viscosity: 300mpa.s
Coating weight: Gu composition, 12g/m
2
Coating process: airblade coating method
Drying condition: 100 ℃ of heated-air dryings.
(3) calendaring technology (paper finishing)
The paper feed moisture content is 110 ℃ of 10%, one nip felt wrapped roll temperature, and linear pressure is 70kg/cm; Two nip felt wrapped roll temperature are 100 ℃, and linear pressure is 150kg/cm; Three nip felt wrapped rolls adopt the water temperature of recirculated cooling water, and linear pressure is 50kg/cm.
Embodiment 2
(1) coating fluid is formed percentage by weight (wt%)
Nanometer grade silica 12
Micron silica 12
Polyvinyl alcohol 1.5
Cinnamic acrylic ester emulsion 1.7
Color-fixing agent (P105G) 2.2
Brightening agent (VBL) 0.15
Polyethylene of dispersing agent pyrrolidones 0.2
Plasticizer glycerine 0.25
Defoamer butanols 0.15
Deionized water 70
(2) coating process
Coating fluid viscosity: 500mpa.s
Coating weight: Gu composition, 7g/m
2
Coating process: wave current extrusion coated method
Drying condition: 100 ℃ of heated-air dryings.
(3) calendaring technology (paper finishing)
The paper feed moisture content is 110 ℃ of 12%, one nip felt wrapped roll temperature, and linear pressure is 50kg/cm, and two nip felt wrapped roll temperature are 80 ℃, and linear pressure is 150kg/cm, and three nip felt wrapped rolls adopt the water temperature of recirculated cooling water, and linear pressure is 60kg/cm.
Embodiment 3
(1) coating fluid is formed percentage by weight (wt%)
Nanometer grade silica 18
Micron silica 5
Polyvinyl alcohol 2.5
Cinnamic acrylic ester emulsion 1.0
Color-fixing agent (P105G) 3.2
Brightening agent (VBL) 0.2
Polyethylene of dispersing agent pyrrolidones 0.3
Plasticizer glycerine 0.5
Defoamer butanols 0.3
Deionized water 69
(2) coating process
Coating fluid viscosity: 800mpa.s
Coating weight: Gu composition, 10g/m
2
Coating process: wave current extrusion coated method
Drying condition: 100 ℃ of heated-air dryings.
(3) calendaring technology (paper finishing)
The paper feed moisture content is 130 ℃ of 15%, one nip felt wrapped roll temperature, and linear pressure is 80kg/cm; Two nip felt wrapped roll temperature are 90 ℃, and linear pressure is 110kg/cm; Three nip felt wrapped rolls adopt the water temperature of recirculated cooling water, and linear pressure is 80kg/cm.
The silk ink-jetting printing paper performance sees the following form
Table: silk ink-jetting printing paper evaluation
| Pilot project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Gloss (60 °) | 36 | 30 | 40 |
| Draw (deceiving) as (viridescent) dense (purple) degree (Huang) | 2.50 | 2.40 | 2.70 |
| 1.70 | 1.70 | 1.90 | |
| 2.13 | 2.00 | 2.20 | |
| 1.85 | 1.77 | 1.90 | |
| Whiteness | 85 | 80 | 87 |
| Anti-purple (deceiving) outside line (viridescent) (rate of change, %) (purple) (Huang) | 98 | 98 | 99 |
| 91 | 96 | 89 | |
| 65 | 66 | 78 | |
| 100 | 100 | 100 |
Illustrate: 1. glossiness is measured 60 ° of gloss measuring silk ink-jetting printing paper with the gloss analyzer.
2. after the concentration of drawing a portrait is printed with EPSON PM-780CS, use マ Network ベ ヌ portrait densimeter (RD-918) that black, dark green, purple, yellow each printing portion is measured.
3. after UV resistant is printed with EPSON PM-780CS,, use マ Network ベ ヌ portrait densimeter (RD-918) that black, dark green, purple, yellow each printing portion is measured, and measure pre-irradiation and postradiation rate of change with ultraviolet lamp irradiation 24 hours.
4. whiteness is measured with SBDY-1 digital display whiteness instrument.
Claims (7)
1. a silk ink-jetting printing paper comprises base material and the ink absorbing layer of coating substrate surface, it is characterized in that containing in the above-mentioned ink absorbing layer nano level silica and micron-sized silica and adhesive.
2. silk ink-jetting printing paper according to claim 1, the particle diameter that it is characterized in that described nanometer grade silica is 5-30nm, the particle diameter of described micron silica is 1-15um; Its ratio is a nanometer grade silica: micron silica=1: 1～4: 1.
3. silk ink-jetting printing paper according to claim 1 is characterized in that described adhesive is polyvinyl alcohol and cinnamic acrylic ester emulsion, and its ratio is a polyvinyl alcohol: styrene acid esters=1: 1～5: 1.
4. according to claim 1 or 3 described silk ink-jetting printing papers, it is characterized in that: also contain color-fixing agent, dispersant, brightening agent, plasticizer in the described ink absorbing layer.
5. according to claim 1,3 or 4 described silk ink-jetting printing papers, the coating fluid of its ink absorbing layer prescription is as follows:
Coating fluid is formed percentage by weight (wt%)
Nanometer grade silica 10-20
Micron silica 5-10
Polyvinyl alcohol 1.5-3.0
Cinnamic acrylic ester emulsion 0.5-1.7
Color-fixing agent (P-105G) 2-5
Brightening agent (VBL) 0.1-0.2
Polyethylene of dispersing agent pyrrolidones 0.1-0.3
Plasticizer glycerine 0.1-0.5
Defoamer butanols 0.1-0.3
Deionized water 70-80
6. the preparation method of a silk ink-jetting printing paper, it is characterized in that each material that will constitute the ink absorbing layer coating fluid earlier mix → stir → coating that generates behind the froth breaking → adopt wave current extrusion or air knife method to be coated with → to enter the multiple pressure district on base material carries out soft calendaring.
7. by the preparation method of the described silk ink-jetting printing paper of claim 6, it is characterized in that:
The coating fluid preparation
At first polyvinyl alcohol is dissolved down for 90 ℃ in temperature, standby.By prescription deionized water is dropped in the container, under high-speed stirred, add polyvinylpyrrolidone and glycerine, add nanometer grade silica and micron silica then, drop into poly-vinyl alcohol solution, cinnamic acrylic ester emulsion, brightening agent, color-fixing agent and plasticizer successively after fully disperseing, after stirring is finished, slowly add butanols again.
Coating, calendaring technology
The viscosity of above-mentioned coating is transferred to 300-800mpa.s, on base material, be coated with wave current extrusion or air knife method, heated-air drying under 100 ℃ of temperature, control base material moisture content is 10-15%, after enter the press polish district and carry out soft calendaring, press polish district process conditions are: the temperature of a nip felt wrapped roll is 110-130 ℃, and linear pressure is 50-80kg/cm; The temperature of two nip felt wrapped rolls is 80-100 ℃, and linear pressure is 110-150kg/cm; Adopt the recirculated cooling water water temperature in the three nip felt wrapped rolls, linear pressure is 50-80kg/cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610035565 CN101073960A (en) | 2006-05-18 | 2006-05-18 | Silk ink-jetting printing paper and its production |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610035565 CN101073960A (en) | 2006-05-18 | 2006-05-18 | Silk ink-jetting printing paper and its production |
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| Publication Number | Publication Date |
|---|---|
| CN101073960A true CN101073960A (en) | 2007-11-21 |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101927631A (en) * | 2010-06-03 | 2010-12-29 | 哈尔滨工业大学 | Ink jet recording ink-absorption layer material and preparation method thereof |
| CN102092209A (en) * | 2010-10-29 | 2011-06-15 | 哈尔滨工业大学 | Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid |
| CN101624802B (en) * | 2008-07-11 | 2011-09-21 | 阿尔卑斯电气株式会社 | Print sheet |
| CN102407707A (en) * | 2011-07-27 | 2012-04-11 | 哈尔滨工业大学 | Method for removing bubbles of ink absorption layer |
| CN104099807A (en) * | 2014-05-29 | 2014-10-15 | 南京泛太克文化产业发展有限公司 | Formula and preparation method for high gloss color ink-jet printing paper coating |
| CN104099806A (en) * | 2014-05-29 | 2014-10-15 | 南京泛太克文化产业发展有限公司 | Formula and preparation method for matt color ink-jet paper coating |
| CN105442384A (en) * | 2015-11-06 | 2016-03-30 | 淄博欧木特种纸业有限公司 | Novel digital ink-jet nonwoven base paper |
| CN106120446A (en) * | 2016-06-29 | 2016-11-16 | 安徽文峰特种纸业有限公司 | A kind of printing paper low luster coating formula |
| CN106120449A (en) * | 2016-06-29 | 2016-11-16 | 安徽文峰特种纸业有限公司 | A kind of printing paper high-gloss paint |
| CN106280344A (en) * | 2016-09-30 | 2017-01-04 | 河南工程学院 | A kind of fused glass pellet sub-light polylactic acid silk material and preparation method thereof |
| CN106585155A (en) * | 2016-11-28 | 2017-04-26 | 江苏格美高科技发展有限公司 | Inkjet printing Chinese art paper and preparation process thereof |
| CN107972378A (en) * | 2017-11-14 | 2018-05-01 | 温州富捷科技股份有限公司 | A kind of cardboard printing technique |
| CN108485403A (en) * | 2018-04-08 | 2018-09-04 | 温州创佳影像材料有限公司 | A kind of digital printing non-woven fabrics and its production technology |
| CN108819530A (en) * | 2018-06-26 | 2018-11-16 | 桐乡市耐箔尔烫印材料有限公司 | A kind of high performance white pigment foil |
| CN111070933A (en) * | 2018-10-19 | 2020-04-28 | 南亚塑胶工业股份有限公司 | Matte synthetic paper |
| CN114855502A (en) * | 2022-05-11 | 2022-08-05 | 北京山川物语科技有限公司 | Aqueous coating liquid for ink-jet digital printing paper and preparation method thereof |
-
2006
- 2006-05-18 CN CN 200610035565 patent/CN101073960A/en active Pending
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101624802B (en) * | 2008-07-11 | 2011-09-21 | 阿尔卑斯电气株式会社 | Print sheet |
| CN101927631A (en) * | 2010-06-03 | 2010-12-29 | 哈尔滨工业大学 | Ink jet recording ink-absorption layer material and preparation method thereof |
| CN101927631B (en) * | 2010-06-03 | 2012-12-26 | 哈尔滨工业大学 | Preparation method of ink jet recording ink-absorption layer material |
| CN102092209A (en) * | 2010-10-29 | 2011-06-15 | 哈尔滨工业大学 | Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid |
| CN102092209B (en) * | 2010-10-29 | 2012-10-31 | 哈尔滨工业大学 | Ink-jet recording material |
| CN102407707A (en) * | 2011-07-27 | 2012-04-11 | 哈尔滨工业大学 | Method for removing bubbles of ink absorption layer |
| CN104099807A (en) * | 2014-05-29 | 2014-10-15 | 南京泛太克文化产业发展有限公司 | Formula and preparation method for high gloss color ink-jet printing paper coating |
| CN104099806A (en) * | 2014-05-29 | 2014-10-15 | 南京泛太克文化产业发展有限公司 | Formula and preparation method for matt color ink-jet paper coating |
| CN105442384A (en) * | 2015-11-06 | 2016-03-30 | 淄博欧木特种纸业有限公司 | Novel digital ink-jet nonwoven base paper |
| CN105442384B (en) * | 2015-11-06 | 2017-10-27 | 淄博欧木特种纸业有限公司 | Novel digital ink-jet nonwoven base paper |
| CN106120449A (en) * | 2016-06-29 | 2016-11-16 | 安徽文峰特种纸业有限公司 | A kind of printing paper high-gloss paint |
| CN106120446A (en) * | 2016-06-29 | 2016-11-16 | 安徽文峰特种纸业有限公司 | A kind of printing paper low luster coating formula |
| CN106280344A (en) * | 2016-09-30 | 2017-01-04 | 河南工程学院 | A kind of fused glass pellet sub-light polylactic acid silk material and preparation method thereof |
| CN106280344B (en) * | 2016-09-30 | 2018-07-03 | 河南工程学院 | A kind of fused glass pellet matt polylactic acid silk material and preparation method thereof |
| CN106585155A (en) * | 2016-11-28 | 2017-04-26 | 江苏格美高科技发展有限公司 | Inkjet printing Chinese art paper and preparation process thereof |
| CN107972378A (en) * | 2017-11-14 | 2018-05-01 | 温州富捷科技股份有限公司 | A kind of cardboard printing technique |
| CN107972378B (en) * | 2017-11-14 | 2019-10-18 | 温州富捷科技股份有限公司 | A kind of cardboard printing technique |
| CN108485403A (en) * | 2018-04-08 | 2018-09-04 | 温州创佳影像材料有限公司 | A kind of digital printing non-woven fabrics and its production technology |
| CN108819530A (en) * | 2018-06-26 | 2018-11-16 | 桐乡市耐箔尔烫印材料有限公司 | A kind of high performance white pigment foil |
| CN108819530B (en) * | 2018-06-26 | 2020-11-03 | 桐乡市耐箔尔烫印材料有限公司 | High-performance white pigment foil |
| CN111070933A (en) * | 2018-10-19 | 2020-04-28 | 南亚塑胶工业股份有限公司 | Matte synthetic paper |
| CN111070933B (en) * | 2018-10-19 | 2022-04-19 | 南亚塑胶工业股份有限公司 | Matte synthetic paper |
| CN114855502A (en) * | 2022-05-11 | 2022-08-05 | 北京山川物语科技有限公司 | Aqueous coating liquid for ink-jet digital printing paper and preparation method thereof |
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