CN101070155A - Method for preparing active charcoal of scripus tubernaemontani stem - Google Patents
Method for preparing active charcoal of scripus tubernaemontani stem Download PDFInfo
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- CN101070155A CN101070155A CN 200710015676 CN200710015676A CN101070155A CN 101070155 A CN101070155 A CN 101070155A CN 200710015676 CN200710015676 CN 200710015676 CN 200710015676 A CN200710015676 A CN 200710015676A CN 101070155 A CN101070155 A CN 101070155A
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Abstract
The invention relates to a kind of preparation method of active carbon of shallot's stalk. The steps are as follows: clear the stalk and dry it or dry it and crush it, mix the power of stalk and phosphoric acid of 30-60%v/v according to the mass ratio of 1:2-3 and then marinate them for 6-8 hours, char and activate the power of the stalk after it is marinated, then clear it with water and dry it, then get active carbon. It is easy to obtain the raw material for the invention; it makes full use of planet straw of marsh. The preparation method is simple, economical and environment protecting.
Description
Technical field
The invention belongs to the preparing technical field of gac, particularly a kind of is the method for preparation of active carbon of raw material with the scripus tubernaemontani stem.
Background technology
Gac is a kind of porous carbonaceous material, have highly developed hole and huge specific surface area, be widely used in fields such as environmental protection, food, medicine, chemical industry as a kind of good sorbent material, carried out multiple uses such as water treatment, gas sweetening, decolouring, taste removal.
Gac can be made by many carbonaceous materials, comprises coal, timber, various shells etc.In recent years, along with the attention day by day to environmental issue, every profession and trade increases year by year to the demand of gac.The scope of gac raw material has been widened in the increase of gac demand.The agriculture byproduct especially cane of farm crop mostly has certain carbon content, and cheap and easy to get, is a kind of raw material of good production gac.
Scirpus tabernaemontani, another name pipe grass, emerald green pipe grass, the Cyperaceae Cyperus, perennial emergent, 1～2 meter of plant height, cane is upright, smooth surface, interior is spongy, widely distributed.Scirpus tabernaemontani is a kind of effective water body purification plant, widely applies in artificial swamp.After the plant maturation, need gather in it usually.Harvested Scirpus tabernaemontani often is dropped, and this has not only taken the soil, and environment is exerted a certain influence, and has also wasted resource.
Summary of the invention
Low at scripus tubernaemontani stem utilization ratio in the prior art, the deficiency of gac scarcity of raw material, the invention provides a kind of preparation method of active charcoal of scripus tubernaemontani stem, can obtain a kind of stay-in-grade active charcoal of scripus tubernaemontani stem, raw material obtains easily, made full use of the wetland plant straw, and manufacture craft is simple, economy, environmental protection.
A kind of preparation method of active charcoal of scripus tubernaemontani stem, step is as follows:
(1) scripus tubernaemontani stem is cleaned, dried or dry;
(2) scripus tubernaemontani stem after will drying or dry is pulverized, the scripus tubernaemontani stem powder;
(3) the scripus tubernaemontani stem powder is mixed immersion with the phosphoric acid that is 30～60% (v/v) with 1: 2～3 mass ratio, soak time is 6～8 hours;
(4) the scripus tubernaemontani stem powder after step (3) immersion is carried out charing and activation;
(5) the scripus tubernaemontani stem powder that will carry out after charing and the activation washes with water, and oven dry promptly obtains gac.
Preferably, the temperature of drying in the step (1) is 10 ℃～35 ℃, and it is 30～35 ℃ that the best is dried temperature.
Preferably, the bake out temperature in the step (1) is 90 ℃～120 ℃.
Preferably, the powder particle diameter in the step (2) is 0.5～1.5mm.
Preferably, charing and activation condition in the step (4): muffle furnace is warming up to 400～550 ℃ of temperature with 3～5 ℃/min of temperature rise rate, soaking time 60～90 minutes.
Preferably, the water washing in the step (5) can slightly be washed recovery phosphoric acid for first water, and then is washed with water to pH=6～7.
Preferably, bake out temperature is 90 ℃～120 ℃ in the step (5).
Excellent results of the present invention is as follows:
1. the present invention has utilized wetland plant straw-scripus tubernaemontani stem first, and raw material is cheap and easy to get, can reduce the production cost of gac.
2. the present invention utilizes scripus tubernaemontani stem to prepare gac, and changing waste into valuable has been realized making full use of the Scirpus tabernaemontani resource.
3. utilize the cane of wetland plant to prepare gac, enlarged the raw material sources of gac.
4. preparation technology of the present invention is simple, economy, environmental protection, meets the needs of recycling economy development, has favorable industrial application prospect.
Embodiment
The invention will be further described below in conjunction with embodiment, but be not limited thereto.
Embodiment 1:
The preparation method of active charcoal of scripus tubernaemontani stem, step is as follows:
Water is cleaned scripus tubernaemontani stem, to remove earth and other impurity; Under 105 ℃ temperature, dry then.The exsiccant straw is crushed to 0.5mm with pulverizer, the phosphoric acid of scripus tubernaemontani stem powder and 50% (v/v) is mixed immersion with 1: 2 mass ratio, soak time is 7 hours; To in muffle furnace, be warmed up to 400 ℃ with the scripus tubernaemontani stem powder after the phosphoric acid dip and carry out charing and activation with the speed of 3～5 ℃/min, soaking time 90 minutes, both gac, wash gac with water, reclaim phosphoric acid; Wash gac again with water to pH=6.5, drain, and under 105 ℃ of conditions, dry.
Embodiment 2:
The preparation method of active charcoal of scripus tubernaemontani stem, step is as follows:
Water is cleaned scripus tubernaemontani stem, to remove earth and other impurity; Dry in the place that is placed on 35 ℃ then.The exsiccant straw is crushed to 1mm with pulverizer, the phosphoric acid of scripus tubernaemontani stem powder and 60% (v/v) is mixed immersion with 1: 3 mass ratio, soak time is 7 hours; To in muffle furnace, be warmed up to 550 ℃ of temperature with the scripus tubernaemontani stem powder after the phosphoric acid dip and carry out charing and activation with the speed of 3～5 ℃/min, soaking time 60 minutes, both gac, wash gac with water, reclaim phosphoric acid; Wash gac again with water to pH=7, drain, and under 110 ℃ of conditions, dry.
Embodiment 3:
The preparation method of active charcoal of scripus tubernaemontani stem, step is as follows:
Water is cleaned scripus tubernaemontani stem, to remove earth and other impurity; Dry in the place that is placed on 30 ℃ then.The exsiccant straw is crushed to 1.5mm with pulverizer, the phosphoric acid of scripus tubernaemontani stem powder and 50% (v/v) is mixed immersion with 1: 2.5 mass ratio, soak time is 8 hours; To in muffle furnace, be warmed up to 450 ℃ of temperature with the scripus tubernaemontani stem powder after the phosphoric acid dip and carry out charing and activation with the speed of 3～5 ℃/min, 70 minutes time, both gac, wash gac with water, reclaim phosphoric acid; Wash gac again with water to pH=7, drain, and under 105 ℃ of conditions, dry.
Claims (7)
1, a kind of preparation method of active charcoal of scripus tubernaemontani stem, step is as follows:
(1) scripus tubernaemontani stem is cleaned, dried or dry;
(2) scripus tubernaemontani stem after will drying is pulverized, the scripus tubernaemontani stem powder;
(3) phosphoric acid of scripus tubernaemontani stem powder and 30～60%v/v is mixed immersion with 1: 2～3 mass ratio, soak time is 6-8 hour;
(4) the scripus tubernaemontani stem powder after step (3) immersion is carried out charing and activation;
(5) the scripus tubernaemontani stem powder that will carry out after charing and the activation washes with water, and oven dry promptly obtains gac.
2, the preparation method of active charcoal of scripus tubernaemontani stem as claimed in claim 1 is characterized in that, the temperature of drying in the step (1) is 10 ℃～35 ℃.
3, the preparation method of active charcoal of scripus tubernaemontani stem as claimed in claim 1 is characterized in that, the bake out temperature in the step (1) is 90 ℃～120 ℃.
4, the preparation method of active charcoal of scripus tubernaemontani stem as claimed in claim 1 is characterized in that, the powder particle diameter in the step (2) is 0.5～1.5mm.
5, the preparation method of active charcoal of scripus tubernaemontani stem as claimed in claim 1 is characterized in that, charing in the step (4) and activation condition are that 3～5 ℃/min of muffle furnace temperature rise rate is warming up to 400～550 ℃ of temperature, soaking time 60～90 minutes.
6, the preparation method of active charcoal of scripus tubernaemontani stem as claimed in claim 1 is characterized in that, the water washing in the step (5) is that first water is slightly washed recovery phosphoric acid, and then is washed with water to pH=6～7.
7, the preparation method of active charcoal of scripus tubernaemontani stem as claimed in claim 1 is characterized in that, bake out temperature is 90 ℃～120 ℃ in the step (5).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100156768A CN100515939C (en) | 2007-06-08 | 2007-06-08 | Method for preparing active charcoal of scripus tubernaemontani stem |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100156768A CN100515939C (en) | 2007-06-08 | 2007-06-08 | Method for preparing active charcoal of scripus tubernaemontani stem |
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| CN101070155A true CN101070155A (en) | 2007-11-14 |
| CN100515939C CN100515939C (en) | 2009-07-22 |
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| CNB2007100156768A Expired - Fee Related CN100515939C (en) | 2007-06-08 | 2007-06-08 | Method for preparing active charcoal of scripus tubernaemontani stem |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101274758B (en) * | 2008-05-19 | 2010-06-02 | 山东大学 | Preparation for water chestnut leather activated char |
| CN101891188A (en) * | 2010-03-22 | 2010-11-24 | 中国科学院等离子体物理研究所 | Method for preparing nano active carbon spheres by using blue-green algae residue |
| CN102267696A (en) * | 2011-07-12 | 2011-12-07 | 华东师范大学 | Method for preparing active carbon from alternanthera philoxeroides |
| CN102423690A (en) * | 2011-10-17 | 2012-04-25 | 山东大学 | Preparation method of multi-mesoporous tomato stem activated carbon |
| CN102757048A (en) * | 2012-07-24 | 2012-10-31 | 河南华美生物工程有限公司 | Method for preparing activated carbon from peonies |
| CN103011159A (en) * | 2012-12-14 | 2013-04-03 | 东华大学 | Preparation method of eggplant stalk activated carbon |
| CN108821282A (en) * | 2018-08-24 | 2018-11-16 | 山东大学 | The method that the modified sedge matrix activated carbon of shrimp chaff prepares the active carbon of high nitrogen-containing functional group |
| CN109160513A (en) * | 2018-09-25 | 2019-01-08 | 山东大学 | A kind of preparation method of reed and the high nitrogen-containing functional group active carbon of extruding feather mixed base |
| CN109565990A (en) * | 2018-11-05 | 2019-04-05 | 塔里木大学 | The method for improveing heavy salinized ground |
| CN109704330A (en) * | 2018-11-26 | 2019-05-03 | 玉山县三清活性炭有限公司 | The production method of activated carbon of phosphoric acid method |
| CN113582174A (en) * | 2021-07-26 | 2021-11-02 | 上海兴长活性炭有限公司 | Preparation method of straw activated carbon, straw activated carbon and application |
| CN114655954A (en) * | 2022-05-07 | 2022-06-24 | 营口三同环保科技开发有限公司 | Activated carbon rod for filtering and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8923662D0 (en) * | 1989-10-20 | 1989-12-06 | Norit Uk Ltd | A method of producing granular activated carbon |
-
2007
- 2007-06-08 CN CNB2007100156768A patent/CN100515939C/en not_active Expired - Fee Related
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101274758B (en) * | 2008-05-19 | 2010-06-02 | 山东大学 | Preparation for water chestnut leather activated char |
| CN101891188A (en) * | 2010-03-22 | 2010-11-24 | 中国科学院等离子体物理研究所 | Method for preparing nano active carbon spheres by using blue-green algae residue |
| CN101891188B (en) * | 2010-03-22 | 2012-06-27 | 中国科学院等离子体物理研究所 | Method for preparing nano active carbon spheres by using blue-green algae residue |
| CN102267696A (en) * | 2011-07-12 | 2011-12-07 | 华东师范大学 | Method for preparing active carbon from alternanthera philoxeroides |
| CN102423690A (en) * | 2011-10-17 | 2012-04-25 | 山东大学 | Preparation method of multi-mesoporous tomato stem activated carbon |
| CN102423690B (en) * | 2011-10-17 | 2013-06-12 | 山东大学 | Preparation method of mesoporous tomato stem active carbon |
| CN102757048A (en) * | 2012-07-24 | 2012-10-31 | 河南华美生物工程有限公司 | Method for preparing activated carbon from peonies |
| CN103011159A (en) * | 2012-12-14 | 2013-04-03 | 东华大学 | Preparation method of eggplant stalk activated carbon |
| CN108821282A (en) * | 2018-08-24 | 2018-11-16 | 山东大学 | The method that the modified sedge matrix activated carbon of shrimp chaff prepares the active carbon of high nitrogen-containing functional group |
| CN108821282B (en) * | 2018-08-24 | 2020-08-25 | 山东大学 | Method for preparing active carbon with high nitrogen-containing functional groups by using shrimp bran modified Cyperaceae plant-based active carbon |
| CN109160513A (en) * | 2018-09-25 | 2019-01-08 | 山东大学 | A kind of preparation method of reed and the high nitrogen-containing functional group active carbon of extruding feather mixed base |
| CN109160513B (en) * | 2018-09-25 | 2020-04-24 | 山东大学 | Preparation method of reed and puffed feather mixed-base activated carbon with high nitrogen-containing functional groups |
| CN109565990A (en) * | 2018-11-05 | 2019-04-05 | 塔里木大学 | The method for improveing heavy salinized ground |
| CN109704330A (en) * | 2018-11-26 | 2019-05-03 | 玉山县三清活性炭有限公司 | The production method of activated carbon of phosphoric acid method |
| CN113582174A (en) * | 2021-07-26 | 2021-11-02 | 上海兴长活性炭有限公司 | Preparation method of straw activated carbon, straw activated carbon and application |
| CN114655954A (en) * | 2022-05-07 | 2022-06-24 | 营口三同环保科技开发有限公司 | Activated carbon rod for filtering and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN100515939C (en) | 2009-07-22 |
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