CN101029258A - Lead-free methanol petroleum - Google Patents

Lead-free methanol petroleum Download PDF

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Publication number
CN101029258A
CN101029258A CN 200610018445 CN200610018445A CN101029258A CN 101029258 A CN101029258 A CN 101029258A CN 200610018445 CN200610018445 CN 200610018445 CN 200610018445 A CN200610018445 A CN 200610018445A CN 101029258 A CN101029258 A CN 101029258A
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China
Prior art keywords
gasoline
lead
free methanol
petroleum
additive
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Pending
Application number
CN 200610018445
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Chinese (zh)
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章鹏
章敏
章龙发
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章鹏
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Priority to CN 200610018445 priority Critical patent/CN101029258A/en
Publication of CN101029258A publication Critical patent/CN101029258A/en
Pending legal-status Critical Current

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Abstract

A lead-free methanol gasoline and its production are disclosed. The gasoline consists of methanol 16-70wt%, gasoline 26-80wt%, additive 1.5-3.5wt%; additive consists of acetone 4-35wt%, isopropanol 8-30wt%, dicyclopentadienylirion 3-6wt%, n-pentane 17-45wt%, Tween-80 7-30wt%, oleinic acid 10-35wt% and potassium hypermanganate 1-3wt%. It's simple and cheap and has no lead, better ignition and start performances.

Description

Lead-free methanol petroleum
Technical field
The present invention relates to a kind of synthetic gasoline, particularly a kind of lead-free methanol petroleum.
Background technology
Along with the Chinese national economy sustained and rapid development, domestic petroleum consumption increases rapidly: 1998 to 2003, in 2.6 hundred million tons, net oil import was above 9,600 ten thousand tons substantially for the domestic petroleum consumption; The consumption of China's oil in 2004 surpasses 2.7 hundred million tons, 1.2 hundred million tons of imported crude oils; And but China's prediction oil production of resources amount is about 15,000,000,000 tons, but now totally verifies 63.4 hundred million tons of oil digging reserves, at present, but 23.7 hundred million tons of residual petroleum digging reserves is arranged, and occupies the 12nd in the world.And per capita oily resource is less, only is equivalent to 1/6 of world average level.According to statistics, after China in 1993 becomes net import of oil state, the external interdependency of oil from 7.6% of nineteen ninety-five be increased to 2000 31%, the external interdependency that expects the year two thousand twenty China's oil may be near 60%.China is as the second-biggest-in-the-world oil consuming countries and reserves approximately only account for world oil total reserves 2%, this means international crude oil market any the rustle of leaves in the wind all will exert an influence to China's economy.Therefore, hydrocarbon resources is the grand strategy resource that concerns China's modernization construction overall situation and national security; It is that the smooth realization of China's Economic development, national security and the target of building a well-off society in an all-round way provides safeguard.
The Hu Jintao General Secretary is mentioning the over half from the Middle East, Africa, south east asia of Conoco import, imported crude oil about 4/5ths is by Strait of Malacca sea transport, and some big countries have a finger in every pie always and attempt to control the shipping channel of the Strait of Malacca.Therefore, he represents, the Oil Safety reality in continent allows of no optimist, and must formulate new petroleum-based energy development strategy from new strategic global height, adhere to saving and lay equal stress on exploitation, domestic resource and foreign resources are laid equal stress on, and set up the strategic reserves of Conoco, progressively set up Energy production support base overseas, develop actively oil replacement product is adopted vigorous measures and is guaranteed national oil sources safety.Therefore, seek a kind of ideal oil fuel surrogate, become one of important subject in the contemporary science and technology field.
Summary of the invention
The objective of the invention is to propose a kind of with synthetic gasoline such as methyl alcohol, gasoline, additives, the methyl alcohol amount of participating in is big, store in the use not stratified, can reduce automobile exhaust pollution to greatest extent, motor car engine is had no adverse effects, combustion efficacy is good, can reduce production costs synthetic high grade lead-free methanol petroleum under normal temperature and pressure conditions.
Content of the present invention is: a kind of synthetic lead-free methanol petroleum, its feature part are to form (weight %) to be:
Methyl alcohol 16.0-70.0%
Gasoline 26.0-80.0%
Additive 1.5-3.5%
Methyl alcohol of the present invention is the methyl alcohol of content 〉=98%.
Gasoline of the present invention is No. 90 to No. 120 gasoline.
Gasoline of the present invention can be straight-run spirit or winterization gasoline or shifting block gasoline.
Additive of the present invention is to constitute (weight %) by following component:
Acetone 4.0-35.0%
Virahol 8.0-30.0%
Ferrocene 3.0-6.0%
Skellysolve A 17.0-45.0%
Tween-80 7.0-30.0%
Oleic acid 10.0-35.0%
Potassium permanganate 1.0-3.0%
The manufacture method of lead-free methanol petroleum, by weight percentage, produce by following steps:
Under normal temperature and pressure conditions, methyl alcohol, gasoline, additive are placed container separately, according to described each component in proportion the amount of getting mix promptly and finish, sealing is deposited; Wherein additive is also under normal temperature and pressure conditions, after the amount of getting mixes in proportion according to described each component with propyl alcohol, Virahol, ferrocene, Skellysolve A, tween-80, oleic acid, potassium permanganate, refilters and gets final product.
Methyl alcohol of the present invention is the main fuel of this fuel, and octane value generally is higher than gasoline, and vaporization heat is big, and the gasification coefficient of expansion is big, the heat utilization efficiency height; Gasoline Zuo Wei Dian fire agent and main fuel; Additive mainly is made up of solubility promoter (acetone, Virahol), stablizer (tween-80, oleic acid), octane promoter (ferrocene), catalyst (potassium permanganate) etc.Promote fuel perfect combustion after adding ferrocene in the component, reduce the black smoke that engine is discharged, realize the purpose of prevention and cure of pollution, clear energy sources, cleaning ambient; Add potassium permanganate and can further promote dissolving each other of each raw material, solved the layering of fuel and played the problem of oil group.
The present invention compared with prior art has following Te Dian:
1, lead-free methanol petroleum of the present invention is operated at normal temperatures and pressures, and technical process is simple, but the technological process continuous production.
2, lead-free methanol petroleum abundant raw material of the present invention, be easy to get, production cost is low.
3, do not need in use other parts such as engine of existing automobile are transformed or upgraded , Dian bad temper can be good for lead-free methanol petroleum of the present invention, easily starts.
4, the methyl alcohol amount of participating in the lead-free methanol petroleum of the present invention is big, has higher anti-knocking property and good vapo(u)rability, and storage is not stratified in using, good stability, and combustion efficacy is good.
5, lead-free methanol petroleum of the present invention can reduce environmental pollution, it is not leaded, and the motor vehicle exhaust less contamination is in operator's atmospheric environment, methanol concentration is lower than the mean intensity value that China's Residential areas atmospheric environment allows, and can not produce detrimentally affect to HUMAN HEALTH.
6, lead-free methanol petroleum of the present invention has oil-saving effect.
Below by embodiment the present invention is further described:
Embodiment one
Methyl alcohol 51.0%
No. 90 gasoline 47.0%
Additive 2.0%
Wherein additive by the weight percent proportioning of following each composition is
Acetone 19.0%
Virahol 5.0%
Ferrocene 5.0%
Skellysolve A 23.0%
Tween one 80 23.0%
Oleic acid 23.0%
Potassium permanganate 2.0%
Embodiment two
Methyl alcohol 70.0%
No. 90 gasoline 27.0%
Additive 3.0%
Wherein additive by the weight percent proportioning of following each composition is
Acetone 19.0%
Virahol 13.0%
Ferrocene 3.5%
Skellysolve A 19.0%
Tween one 80 19.0%
Oleic acid 25.0%
Potassium permanganate 1.5%
Embodiment three
Methyl alcohol 25.0%
No. 90 gasoline 73.0%
Additive 1.8%
Wherein additive by the weight percent proportioning of following each composition is
Acetone 14.0%
Virahol 19.0%
Triscyclopentadienyl iron 5.0%
Skellysolve A 32.0%
Tween one 80 9.0%
Oleic acid 19.0%
Potassium permanganate 2.0%
During preparation, only need under normal temperature and pressure conditions, the methyl alcohol of content 〉=98%, No. 90 gasoline, additives are dropped into to mix promptly in the container by the various embodiments described above proportional quantity and finish; Its additive after mixing according to the various embodiments described above additive formula amount, refilters and gets final product also under normal temperature and pressure conditions.

Claims (5)

1, lead-free methanol petroleum is by methyl alcohol, gasoline, additive synthetic, it is characterized in that this lead-free methanol petroleum is that methyl alcohol 16.0-70.0%, gasoline 26.0-80.0%, additive 1.5-3.5% form with the weight percent.
2, root a tree name right 1 described lead-free methanol petroleum is characterized in that described methyl alcohol is the methyl alcohol of content 〉=98%.
3, root a tree name right 1 described lead-free methanol petroleum is characterized in that described gasoline is No. 90 to No. 120 gasoline.
4, root a tree name right 1 and right 2 described lead-free methanol petroleums is characterized in that described gasoline can be straight-run spirit or winterization gasoline or shifting block gasoline.
5, root a tree name right 1 described lead-free methanol petroleum is characterized in that described additive is acetone 4.0-35.0%, Virahol 8.0-30.0%, ferrocene 3.0-6.0%, Skellysolve A 17.0-45.0%, tween one 80 7.0-30.0%, oleic acid 10.0-35.0%, potassium permanganate 1.0-3.0% composition with the weight percent.
CN 200610018445 2006-02-27 2006-02-27 Lead-free methanol petroleum Pending CN101029258A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200610018445 CN101029258A (en) 2006-02-27 2006-02-27 Lead-free methanol petroleum

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200610018445 CN101029258A (en) 2006-02-27 2006-02-27 Lead-free methanol petroleum

Publications (1)

Publication Number Publication Date
CN101029258A true CN101029258A (en) 2007-09-05

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102115682A (en) * 2009-12-31 2011-07-06 薛广华 Fuel aid
CN102304398A (en) * 2011-08-01 2012-01-04 长安大学 Moderate-proportion methanol gasoline additive
CN102618337A (en) * 2012-04-11 2012-08-01 韦唯 Method for manufacturing civil fuel of biological alcohol oil
CN101445752B (en) * 2008-12-26 2012-12-19 西安安得利清洁能源有限公司 Alcohol-based gasoline fuel
CN102876399A (en) * 2012-10-29 2013-01-16 孙建国 Production technical formula of high-methanol-proportion gasoline
CN103666596A (en) * 2013-12-02 2014-03-26 济南开发区星火科学技术研究院 Preparation method of biomass clean gasoline
CN103980958A (en) * 2014-04-14 2014-08-13 王树廷 Synthetic liquid fuel
CN104560228A (en) * 2014-12-26 2015-04-29 深圳市涤牌燃料开发有限公司 Automotive alcohol-hydrocarbon and gasoline composite fuel and preparation method thereof
CN107384490A (en) * 2017-09-01 2017-11-24 于仰坤 A kind of biogasoline containing additive and its preparation method and application
CN108795494A (en) * 2017-05-04 2018-11-13 中国石油化工股份有限公司 Recapitalization generating oil hydrogenation device and cut light tower coupled system
CN108929729A (en) * 2018-07-18 2018-12-04 宁波蒙曼生物科技有限公司 A kind of novel alcohol-based liquid fuel and its preparation method and application
CN109321288A (en) * 2017-07-30 2019-02-12 章敏 A kind of automobile-used another name for gasoline and its preparation method

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445752B (en) * 2008-12-26 2012-12-19 西安安得利清洁能源有限公司 Alcohol-based gasoline fuel
CN102115682A (en) * 2009-12-31 2011-07-06 薛广华 Fuel aid
CN102304398A (en) * 2011-08-01 2012-01-04 长安大学 Moderate-proportion methanol gasoline additive
CN102618337A (en) * 2012-04-11 2012-08-01 韦唯 Method for manufacturing civil fuel of biological alcohol oil
CN102876399A (en) * 2012-10-29 2013-01-16 孙建国 Production technical formula of high-methanol-proportion gasoline
CN103666596A (en) * 2013-12-02 2014-03-26 济南开发区星火科学技术研究院 Preparation method of biomass clean gasoline
CN103980958A (en) * 2014-04-14 2014-08-13 王树廷 Synthetic liquid fuel
CN104560228A (en) * 2014-12-26 2015-04-29 深圳市涤牌燃料开发有限公司 Automotive alcohol-hydrocarbon and gasoline composite fuel and preparation method thereof
CN108795494A (en) * 2017-05-04 2018-11-13 中国石油化工股份有限公司 Recapitalization generating oil hydrogenation device and cut light tower coupled system
CN108795494B (en) * 2017-05-04 2023-07-28 中国石油化工股份有限公司 Coupling system of hydrogenation device and light component removing tower for reforming generated oil
CN109321288A (en) * 2017-07-30 2019-02-12 章敏 A kind of automobile-used another name for gasoline and its preparation method
CN107384490A (en) * 2017-09-01 2017-11-24 于仰坤 A kind of biogasoline containing additive and its preparation method and application
CN108929729A (en) * 2018-07-18 2018-12-04 宁波蒙曼生物科技有限公司 A kind of novel alcohol-based liquid fuel and its preparation method and application

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