CN1010193B - Protecting dregs made of residue of boron as the main component for steel smelt-pouring - Google Patents

Protecting dregs made of residue of boron as the main component for steel smelt-pouring

Info

Publication number
CN1010193B
CN1010193B CN 85107824 CN85107824A CN1010193B CN 1010193 B CN1010193 B CN 1010193B CN 85107824 CN85107824 CN 85107824 CN 85107824 A CN85107824 A CN 85107824A CN 1010193 B CN1010193 B CN 1010193B
Authority
CN
China
Prior art keywords
slag
pouring
steel
residue
boron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CN 85107824
Other languages
Chinese (zh)
Other versions
CN85107824A (en
Inventor
李广田
郭东章
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yan Wengong Feng Sufan
Original Assignee
Yan Wengong Feng Sufan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yan Wengong Feng Sufan filed Critical Yan Wengong Feng Sufan
Priority to CN 85107824 priority Critical patent/CN1010193B/en
Publication of CN85107824A publication Critical patent/CN85107824A/en
Publication of CN1010193B publication Critical patent/CN1010193B/en
Expired legal-status Critical Current

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The present invention relates to a new protection slag system in the production process of steel smelting and pouring. Alkaline waste slag containing 33 to 38% of MgO, SiO2Na2OB2O3, etc. generated in the production process of borax is used as principal raw material, and is matched with less than 50% of power plant ashes, high furnace grain slag or more than two kinds of additive agents, such as carbon, etc. to form the protection slag of which the MgO content is between 15 and 28% for steel smelting and pouring. The protection slag has the advantages of poor water absorption, strong impurity adsorption capability, no soldering of poured steel ingots, no carburization, etc. besides the advantages of home or foreign protection slag.

Description

Protecting dregs made of residue of boron as the main component for steel smelt-pouring
The present invention is the protection slag system that a kind of pouring in steel smelting production process is used.
In the pouring in steel smelting production process, cover the molten steel surface, prevent the molten steel oxidation and molten steel is had the adiabatic heat-insulation effect with covering slag; Covering slag can adsorb the Al in the molten steel uphill process 2O 3Deng non-metallic inclusion; Between ingot mould and solidification of molten steel shell, form the uniform slag film and serve as lubricant.
Existing pouring in steel smelting is to use graphite tailing with covering slag mostly, perlite, power plant's ash and wollastonite etc. add cosolvents such as a certain amount of soda ash, solid water glass, aluminium powder or silicon calcium powder for primary raw material and exothermic mixture formulated.The chemical composition of slag system is to rely on CaO-SiO-Al mostly 2O 3Phasor is adjusted the composition of positive slag, and the cosolvent of adding and exothermic mixture are in order to physical and chemical performances such as the fusing point of adjusting slag, molten speed, viscosity.Though this slag system has satisfied the covering slag that pouring in steel smelting is used substantially, part still has some deficits.Show that mainly this slag system phosphorus content can make steel ingot, the center carburetting of steel cap oral area when higher, phosphorus content is crossed the low steel ingot sticking to mould after cast that makes again.For this reason, the protection slag system of selecting new pouring in steel smelting to use then is a research topic new in the metallurgical industry.
The present invention is based on having selected new protection slag system, i.e. MgO-CaO-SiO in the analysis of original protection slag system and the utilization of resources 2Slag system.
The present invention has SiO concurrently with MgO33~38% that contains that the borax production process produces 2Na 2O and B 2O 3Deng alkaline scrap material is primary raw material, and as required with addition of the power plant's ash below 50%, two or more additives such as blast furnace granulated slag or carbon element form the pouring in steel smelting covering slag of MgO content between 15~28%.
It is composed as follows:
MgO CaO SiO 2Na 2O B 2O 3
15~28% 6~18% 20~38% 2~4% 1~3%
Al 2O 3C other
4~12% 4~16% 1~10%。
Be used for the pouring in steel smelting embodiment with the covering slag of this slag system preparation:
Covering slag composition %:
MgO CaO SiO 2Al 2O 3Na 2O B 2O 3C other
22 16 37 84 2.5 5 is residual
Add at steel per ton under the situation of 2.5kg in order to the cast straight carbon steel, surface of steel ingot first class product rate reaches 90% and absorbs Al 2O 3Field trash increment 200%.Steel ingot is sticking to mould not, not carburetting of ingot head.
The present invention adopts MgO-CaO-SiO 2New slag system makes the Al in the slag 2O 3Content is low, the basicity height of slag, absorption molten steel come-up Al 2O 3The field trash ability is strong; This new slag system utilizes MgCO 3The CO that decomposes produces 2Gas is adjusted the molten speed of slag, and the spreadability of improving slag makes new slag system have good melting characteristic, thereby makes the ingot quality of cast that improvement significantly be arranged.
Raw material of the present invention are industrial residue mostly; no longer in slag, add the high materials of price such as soda ash and solid water glass; make the cost of raw and processed materials of covering slag that decline significantly be arranged, thereby reduced steel-making cost, the natural water absorption rate of slag in storage and transportation reduced.

Claims (1)

  1. The protection slag system that a kind of pouring in steel smelting is used is characterized in that it is based on borax slag that raw material is formed, its chemical composition:
    MgO CaO SiO 2Na 2O B 2O 3
    15~28%?6~18% 20~38% 2~4% 1~3%
    Al 2O 3C other
    4~12% 4~16% 1~10%。
CN 85107824 1985-10-17 1985-10-17 Protecting dregs made of residue of boron as the main component for steel smelt-pouring Expired CN1010193B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 85107824 CN1010193B (en) 1985-10-17 1985-10-17 Protecting dregs made of residue of boron as the main component for steel smelt-pouring

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 85107824 CN1010193B (en) 1985-10-17 1985-10-17 Protecting dregs made of residue of boron as the main component for steel smelt-pouring

Publications (2)

Publication Number Publication Date
CN85107824A CN85107824A (en) 1987-04-22
CN1010193B true CN1010193B (en) 1990-10-31

Family

ID=4795797

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 85107824 Expired CN1010193B (en) 1985-10-17 1985-10-17 Protecting dregs made of residue of boron as the main component for steel smelt-pouring

Country Status (1)

Country Link
CN (1) CN1010193B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1318165C (en) * 2004-02-27 2007-05-30 宝山钢铁股份有限公司 Coverage dregs for ladle
CN102059330B (en) * 2011-02-15 2013-01-23 江苏大学 Boron-containing fluoride-free covering slag for steel continuous-casting crystallizer and preparation method thereof

Also Published As

Publication number Publication date
CN85107824A (en) 1987-04-22

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