CN101025501A - Reflexible color LCD and its manufacturing method - Google Patents

Reflexible color LCD and its manufacturing method Download PDF

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Publication number
CN101025501A
CN101025501A CN 200710005191 CN200710005191A CN101025501A CN 101025501 A CN101025501 A CN 101025501A CN 200710005191 CN200710005191 CN 200710005191 CN 200710005191 A CN200710005191 A CN 200710005191A CN 101025501 A CN101025501 A CN 101025501A
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Prior art keywords
liquid crystal
glass substrate
crystal layer
light absorbing
absorbing zone
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CN 200710005191
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鸟原秀胜
高野敦史
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Nanox Co Ltd
Nanox Corp
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Nanox Co Ltd
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Abstract

The present invention provides a reflection type color liquid crystal display device which can maintain the homogeneity of liquid crystal display and can reduce the parallax and its manufacturing method. The reflection type color liquid crystal display device has a light absorbing layer (11) and a red reflect LCD (15), a green reflect LCD (19) and a blue reflect LCD (23) cascaded on the light absorbing layer (11) in sequence. These reflect liquid crystal displays (15, 19 and 23) have plural glass base plates (13 and 14, 17 and 18, 21 and 22) and liquid crystal layers (12, 16 and 20) formed among the plural glass base plates (13 and 14, 17 and 18, 21 and 22). At least two surfaces of the plural glass base plate surfaces between the first liquid crystal layer (12) disposed nearest to the light absorbing layer (11) and the second liquid crystal layer (20) disposed farthest to the light absorbing layer (11) are grinded; and the maximum value of the parallax B (mm) represented by the follow formula is lower than 0.51 mm. B=A x tan(arcsin(sinTheta/n) x cosTheta); Theta: view angle; A: distance (mm) between reflect liquid crystal layer; n: the refractivity of the grinded glass base plate.

Description

Reflexible color LCD and manufacture method thereof
Technical field
The present invention relates to Reflexible color LCD and manufacture method thereof, particularly by the stacked colour that constitutes of reflection liquid crystal display (reflective LCD) is shown cholesteric liquid crystal display and manufacture method thereof.
Background technology
Colored show that cholesteric liquid crystal display is that the reflection liquid crystal display (reflective LCD) that reflects by the wavelength that will select to stipulate is stacked and constitutes.For example, as shown in Figure 9, colored demonstration cholesteric liquid crystal display 100 possesses: the light absorbing zone 101 of black; Be layered in the red reflex LCD105 on the light absorbing zone 101, it is formed with the red reflex liquid crystal layer 102 that shows red reflected colour between substrate 103,104; Be layered in the green reflective LCD 109 on the red reflex LCD105, it is formed with the green reflective liquid crystal layer 106 that shows green reflected colour between substrate 107,108; With the blue reflective LCD 113 that is layered on the green reflective LCD 109, it is formed with the blue reflective liquid crystal layer 110 that shows blue reflected colour between substrate 111,112.Like this, the reflective LCD 105,109,113 of the reflected colour by will showing RGB (red, green, blue) 3 looks is layered on the light absorbing zone 101, thereby makes and coloredly show that cholesteric liquid crystal display 100 can carry out full color and show.
As the substrate 103,104,107,108,111,112 of above-mentioned reflective LCD 105,109,113, use glass substrate that constitutes by glass or the flexible base, board (for example opening the 2004-2765 communique) that constitutes by resins such as polycarbonate with reference to the spy with light transmission.
But, using under the situation of glass substrate as the substrate 103,104,107,108,111,112 of reflective LCD 105,109,113, as shown in Figure 9, because the thickness of slab t of glass substrate is thicker, so (reflective liquid crystal interfloor distance A) is elongated for the distance that red reflex liquid crystal layer 102 and blue reflective liquid crystal layer are 110, produce parallax (angle dependence of visuognosis) B based on this reflective liquid crystal interfloor distance A, the demonstration of thinner literal etc. fogs and can not realize high meticulous demonstration.Here, also can consider to use the situation of the thin glass substrate of thickness of slab t, but the glass substrate that thickness of slab t is thin is expensive, and, the manufacturing process that shows cholesteric liquid crystal display 100 at colour is less than under the situation corresponding to thin glass substrate, in order to make manufacturing process need the huge installation cost of cost corresponding to thin glass substrate, and the yield rate step-down is arranged and situation that cost uprises.
In addition, using under the situation of flexible base, board as the substrate 103,104,107,108,111,112 of reflective LCD 105,109,113, though make the flexible base, board attenuation easily, but the flexible base, board that is formed with nesa coating (ITO film) is expensive, and because flexible base, board has high flexibility, so be difficult to be formed uniformly liquid crystal cell (cell) gap of injecting liquid crystal, damage the homogeneity of liquid crystal display sometimes.
Summary of the invention
The purpose of this invention is to provide a kind of Reflexible color LCD and the manufacture method thereof that can keep the homogeneity of liquid crystal display and can reduce parallax.
In order to achieve the above object, according to the 1st technical scheme of the present invention, a kind of Reflexible color LCD is provided, be to possess light absorbing zone and the Reflexible color LCD that stacks gradually a plurality of reflection liquid crystal displays on above-mentioned light absorbing zone, it is characterized in that: above-mentioned a plurality of reflection liquid crystal displays have a plurality of glass substrates respectively and are formed on liquid crystal layer between above-mentioned a plurality of glass substrate; And at least two faces that are provided in a plurality of glass substrate faces between the 2nd liquid crystal layer that forms on the 1st liquid crystal layer that forms on the nearest position of above-mentioned light absorbing zone and the above-mentioned light absorbing zone of the distance position are farthest ground; And the maximal value of the parallax B (mm) that is expressed from the next is below the 0.51mm, wherein:
B=A×tan(arcsin(sinθ/n)×cosθ)
θ: visual angle
A: reflective liquid crystal interfloor distance (mm)
N: the refractive index of the glass substrate after the above-mentioned grinding.
Structure according to the 1st technical scheme of the present invention, because at least two faces that are provided in a plurality of glass substrate faces between the 1st liquid crystal layer and the 2nd liquid crystal layer are ground, and the maximal value of the parallax B (mm) that is expressed from the next is below the 0.51mm, so can keep the homogeneity of liquid crystal display, and can shorten the distance between the 1st liquid crystal layer and the 2nd liquid crystal layer and reduce parallax.
B=A×tan(arcsin(sinθ/n)×cosθ)
θ: visual angle
A: reflective liquid crystal interfloor distance (mm)
N: the refractive index of the glass substrate after the above-mentioned grinding
In the 1st technical scheme of the present invention, preferably, the thickness of slab with glass substrate of the glass substrate face after the above-mentioned grinding is below the 0.3mm.
In order to achieve the above object, according to the 2nd technical scheme of the present invention, a kind of manufacture method of Reflexible color LCD is provided, be to possess light absorbing zone and the manufacture method that stacks gradually the Reflexible color LCD of a plurality of reflection liquid crystal displays on above-mentioned light absorbing zone, it is characterized in that: possess the liquid crystal layer that liquid crystal is injected between a plurality of glass substrates separately of above-mentioned a plurality of reflection liquid crystal displays and forms liquid crystal layer and form step, with to being provided in the glass substrate face grinding steps that the 1st nearest liquid crystal layer of the above-mentioned light absorbing zone of distance and at least two faces in a plurality of glass substrate faces between above-mentioned light absorbing zone the 2nd liquid crystal layer farthest grind; And the maximal value of the parallax B (mm) that is expressed from the next is below the 0.51mm,
B=A×tan(arcsin(sinθ/n)×cosθ)
θ: visual angle
A: reflective liquid crystal interfloor distance (mm)
N: the refractive index of the glass substrate after the above-mentioned grinding.
Structure according to the 2nd technical scheme of the present invention, because at least two faces that are provided in a plurality of glass substrate faces between the 1st liquid crystal layer and the 2nd liquid crystal layer are ground, and the maximal value of the parallax B (mm) that is expressed from the next is below the 0.51mm, so can keep the homogeneity of liquid crystal display, and can shorten the distance between the 1st liquid crystal layer and the 2nd liquid crystal layer and reduce parallax
B=A×tan(arcsin(sinθ/n)×cosθ)
θ: visual angle
A: reflective liquid crystal interfloor distance (mm)
N: the refractive index of the glass substrate after the above-mentioned grinding
In the 2nd technical scheme of the present invention, preferably, the thickness of slab with glass substrate of the glass substrate face after grinding in above-mentioned glass substrate face grinding steps is below the 0.3mm.
Above-mentioned and other purposes, feature and advantage of the present invention will become clearer by the following detailed explanation based on accompanying drawing.
Description of drawings
Fig. 1 is the cut-open view of structure of roughly representing the Reflexible color LCD of embodiments of the present invention.
Fig. 2 A is the figure that the grinding to the glass substrate among Fig. 1 describes, and is the figure of the state before expression is ground glass substrate.
Fig. 2 B is the figure that the grinding to the glass substrate among Fig. 1 describes, and is the figure of the state after expression is ground glass substrate.
Fig. 3 is the process flow diagram of the manufacture method of the reflective LCD in the presentation graphs 1.
Fig. 4 is the figure of the cut-out step S303 in the key diagram 3.
Fig. 5 is the cut-open view of structure of the 1st variation of the Reflexible color LCD of presentation graphs 1 roughly.
Fig. 6 is the cut-open view of structure of the 2nd variation of the Reflexible color LCD of presentation graphs 1 roughly.
Fig. 7 is the cut-open view of structure of the 3rd variation of the Reflexible color LCD of presentation graphs 1 roughly.
Fig. 8 is the cut-open view of structure of the 4th variation of the Reflexible color LCD of presentation graphs 1 roughly.
Fig. 9 is a cut-open view of roughly representing the structure of Reflexible color LCD in the past.
Embodiment
Below, the Reflexible color LCD of embodiments of the present invention is described with reference to accompanying drawing.
Fig. 1 is the cut-open view of structure of roughly representing the Reflexible color LCD of embodiments of the present invention.
In Fig. 1, show that as the colour of Reflexible color LCD cholesteric liquid crystal display 10 possesses: the light absorbing zone 11 of black; Be layered in the red reflex LCD15 on the light absorbing zone 11, it is formed with the red reflex liquid crystal layer 12 that shows red reflected colour between glass substrate 13,14; Be layered in the green reflective LCD 19 on the red reflex LCD15, it is formed with the green reflective liquid crystal layer 16 that shows green reflected colour between glass substrate 17,18; And being layered in blue reflective LCD 23 on the green reflective LCD 19, it is formed with the blue reflective liquid crystal layer 20 that shows blue reflected colour between glass substrate 21,22.In addition, reflective LCD 15,19,23 is fixed by bonding agent mutually.Like this, the reflective LCD 15,19,23 of the reflected colour by will showing RGB (red, green, blue) 3 looks is layered on the light absorbing zone 11, thereby makes and coloredly show that cholesteric liquid crystal display 10 can carry out full color and show.
In addition, reflective liquid crystal interfloor distance A among Fig. 1 is the thickness of the following side of blue reflective liquid crystal layer 20, the thickness of slab t of glass substrate 21, the thickness of the bonding agent (not shown) that glass substrate 21 and glass substrate 18 is bonding, the thickness t of glass substrate 18, the thickness of green reflective liquid crystal layer 16, the thickness of slab t of glass substrate 17, the thickness of the bonding agent (not shown) that glass substrate 17 and glass substrate 14 is bonding, the thickness t of glass substrate 14, with the total of the thickness of the upper lateral part of red reflex liquid crystal layer 12, but liquid crystal layer 12,16,20 and the thickness and a lot of and negligible situations of thickness of slab t thin in comparison of bonding agent (not shown) more.
Fig. 2 A is the figure that the grinding to the glass substrate among Fig. 1 describes, and is the figure of the state before expression is ground glass substrate.Fig. 2 B is the figure that the grinding to the glass substrate among Fig. 1 describes, and is the figure of the state after expression is ground glass substrate.
In Fig. 2 A and Fig. 2 B, glass substrate face 14a, 17a, 18a, the 21a that is provided between red reflex liquid crystal layer 12 and the blue reflective liquid crystal layer 20 ground, so that be provided in apart from the nearest red reflex liquid crystal layer 12 of light absorbing zone 11 (with reference to Fig. 1) (the 1st liquid crystal layer) and be more than the 0.05mm (reflective liquid crystal interfloor distance A is 0.20mm) and below the 0.30mm (reflective liquid crystal interfloor distance A is 1.20mm) apart from the thickness of slab t of the glass substrate 14,17,18,21 between light absorbing zone 11 (with reference to Fig. 1) the blue reflective liquid crystal layer 20 (the 2nd liquid crystal layer) farthest.Here, only to glass substrate face 14a, 17a, 18a, 21a grind be because, even glass substrate face 13a, the 22a beyond glass substrate face 14a, 17a, 18a, the 21a ground, can not reduce colour and show the parallax of cholesteric liquid crystal display 10 and can reduce the colored intensity that shows cholesteric liquid crystal display 10.
In addition, the grinding of glass substrate face 14a, 17a, 18a, 21a is to be to grind in two stages of carrying out etching in the etching solution of major component, then glass substrate being carried out mechanical lapping to implement by being impregnated into hydrofluorite.Here, concentration that above-mentioned etched speed can be by regulating hydrofluoric acid aqueous solution and temperature wait to be controlled, and etch quantity can be controlled by regulating etching period.In addition, load, the milling time the when concentration that the grinding rate of above-mentioned mechanical lapping and amount of grinding can be by regulating abrasive substance, particle diameter, grinding waits and controls.
Fig. 3 is the process flow diagram of the manufacture method of the reflective LCD in the presentation graphs 1.
In Fig. 3, when making reflective LCD, at first, go up (step S301) such as formation nesa coatings at two basic pattern glass (motherglass, glass substrate); Seal with the epoxy resin of UV curing type periphery, two sheet glass substrates are fitted in the mode that becomes predetermined distance make face glass (step S302) two sheet glass substrates; This face glass is cut to the state (step S303) of the transversely arranged billet 41 (Fig. 4) of liquid crystal cell 40 (Fig. 4); Form liquid crystal layer (step S304) by liquid crystal being injected in the liquid crystal cell 40 and sealing; (step S305) ground on two surfaces or single surface to billet 41; Downcut single liquid crystal cell 40 (step S306) from billet 41; Make reflective LCD thus.
Then, specifically describe embodiments of the invention.
Prepare the following colored cholesteric liquid crystal display that shows: with the light absorbing zone of black, red reflex LCD, green reflective LCD, stack gradually with blue reflective LCD, the thickness of slab t that is provided in the glass substrate between red reflex liquid crystal layer and the blue reflective liquid crystal layer is 0.30mm (reflective liquid crystal interfloor distance A is 1.20mm) (embodiment 1), thickness of slab t is 0.25mm (reflective liquid crystal interfloor distance A is 1.00mm) (embodiment 2), thickness of slab t is 0.20mm (reflective liquid crystal interfloor distance A is 0.80mm) (embodiment 3), thickness of slab t is 0.15mm (reflective liquid crystal interfloor distance A is 0.60mm) (embodiment 4), thickness of slab t is 0.10mm (reflective liquid crystal interfloor distance A is 0.40mm) (embodiment 5), thickness of slab t is 0.05mm (reflective liquid crystal interfloor distance A is 0.20mm) (embodiment 6), thickness of slab t is 0.55mm (reflective liquid crystal interfloor distance A is 2.20mm) (comparative example 1), thickness of slab t is 0.03mm (reflective liquid crystal interfloor distance A is 0.12mm) (comparative example 2).Use these ready colored cholesteric liquid crystal displays that shows, the measurement view angle theta is 10 °~60 ° the interior parallax B (mm) of scope, and the result is represented in table 1.Here, ◎ in the table 1 represents that the degree of parallax B (mm) is very low or show uniformity is very high, the degree of zero expression parallax B (mm) is lower or show uniformity is higher, and the degree of * expression parallax B (mm) is beyond the permissible range or show uniformity is beyond the permissible range.
[table 1]
Thickness of slab t (mm) Reflective liquid crystal interfloor distance A (mm) The degree of parallax Show uniformity
10 ° of view angle theta 20 ° of view angle theta 30 ° of view angle theta 40 ° of view angle theta 50 ° of view angle theta 60 ° of view angle theta
Embodiment 1 0.30 1.20 0.14 0.27 0.38 0.46 0.51 0.50
Embodiment 2 0.25 1.00 0.12 0.22 0.32 0.38 0.42 0.42
Embodiment 3 0.20 0.80 0.09 0.18 0.25 0.31 0.34 0.34
Embodiment 4 0.15 0.60 0.07 0.13 0.19 0.23 0.25 0.25
Embodiment 5 0.10 0.40 0.05 0.09 0.13 0.15 0.17 0.17
Embodiment 6 0.05 0.20 0.02 0.04 0.06 0.07 0.08 0.07
Comparative example 1 0.55 2.20 0.25 0.49 0.69 0.85 0.93 0.92 ×
Comparative example 2 0.03 0.12 0.02 0.04 0.06 0.08 0.08 0.08 ×
In addition, the value of reflective liquid crystal interfloor distance A in the table 1 and parallax B is that refractive index n at hypothesis media (glass substrate, liquid crystal layer, bonding agent) equates that all the thickness of (n=1.5), liquid crystal layer and bonding agent compares the calculated value that very thin and negligible condition is got off and calculated with thickness of slab.
As shown in Table 1, if attenuate is provided in the thickness of slab t of the glass substrate between red reflex liquid crystal layer and the blue reflective liquid crystal layer and shortens reflective liquid crystal interfloor distance A, then can reduce view angle theta and be the parallax B (mm) in 10 °~60 ° the scope.
In addition, as shown in Table 1, attenuate thickness of slab t can reduce parallax B (mm) more, but considers installation, attrition process and the yield rate etc. of glass substrate, selects to have the thickness of slab t of actuality.
According to present embodiment, glass substrate face 14a, 17a, 18a, the 21a that is provided between red reflex liquid crystal layer 12 and the blue reflective liquid crystal layer 20 ground, so that set the thickness of slab t of the glass substrate 14,17,18,21 between red reflex liquid crystal layer 12 and the blue reflective liquid crystal layer 20 is more than the 0.05mm (reflective liquid crystal interfloor distance A is 0.20mm) and below the 0.30mm (reflective liquid crystal interfloor distance A is 1.20mm), so can keep the homogeneity of liquid crystal display, and can reduce parallax.
In the present embodiment, glass substrate face 14a, 17a, 18a, 21a are all ground, but be not limited to this, as long as grind just passable glass substrate face 14a, 21a among glass substrate face 14a, 17a, 18a, the 21a.
In the present embodiment, colored demonstration cholesteric liquid crystal display 10 is to possess red reflex LCD15, green reflective LCD 19, the colour that shows with 3 laminar full colors of blue reflective LCD 23 shows cholesteric liquid crystal display, but be not limited to this, as shown in Figure 5, also can be to possess light absorbing zone 51, be layered on the light absorbing zone 51 and at glass substrate 53, be formed with the red reflex LCD55 of the red reflex liquid crystal layer 52 that shows red reflected colour between 54, with be layered on the red reflex LCD55 and at glass substrate 57, two-layer 4 looks that are formed with the green reflective LCD 59 of the green reflective liquid crystal layer 56 that shows green reflected colour between 58 are (white, black, red, green) cholesteric liquid crystal display that shows, in addition, as shown in Figure 6, also can be to possess light absorbing zone 61, be layered on the light absorbing zone 61 and at glass substrate 63, be formed with the yellow reflective LCD 65 of the yellow reflective liquid crystal layer 62 that shows yellow reflected colour between 64, with be layered on the yellow reflective LCD 65 and at glass substrate 67, two-layer 4 looks that are formed with the blue reflective LCD 69 of the blue reflective liquid crystal layer 66 that shows blue reflected colour between 68 are (white, black, yellow, indigo plant) cholesteric liquid crystal display that shows; In addition, as shown in Figure 7, also can be the cholesteric liquid crystal display that 6 laminar full colors of the blue reflective liquid crystal layer 76 of the green reflective liquid crystal layer 74 of the red reflex liquid crystal layer 72 that possesses left-handed red reflex liquid crystal layer 71, dextrorotation, left-handed green reflective liquid crystal layer 73, dextrorotation, left-handed blue reflective liquid crystal layer 75 and dextrorotation show.In addition, by reflective liquid crystal layer combination, can improve the image quality (contrast) of display image with left-handed reflective liquid crystal layer and dextrorotation.
In the present embodiment, only glass substrate face 14a, 17a, 18a, 21a are ground, but be not limited to this, for example as shown in Figure 8, also can also grind, thereby reduce colored gross thickness or the weight that shows cholesteric liquid crystal display 80 the glass substrate face 81a of glass substrate 81 and the glass substrate face 82a of glass substrate 82.
In the present embodiment, be to grind by two stages that constitute by etching and mechanical lapping to implement to the grinding of glass substrate face 14a, 17a, 18a, 21a, but be not limited to this, also can implement by in etching and the mechanical lapping any.
In the present embodiment, after being cut to the state of billet 41 (with reference to Fig. 4) and forming liquid crystal layer (step S304), the two sheet glass substrates that will fit grind (step S305), which but be not particularly limited in stage grinding, also can directly grind the surface of basic pattern glass, in addition, also two sheet glass baseplate-laminatings can made face glass (step S302) afterwards, and grind before at the state (step S303) that this face glass is cut to billet 41, also independent liquid crystal cell 40 can ground after billet 41 downcuts (step S306) in addition.
In the present embodiment, being to make a plurality of mode of cutting of a plurality of liquid crystal cells 40 by 1 pair of basic pattern glass, but being not limited to this, also can be one the mode of cutting of being made 1 liquid crystal cell 40 by 1 pair of basic pattern glass.

Claims (4)

1, a kind of Reflexible color LCD is the Reflexible color LCD that possesses light absorbing zone and stack gradually a plurality of reflection liquid crystal displays on described light absorbing zone, it is characterized in that,
Described a plurality of reflection liquid crystal display has a plurality of glass substrates respectively and is formed on liquid crystal layer between described a plurality of glass substrate, and at least two faces that are provided in a plurality of glass substrate faces between nearest the 1st liquid crystal layer of described light absorbing zone and the described light absorbing zone of distance the 2nd liquid crystal layer are farthest ground; And the maximal value of the parallax B (mm) that is expressed from the next is below 0.5 1 mm,
B=A×tan(arcsin(sinθ/n)×cosθ)
θ: visual angle
A: reflective liquid crystal interfloor distance (mm)
N: the refractive index of the glass substrate after the described grinding.
2, Reflexible color LCD as claimed in claim 1 is characterized in that, the thickness of slab with glass substrate of the glass substrate face after the described grinding is below the 0.3mm.
3, a kind of manufacture method of Reflexible color LCD is the manufacture method that possesses light absorbing zone and stack gradually the Reflexible color LCD of a plurality of reflection liquid crystal displays on described light absorbing zone, it is characterized in that,
Possesses the glass substrate face grinding steps that the liquid crystal layer that liquid crystal is injected between a plurality of glass substrates separately of described a plurality of reflection liquid crystal displays and forms liquid crystal layer forms step and at least two faces that are provided in a plurality of glass substrate faces between the 2nd liquid crystal layer that forms on the 1st liquid crystal layer that forms on the nearest position of described light absorbing zone and the described light absorbing zone of the distance position are farthest ground; And the maximal value of the parallax B (mm) that is expressed from the next is below the 0.51mm,
B=A×tan(arcsin(sinθ/n)×cosθ)
θ: visual angle
A: reflective liquid crystal interfloor distance (mm)
N: the refractive index of the glass substrate after the described grinding.
4, the manufacture method of Reflexible color LCD as claimed in claim 3 is characterized in that, the thickness of slab with glass substrate of the glass substrate face after grinding in described glass substrate face grinding steps is below the 0.3mm.
CN 200710005191 2006-02-20 2007-02-15 Reflexible color LCD and its manufacturing method Pending CN101025501A (en)

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CN109407437A (en) * 2018-11-19 2019-03-01 南京华日触控显示科技有限公司 The ultra-thin glass structure cholesteric phase chromatic liquid crystal screen of glass Milling Technique In The Microstructure Study production
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CN111142284A (en) * 2019-12-20 2020-05-12 维沃移动通信有限公司 Preparation method of display module, display module and electronic equipment

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