CN101020833A - Electromagnetically inducing biomass pyrolyzing and liquefying reactor - Google Patents

Electromagnetically inducing biomass pyrolyzing and liquefying reactor Download PDF

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Publication number
CN101020833A
CN101020833A CN 200710055364 CN200710055364A CN101020833A CN 101020833 A CN101020833 A CN 101020833A CN 200710055364 CN200710055364 CN 200710055364 CN 200710055364 A CN200710055364 A CN 200710055364A CN 101020833 A CN101020833 A CN 101020833A
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housing
liquefying reactor
electromagnetically inducing
pyrolyzing
biomass pyrolyzing
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CN100516174C (en
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王擎
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Northeast Electric Power University
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Northeast Dianli University
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Abstract

The present invention relates to carbon material pyrolyzing technology, and is especially one kind of electromagnetically inducing biomass pyrolyzing and liquefying reactor. The electromagnetically inducing biomass pyrolyzing and liquefying reactor includes one spiral material conveyer on a support and comprise one shell with feeding bin, gas exhaust pipe and slag exhaust pipe, and one spiral shaft inside the shell; one electromagnetic coil around the shell of hollow pipe with cooling liquid flow channel; one water seal trough; one speed reducer with motor and shaft connected to the spiral shaft; and gas exhaust channel set axially to the spiral shaft. The present invention has simple structure, convenient operation, continuous running, environment friendship and other advantages. The present invention is especially suitable for pyrolysis of core firewood, crop stalk, etc.

Description

Electromagnetically inducing biomass pyrolyzing and liquefying reactor
Technical field
The present invention relates to the pyrolysis art of carbonaceous material, it is a kind of Electromagnetically inducing biomass pyrolyzing and liquefying reactor, be specially adapted to the pyrolysis of biomass such as fuel wood, agricultural crop straw, waterplant, also applicable to solid-fuelled pyrolysis such as coal, resinous shale and municipal wastess.
Background technology
Biomass energy is one of human use's energy the earliest, has wide, renewable, the low cost and other advantages of distribution.Biomass account for 15% in global Energy Consumption, are only second to coal, oil and natural gas.
To be sun power be stored in a kind of form of energy in the biology with the chemical energy form to biomass energy, it derives from photosynthesis of plants directly or indirectly, and in various renewable energy sources, biomass are unique, it is the sun power of storing, a kind of especially unique reproducible carbon source.Biomass are widely distributed occurring in nature, and in China's plant husbandry prosperity, annual photosynthesis produces the available biomass energy and amounts to 5.12 hundred million tons of standard coals.These raw material major parts are directly burnt, and do not have fine utilization, and transformation efficiency is only about 10%.If be liquid bio matter oil with Wood Adhesives from Biomass then will have improved the quality of utilizing of biomass energy greatly, also improved energy density simultaneously, and easily stored transportation.
Biomass pyrolysis liquefaction is biomass are degraded to product liquid and a part of gaseous product and solid product after being heated under the situation of complete anoxic or limited oxygen supply a process.
Biomass pyrolysis liquefaction be middle temperature (500~650 ℃), high heating rate (104~105 ℃/s) and the utmost point lose heart under the condition of the body residence time (less than 2s), with the direct pyrolysis of biomass, product is through cooling fast, can make the condensation before further fracture generates gas of middle liquid product molecule, thereby obtain the biomass liquid oils of high yield.The bio oil that the biomass pyrolysis liquefaction reaction produces can be made oil fuel and industrial chemicals by further separation and extraction; Gas is looked the height of its calorific value, can mix as industry or domestic gas separately or with other high heat value gas; Biomass charcoal can be used as promoting agent etc.
The biomass pyrolysis liquefaction system generally comprises raw material crushing and drying plant, feeding unit, liquefying reactor (pyrolysis producer), gas-solid separating device, quickly cooling device and gas transportation facilities etc., wherein, liquefying reactor is the core, and its operation scheme has determined the kind of liquefaction technology.At present, the fast pyrolysis legal system is equipped with the liquefying reactor that bio-oil adopts and mainly contains two big classes: a class is for there being carrier gas, be commonly referred to: fluidized bed reactor, be characterized in that drag force that biological particles and thermal barrier mainly rely on gas motion and produced collides and mix, to realize the exchange of momentum and heat, as fluidized bed type, circulating fluid bed type and spouted fluidized bed formula; Another kind of is no carrier gas, be commonly referred to: un-fluidized-bed formula reactor, be characterized in that biological particles and heating carrier mainly rely on the displacement movement of self to collide and mix, to realize the exchange of momentum and heat, as rotation conical, vacuum moving-bed type.
The advantage of fluidized bed reactor does not mainly contain moving parts, and structure is comparatively simple, and working reliability is big, and operation life is long etc.; But shortcoming is to need the introducing of fluidizing agent and keep a certain amount of solid thermal carriers in fluidized-bed.Fluidizing agent is generally the part of pyrogenous origin gas or high-temperature flue gas, and solid thermal carriers are generally sand.The introducing of fluidizing agent has improved system's operation energy consumption on the one hand, because this part adds the technological process that gas also will experience heating and cooling; On the other hand, the introducing of fluidizing agent can be diluted the not condensable gases that pyrolysis produces, and its calorific value is greatly reduced, and uses to run into certain difficulty.Owing to require a certain amount of hot sand, and in bed, to keep fluidized state in the fluidized-bed, so to the serious wear in the bed as solid thermal carriers.
Un-fluidized-bed formula reactor is just in time opposite with fluidized bed reactor, advantage is seldom or not to need to add gas, the energy consumption and the pyrolysis cost of system have been reduced, avoided the dilution of inflammable gas, but shortcoming is a reactor contains moving parts, requires quite high to material with thermotolerance bearing, wear resistance, stopping property etc.The rotation conical reactor, it is bored with one heart by inside and outside two and forms jointly, and inner cone is motionless, and outer cone pivots.The inner rotary awl must be rotated by the overhanging support of a spiral arm, and the bearing that supports outrigger shaft must be worked under high temperature and high dust operating mode for a long time, difficulty is quite big, in addition, the rotation conical reactor also needs inert heat carriers such as sand, and sand will ceaselessly be done geneva motion between two awl walls, and it is also quite serious to the wearing and tearing of high-temperature wall surface, therefore, the rotation conical reactor exists deficiencies such as complex structure, cost height, work-ing life be short.
The vacuum moving bed reactor is to adopt molten salt mixture to heat biomass to realize pyrolytic, and the heating of molten salt mixture needs pyrogenous origin not condensable gases additional combustion chamber burning liberated heat again.And not only frictional wear is more serious owing to adopt moving-bed, and sealing is also comparatively difficult.
Summary of the invention
Technical problem to be solved by this invention is to overcome the deficiencies in the prior art, a kind of gaseous heat-carrier that neither needs is provided, do not need solid thermal carriers yet, simple in structure, easy to operate, operation continuously, homogeneous heating, pyrolysis rate is fast, quality good, cleaning, environmental protection, cost is low, the Electromagnetically inducing biomass pyrolyzing and liquefying reactor of long service life.
Solving the technical scheme that its technical problem adopts is: a kind of Electromagnetically inducing biomass pyrolyzing and liquefying reactor, its special character is, it comprises bracing frame 11, on bracing frame 11, be equipped with screw input feeder 6, the structure of described screw input feeder 6 is, have housing 5, on housing 5, be provided with feeding hopper 3, vapor pipe 7 and residue outlet 9, be built-in with screw shaft 14 at housing 5; Telefault 12 around the home on the housing 5 of described screw input feeder 6.
Described telefault 12 is for being wound on the hollow of one deck at least pipe on housing 5 cylinders, and the hollow of hollow pipe is a cooling liquid flow channel 4.
The lower port of described residue outlet 9 places in the water sealed tank 10.
The screw shaft 14 of described screw input feeder 6 is connected with the reducer shaft 15 of motor 1.
Described screw shaft 14 axially on be provided with exhaust notch 16.
Electromagnetically inducing biomass pyrolyzing and liquefying reactor of the present invention compared with prior art, owing to adopted electromagnetic induction heating screw input feeder feeding style, in heat-processed, the screw shaft of screw input feeder rotates in housing, make biological particles continuously along the gap between screw displacement of rolling, biological particles is all had an opportunity to contact screw input feeder and is heated, strengthened the being heated evenly property of biological particles, simultaneously, the biomass oil gas that pyrolysis goes out obtains diffusion very soon, accelerated pyrolytic speed, the pyrolysis quality is good; The treatment capacity of pyrolysis biomass can easily realize by regulating rotating speed of motor and power; Without any need for gas or solid thermal carriers just can be implemented under the anoxybiotic condition and make biomass fast pyrogenation.Have simple in structure, easy to operate, operation continuously, homogeneous heating, pyrolysis rate is fast, quality good, cleaning, environmental protection, cost is low, advantages such as long service life.Be specially adapted to the pyrolysis of biomass such as fuel wood, agricultural crop straw, waterplant, also applicable to solid-fuelled pyrolysis such as coal, resinous shale and municipal wastess.
Description of drawings
Fig. 1 is an Electromagnetically inducing biomass pyrolyzing and liquefying reactor structure cross-sectional schematic of the present invention.
Fig. 2 is telefault 12 structure enlarged diagrams.
Fig. 3 is an A-A cross-sectional schematic among Fig. 2.
Fig. 4 is screw shaft 14 structural upright enlarged diagrams.
Among the figure: 1 motor, 2 bearings, 3 feeding hoppers, 4 cooling liquid flow channel, 5 housings, 6 screw input feeders, 7 escape pipes, 8 bases, 9 residue outlets, 10 water sealed tanks, 11 bracing frames, 12 telefaults, 13 bearing spiders.14 screw shaft, 15 reducer shafts, 16 exhaust notches, 17 protective layers.
Embodiment
The invention will be further described to utilize drawings and Examples below.
With reference to Fig. 1-4, Electromagnetically inducing biomass pyrolyzing and liquefying reactor has bracing frame 11, is equipped with screw input feeder 6 on bracing frame 11.The structure of described screw input feeder 6 is, has housing 5, is provided with feeding hopper 3, vapor pipe 7 and residue outlet 9 on housing 5, is built-in with screw shaft 14 at housing 5.The housing 5 and the bracing frame 11 of screw input feeder 6 are connected.Telefault 12 around the home on the housing 5 of described screw input feeder 6.The upper port place of described residue outlet 9 is provided with base 8, and the base 8 of residue outlet 9 is connected with the bracing frame 11 of housing 5, and the lower port of residue outlet 9 places in the water sealed tank 10.The screw shaft 14 of described screw input feeder 6 is connected with the reducer shaft 15 of motor 1.Motor 1 adopts buncher, and buncher and speed reduction unit are the commercially available prod.Screw shaft 14 is provided with bearing spider 13, is built-in with the bearing 2 that matches with screw shaft 14 at bearing spider 13, and bearing spider 13 is connected with bracing frame 11.Described screw shaft 14 axially on be provided with exhaust notch 16.Described telefault 12 is for being wound on the hollow of one deck at least pipe on housing 5 cylinders, and the hollow of hollow pipe is a cooling liquid flow channel 4.Be provided with protective layer 17 at telefault 12 outermost one decks.Telefault 12 is electrically connected with power source circuit.Power source circuit is a prior art, can adopt thyristor supply or IGBT power supply that exchange current is provided, producing alternating magnetic field in telefault 12 makes screw input feeder 6 be heated to 500~650 ℃, make the normal temperature biological particles about 20 ℃ in spiral conveyer 6 be heated to 500~650 ℃, its watt level can be according to inlet amount, and the charging kind is adjusted continuously.Be provided with in the hollow pipe of telefault 12 and pass to water coolant formation cooling circuit in the equipment such as cooling liquid flow channel 4 and power source circuit, to guarantee that equipment works such as telefault 12, power source circuit are in normal temperature range.Electromagnetically inducing biomass pyrolyzing and liquefying reactor also can be connected with the automatic temperature monitoring closed control circuit, monitors screw input feeder 6 self-temperatures automatically, and when temperature was higher than design temperature, automatic powered-down circuit also started holding circuit.The housing 5 of screw input feeder 6 adopts higher high temperature resistant furnace lining of not magnetic conduction of intensity or magnetic conduction refractory ceramics pipe not.The screw shaft 14 of screw input feeder 6 selects for use materials such as Cr28Ni20MoW high temperature steel, 3YC52 or Ni-Fe-Cr-Al based high-temperature alloy all can.
During use, the screw shaft 14 of screw input feeder 6 rotates in housing 5, the feeding hopper 3 of biological particles from housing 5 entered in the housing 5, and continuously along the gap between screw displacement of rolling, biological particles all has an opportunity to contact screw input feeder 6, absorbs the heat of screw input feeder 6 while rolling, and temperature is increased to 500~650 ℃ fast and carries out pyrolysis, gas after the pyrolysis is drawn by escape pipe 7, and the solid semicoke pushes residue outlet 9 by screw shaft 14.Pyrolytic process is to carry out in the housing 5 of sealing, and the pyrolysis product semicoke is discharged by residue outlet 9, enters water sealed tank 10 internal cooling, and water sealed tank 10 also prevents air admission in the cooling semicoke, and pyrolysis product gas is drawn by escape pipe 7.

Claims (5)

1. Electromagnetically inducing biomass pyrolyzing and liquefying reactor, it is characterized in that, it comprises bracing frame (11), on bracing frame (11), be equipped with screw input feeder (6), the structure of described screw input feeder (6) is, have housing (5), on housing (5), be provided with feeding hopper (3), vapor pipe (7) and residue outlet (9), be built-in with screw shaft (14) at housing (5); Telefault (12) around the home on the housing (5) of described screw input feeder (6).
2. Electromagnetically inducing biomass pyrolyzing and liquefying reactor according to claim 1 is characterized in that: described telefault (12) is for being wound on the hollow of one deck at least pipe on housing (5) cylinder, and the hollow of hollow pipe is cooling liquid flow channel (4).
3. Electromagnetically inducing biomass pyrolyzing and liquefying reactor according to claim 1 is characterized in that: the lower port of described residue outlet (9) places in the water sealed tank (10).
4. Electromagnetically inducing biomass pyrolyzing and liquefying reactor according to claim 1 is characterized in that: the screw shaft (14) of described screw input feeder (6) is connected with the reducer shaft (15) of motor (1).
5. Electromagnetically inducing biomass pyrolyzing and liquefying reactor according to claim 1 is characterized in that: described screw shaft (14) axially on be provided with exhaust notch (16).
CNB200710055364XA 2007-02-15 2007-02-15 Electromagnetically inducing biomass pyrolyzing and liquefying reactor Expired - Fee Related CN100516174C (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101857197A (en) * 2010-06-09 2010-10-13 江苏大学 Biomass gasifying hydrogen making reactor based on induction heating
CN101885472A (en) * 2010-06-29 2010-11-17 镇江市丹徒区天龙化工有限公司 Circulating fluidized bed reactor for preparing hydrogen by gasifying biomass
CN102839002A (en) * 2012-09-20 2012-12-26 江西鹏源环保科技发展有限公司 High-frequency and ultrasonic-frequency biomass dry distillation oxygen-free heating furnace
CN103725299A (en) * 2013-07-29 2014-04-16 北京瑞增兰宇新能源科技有限公司 Method for continuously discharging biomass charcoal in plant-based oil and gas synthesis process
CN103952163A (en) * 2014-05-13 2014-07-30 河南农业大学 Electromagnetic carbonizing device and biomass carbonizing system comprising same
CN104946278A (en) * 2015-05-27 2015-09-30 台山市合利生物质科技有限公司 Wood garbage retort furnace
CN104942954A (en) * 2015-05-27 2015-09-30 台山市合利生物质科技有限公司 Gas retort for wood waste
CN105885951A (en) * 2016-05-20 2016-08-24 北京化工大学 Dual bed coupled pyrolysis and gasification system combining direct heating with indirect heating
CN107043635A (en) * 2017-01-12 2017-08-15 中国科学院过程工程研究所 A kind of device for being used to be pyrolyzed, gasify, bakee or dry
CN109762581A (en) * 2019-03-25 2019-05-17 广东洁冠能源科技有限公司 Biomass energy thermal cracker and charcoal preparation method
CN109971500A (en) * 2019-03-25 2019-07-05 广东洁冠能源科技有限公司 Biomass energy thermal cracker and fuel gas preparation method
CN110257090A (en) * 2019-07-05 2019-09-20 深圳市科鸿环保新能源科技有限公司 Division solves garbage carbonized processing system
CN110651025A (en) * 2017-03-27 2020-01-03 扫描船有限公司 Microwave pyrolysis reactor

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101857197A (en) * 2010-06-09 2010-10-13 江苏大学 Biomass gasifying hydrogen making reactor based on induction heating
CN101857197B (en) * 2010-06-09 2012-08-15 江苏大学 Biomass gasifying hydrogen making reactor based on induction heating
CN101885472A (en) * 2010-06-29 2010-11-17 镇江市丹徒区天龙化工有限公司 Circulating fluidized bed reactor for preparing hydrogen by gasifying biomass
CN102839002A (en) * 2012-09-20 2012-12-26 江西鹏源环保科技发展有限公司 High-frequency and ultrasonic-frequency biomass dry distillation oxygen-free heating furnace
CN103725299A (en) * 2013-07-29 2014-04-16 北京瑞增兰宇新能源科技有限公司 Method for continuously discharging biomass charcoal in plant-based oil and gas synthesis process
CN103952163B (en) * 2014-05-13 2016-01-20 河南农业大学 A kind of electromagnetism carbonizing apparatus and the biomass carbonated system comprising this device
CN103952163A (en) * 2014-05-13 2014-07-30 河南农业大学 Electromagnetic carbonizing device and biomass carbonizing system comprising same
CN104946278A (en) * 2015-05-27 2015-09-30 台山市合利生物质科技有限公司 Wood garbage retort furnace
CN104942954A (en) * 2015-05-27 2015-09-30 台山市合利生物质科技有限公司 Gas retort for wood waste
CN105885951A (en) * 2016-05-20 2016-08-24 北京化工大学 Dual bed coupled pyrolysis and gasification system combining direct heating with indirect heating
CN105885951B (en) * 2016-05-20 2018-10-23 北京化工大学 A kind of double bed coupling pyrolysis gasification system directly or indirectly heating combination
CN107043635A (en) * 2017-01-12 2017-08-15 中国科学院过程工程研究所 A kind of device for being used to be pyrolyzed, gasify, bakee or dry
CN110651025A (en) * 2017-03-27 2020-01-03 扫描船有限公司 Microwave pyrolysis reactor
CN110651025B (en) * 2017-03-27 2021-05-25 扫描船有限公司 Microwave pyrolysis reactor
US11826717B2 (en) 2017-03-27 2023-11-28 Scanship As Microwave pyrolysis reactor
CN109762581A (en) * 2019-03-25 2019-05-17 广东洁冠能源科技有限公司 Biomass energy thermal cracker and charcoal preparation method
CN109971500A (en) * 2019-03-25 2019-07-05 广东洁冠能源科技有限公司 Biomass energy thermal cracker and fuel gas preparation method
CN110257090A (en) * 2019-07-05 2019-09-20 深圳市科鸿环保新能源科技有限公司 Division solves garbage carbonized processing system

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