CN101058943A - Composite fibre for substituting asbestos - Google Patents
Composite fibre for substituting asbestos Download PDFInfo
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- CN101058943A CN101058943A CN 200610025777 CN200610025777A CN101058943A CN 101058943 A CN101058943 A CN 101058943A CN 200610025777 CN200610025777 CN 200610025777 CN 200610025777 A CN200610025777 A CN 200610025777A CN 101058943 A CN101058943 A CN 101058943A
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Abstract
The present invention discloses a composite fiber which can replace asbestos. It includes enhanced short fiber and adjuvant producing pulp fiber, among the both, the pulp fiber covers the face of short fiber uniformly. Said enhanced short fiber contains at least one of the following fibers: polyacrylonitrile fiber, polyvinyl alcohol fibers, aromatic amide fiber, polyamide fiber, polyolefin fiber, glass fiber and so on; said pulp fiber contains at least one of the following pulps: polyacrylonitrile pulp, aromatic amide pulp, polyester pulp, cellulose pulp and so on. The composite fiber can replace asbestos in composite materials of friction materials, sealing materials, cement concrete products and so on, the enhanced short fiber provides base mechanical strength, the adjuvant producing pulp fiber catches fine particles and inhibits components leaking, the adjuvant producing pulp fiber covers the face of short fiber and avoids the short fiber entanglement each other in the materials mixing process and the phenomenon of fiber balling up, the fiber has excellent integrated performance.
Description
Technical field
The present invention relates to a class and substitute the asbestos composite fibre, comprise enhanced short fiber and help the processing dissolving pulp-like fibre, wherein dissolving pulp-like fibre is coated on the surface of staple fiber equably.
Background technology
As everyone knows, asbestos fibre is the inorfil that has fire-retardant, enhancing, thixotroping concurrently, helps excellent comprehensive performances such as processing, be widely used in multiple fields such as friction material, encapsulant, cement concrete product, but no matter asbestos friction material all can cause serious harm to health in production or use, and countries in the world all are being devoted to seek suitable non-asbestos fiber to substitute asbestos fibre.
Replace asbestos fibre at present and be used for friction, encapsulant, mainly contain Dupont in the composites such as cement concrete product, the contraposition virtue acid amides pulp that Japan Supreme Being people company takes the lead in developing, dissolving pulp-like fibres such as the polyacryl-nitrile dissolving pulp of the leading exploitation of U.S. Sterling company and cellulose pulp, the structure that all has height fibrillation, replace asbestos fibre and be used for composite, has the stronger fine particle of catching, hold back the ability of component, contraposition virtue acid amides pulp particularly, synthetic fiber pulps such as polyacryl-nitrile dissolving pulp have better environmental suitability and stability than cellulose pulp, but dissolving pulp-like fibre can not provide matrix enough intensity.
Except above-mentioned dissolving pulp-like fibre, what also be used to replace asbestos fibre has chopped carbon fiber, aramid fiber, vinal, a glass fibre etc., they can provide the matrix certain mechanical strength, but ganoid staple fiber can not be caught fine particle, wayward component runs off, and and the poor adhesion between matrix, in use be prone to " extracting " phenomenon.
CN87100349 discloses a kind of employing vinal and has prepared the vinylon fiber cement products as main reinforcing material, cellulose fiber peacekeeping inorfil as auxiliary fiber.In this invention, fortifying fibre and auxiliary fiber add the shaping system successively, and fiber is difficult to be scattered in the cement matrix equably.
JP10007811, JP9241063 discloses and has obtained the island structure fiber by polyvinyl alcohol and polyacrylonitrile polymer co-blended spinning and be used for reinforcing rubber articles and cement concrete product, shape in the process at composite, fibrillation takes place in the island structure fiber surface under the effect of strong shearing force, and has the effect of certain trapped particle, fiber also can maintain certain intensity simultaneously, but island structure fiber spinning process complexity, and only making fiber show fibrillation by means of the shear action in the shaping process, its original fiber degree is difficult to satisfy the needs of catching fine particle in the composite-material formula.
Summary of the invention
The object of the present invention is to provide a class to substitute the asbestos composite fibre, comprise enhanced short fiber and help the processing dissolving pulp-like fibre, wherein dissolving pulp-like fibre is coated on the surface of staple fiber equably.
Technical scheme of the present invention is: with in polyacrylonitrile fibre, vinal, aramid fiber, polyamide fiber, polyamide fiber, the glass fibre one or more, cut into the long staple fiber of 3～10mm, with Canadian Standard Freeness is that in the polyacryl-nitrile dissolving pulp of 125～600ml, fragrant acid amides pulp, polyester pulp, the cellulose pulp one or more mix and are scattered in the water, form the suspension of 0.1～10wt%, adopt 15-45s
-1High-rate of shear it is forced dispersing and mixing, make the dissolving pulp-like fibre of height fibrillation be coated on the surface of staple fiber equably.
The present invention has the following advantages:
The invention discloses a class and substitute the asbestos composite fibre, comprise enhanced short fiber and help the processing dissolving pulp-like fibre, wherein dissolving pulp-like fibre is coated on the surface of staple fiber equably.This composite fibre replaces asbestos and is used for composites such as friction material, encapsulant, cement concrete product, easily be scattered in the matrix material, wherein, enhanced short fiber provides the matrix mechanical strength, helps the processing dissolving pulp-like fibre to arrest various fine particles, and constituents for suppressing runs off, and be coated on the surface of staple fiber, avoided in the batch mixing process, easily tangling mutually between the staple fiber, the phenomenon of fiber balling-up occurred, had high cost performance.
The specific embodiment
One class substitutes the asbestos composite fibre, comprises enhanced short fiber and helps the processing dissolving pulp-like fibre, and wherein dissolving pulp-like fibre is coated on the surface of staple fiber equably.
Described enhanced short fiber, according to requirements such as composite heat resistance and intensity, one or more in the fibers such as selection polyacrylonitrile fibre, vinal, aramid fiber, polyamide fiber, polyamide fiber, glass fibre.
Described dissolving pulp-like fibre, according to requirements such as composite heat resistance and processing characteristicies, one or more in the dissolving pulp-like fibres such as selection polyacryl-nitrile dissolving pulp, fragrant acid amides pulp, polyester pulp, cellulose pulp.
Described enhanced short fiber fiber number is 0.6～15dtex, and length is 3～10mm, and fracture strength is 0.3～3GPa, and stretch modulus is 5～500GPa.
Described dissolving pulp-like fibre length is 0.8～3mm, and Canadian Standard Freeness is 125～600ml.
Enhanced short fiber is 10: 90～90: 10 with the mixed proportion that helps the processing dissolving pulp-like fibre in the described composite fibre.
Described composite fibre, the enhanced short fiber of Hun Heing and help the processing dissolving pulp-like fibre to be scattered in the water forms the suspension of 0.1～10wt% according to the above ratio.
Described composite fibre is that above-mentioned suspension is adopted 15～45s
-1High-rate of shear it is forced dispersing and mixing, make the dissolving pulp-like fibre of height fibrillation be coated on the surface of staple fiber equably.
Described composite fibre is used for composites such as friction material, encapsulant, cement concrete product, described staple fiber provides the matrix mechanical strength, described dissolving pulp-like fibre has arrests various fine particles, the effect that constituents for suppressing runs off, be coated on the surface of staple fiber, also avoided in the batch mixing process easy intermeshing phenomenon between the staple fiber.
Example 1
Taking by weighing 50kg length is 5mm, and fiber number is that polyacrylonitrile staple fiber and the 50kg distribution of lengths of 3d is 2.0 ± 0.4mm, and Canadian Standard Freeness is that the polyacryl-nitrile dissolving pulp of 225 ± 25ml mixes to be scattered in the 4t water and forms suspension, adopts 34s
-1High-rate of shear suspension is forced dispersing and mixing after, obtain the composite fibre A that polyacryl-nitrile dissolving pulp-like fibre is coated on polyacrylonitrile staple fiber surface equably through centrifugal drying.
Example 2
Taking by weighing 50kg length is 4mm, and fiber number is that polyacrylonitrile staple fiber and the 50kg distribution of lengths of 1.5d is 2.0 ± 0.4mm, and Canadian Standard Freeness is that the polyacryl-nitrile dissolving pulp of 225 ± 25ml mixes to be scattered in the 4t water and forms suspension, adopts 34s
-1High-rate of shear suspension is forced dispersing and mixing after, obtain the composite fibre B that polyacryl-nitrile dissolving pulp-like fibre is coated on polyacrylonitrile staple fiber surface equably through centrifugal drying.
Example 3
Taking by weighing 75kg length is 6mm, and fiber number is that polyvinyl alcohol polyacrylonitrile staple fiber and the 25kg distribution of lengths of 1.5d is 2.0 ± 0.4mm, and Canadian Standard Freeness is that the polyacryl-nitrile dissolving pulp of 225 ± 25ml mixes to be scattered in the 4t water and forms suspension, adopts 34s
-1High-rate of shear suspension is forced dispersing and mixing after, obtain the composite fibre C that polyacryl-nitrile dissolving pulp-like fibre is coated on polyvinyl alcohol staple fiber surface equably through centrifugal drying.
Example 4
Prescription by following friction material: composite fibre A 10%, phenol-formaldehyde resin modified 25%, Iron Ore Powder 25%, calcium carbonate 15%, barium sulfate 20%, carbon black 5% adopts the dry process moulding, and flow process is: batching → mixing → hot pressing → heat treatment → sample, wherein, molding temperature is 155 ± 5 ℃, and pressure is 20Mpa, and the time is 10min; Heat-treat condition is: 180 ℃ of insulation 8h.By GB11834-89 the sample of 25mm * 25mm * 5mm is tested on constant speed formula frictional testing machine, the result is as shown in table 1.
Table 1 composite fibre A strengthens the frictional behaviour test result of friction material
| Pilot project | Test temperature | ||
| 100℃ | 150℃ | 200℃ | |
| Coefficient of friction, μ | 0.39 | 0.47 | 0.45 |
| The backhaul coefficient of friction, μ | 0.43 | 0.45 | 0.45 |
| Wear rate V, 10 -7cm 3/Nm | 0.11 | 0.17 | 0.21 |
Example 5
The prescription of following rubber gasket sheet: rubber 25 parts of (20 parts of acrylonitrile-butadiene rubbers, 5 parts of natural rubbers), 15 parts of composite fibre B, 20 parts of white carbons, 20 parts of wollastonites, 10 parts in calcium carbonate, 5 parts in potter's clay, 0.2 part in sulphur, 1.5 parts in zinc oxide, 0.15 part of stearic acid, 0.1 part of tetramethylthiuram disulfide, 0.15 part of thiazolesulfenamide, nonox 0.4%, dibutyl phthalate: 1.7 parts of 0.8 parts, iron oxide red; Produce no asbestos rubber sealing plate by following technological process, wherein curing temperature is: 135 ℃, sulfide stress is: 3Mpa, cure time is: 10min.The no asbestos seal rubber slab smooth surface, the resilience that make are good, and its The performance test results is as shown in table 2.
Table 2 composite fibre B strengthens the performance of no asbestos seal plate
| Test event | Unit | The result | Remarks |
| Density flexibility transverse tensile strength compression ratio percent reduction B# thickness increment rate B# weight increase 903# thickness increment rate 903# weight increase immersion oil transverse tensile strength slip (no sealing compound) slip (sealing compound is arranged) | Kg/m 3Times MPa % % % % % % MPa Pa*m3/s Pa*m 3/s | 1.78*10 3 7.8 11.2 11.5 62.8 2.7 2.6 2.2 2.1 11.5 0 0 | -----5 hours 903# oil 150 degree of 5 hours B# oil of B# oil soak at room temperature soak at room temperature soak 5 hours 903# oil 150 degree and soak 5 hours 903# oil 150 degree and soak in 5 hours and press 1Mpa; Face is pressed and is pressed 1Mpa in the 0.1Mpa, and face is pressed 0.1Mpa |
Example 6
Copy the prescription of following the example of the preparation lightweight fibre-cement slab: cement 60%, composite fibre C 10%, powdery perlite 27%, mica 3%.Dissolving pulp-like fibre among the composite fibre C has the effect of well catching the cement particle, has lowered the loss of cement particle effectively, and the long vinal of 6mm can improve wet base pulling force, reduces the feed back amount.The papermaking process flow process is: pull an oar → copy get → cut edge → Pressure water discharging is closely knit → steam-cured → demoulding warehouse-in maintenance, copies base moisture 45%, briquetting pressure 10MPa.The fiber cement board proportion that obtains is: 1.09g/cm
3, rupture strength 11.5Mpa, impact strength 3.5KJ/m
2
Claims (9)
1. a class substitutes the asbestos composite fibre, it is characterized in that: composite fibre comprises enhanced short fiber and helps the processing dissolving pulp-like fibre, and wherein dissolving pulp-like fibre is coated on the surface of staple fiber equably.
2. enhanced short fiber according to claim 1 is characterized in that: include a kind of of following fiber at least, polyacrylonitrile fibre, vinal, aramid fiber, polyamide fiber, polyamide fiber, glass fibre etc.
3. dissolving pulp-like fibre according to claim 1 is characterized in that: include a kind of of following pulp at least, polyacryl-nitrile dissolving pulp, fragrant acid amides pulp, polyester pulp, cellulose pulp etc.
4. according to claim 1 and 2 described enhanced short fiber, it is characterized in that: fiber number is 0.6～15dtex, and length is 3～10mm, and fracture strength is 0.3～3GPa, and stretch modulus is 5～500GPa.
5. according to claim 1 and 3 described dissolving pulp-like fibres, it is characterized in that: dissolving pulp-like fibre length is 0.8～3mm, and Canadian Standard Freeness is 125～600ml.
6. composite fibre according to claim 1 is characterized in that: the enhanced short fiber in the described claim 4 and 5 is 10: 90～90: 10 with the mixed proportion that helps the processing dissolving pulp-like fibre.
7. composite fibre according to claim 1 is characterized in that: the enhanced short fiber in the described claim 6 and help the processing dissolving pulp-like fibre to be scattered in the water forms the suspension of 0.1～10wt%.
8. composite fibre according to claim 1 is characterized in that: the suspension described in the claim 6 adopts 15～45s
-1High-rate of shear it is forced dispersing and mixing, make the dissolving pulp-like fibre of height fibrillation be coated on the surface of staple fiber equably.
9. composite fibre according to claim 1, it is characterized in that: be used for composite, described staple fiber provides the matrix mechanical strength, described dissolving pulp-like fibre has arrests various fine particles, the effect that constituents for suppressing runs off, be coated on the surface of staple fiber, also avoided in the batch mixing process easy intermeshing phenomenon between the staple fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100257779A CN100572652C (en) | 2006-04-17 | 2006-04-17 | Composite fibre for substituting asbestos |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100257779A CN100572652C (en) | 2006-04-17 | 2006-04-17 | Composite fibre for substituting asbestos |
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| Publication Number | Publication Date |
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| CN101058943A true CN101058943A (en) | 2007-10-24 |
| CN100572652C CN100572652C (en) | 2009-12-23 |
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| CNB2006100257779A Expired - Fee Related CN100572652C (en) | 2006-04-17 | 2006-04-17 | Composite fibre for substituting asbestos |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102849981A (en) * | 2011-06-30 | 2013-01-02 | 韦尔豪泽Nr公司 | Internally curing cement based materials |
| CN105174768A (en) * | 2015-08-31 | 2015-12-23 | 南京林业大学 | Nanometer cellulose fiber reinforced cement-based material |
| CN106906689A (en) * | 2017-03-06 | 2017-06-30 | 陕西科技大学 | A kind of polyamine epichlorohydrin resin self-crosslinking polyacrylonitrile fibre paper and preparation method thereof |
| CN110616065A (en) * | 2018-06-20 | 2019-12-27 | 中国石油化工股份有限公司 | High-interface-binding-force fiber particles for well cementation and preparation method thereof |
-
2006
- 2006-04-17 CN CNB2006100257779A patent/CN100572652C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102849981A (en) * | 2011-06-30 | 2013-01-02 | 韦尔豪泽Nr公司 | Internally curing cement based materials |
| US9056792B2 (en) | 2011-06-30 | 2015-06-16 | Weyerhaeuser Nr Company | Internally curing cement based materials |
| CN105819734A (en) * | 2011-06-30 | 2016-08-03 | 韦尔豪泽Nr公司 | Internally curing cement based material |
| CN105174768A (en) * | 2015-08-31 | 2015-12-23 | 南京林业大学 | Nanometer cellulose fiber reinforced cement-based material |
| CN105174768B (en) * | 2015-08-31 | 2017-06-20 | 南京林业大学 | A kind of nano-cellulose fiber strengthens cement-based material |
| CN106906689A (en) * | 2017-03-06 | 2017-06-30 | 陕西科技大学 | A kind of polyamine epichlorohydrin resin self-crosslinking polyacrylonitrile fibre paper and preparation method thereof |
| CN106906689B (en) * | 2017-03-06 | 2018-06-05 | 陕西科技大学 | A kind of polyamine epichlorohydrin resin self-crosslinking polyacrylonitrile fibre paper and preparation method thereof |
| CN110616065A (en) * | 2018-06-20 | 2019-12-27 | 中国石油化工股份有限公司 | High-interface-binding-force fiber particles for well cementation and preparation method thereof |
| CN110616065B (en) * | 2018-06-20 | 2022-03-08 | 中国石油化工股份有限公司 | High-interface-binding-force fiber particles for well cementation and preparation method thereof |
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| CN100572652C (en) | 2009-12-23 |
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Granted publication date: 20091223 Termination date: 20120417 |