CN101054299A - Method of preparing ceramic coating by flame heat spray painting thermit packaged silicon carbide particles - Google Patents
Method of preparing ceramic coating by flame heat spray painting thermit packaged silicon carbide particles Download PDFInfo
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- CN101054299A CN101054299A CN 200710017696 CN200710017696A CN101054299A CN 101054299 A CN101054299 A CN 101054299A CN 200710017696 CN200710017696 CN 200710017696 CN 200710017696 A CN200710017696 A CN 200710017696A CN 101054299 A CN101054299 A CN 101054299A
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Abstract
The present invention relates to a preparation method for ceramic coating of flame thermal spraying thermite coated silicon carbide grain, which comprises the steps of that: firstly, the ferric oxide powder and the aluminum powder are compounded to form thermite; and then the thermite, the alumina grain and the silicon carbide grain are compounded and rebuilt by macromolecule anchoring agent to form the spherical compounded grain with a three layers packaged structure, that is an inner layer of silicon carbide, a middle layer of thermite and an outer layer of alumina; finally, the spherical compounded grain is loaded in the powder bucket of the spraying gun, and the thermal spraying is executed by means of oxy-acetylene flame to form ceramic coating. In the present invention, the spraying raw materials are rebuilt and compounded, so that the silicon carbide grain will not contact with the flame directly in the oxy-acetylene flame thermal spraying process, which effectively prevent the silicon carbide grain from thermal sublimation in high temperature, thereby the silicon carbide grain can sediment onto the surface of the substrate uniformly and compactly so as to obtain the high performance ceramic thermal spraying coating of alumina enhanced by silicon carbide.
Description
Technical field
The present invention relates to a kind of preparation method of thermite packaged silicon carbide particles ceramic coating, be specifically related to a kind of preparation method of ceramic coating by flame heat spray painting thermit packaged silicon carbide particles.
Background technology
Hot-spraying techniques is crucial technology in the Surface Engineering field, it is to utilize thermal source that coated material is heated to fusion or semi-melting state, by flame stream itself or compressed-air actuated surging force it is injected into pretreated matrix surface with certain speed then, forms and to have certain function the coating of (wear-resisting, anti-corrosion, thermal boundary etc.).
Stupalith is anti-oxidant with it, high rigidity, series of advantages such as wear-resistant, high temperature resistant become the ideal coated material.It is strong that silicon carbide (SiC) has oxidation-resistance, and wear resisting property is good, the hardness height, and Heat stability is good, hot strength is big, and thermal expansivity is little, and the big and good characteristics such as anti-thermal shock and resistance to chemical attack of thermal conductivity are a kind of good coated materials.But, its application in technical field of hot is restricted owing to can decompose distillation under the silicon carbide high temperature.
Summary of the invention
The object of the present invention is to provide a kind of preparation method that can obtain the ceramic coating by flame heat spray painting thermit packaged silicon carbide particles of high performance silicon carbide enhanced alumina ceramic coating.
For achieving the above object, the technical solution used in the present invention is: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Then with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon carbide by 1: (0.1-2.0): mass ratio (0.1-2.0) is the compound reconstruct of 1000-5000 polymer wedding agent by the polymerization degree, reconstitutes granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
Because the present invention is reconstructed each spraying starting material compound, compound back silicon-carbide particle does not directly contact with flame in the oxy-acetylene flame thermal spray process, effectively stop its heat sublimation under the condition of high temperature, jet deposition is to matrix surface evenly, densely to make it, thereby obtains high performance silicon carbide enhanced alumina-ceramic thermally sprayed coating.
Description of drawings
Fig. 1 is three layers of package structure synoptic diagram of composite particles of the present invention.
Embodiment
Below in conjunction with accompanying drawing the present invention is described in further detail.
Embodiment 1: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 0.5: 2.0 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon carbide then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
Embodiment 2: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 1.0: 0.5 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon carbide then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
Embodiment 3: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 0.1: 1.5 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon carbide then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
Embodiment 4: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 1.5: 1.0 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon carbide then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
Embodiment 5: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 2.0: 0.1 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon carbide then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
The present invention for make silicon-carbide particles can not distil because of temperature is too high when spraying (2700 ℃) be deposited in the coating with disperse as far as possible fully, also in order to make full use of the heat that thermite reaction discharges, it is that silicon carbide, middle level are that thermite, skin are the spherical composite particles of three layers of package structure of aluminum oxide that the spy reconstitutes internal layer with ready thermite particle, alumina particle, silicon-carbide particle simultaneously; Then this composite particles is packed into and spray enforcement in the spray gun powder bucket.Composite particles is fusion rapidly under the high temperature of oxy-acetylene flame and thermite reaction release of heat, and deposit to matrix surface through certain pre-treatment (purification, alligatoring, preheating etc.) with flame stream and pressurized air stream high-velocity jet, form high rigidity, high abrasion, bonding strength height, the porosity ceramic structure coating that possesses a series of premium propertiess such as low.
Referring to Fig. 1, the internal layer of package structure composite particles is a silicon carbide 1; The middle level is a thermite 2; Skin is an aluminum oxide 3.During spraying, composite particles is under the effect of oxy-acetylene flame, and particle top layer aluminum oxide melts gradually; Thermite reaction then takes place in the middle level thermite, and equation is as follows:
Fe
2O
3+2Al→Al
2O
3+2Fe+3500kJ
A large amount of heat energy is emitted in reaction, further impels the aluminum oxide fusing; Internal layer silicon carbide also begins to soften.Certainly, this process is to carry out in the high-speed flight of raw material with flame stream and air-flow, and the time length is quite of short duration.Very fast, raw material just jet deposition forms alumina ceramic coating at matrix surface, owing to be package structure, silicon-carbide particle has kept to get off and disperse is distributed in the coating as much as possible.Reaction is constantly carried out, and coating progressively thickens.
Claims (6)
1, the preparation method of ceramic coating by flame heat spray painting thermit packaged silicon carbide particles is characterized in that:
1) at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite;
2) then with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon carbide by 1: (0.1-2.0): mass ratio (0.1-2.0) is the compound reconstruct of 1000-5000 polymer wedding agent by the polymerization degree, reconstitutes granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide;
3) this spherical composite particles is packed into carry out thermospray by oxy-acetylene flame in the spray gun powder bucket at last, form ceramic coating.
2, the preparation method of ceramic coating by flame heat spray painting thermit packaged silicon carbide particles according to claim 1 is characterized in that: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 0.5: 2.0 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon-carbide particle then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
3, the preparation method of ceramic coating by flame heat spray painting thermit packaged silicon carbide particles according to claim 1 is characterized in that: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 1.0: 0.5 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon-carbide particle then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
4, the preparation method of ceramic coating by flame heat spray painting thermit packaged silicon carbide particles according to claim 1 is characterized in that: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 0.1: 1.5 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon-carbide particle then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
5, the preparation method of ceramic coating by flame heat spray painting thermit packaged silicon carbide particles according to claim 1 is characterized in that: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 1.5: 1.0 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon-carbide particle then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
6, the preparation method of ceramic coating by flame heat spray painting thermit packaged silicon carbide particles according to claim 1 is characterized in that: at first, 400-800 purpose ferric oxide powder and 400-800 order aluminium powder are compounded to form thermite; Be 1000-5000 polymer wedding agent compound reconstruct by 1: 2.0: 0.1 mass ratio by the polymerization degree with this thermite and 400-800 purpose alumina particle, 400-800 purpose silicon-carbide particle then, reconstitute granularity and be 160-400 purpose internal layer and be silicon carbide, middle level and be the spherical composite particles of thermite, outer three layers of package structure for aluminum oxide; At last this spherical composite particles is packed into and carry out thermospray by oxy-acetylene flame in the spray gun powder bucket, form ceramic coating.
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WO2014068082A2 (en) * | 2012-11-01 | 2014-05-08 | Norwegian University Of Science And Technology (Ntnu) | Thermal spraying of ceramic materials |
CN109437148A (en) * | 2018-11-02 | 2019-03-08 | 山东天岳先进材料科技有限公司 | By the method for the long brilliant surplus material preparation high purity carbon material of silicon carbide |
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CN111270190A (en) * | 2020-03-15 | 2020-06-12 | 河北工业大学 | Preparation method of high-entropy ceramic-alumina composite coating |
CN113185268A (en) * | 2021-04-29 | 2021-07-30 | 湖南大学 | Preparation method of alumina ceramic material and alumina ceramic substrate |
CN116162931A (en) * | 2023-04-26 | 2023-05-26 | 中国恩菲工程技术有限公司 | Bottom blowing spray gun composite coating, preparation method thereof and bottom blowing spray gun |
US11697880B2 (en) | 2016-08-16 | 2023-07-11 | Seram Coatings As | Thermal spraying of ceramic materials comprising metal or metal alloy coating |
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CN1162567C (en) * | 2001-12-28 | 2004-08-18 | 河北工业大学 | Spraying self-reaction composite powder onto metal surface to form composite metal/ceramic coating |
CN1865190A (en) * | 2006-06-01 | 2006-11-22 | 上海新业喷涂机械有限公司 | Zirconia/silicon carbide composite nano powder for hot spraying and its production method |
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Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014068082A2 (en) * | 2012-11-01 | 2014-05-08 | Norwegian University Of Science And Technology (Ntnu) | Thermal spraying of ceramic materials |
WO2014068082A3 (en) * | 2012-11-01 | 2014-12-31 | Norwegian University Of Science And Technology (Ntnu) | Thermal spraying of ceramic materials |
CN104903486A (en) * | 2012-11-01 | 2015-09-09 | 塞兰涂层公司 | Thermal spraying of ceramic materials |
AU2013340802B2 (en) * | 2012-11-01 | 2018-03-29 | Seram Coatings As | Thermal spraying of ceramic materials |
EA030816B1 (en) * | 2012-11-01 | 2018-10-31 | Серам Коатингз Ас | Thermal spraying of ceramic materials |
CN104903486B (en) * | 2012-11-01 | 2018-11-16 | 塞兰涂层公司 | The thermal spraying of ceramic material |
CN109279896A (en) * | 2012-11-01 | 2019-01-29 | 塞兰涂层公司 | The thermal spraying of ceramic material |
US11697880B2 (en) | 2016-08-16 | 2023-07-11 | Seram Coatings As | Thermal spraying of ceramic materials comprising metal or metal alloy coating |
CN110382440A (en) * | 2016-11-07 | 2019-10-25 | 科罗拉多大学董事会 | The performance of improved technology grade ceramics |
US11613502B2 (en) | 2016-11-07 | 2023-03-28 | The Regents Of The University Of Colorado | Core-shell ceramic particle colloidal gel and solid oxide fuel cell electrolyte |
CN109437148A (en) * | 2018-11-02 | 2019-03-08 | 山东天岳先进材料科技有限公司 | By the method for the long brilliant surplus material preparation high purity carbon material of silicon carbide |
CN111270190A (en) * | 2020-03-15 | 2020-06-12 | 河北工业大学 | Preparation method of high-entropy ceramic-alumina composite coating |
CN111270190B (en) * | 2020-03-15 | 2022-04-01 | 河北工业大学 | Preparation method of high-entropy ceramic-alumina composite coating |
CN113185268A (en) * | 2021-04-29 | 2021-07-30 | 湖南大学 | Preparation method of alumina ceramic material and alumina ceramic substrate |
CN113185268B (en) * | 2021-04-29 | 2022-04-22 | 湖南大学 | Preparation method of alumina ceramic material and alumina ceramic substrate |
CN116162931A (en) * | 2023-04-26 | 2023-05-26 | 中国恩菲工程技术有限公司 | Bottom blowing spray gun composite coating, preparation method thereof and bottom blowing spray gun |
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