CN101037589A - Dust preventing agent and preparation method thereof - Google Patents

Dust preventing agent and preparation method thereof Download PDF

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Publication number
CN101037589A
CN101037589A CN 200710021620 CN200710021620A CN101037589A CN 101037589 A CN101037589 A CN 101037589A CN 200710021620 CN200710021620 CN 200710021620 CN 200710021620 A CN200710021620 A CN 200710021620A CN 101037589 A CN101037589 A CN 101037589A
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China
Prior art keywords
weight part
preventing agent
dust preventing
water
quotient
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CN 200710021620
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Chinese (zh)
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CN100509990C (en
Inventor
施斌
黄河
刘瑾
高玮
王宝军
姜洪涛
徐建平
徐洁
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Nanjing University
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Nanjing University
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Priority to CNB2007100216203A priority Critical patent/CN100509990C/en
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Publication of CN100509990C publication Critical patent/CN100509990C/en
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Abstract

The invention discloses a dust preventing agent, which includes components of water or deionized water, acrylic acid, methacrylate, acrylamide and initiator, wherein proportion of each component is: 90-120 quotient of water or deionized water; 7-12 quotient of acrylic acid or 2-4 quotient of methyl methacrylate, ethyl methacrylate or propyl methacrylate; 2-4 quotient of acrylamide; 0.05-0.1 quotient of persulfate initiator; 0.03-0.05 quotient of crosslinking agent and 5-10 quotient of neutralizer which are also added. The dust preventing agent is thick liquid and is used after diluting, when being sprayed, the dust preventing agent can adsorb dust in air and combine with granule on ground surface to form film structure, and the dust preventing agent also possesses water-absorbing quality and water-retention property to prevent dust flying and clean air.

Description

Dust preventing agent and preparation method thereof
Technical field
The invention belongs to a kind of organic dedusting agent field, be specifically related to organic chemical industry's class dust preventing agent and preparation method thereof.
Background technology
Urban construction, all kinds of building field, mining, road construction, garbage loading embeading, industrial residue storage etc. can produce a large amount of dust, these dust granules are easily kicked up by wind and are swum in the air, cause atmospheric pollution, give rise to diseases, therefore the quality of life that has a strong impact on people must adopt an effective measure and be controlled with physically and mentally healthy.At present, the method that prevents of dust mainly contains spray sprinkler depositing dust, fly-ash separator dedusting etc., but all there is tangible limitation in these methods, and spraying and watering and lowering dust are provisional, in case dry air, floor-dust can be kicked up once again; The fly-ash separator dedusting just is used for regional area, is not suitable for the big area dedusting.Research and develop new technology and method and carry out the urgent task that dedusting is the environmentalist.
Summary of the invention
The objective of the invention is:, provide a kind of effective, dust preventing agent that cost is low, nontoxic, pollution-free, easy to use at the deficiency of existing dedusting method.
Technical scheme of the present invention is: dust preventing agent, main component comprise water or deionized water, vinylformic acid, methyl methacrylate, acrylamide.Wherein each set of dispense ratio is:
Water or deionized water 90-120 weight part
Vinylformic acid 7-12 weight part
Methyl methacrylate, ethyl ester or propyl ester 2-4 weight part
Acrylamide 2-4 weight part
Initiator (as persulphate) 0.05-0.1 weight part
The present invention adds in addition:
Linking agent (as quadrol) 0.03-0.05 weight part
Neutralizing agent (as ammoniacal liquor or sodium bicarbonate) 5-10 weight part
Its preparation method is: with deionized water, vinylformic acid, methyl methacrylate, acrylamide and linking agent Hybrid Heating, do not stop to stir, add initiator when being heated to 65-75 ℃, reacted 30-60 minute, the cooling back adds neutralizing agent and transfers to neutrality, obtains described dust preventing agent.
Characteristics of the present invention are: the present invention is viscous liquid, use the dilution back, dust during sprinkling in the energy absorbed air, combine with the fine particle of ground surface, easily form membrane structure, dust granule is played parcel, binding, firm effect, and have certain water-absorbent and water-retentivity, thereby prevent that dust from kicking up, play the effect that purifies air.
The present invention is neutral liquid, has nontoxic, free of contamination advantage, and used water is pressed the arbitrary proportion dilution, easy to use, good dedusting effect is a kind of high performance dust preventing agent, meeting " environmental labelling product technical requirements " basic demand (HJB2004-94), is environmentally friendly product.Cost of the present invention is low, easy to prepare, and is nontoxic, pollution-free, easy to use.
Embodiment
The present invention is mainly used in the airborne dust in places such as preventing all kinds of building fields, road construction, refuse landfill, storage ashpit, army campsite, mining, poisonous hazardous area, the effect of playing dust suppression and purifying air.
With deionized water, vinylformic acid, methyl methacrylate, acrylamide and linking agent Hybrid Heating, do not stop to stir, add initiator when being heated to 65-75 ℃, to react 30-60 minute, the cooling back adds neutralizing agent and transfers to neutrality, obtains described dust preventing agent.Wherein each set of dispense ratio is:
Deionized water 100-120 weight part: all can for 100 or 120 parts; Vinylformic acid 7-12 weight part: 7 or 12 parts all can, or methyl methacrylate 2-4 weight part: 2 or 4; Add acrylamide 2-4 weight part again: all can for 2 or 4 parts; Linking agent 0.03-0.05 weight part all can for 0.03 or 0.05 part; Initiator 0.05-0.1 weight part: 0.05 or 0.1 weight part all can; Neutralizing agent (typical in sodium hydroxide or potassium hydroxide) 5-10 weight part all can for 5 or 10 parts.Used water was diluted by arbitrary proportion when the present invention used.Can adopt as Potassium Persulphate is initiator.Linking agent: one of Resins, epoxy, isocyanic ester, urea resin, quadrol, also can adopt polyvalent metal salt 0.04 weight part.
Preparation method of the present invention: deionized water, vinylformic acid, methyl methacrylate, acrylamide and linking agent are pressed above-mentioned prescription Hybrid Heating, do not stop to stir, add initiator when being heated to 70 ℃, reaction times is 40 minutes, the cooling back adds neutralizing agent (general alkaline matter, as adopt sodium hydroxide or yellow soda ash) to transfer to pH neutral be 6.5-7.5, obtains described dust preventing agent.
Other embodiment:
1, water or deionized water 90-110, vinylformic acid 8-12, ammonium persulphate 0.05-0.15, ammoniacal liquor (1: 1) 4-6, the preparation method is heated to 65 ℃ (not stopping in the heat-processed to stir) with water or deionized water and vinylformic acid, added the ammonium persulphate afterreaction 30 minutes, the cooling back adds ammoniacal liquor and transfers to neutrality, promptly obtains goods of the present invention; Concrete prescription: water or deionized water 90 also can; Vinylformic acid 8, ammonium persulphate 0.10, ammoniacal liquor (1: 1) 6.
2, water or deionized water 90-110, vinylformic acid 7-9, ammonium persulphate 0.05-0.15, methyl methacrylate 3-5, ammoniacal liquor (1: 1) 4-6, the preparation method is heated to 65 ℃ (not stopping in the heat-processed to stir) with water or deionized water and vinylformic acid, methyl methacrylate, added the ammonium persulphate afterreaction 30 minutes, the cooling back adds ammoniacal liquor and transfers to neutrality, promptly obtains goods of the present invention; Concrete prescription: water or deionized water 110 also can; Vinylformic acid 8, ammonium persulphate 0.15, ammoniacal liquor (1: 1) 4.
3, with above-mentioned prescription, methyl methacrylate 3-5, quadrol 0.04-0.06, acrylamide 1-3, ammoniacal liquor (1: 1) 4-6, the preparation method is heated to 65 ℃ (not stopping in the heat-processed to stir) with water or deionized water and vinylformic acid, methyl methacrylate, acrylamide, quadrol etc., added the ammonium persulphate afterreaction 30 minutes, the cooling back adds ammoniacal liquor and transfers to neutrality, promptly obtains goods of the present invention;
Above-mentioned several goods example is viscous liquid, and concrete proterties sees the following form:
Goods Emulsion appearance Result of use
1 Colourless, thickness Good water solubility, dustproof effect is better
2 Oyster white, thickness Water-soluble general, dustproof effect is good
3 Oyster white, thickness Water-soluble general, dustproof effect is fine

Claims (5)

1, dust preventing agent is characterized in that composition comprises water or deionized water, vinylformic acid, methacrylic ester, acrylamide and initiator, and wherein each set of dispense ratio is:
Water or deionized water 90-120 weight part
Vinylformic acid 7-12 weight part
Or methyl methacrylate, ethyl ester or propyl ester 2-4 weight part
Persulfate initiator 0.05-0.1 weight part.
2, dust preventing agent according to claim 1 is characterized in that being added with acrylamide 2-4 weight part.
3, dust preventing agent according to claim 1 is characterized in that being added with linking agent 0.03-0.05 weight part, neutralizing agent 5-10 weight part.
4, dust preventing agent according to claim 1 is characterized in that linking agent is Resins, epoxy, isocyanic ester, urea resin, quadrol or polyvalent metal salt.
5, the preparation method of dust preventing agent: it is characterized in that with deionized water, vinylformic acid, methyl methacrylate, acrylamide and linking agent Hybrid Heating, do not stop to stir, add initiator when being heated to 65-75 ℃, reacted 30-60 minute, it is 6.5-7.5 that adding neutralizing agent in cooling back transfers to pH neutral, obtains described dust preventing agent.
CNB2007100216203A 2007-04-18 2007-04-18 Dust preventing agent and preparation method thereof Expired - Fee Related CN100509990C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2007100216203A CN100509990C (en) 2007-04-18 2007-04-18 Dust preventing agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2007100216203A CN100509990C (en) 2007-04-18 2007-04-18 Dust preventing agent and preparation method thereof

Publications (2)

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CN101037589A true CN101037589A (en) 2007-09-19
CN100509990C CN100509990C (en) 2009-07-08

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101418208B (en) * 2008-11-18 2012-07-04 太原晋太实业(集团)有限公司新星月环能科技分公司 Dust preventive for preventing throwing of coal car
CN103343012A (en) * 2013-07-02 2013-10-09 内蒙古大学 Method for preparing hydrophobic sand from waste organic glass
CN103555275A (en) * 2013-11-01 2014-02-05 朱红 High molecular thin film dust suppressant in netty structure and preparation method thereof
CN103700416A (en) * 2013-12-03 2014-04-02 中国人民解放军总参谋部工程兵科研三所 Method for removing radioactive contamination dust
CN104194725A (en) * 2014-07-21 2014-12-10 日照凯格环保科技有限公司 Goods stack dust suppressant and preparation method thereof
CN104693339A (en) * 2015-03-30 2015-06-10 河北工业大学 Water-based dust depressor and preparation method thereof
CN105037634A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Preparation method of bi-component liquid dust agglutinant
CN105037622A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Fine dust coagulant
CN105038068A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Liquid dust coagulant
CN105061967A (en) * 2015-08-27 2015-11-18 保护伞环保科技成都有限公司 Method for preparing double-component fine dust agglutinant
CN105086321A (en) * 2015-08-27 2015-11-25 保护伞环保科技成都有限公司 Dust coagulant
CN105086944A (en) * 2015-08-27 2015-11-25 保护伞环保科技成都有限公司 Preparation method of fine dust particle agglutinant
CN105985753A (en) * 2015-02-06 2016-10-05 宝山钢铁股份有限公司 Foaming agent capable of inhibiting raise dust and injection apparatus thereof
CN106010453A (en) * 2016-07-21 2016-10-12 合肥市东方美捷分子材料技术有限公司 Dust prevention and suppression agent
CN106085359A (en) * 2016-05-30 2016-11-09 鄂尔多斯市神东天隆化工有限责任公司 A kind of coal dust depressor and the method for suppression Coal Transport airborne dust
CN106479101A (en) * 2015-08-25 2017-03-08 南京理工大学 A kind of moisture-absorbing moisture-keeping type is combined small particle Fugitive dust inhibiting agent and preparation method thereof
CN109852346A (en) * 2018-09-19 2019-06-07 北京绿源鑫达科技有限公司 A kind of preparation method of environmental protection humidity-preserving type dust-proofing agent
CN110157379A (en) * 2019-06-21 2019-08-23 陕西科技大学 A kind of fire-retardant dust suppressant of soft film type coal and preparation method thereof
CN114214073A (en) * 2022-01-10 2022-03-22 江西润垚生物科技有限公司 Solid-state microbial soil remediation agent and preparation method thereof

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101418208B (en) * 2008-11-18 2012-07-04 太原晋太实业(集团)有限公司新星月环能科技分公司 Dust preventive for preventing throwing of coal car
CN103343012A (en) * 2013-07-02 2013-10-09 内蒙古大学 Method for preparing hydrophobic sand from waste organic glass
CN103555275A (en) * 2013-11-01 2014-02-05 朱红 High molecular thin film dust suppressant in netty structure and preparation method thereof
CN103555275B (en) * 2013-11-01 2015-01-14 朱红 High molecular thin film dust suppressant in netty structure and preparation method thereof
CN103700416B (en) * 2013-12-03 2016-02-03 中国人民解放军总参谋部工程兵科研三所 A kind of sweep-out method of radioactive contamination dust
CN103700416A (en) * 2013-12-03 2014-04-02 中国人民解放军总参谋部工程兵科研三所 Method for removing radioactive contamination dust
CN104194725A (en) * 2014-07-21 2014-12-10 日照凯格环保科技有限公司 Goods stack dust suppressant and preparation method thereof
CN104194725B (en) * 2014-07-21 2016-09-07 日照凯格环保科技有限公司 Stack dust suppressant and preparation method thereof
CN105985753A (en) * 2015-02-06 2016-10-05 宝山钢铁股份有限公司 Foaming agent capable of inhibiting raise dust and injection apparatus thereof
CN104693339A (en) * 2015-03-30 2015-06-10 河北工业大学 Water-based dust depressor and preparation method thereof
CN106479101A (en) * 2015-08-25 2017-03-08 南京理工大学 A kind of moisture-absorbing moisture-keeping type is combined small particle Fugitive dust inhibiting agent and preparation method thereof
CN105086321A (en) * 2015-08-27 2015-11-25 保护伞环保科技成都有限公司 Dust coagulant
CN105086944A (en) * 2015-08-27 2015-11-25 保护伞环保科技成都有限公司 Preparation method of fine dust particle agglutinant
CN105061967A (en) * 2015-08-27 2015-11-18 保护伞环保科技成都有限公司 Method for preparing double-component fine dust agglutinant
CN105038068A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Liquid dust coagulant
CN105037622A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Fine dust coagulant
CN105037634A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Preparation method of bi-component liquid dust agglutinant
CN106085359A (en) * 2016-05-30 2016-11-09 鄂尔多斯市神东天隆化工有限责任公司 A kind of coal dust depressor and the method for suppression Coal Transport airborne dust
CN106085359B (en) * 2016-05-30 2018-06-29 鄂尔多斯市神东天隆化工有限责任公司 A kind of method of coal dust depressor and inhibition Coal Transport airborne dust
CN106010453A (en) * 2016-07-21 2016-10-12 合肥市东方美捷分子材料技术有限公司 Dust prevention and suppression agent
CN109852346A (en) * 2018-09-19 2019-06-07 北京绿源鑫达科技有限公司 A kind of preparation method of environmental protection humidity-preserving type dust-proofing agent
CN110157379A (en) * 2019-06-21 2019-08-23 陕西科技大学 A kind of fire-retardant dust suppressant of soft film type coal and preparation method thereof
CN110157379B (en) * 2019-06-21 2022-04-26 陕西科技大学 Soft film type coal flame-retardant dust suppressant and preparation method thereof
CN114214073A (en) * 2022-01-10 2022-03-22 江西润垚生物科技有限公司 Solid-state microbial soil remediation agent and preparation method thereof
CN114214073B (en) * 2022-01-10 2022-07-26 江西润垚生物科技有限公司 Solid-state microbial soil remediation agent and preparation method thereof

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