CN101035846A - Aromatic high glass transition temperature sulfone polymer composition - Google Patents
Aromatic high glass transition temperature sulfone polymer composition Download PDFInfo
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- CN101035846A CN101035846A CNA2005800336736A CN200580033673A CN101035846A CN 101035846 A CN101035846 A CN 101035846A CN A2005800336736 A CNA2005800336736 A CN A2005800336736A CN 200580033673 A CN200580033673 A CN 200580033673A CN 101035846 A CN101035846 A CN 101035846A
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- polymer composition
- transition temperature
- aromatic sulfones
- repeating unit
- aromatic
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- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 229920000642 polymer Polymers 0.000 title claims abstract description 41
- 230000009477 glass transition Effects 0.000 title claims abstract description 27
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 21
- 150000003457 sulfones Chemical class 0.000 title claims description 8
- -1 aromatic sulfone Chemical class 0.000 claims abstract description 75
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims description 40
- 150000001875 compounds Chemical class 0.000 claims description 18
- 229920000515 polycarbonate Polymers 0.000 claims description 10
- 239000004417 polycarbonate Substances 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 125000003368 amide group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000005462 imide group Chemical group 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000005647 linker group Chemical group 0.000 claims description 2
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 230000017105 transposition Effects 0.000 claims description 2
- 229920002492 poly(sulfone) Polymers 0.000 abstract description 9
- 239000004695 Polyether sulfone Substances 0.000 abstract description 6
- 229920006393 polyether sulfone Polymers 0.000 abstract description 6
- 229920000491 Polyphenylsulfone Polymers 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- 150000002500 ions Chemical class 0.000 description 10
- 239000000654 additive Substances 0.000 description 8
- 239000012943 hotmelt Substances 0.000 description 8
- HNSDLXPSAYFUHK-UHFFFAOYSA-N 1,4-bis(2-ethylhexyl) sulfosuccinate Chemical compound CCCCC(CC)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(CC)CCCC HNSDLXPSAYFUHK-UHFFFAOYSA-N 0.000 description 7
- 229920012287 polyphenylene sulfone Polymers 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
- 229920003295 Radel® Polymers 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000012763 reinforcing filler Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000002146 bilateral effect Effects 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000012745 toughening agent Substances 0.000 description 2
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-M 9-cis,12-cis-Octadecadienoate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O OYHQOLUKZRVURQ-HZJYTTRNSA-M 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 241001553178 Arachis glabrata Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 102100022005 B-lymphocyte antigen CD20 Human genes 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 101000897405 Homo sapiens B-lymphocyte antigen CD20 Proteins 0.000 description 1
- 239000004420 Iupilon Substances 0.000 description 1
- 229920004142 LEXAN™ Polymers 0.000 description 1
- 239000004418 Lexan Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004425 Makrolon Substances 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 238000003436 Schotten-Baumann reaction Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 108010059485 brain synaptic membrane glycoprotein gp 50 Proteins 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 125000005534 decanoate group Chemical group 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- IMHDGJOMLMDPJN-UHFFFAOYSA-N dihydroxybiphenyl Natural products OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 229940049918 linoleate Drugs 0.000 description 1
- 229940040452 linolenate Drugs 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-M linolenate Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC([O-])=O DTOSIQBPPRVQHS-PDBXOOCHSA-M 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical class CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005649 polyetherethersulfone Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 229910052705 radium Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention relates to an aromatic high glass transition temperature polymer composition comprising : at least one aromatic sulfone polymer (P); at least one oxide of a metal; at least one carboxylate of a metal, said carboxylate comprising at least 10 carbon atoms. Preferably, the aromatic sulfone polymer (P) is chosen among the group consisting of polybiphenyldisulfone, polysulfone, polyphenylsulfone, polyethersulfone, copolymers and mixtures thereof.
Description
The cross reference of related application
The application requires the right of priority of U.S. Provisional Application of submitting on October 4th, 2,004 60/615,025 and the european patent application of submitting on February 24th, 2,005 05101408.2, and its disclosure is incorporated herein by reference herein.
On the one hand, the character of sulfone polymer makes polymkeric substance have a certain amount of vitriol that extracts inevitably.On the other hand, need aromatic high glass transition temperature polymer, for example polysulfones, polyethersulfone and Polyphenylene Sulfone are suitable for minimizing and can extract ionic and use, as responsive electronic application semi-conductor industry for example.Attempted to develop composite additive, to reduce the extraction sulphate content.
Lamentedly, these reductions additive that can extract sulphate content also is extracted.As a result, the further generation of these additives consequence that can extract.Obviously solve these and other defective with aromatic high glass transition temperature polymer composition of the present invention.
Therefore, the present invention seeks to the aromatic sulfones polymer composition of high glass-transition temperature, comprising:
-at least a aromatic sulfones polymkeric substance (P);
-at least a metal oxide;
-at least a metal carboxylate, described carboxylate salt comprises at least 10 carbon atoms.
Surprisingly, the combination of oxide compound and carboxylate salt advantageously provides the efficient of good chelating sulfate ion.Preferred these additives provide this benefit, and in addition, they keep the transparent appearance of aromatic sulfones polymkeric substance.
Be used for the object of the invention, term " polymer " " any material of forming by repeating unit basically of representative, and have and be higher than 2000 molecular weight.
Be used for the object of the invention, any such polymkeric substance of term " aromatic sulfones polymkeric substance (P) " representative, its at least the 5wt% repeating unit comprise at least one general formula 1 group:
(general formula 1)
Aromatic sulfones polymkeric substance (P) advantageously has at least 150 ℃ second-order transition temperature, preferably at least 160 ℃, more preferably at least 175 ℃.
Aromatic sulfones polymkeric substance (P) comprises 5wt% at least, preferred 20wt% at least, and more preferably 30wt% at least is more preferably 50wt% at least, is more preferably the repeating unit that 75wt% at least comprises at least one above-mentioned general formula 1 group.Most preferably, except comprising the repeating unit of at least one above-mentioned general formula 1 group, aromatic sulfones polymkeric substance (P) does not comprise other repeating units.
The repeating unit that the applicant finds to comprise in the aromatic sulfones polymkeric substance (P) at least one the above-mentioned general formula 1 group percentage of 5wt% at least enough gives the responsive electronic application of the present composition required high-temperature behavior.
Be not the qualification to invention scope, the applicant thinks that the existence of aromatic polycarbonate polymkeric substance may be harmful to the machinery and the ion extractuin performance of the present composition.
Therefore, the present composition advantageously comprises the aromatic polycarbonate (PC) that is lower than 10wt% based on the composition gross weight.
Be used for the object of the invention, on behalf of the above repeating unit of its 50wt%, term " aromatic polycarbonate (PC) " meet any polymkeric substance of following general formula 2:
Wherein Ar is the divalent group that comprises at least one aromatic ring, preferably comprises at least two aromatic rings.
The example of aromatic polycarbonate (PC) is the polymkeric substance that comprises following general formula 3 and/or 4 repeating units:
(general formula 3) (general formula 4)
Wherein:
-Ra and Rb are identical or different separately, and are hydrogen atom, halogen or C independently
1-C
6Alkyl;
-E is the divalent bridging group that is selected from down array structure:
Aromatic polycarbonate (PC) is particularly with trade(brand)name LEXAN
(from GE), MAKROLON
(from Bayer), CALIBER
(from Dow), PANLITE
(from Teijin) and IUPILON
Those that (from Mitsubishi) is purchased.
Commercially can prepare aromatic polycarbonate (PC) with two kinds of diverse ways: carry out Xiao Dun-Bao Man (Schotten-Baumann) reaction of carbonyl chloride and aromatic diol with amine catalytic interface condensation reaction, or through bis-phenol and the free carbon acid esters base-catalyzed transesterification of diphenyl carbonate for example.
Based on the gross weight of composition, the present composition preferably comprises less than 8wt%, is more preferably less than 7wt%, is more preferably the aromatic polycarbonate (PC) less than 5wt%.
According to the preferred embodiment for the present invention, the present composition does not have aromatic polycarbonate (PC).
Based on the gross weight of composition, the present composition advantageously comprises and is higher than 90wt%, preferably is higher than 92wt%, more preferably is higher than 95wt%, is more preferably the aromatic sulfones polymkeric substance (P) that is higher than 97.5wt%.
When the gross weight based on composition, when composition comprised the aromatic sulfones polymkeric substance (P) that is higher than 90wt%, then it had outstanding mechanical property and thermotolerance, is applicable to responsive electronic application, for example semi-conductor industry.
In the present invention's first preferred implementation, the repeating unit of the 5wt% at least of aromatic sulfones polymkeric substance (P) is repeating unit (R1), is its imide forms (R1-A) and/or amido acid form [(R1-B) and (R1-C)]:
Wherein:
-→ represent isomery, thus arrow indication group can exist or exist with transposition as shown in any repeating unit.
-Ar " be selected from down array structure:
With its mixture.
First preferred implementation according to the present invention, aromatic sulfones polymkeric substance (P) comprises 5wt% at least, preferred 20wt% at least, more preferably 30wt% at least is more preferably 50wt% at least, is more preferably the repeating unit of 75wt% (R1) at least.Most preferably, it does not comprise the repeating unit except that repeating unit (R1).
In the present invention's second preferred implementation, the repeating unit of 5wt% at least of aromatic sulfones polymkeric substance (P) is repeating unit (R2) and/or repeating unit (R3):
Wherein:
-Q is the group that is selected from down array structure:
With its mixture;
-Ar is the group that is selected from down array structure:
N is an integer 1 to 6, or high straight chain or branched aliphatic divalent group to 6 carbon atoms;
With its mixture;
-Ar ' is the group that is selected from down array structure:
Integer 1 to 6, or high straight chain or branched aliphatic divalent group to 6 carbon atoms;
With its mixture.
Repeating unit (R2) is preferably selected from:
With its mixture.
Repeating unit (R3) is preferably selected from:
With its mixture.
Second preferred implementation according to the present invention, aromatic sulfones polymkeric substance (P) comprises 5wt% at least, preferred 20wt% at least, more preferably 30wt% at least is more preferably 50wt% at least, is more preferably at least the repeating unit of 75wt% (R2) and/or (R3).Most preferably, it does not comprise except that repeating unit (R2) and/or other repeating units (R3).
With repeating unit wherein is the aromatic sulfones polymkeric substance (P) that repeating unit (ii) (is called poly-xenyl two sulfones) hereinafter, with repeating unit wherein is the aromatic sulfones polymkeric substance (P) of repeating unit (j) (being called polyphenylsulphine hereinafter), with repeating unit wherein is the aromatic sulfones polymkeric substance (P) of repeating unit (jj) (being called polyether ethersulfone hereinafter), with repeating unit wherein is the repeating unit (jjj) and the aromatic sulfones polymkeric substance (P) of optional repeating unit (jj) (being called polyethersulfone hereinafter) in addition, and be that the aromatic sulfones polymkeric substance (P) of repeating unit (jv) (being called polysulfones hereinafter) obtains good product with repeating unit wherein.
Polyphenylene Sulfone particularly can RADEL
R PPSF is from Solvay Advanced Polymers, those that L.L.C. obtains.Polysulfones particularly can UDEL
PSF is from Solvay AdvancedPolymers, those that L.L.C. obtains.Polyethersulfone particularly can RADEL
A PES is from Solvay Advanced Polymers, those that L.L.C. obtains.
Preferably, aromatic sulfones polymkeric substance (P) is selected from poly-xenyl two sulfones, polysulfones, Polyphenylene Sulfone, polyethersulfone, its multipolymer and mixture.
Preferably, metal oxide is the oxide compound of alkaline-earth metal or 12 group 4 transition metals.
Be used for goal of the invention,, specify the metals of forming by Zn, Cd, Hg, Uub for 12 group 4 transition metals.
More preferably, oxide compound is selected from CaO, MgO, ZnO and its mixture.Being more preferably oxide compound is ZnO.
Preferably, the carboxylate salt of metal is the carboxylate salt of alkaline-earth metal or 12 group 4 transition metals.
More preferably, carboxylate salt is selected from carboxylate salt and its mixture of Ca, Mg, Zn.Be more preferably, carboxylate salt is the zinc carboxylate salt.
Preferably, carboxylate salt is selected from caprate (C
10), lauroleate (C
12), tetradecanoate (C
14), palmitate (C
16), stearate (C
18), peanut hydrochlorate (C
20), elm hydrochlorate (C
22), physetoleic acid salt (C
16), oleate (C
18), eicosylene hydrochlorate (C
20), ricinoleate (C
18), linoleate (C
18), linolenate (C
18) and its mixture.Be more preferably, carboxylate salt is a stearate.
Obtain excellent product with Zinic stearas.
Based on the gross weight of composition, the aromatic high glass transition temperature polymer composition advantageously comprises 0.001wt% at least, preferred 0.005wt% at least, the more preferably oxide compound of 0.01wt% at least.
Based on the gross weight of composition, the aromatic high glass transition temperature polymer composition advantageously comprises 0.7wt% at the most, preferred 0.6wt% at the most, and more preferably 0.5wt% at the most is more preferably 0.3wt% at the most, most preferably the oxide compound of 0.2wt% at the most.
When the gross weight based on composition, composition comprises 0.02 when the 0.10wt% oxide compound, obtains excellent product.
Based on the gross weight of composition, the aromatic high glass transition temperature polymer composition advantageously comprises 0.005wt% at least, preferred 0.01wt% at least, the more preferably carboxylate salt of 0.05wt% at least.
Based on the gross weight of composition, the aromatic high glass transition temperature polymer composition advantageously comprises 1.00wt% at the most, preferred 0.75wt% at the most, the more preferably carboxylate salt of 0.50wt% at the most.
When the gross weight based on composition, composition comprises 0.05 when the 0.35wt% carboxylate salt, obtains excellent product.
Weight ratio in the present composition between oxide compound and the carboxylate salt is 1wt/wt at the most advantageously, preferred 0.75wt/wt at the most, more preferably 0.5wt/wt at the most.
Weight ratio in the present composition between oxide compound and the carboxylate salt is 0.05wt/wt at least advantageously, preferred 0.075wt/wt at least, more preferably 0.10wt/wt at least.
Obtain excellent result with 0.1 to 0.5wt/wt weight ratio between oxide compound and the carboxylate salt.
Randomly, the sulfone polymer composition of high glass-transition temperature of the present invention may further include filler, lubricant, thermo-stabilizer, static inhibitor, supplement, toughener, organic and/or mineral dye such as TiO
2, carbon black, antioxidant, fire retardant, the inhibitor of being fuming.
The present composition advantageously comprises at least a filler that is selected from reinforcing filler, structural fibers and its mixture.Structural fibers can comprise glass fibre, carbon fiber or graphite fibre, and the fiber that forms by silicon carbide, aluminum oxide, titanium dioxide, boron etc., and can comprise the mixture that contains two or more these fibers.The reinforcing filler that also can be used for the present composition comprises particularly pigment, thin slice, sphere and fibrous particles packing strengthening agent and nucleator, for example talcum, mica, titanium dioxide, potassium titanate, silicon-dioxide, kaolinite, chalk, aluminum oxide, mineral filler etc.Reinforcing filler and structural fibers can use separately or be used in combination with any.
Another aspect of the present invention relates to the manufacture method of the sulfone polymer composition of above-mentioned high glass-transition temperature, and it comprises mixing:
-aromatic sulfones polymkeric substance (P);
-metal oxide;
-metal carboxylate.
Advantageously, the inventive method comprise to polymkeric substance (P), oxide compound and carboxylate salt carry out dry blend/or hot melt be mixed, thereby make it to mix.
Preferably, be mixed and make it to mix by polymkeric substance (P), oxide compound and carboxylate salt being carried out hot melt.
Advantageously, in continuous or batch processing equipment polymkeric substance (P), oxide compound and carboxylate salt being carried out hot melt is mixed.This equipment is that those skilled in the art are known.
Sulfone polymer composition of the present invention is carried out particularly screw extrusion press of suitable continuous device example that hot melt is mixed.Therefore, advantageously polymkeric substance (P), oxide compound, carboxylate salt and optional other with powder or particle form becomes to be distributed into forcing machine, composition is extruded as strand, and this strand is cut into granular substance.
Randomly, can be during the step that is mixed with filler, lubricant, thermo-stabilizer, static inhibitor, supplement, toughener, organic and/or mineral dye such as TiO
2, carbon black, fire retardant, the inhibitor of being fuming is added to composition.
Preferably, in twin screw extruder polymkeric substance (P), oxide compound and carboxylate salt being carried out hot melt is mixed.
Can be according to injection molding, extrude, the standard method of thermoforming, mechanical workout and blowing further handles said composition.Also can carry out in addition the solution-based of coating and film is handled.After can experiencing standard manufacture, the end article that comprises above-mentioned composition operates for example ultrasonic welding, bonding and laser labelling and hot melt (heat staking), tapping (threading) and mechanical workout.
Another object of the present invention is the goods that comprise above-mentioned polymer composition.
Advantageously, these goods are injection molded article, extrusion die goods, molded article, coated article or casted article.Preferably it is an injection molded article.
Can make goods of the present invention by handling above-mentioned composition according to standard method.
Reference example is described the present invention in more detail; Yet the present invention is not limited to these embodiment.
Embodiment 1 to 5:
Raw material:
Can be from Solvay Advanced Polymers, the RADEL that L.L.C. is purchased
R 5600 Polyphenylene Sulfone be by polycondensation 4,4 '-dihalo diphenyl sulfone and 4,4 '-Polyphenylene Sulfone that dihydroxybiphenyl obtains.
Be mixed:
With zinc oxide, Zinic stearas and Magnesium Stearate and RADEL
R 5600 Polyphenylene Sulfone particles mix, and use 25mm diameter twin screw bilateral wind Berstorff forcing machine to carry out hot melt to be mixed, and this forcing machine has 33/1 L/D ratio.Detailed consumption among the embodiment is listed in table 1.
Ion extractuin and analysis are determined
According to follow procedure, to the particulate samples that is mixed from each prescription, and RADEL
The sample of R5600 Polyphenylene Sulfone itself carries out ion extractuin:
The 1.0g sample is placed in the 5.0ml 18m Ω water (can be from Alltech Associates, the Milli-Q that Inc. obtains).Then sample was placed in 85 ℃ of baking ovens 24 hours, with the extraction ion.
After 24 hours, use following analytical system,, and analyze water with IC (chromatography of ions) separating particles:
Dionex DX500 chromatographic system;
Dionex GP50 standard orifice gradient pump;
Dionex ASRS Ultra 4mm suppressor;
Dionex CD20 electric conductivity detector;
Dionex AS11A post, 4mm;
Dionex AG11A guard column, 4mm;
Dionex AS40 self-actuated sampler, inertia observation (Peek) flow path.
The elutriant that uses is a 18m Ω water, the 0.2-0.4mM KOH that is provided by the EG40 eluent generator.
For every kind of ion, use minimum 5 linear calibration curves that chromatography of ions is quantized.
The results are shown in table 1.
Table 1
| Component/performance | Comparative Examples 1 | Comparative Examples 2 | Comparative Examples 3 | Comparative Examples 4 | Embodiment 5 |
| There is not composite additive | Composite additive | ||||
| ZnO (wt％) | 0 | 0 | 0.50 | 0.03 | |
| Zinic stearas (wt%) | 0 | 0.30 | 0 | 0.30 | |
| Magnesium Stearate (wt%) | 0.30 | 0 | 0 | 0 | |
| The composition outward appearance | |||||
| The transparency | Transparent | Opaque | Transparent | Transparent | Transparent |
| Ion extractuin result (ng/g) | |||||
| Vitriol | 730 | 56 | 180 | 68 | 62 |
| Zinc | 55 | ＜40 | 37 | 3400 | 80 |
| Magnesium | n.d. | 76 | n.d. | n.d. | n.d. |
Embodiment 6 to 8:
Raw material:
Can be from Solvay Advanced Polymers, the UDEL that L.L.C. is purchased
The P3703 polysulfones be by polycondensation 4,4 '-polysulfones that dihalo sulfobenzide and dihydroxyphenyl propane obtain.
Be mixed:
With zinc oxide and Zinic stearas and UDEL
P3703 polysulfones particle mixes, and uses 25mm diameter twin screw bilateral wind Berstorff forcing machine that the mixture hot melt is mixed, and this forcing machine has 33/1 L/D ratio.Detailed usage quantity among the embodiment is listed in table 2.
Ion extractuin and analysis are determined
Composition and UDEL for embodiment 7 and 8
P3703 polysulfones itself (Comparative Examples 6) repeats the program identical with embodiment 1 to 5.The results are shown in table 2.
Table 2
| Component/performance | Comparative Examples 6 | Embodiment 7 | Embodiment 8 |
| Composite additive | |||
| ZnO (wt％) | There is not composite additive | 0.05 | 0.10 |
| Zinic stearas (wt%) | 0.25 | 0.20 | |
| Ion extractuin result (ng/g) | |||
| Vitriol | 3.0 | 0.29 | 0.30 |
| Zinc | ＜5.0 | ＜5.0 | ＜5.0 |
Claims (15)
1. the aromatic sulfones polymer composition of a high glass-transition temperature comprises:
-at least a aromatic sulfones polymkeric substance (P), wherein the repeating unit of the 5wt% at least of aromatic sulfones polymkeric substance (P) comprises at least one general formula 1 group:
(general formula 1);
-at least a metal oxide;
-at least a metal carboxylate, described carboxylate salt comprises at least 10 carbon atoms.
2. the aromatic sulfones polymer composition of the high glass-transition temperature of claim 1 is characterized in that, described aromatic sulfones polymkeric substance (P) comprises the repeating unit that 50wt% at least contains at least one general formula 1 group.
3. the aromatic sulfones polymer composition of claim 1 or 2 high glass-transition temperature is characterized in that based on the gross weight of composition, described aromatic sulfones polymer composition comprises the aromatic polycarbonate (PC) less than 10wt%.
4. each the aromatic sulfones polymer composition of high glass-transition temperature of claim 1 to 3 is characterized in that based on the gross weight of composition, described aromatic sulfones polymer composition comprises at least a aromatic sulfones polymkeric substance (P) that is higher than 90wt%.
5. each aromatic high glass transition temperature polymer composition is characterized in that metal oxide is the oxide compound of alkaline-earth metal or 12 group 4 transition metals during aforesaid right required.
6. each aromatic high glass transition temperature polymer composition is characterized in that metal carboxylate is the carboxylate salt of alkaline-earth metal or 12 group 4 transition metals during aforesaid right required.
7. the aromatic sulfones polymer composition of each high glass-transition temperature during aforesaid right requires, it is characterized in that, at least the repeating unit of the 5wt% of aromatic sulfones polymkeric substance (P) is repeating unit (R1), and it is imide forms (R1-A) and/or amido acid form [(R1-B) and (R1-C)]:
Wherein:
-→ represent isomery, thus arrow indication group can exist or exist with transposition as shown in any repeating unit;
-Ar " be selected from down array structure:
8. the aromatic sulfones polymer composition of each high glass-transition temperature during aforesaid right requires, it is characterized in that, at least the repeating unit of the 50wt% of aromatic sulfones polymkeric substance (P) is repeating unit (R1), and it is imide forms (R1-A) and/or amido acid form [(R1-B) and (R1-C)].
9. each the aromatic sulfones polymer composition of high glass-transition temperature of claim 1 to 6 is characterized in that the repeating unit of the 5wt% at least of aromatic sulfones polymkeric substance (P) is repeating unit (R2) and/or repeating unit (R3):
Wherein:
-Q is the group that is selected from down array structure:
With its mixture;
-Ar is the group that is selected from down array structure:
N is an integer 1 to 6, or high straight chain or branched aliphatic divalent group to 6 carbon atoms;
With its mixture;
-Ar ' is the group that is selected from down array structure:
With its mixture.
10. each the aromatic sulfones polymer composition of high glass-transition temperature of claim 1 to 6 or claim 9 is characterized in that the repeating unit of the 50wt% at least of aromatic sulfones polymkeric substance (P) is repeating unit (R2) and/or repeating unit (R3).
11. the aromatic sulfones polymer composition of each high glass-transition temperature is characterized in that based on the gross weight of composition, described aromatic sulfones polymer composition comprises 0.02 to 0.10wt% oxide compound during aforesaid right required.
12. the aromatic sulfones polymer composition of each high glass-transition temperature is characterized in that based on the gross weight of composition, described aromatic sulfones polymer composition comprises 0.05 to 0.35wt% carboxylate salt during aforesaid right required.
13. the aromatic sulfones polymer composition of each high glass-transition temperature is characterized in that during aforesaid right required, the weight ratio between oxide compound and the carboxylate salt is 0.1 to 0.5wt/wt.
14. a method of making the sulfone polymer composition of each high glass-transition temperature in the aforesaid right requirement, it comprises mixing:
-aromatic sulfones polymkeric substance (P);
-metal oxide;
-metal carboxylate.
15. goods, it comprises each the aromatic sulfones polymer composition of high glass-transition temperature of claim 1 to 13.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US61502504P | 2004-10-04 | 2004-10-04 | |
| US60/615,025 | 2004-10-04 | ||
| EP05101408A EP1695994B1 (en) | 2005-02-24 | 2005-02-24 | Aromatic high glass temperature sulfone polymer composition |
| EP05101408.2 | 2005-02-24 | ||
| PCT/EP2005/054975 WO2006037773A1 (en) | 2004-10-04 | 2005-10-03 | Aromatic high glass transition temperature sulfone polymer composition |
Publications (2)
| Publication Number | Publication Date |
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| CN101035846A true CN101035846A (en) | 2007-09-12 |
| CN101035846B CN101035846B (en) | 2012-04-25 |
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|---|---|---|---|
| CN2005800336736A Expired - Fee Related CN101035846B (en) | 2004-10-04 | 2005-10-03 | Aromatic high glass transition temperature sulfone polymer composition |
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| Country | Link |
|---|---|
| US (1) | US20080064801A1 (en) |
| EP (2) | EP1695994B1 (en) |
| KR (1) | KR101209532B1 (en) |
| CN (1) | CN101035846B (en) |
| AT (1) | ATE430777T1 (en) |
| DE (1) | DE602005014334D1 (en) |
| IN (1) | IN2007CH01376A (en) |
| MY (1) | MY139977A (en) |
| TW (1) | TWI384030B (en) |
| WO (1) | WO2006037773A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108026371A (en) * | 2015-06-10 | 2018-05-11 | 索尔维特殊聚合物美国有限责任公司 | Polymer composition and by its obtainable sterilized article |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20050250885A1 (en) * | 2004-05-04 | 2005-11-10 | General Electric Company | Halogen-free flame retardant polyamide composition with improved electrical properties |
| EP1524297A1 (en) * | 2004-12-22 | 2005-04-20 | Solvay Advanced Polymers, L.L.C. | Sulfone polymer composition |
| WO2009000741A1 (en) * | 2007-06-22 | 2008-12-31 | Basf Se | Molding materials comprising polyaryl ethers with improved surface quality |
| JP2017500228A (en) * | 2013-12-12 | 2017-01-05 | ソルベイ スペシャルティ ポリマーズ ユーエスエー， エルエルシー | Portable electronic device parts |
| KR102506317B1 (en) * | 2014-12-12 | 2023-03-06 | 퍼포먼스 폴리아미드 에스에이에스 | Polyamide compositions comprising a blend of polyamide 6,6 and at least one high chain-length polyamide, and al stearate, use thereof, and articles obtained therefrom |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS5714849A (en) * | 1980-06-30 | 1982-01-26 | Fuji Photo Film Co Ltd | Transfer film for electrophotographic copier |
| US4870155A (en) * | 1987-12-02 | 1989-09-26 | Amoco Corporation | Novel poly (etherimide) compositions |
| JPH062879B2 (en) * | 1988-12-19 | 1994-01-12 | 住友化学工業株式会社 | Method for producing aromatic polysulfone resin molding material with improved releasability |
| US5037587A (en) * | 1989-07-17 | 1991-08-06 | Mitsui Toatsu Chemicals, Inc. | Preparation process of polyimide film |
| US5017622A (en) * | 1990-10-16 | 1991-05-21 | The Dow Chemical Company | Sulfone polymer foam produced with aqueous blowing agent |
| JPH07238216A (en) * | 1994-03-01 | 1995-09-12 | Plus Teku Kk | Heat-resistant, electrically-conductive resin composition and heat-resistant ic tray using the same |
| DE4429107A1 (en) * | 1994-08-17 | 1996-02-22 | Basf Ag | Molding compounds made from polyarylene ethers and copolyamides |
| JPH08217976A (en) * | 1995-02-16 | 1996-08-27 | Sumitomo Chem Co Ltd | Aromatic polysulfone resin composition |
| DE19839331A1 (en) * | 1998-08-28 | 2000-03-02 | Basf Ag | Molding compositions based on polyarylene ether sulfones and aliphatic polyamides |
| US6329493B1 (en) * | 1998-10-06 | 2001-12-11 | Bp Corporation North America Inc. | Plumbing articles from poly(aryl ether sulfones) |
| KR100592832B1 (en) * | 2001-05-18 | 2006-06-26 | 쇼와 덴코 가부시키가이샤 | Coated Zinc Oxide Particle, and Production Process and Applications Thereof |
| US6919389B2 (en) * | 2003-03-13 | 2005-07-19 | Crompton Corporation | Polymer compositions containing benzimidazole based stabilizer compounds |
| US7186853B2 (en) * | 2003-06-05 | 2007-03-06 | Crompton Corporation | Polymer compositions containing stabilizer compounds comprising tricyclodecylmethyl groups |
| US20080058480A1 (en) * | 2004-10-04 | 2008-03-06 | Solvay Advanced Polymers | Sulfone Polymer Composition |
-
2005
- 2005-02-24 EP EP05101408A patent/EP1695994B1/en not_active Revoked
- 2005-02-24 AT AT05101408T patent/ATE430777T1/en not_active IP Right Cessation
- 2005-02-24 DE DE602005014334T patent/DE602005014334D1/en active Active
- 2005-09-29 TW TW094133996A patent/TWI384030B/en not_active IP Right Cessation
- 2005-10-03 US US11/576,524 patent/US20080064801A1/en not_active Abandoned
- 2005-10-03 WO PCT/EP2005/054975 patent/WO2006037773A1/en active Application Filing
- 2005-10-03 CN CN2005800336736A patent/CN101035846B/en not_active Expired - Fee Related
- 2005-10-03 MY MYPI20054659A patent/MY139977A/en unknown
- 2005-10-03 KR KR1020077007682A patent/KR101209532B1/en active IP Right Grant
- 2005-10-03 EP EP05797217.6A patent/EP1799757B1/en not_active Not-in-force
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108026371A (en) * | 2015-06-10 | 2018-05-11 | 索尔维特殊聚合物美国有限责任公司 | Polymer composition and by its obtainable sterilized article |
| CN108026371B (en) * | 2015-06-10 | 2021-09-03 | 索尔维特殊聚合物美国有限责任公司 | Polymer composition and sterilized article obtainable therefrom |
Also Published As
| Publication number | Publication date |
|---|---|
| MY139977A (en) | 2009-11-30 |
| KR20070058587A (en) | 2007-06-08 |
| ATE430777T1 (en) | 2009-05-15 |
| KR101209532B1 (en) | 2012-12-07 |
| EP1695994B1 (en) | 2009-05-06 |
| EP1695994A1 (en) | 2006-08-30 |
| WO2006037773A1 (en) | 2006-04-13 |
| DE602005014334D1 (en) | 2009-06-18 |
| TWI384030B (en) | 2013-02-01 |
| IN2007CH01376A (en) | 2007-08-31 |
| CN101035846B (en) | 2012-04-25 |
| EP1799757A1 (en) | 2007-06-27 |
| US20080064801A1 (en) | 2008-03-13 |
| EP1799757B1 (en) | 2017-01-04 |
| TW200619319A (en) | 2006-06-16 |
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