CN101011231A - Wet towel for eliminating harmful gas and curing leather, method for making and using same - Google Patents

Wet towel for eliminating harmful gas and curing leather, method for making and using same Download PDF

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Publication number
CN101011231A
CN101011231A CN 200610165523 CN200610165523A CN101011231A CN 101011231 A CN101011231 A CN 101011231A CN 200610165523 CN200610165523 CN 200610165523 CN 200610165523 A CN200610165523 A CN 200610165523A CN 101011231 A CN101011231 A CN 101011231A
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flexible sheet
pernicious gas
leather
wet tissue
cellulosic
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CN 200610165523
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CN101011231B (en
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陈晓鹏
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Abstract

The invention relates to a method for producing the wet towel for eliminating harmful gas and maintaining the leather. The invention comprises a sealed package layer, and flexible sheet fiber which contains the solution used to decompose and eliminate the harmful gas. The invention has simple operation without any special tools, while it can save solution. The protein liquid can improve the brightness and flexibility of leather, to avoid pollution of TVOC or the like. The test has proved that the inventive wet towel can remove 60-80% of TVOC and formaldehyde, or the like.

Description

Wet tissue of elimination pernicious gas curing leather and preparation method thereof and using method
Technical field
The present invention relates to a kind of wet tissue of eliminating the pernicious gas curing leather and preparation method thereof and using method; be that a kind of chemical method of utilizing is eliminated toxic and harmful and peculiar smell that furniture, leather, artificial leather etc. distribute; and have the wet tissue of leather defencive function, and prepare the method for wet tissue and the method for use wet tissue.
Background technology
At present, in house decoration, because the exceeding standard of harmful substance in house ornamentation pollution that various finishings cause with harmful substances such as formaldehyde that material brought, benzene series thing, TVOC and the room air.Seriously disturbed our daily life.This gas that contains formaldehyde of the long-time absorption of human body can give rise to diseases, and serious also can crisis arrive people's life security.Therefore to carry out the improvement of room air pollution to room behind the finishing and the new furniture of buying, and eliminate the harmful gas pollution that new furniture brought.In the scope of national regulation, people are lived in the environment of a health with the content that guarantees indoor harmful gas.
For the improvement of the pollution sources of various furniture and office furniture etc., existing technology has: the decomposition technique of various chemical agents and photocatalyst etc.As a application number is 01133329, and the applying date is October 23 calendar year 2001, and denomination of invention is the Chinese invention patent of formaldehyde remover, it is by triethanolamine, Sodium Metabisulfite, disodium ethylene diamine tetraacetate, 2,3,4,5, the aqueous solution that 6-penta hydroxy group acetaldehyde and distilled water are formed.The way of utilizing above-mentioned formaldehyde eliminating agent to eliminate formaldehyde is in indoor spraying, but owing to the release of formaldehyde in the indoor furniture is a process slowly, and spraying is the process of a short time, thereby need constantly spray and just can effectively eliminate.The aforesaid way troublesome poeration, effect is unsatisfactory.Along with the decomposition technique of the continuous development photocatalyst of science and technology is day by day ripe.As a application number is CN03124474.2, publication number is CN1552458, the open date is on December 08th, 2004, denomination of invention is the Chinese invention patent of air cleaning with nanometer eliminating smell agent and preparation method thereof, it is made up of nanometer titanium dioxide titanium valve, eliminating smell agent component, binder component, be sprayed on furniture surface, utilize photocatalyst decomposition technique and chemical breakdown to remove foreign flavor indoors, the benzene in the room air, ammonia, formaldehyde are removed.But the processing of various chemical agents and photocatalyst decomposition technique all need with spray gun or watering can and hairbrush, with medicine liquid spray or brushing on the surface of furniture.Such processing need be equipped with special-purpose instrument, and deals with more loaded down with trivial details. and be exactly the bad control of soup purchase volume in addition, the medicament wastage is bigger, and is unreasonable economically.In addition, chemical agents such as present most formaldehyde scavengers are not that meta-acid is exactly inclined to one side alkali, and skin is had injury or stimulation.
Summary of the invention
It is simple to operate that purpose of the present invention is exactly a kind of use that provides in order to solve above-mentioned deficiency, eliminate effective being used to of toxic gas such as formaldehyde eliminate wood furniture, office furniture, leather artificial leather sofa, etc. objects such as all kinds of furniture formaldehyde and peculiar smell and have the wet tissue and preparation method thereof and the using method of curing leather effect.
The present invention is that to solve the problems of the technologies described above the technical solution that adopts as follows: the wet tissue of eliminating the pernicious gas curing leather, comprise: the integument of sealing, the flexible sheet cellulosic is characterized in that, is full of the solution that decomposes and eliminate pernicious gas in the described flexible sheet cellulosic.
Described flexible sheet cellulosic is nonwoven, cloth or paper.The solution of decomposition that is full of in the described flexible sheet cellulosic and elimination pernicious gas is formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup, is to be made of following compositions in weight percentage mixing preparation:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~20%
Nano titanium oxide 0.8%~1.5%
Water 1%~60%.
Described protein solution is a protein liquid.
Eliminate the preparation method of the wet tissue of pernicious gas curing leather, comprising: the flexible sheet cellulosic, the lapping of secluding air is characterized in that, described step:
Following compositions in weight percentage mixing preparation is constituted the solution of formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~20%
Nano titanium oxide 0.8%~1.5%
Water 1%~60%;
The flexible sheet cellulosic is placed on immersion and impregnation technology processing in the above-mentioned solution, makes it be full of the step of solution;
The lapping of use secluding air will be full of the step of the flexible sheet cellulosic sealing of solution.
Described flexible sheet cellulosic is nonwoven, cloth or paper.
Eliminate the using method of the wet tissue of pernicious gas curing leather, flexible sheet cellulosic by the sealing of the lapping of secluding air, it is characterized in that the using method that described flexible sheet cellulosic is full of formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup comprises the steps:
Open the lapping of sealing, expose the cellulosic step of flexible sheet;
Extract the cellulosic step of flexible sheet out;
The solution that is full of in the flexible sheet cellulosic is evenly spread upon the step of distributing the pernicious gas object surface;
Formaldehyde scavenger, eliminating smell agent and photocatalyst soup decompose the step that absorbs the pernicious gas curing leather.
Described formaldehyde scavenger, eliminating smell agent leather maintaining agent photocatalyst soup are made of following compositions in weight percentage mixing preparation:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~20%
Nano titanium oxide 0.8%~1.5%
Water 1%~60%.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
1) simple to operate, the surface that the consumer only need open external packing taking-up wet tissue wiping furniture gets final product.Do not need any specific purpose tool.
2) can make the product of various uses, both can reduce the use amount of medicament, avoid the waste of soup.Economical rationality.And can solve various problems with a kind of mode.
3) be convenient to preserve and carry, very convenient to use.Treatment effect is better simultaneously.
4) the soup PH matter in the wet tissue is neutral, and is harmless, to skin without any stimulation.
5) so because protein liquid has the gentle function of well adding lustre to can be used for nursing leather to leather.
Therefore the handling problem that has not only solved the pollutants such as formaldehyde, benzene series thing and TVOC of all kinds of furniture well still is a kind of excellent leather conditioning liquid simultaneously.
Is more than 60%~80% through test to organic clearances such as furniture surface benzene, TVOC, formaldehyde.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples.
Fig. 1 is a structural representation of the present invention.
The specific embodiment
Embodiment one:
As shown in Figure 1, present embodiment is made of three parts, comprising: the integument 1 of sealing, flexible sheet cellulosic 2 is full of the solution that decomposes and eliminate pernicious gas in the flexible sheet cellulosic 2.The integument 10 minutes of sealing is important, and it makes the inside and outside air of parcel isolated, has guaranteed that the moisture in the solution in the flexible sheet cellulosic 2 is kept the long time in the parcel, is unlikely to very fast drying.The effect of soup is kept effectively, be unlikely to oxidation and absorb unnecessary material and lost efficacy.Flexible sheet cellulosic 2 can be the nonwoven that common being easy to absorbs liquid, or other are easy to absorb the cloth or the paper of liquid.Flexible sheet cellulosic 2 removes that to require to be easy to absorption liquid external, also requires pliability better, can also keep toughness and do not break after having absorbed liquid, so that continue the long period in the process of smearing.
The solution of decomposition that is full of in the flexible sheet cellulosic and elimination pernicious gas is formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup, is that (percentage by weight) composed of the following components mixing preparation constitutes:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~20%
Nano titanium oxide 0.8%~1.5%
Water 1%~60%.
Protein solution wherein is that protein liquid preferably is worth and is: 8%~28%.The present invention why in main component, added protein liquid be because:
1) protein liquid has not only served as the component of binder in the eliminating smell agent prescription, and protein liquid itself is again the leather polishing material.So the present invention not only can remove the peculiar smell of leather, can also make leather submissiveer, smooth, and the surface is more glossy, waterproof durable is superior in quality.
2) component that protein liquid has served as binder on the one hand aspect eliminating smell agent, and protein liquid is wiping the surperficial rear surface protein precipitation of furniture on the other hand, forms protein film and a large amount of adsorbed gas poisonous substances of energy, mainly is macromolecule organic.
3) protein liquid also has a kind of regulating action, promptly along with temperature raises, humidity increases, the release of harmful substances such as formaldehyde will strengthen, and protein liquid is run into this situation and will fully be absorbed moisture and " get damp ", thereby the phenomenon of getting damp has strengthened the adsorption efficiency of albumen has guaranteed that the furniture of administering can be because of temperature raise, and humidity strengthens and the phenomenon that smell strengthens occurs.Solved the effect problem repeatedly that common product occurs.
Present embodiment is obvious through result of use, and its method of testing and test effect are as follows:
Method of testing
The solution that discharges harmful substances such as benzene, TVOC, formaldehyde is sprayed into respectively in the climate box of two airtight same volumes, putting the formaldehyde that scribbles among the present invention, the glass plate of foreign smell eliminating agent solution in one of them climate box, in the integral point time period, detect then with benzene detector tube, TVOC detector tube and the U.S.'s 4160 type methylene oxide detecting instruments; Or detect with the portable benzene organic gas of TLV FALCON, VOC organic gas PID monitor and the U.S.'s 4160 type methylene oxide detecting instruments that the U.S. produces.
Concrete grammar following (is example with the formaldehyde test):
Select two airtight experimental box (about 1 cubic metre) A, B that size is similar, respectively spray into 37% formaldehyde liquid of same amount, control stationary temperature (23C ± 2), humidity (60%) mix formaldehyde in experimental box, through 30min, allow formaldehyde fully volatilize and fill the air.Experimental box A is placed with 50 centimetres of glass plates of 50 cm x that the surface sprays formaldehyde, odor scavenging agent; Control experiment case B does not spray formaldehyde, foreign smell eliminating agent.With atmosphere sampling instrument each airtight breadboard air is respectively taken a sample 1 time on 3 hours, 6 hours, 9 hours, 12 hours at the interval the time point of same method, each sampling time is 40min, and carries out blank determination with the absorption liquid of on-the-spot unsampled blank absorption tube.According to GB/T15516-1995 " (air quality---formaldehyde determination acetylacetone,2,4-pentanedione AAS " test air formaldehyde concentration.Or detect, and carry out record with the U.S.'s 4160 type methylene oxide detecting instruments.
The detection method of benzene and TVOC is basic identical with formaldehyde, different only be that the solution instruments different and detection usefulness of the pernicious gas that sprays into are different.
The result is as the formula (1):
X=(C 1-C 2)/C 1×100% (1)
Wherein: C 2---with the detection data of wet tissue Wiper plate;
C 1---the detection data of wet tissue Wiper plate of no use;
The clearance of X---benzene, TVOC, formaldehyde etc.;
2. test result:
Time (hour) Do not spray benzene content value mg/M in the glass plate B case of wet tissue soup 3 Do not spray formolite number PPM in the glass plate B case of wet tissue soup Do not spray TVOC value mg/M in the glass plate B case of wet tissue soup 3 Be placed with benzene content value mg/M in the glass plate A case that sprays the wet tissue soup 3 Be placed with formolite number PPM in the glass plate A case that sprays the wet tissue soup Be placed with TVOC value mg/M in the glass plate A case that sprays the wet tissue soup 3
Initial value 8 points 1.55 1.2 2.25 1.55 1.2 2.25
11 points 1.53 1.18 2.20 0.9 0.25 1.5
14 points 1.50 1.16 2.15 0.7 0.08 1.2
17 points 1.48 1.15 2.10 0.5 0.10 1.0
20 points 1.45 1.13 2.08 0.1 0.09 0.6
Benzene clearance=0.93 * 100%=93%; Formaldehyde clearance=092 * 100%=92%
TVOC clearance=0.71 * 100%=71%.
Embodiment two
Present embodiment is the preparation method that embodiment one eliminates the wet tissue of pernicious gas curing leather, and employed material comprises: flexible sheet cellulosic, the lapping of secluding air.The step of preparation:
Following compositions in weight percentage mixing preparation is constituted the solution of formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~2 0%
Nano titanium oxide 0.8%~1.5%
Water 1%~60%.
The flexible sheet cellulosic is placed on immersion and impregnation technology processing in the above-mentioned solution, makes it be full of the step of solution;
The lapping of use secluding air will be full of the step of the flexible sheet cellulosic sealing of solution.
The lapping of secluding air can be plastics, or other materials, and key is a good stability, is difficult for being corroded, oxidation deterioration, secluding air fully.The flexible sheet cellulosic is nonwoven or cloth or paper.Selected flexible sheet cellulosic should have the performance that absorbs liquid preferably, and can well keep liquid therein.Though the sponge absorbent properties are fine, can not well keep, therefore not good selection.So it is good selections that cloth, nonwoven and paper have these characteristics.
Protein solution in the leather maintaining solution is a protein liquid.The present invention why in main component, added protein liquid be because:
1) protein liquid has not only served as the component of binder in the eliminating smell agent prescription, and protein liquid itself is again the leather polishing material.So the present invention not only can remove the peculiar smell of leather, can also make leather submissiveer, smooth, and the surface is more glossy, waterproof durable is superior in quality.
2) component that protein liquid has served as binder on the one hand aspect eliminating smell agent; and protein liquid is wiping leather surface rear surface protein precipitation on the other hand, forms protein film, adsorbed gas poisonous substance in a large number; mainly be macromolecule organic, can also protect leather.
Embodiment three:
Present embodiment is a using method of eliminating the wet tissue of pernicious gas curing leather.Present embodiment is employed to be embodiment one described wet tissue, the promptly described flexible sheet cellulosic that seals by the lapping of secluding air, and described flexible sheet cellulosic is full of formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup.Its using method comprises the steps:
Open the lapping of sealing, expose the cellulosic step of flexible sheet;
Extract the cellulosic step of flexible sheet out;
The solution that is full of in the flexible sheet cellulosic is evenly spread upon the step of distributing the pernicious gas object surface;
Formaldehyde scavenger, eliminating smell agent and photocatalyst soup decompose the step that absorbs the pernicious gas curing leather.
Flexible sheet cellulosic in the wet tissue of described elimination pernicious gas curing leather is that cloth, nonwoven or paper etc. have good adsorption moisture and keep the analog of moisture characteristic.Described formaldehyde scavenger, eliminating smell agent leather maintaining agent photocatalyst soup are made of following weight percentages of components mixing preparation:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~20%
Nano titanium oxide 0.8%~1.5%
Water 1%~60%.
The key of this using method is that the solution that will be full of in the flexible sheet cellulosic evenly spreads upon the step of distributing the pernicious gas object surface.Traditional wet tissue institute wiping generally at be the position of human body, more direct theory is people's skin normally, so the quality of wet tissue must be soft, can not injure skin.The composition of contained liquid can not injure skin in the wet tissue, and the composition in the employed wet tissue can not injure skin in the present embodiment, but the flexibility of wet tissue does not then have this requirement, can relatively exert oneself in wiping yet, and it mainly acts on is the surface that the soup in the wet tissue is spread upon object.Can release thus, the fundamental difference of the using method of method of the present invention and common wet tissue is: the effect of common wet tissue is to wipe some materials of being wiped the surface, for example, and people's dirt on the face.The effect of wet tissue contained humidity or soup is to help away dirt, or complementary some skin cares that play a part preserve moisture, and promptly only is booster action.And the wet tissue effect in the described method of present embodiment is that wherein soup is spread upon object surface, promptly increases material being wiped on the surface, rather than wipes by the material on the wiping face.Be a process of smearing, utilize the material of smearing to remove and smeared the toxic gas that object distributes.
The first, the object difference, common wet tissue wiping be human body skins such as hand, face; The present embodiment wiping be furniture, leather surface.The second, purpose difference, the purpose of common wet tissue wiping are to eliminate visible dirt, bacterium etc.; Present embodiment forms a skim at furniture, leather surface, and adsorbs, decomposes invisible toxic and harmful with this by smearing.The 3rd, common wet tissue is from being wiped thing, as hand, clean out dirt etc. on the face; Present embodiment then is to smear back formation thin film on by the wiping thing.The 4th, common wet tissue is seriously located emphasis at dirt and is wiped, and gently wipe away and gets final product at non-serious place; Present embodiment will be evenly, smear comprehensively, and omission place can not be arranged.The 5th, common wet tissue wipes the effect that furniture, leather surface can not have taste removal, nursing leather; Though present embodiment does not stimulate skin, does not also have injury, can not clip skin surface, will wash one's hands with clear water immediately after the use yet.

Claims (10)

1. eliminate the wet tissue of pernicious gas curing leather, comprising: the integument of sealing, the flexible sheet cellulosic is characterized in that, is full of the solution that decomposes and eliminate pernicious gas in the described flexible sheet cellulosic.
2. the wet tissue of elimination pernicious gas curing leather according to claim 1 is characterized in that, described flexible sheet cellulosic is a nonwoven.
3. the wet tissue of elimination pernicious gas curing leather according to claim 1 is characterized in that, described flexible sheet cellulosic is cloth or paper.
4. the wet tissue of elimination pernicious gas curing leather according to claim 1, it is characterized in that, the solution of decomposition that is full of in the described flexible sheet cellulosic and elimination pernicious gas is formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup, is to be made of following compositions in weight percentage mixing preparation:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~2 0%
Nano titanium oxide 0.8%~1.5%
Water 1%~60%.
5. the wet tissue of elimination pernicious gas curing leather according to claim 4 is characterized in that, described protein solution is a protein liquid.
6. eliminate the preparation method of the wet tissue of pernicious gas curing leather, comprising: the flexible sheet cellulosic, the lapping of secluding air is characterized in that, described step:
Following compositions in weight percentage mixing preparation is constituted the solution of formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~20%
Nanometer titanium dioxide 0.8%~1.5%
Water 1%~60%;
The flexible sheet cellulosic is placed on immersion and impregnation technology processing in the above-mentioned solution, makes it be full of the step of solution;
The lapping of use secluding air will be full of the step of the flexible sheet cellulosic sealing of solution.
7. the preparation method of the wet tissue of elimination pernicious gas curing leather according to claim 6 is characterized in that, described flexible sheet cellulosic is a nonwoven.
8. the preparation method of the wet tissue of elimination pernicious gas curing leather according to claim 6 is characterized in that, described flexible sheet cellulosic is cloth or paper.
9. eliminate the using method of the wet tissue of pernicious gas curing leather, flexible sheet cellulosic by the sealing of the lapping of secluding air, it is characterized in that the using method that described flexible sheet cellulosic is full of formaldehyde scavenger, eliminating smell agent, leather maintaining agent and photocatalyst soup comprises the steps:
Open the lapping of sealing, expose the cellulosic step of flexible sheet;
Extract the cellulosic step of flexible sheet out;
The solution that is full of in the flexible sheet cellulosic is evenly spread upon the step of distributing the pernicious gas object surface;
Formaldehyde scavenger, eliminating smell agent and photocatalyst soup decompose the step that absorbs the pernicious gas curing leather.
10. the using method of the wet tissue of elimination pernicious gas curing leather according to claim 9, described formaldehyde scavenger, eliminating smell agent leather maintaining agent photocatalyst soup are made of following compositions in weight percentage mixing preparation:
Protein solution 1%~30%
Triethanolamine 0.5%~30%
Disodium ethylene diamine tetraacetate 0.1%~20%
Nano titanium oxide 0.8%~1.5%
Water 1%~60%.
CN2006101655237A 2006-12-21 2006-12-21 Wet towel for eliminating harmful gas and curing leather, method for making and using same Expired - Fee Related CN101011231B (en)

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CN2006101655237A CN101011231B (en) 2006-12-21 2006-12-21 Wet towel for eliminating harmful gas and curing leather, method for making and using same

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Application Number Priority Date Filing Date Title
CN2006101655237A CN101011231B (en) 2006-12-21 2006-12-21 Wet towel for eliminating harmful gas and curing leather, method for making and using same

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CN101011231B CN101011231B (en) 2010-12-29

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101828897A (en) * 2010-05-04 2010-09-15 江西生成卫生用品有限公司 Leather shoes wiper
CN101314100B (en) * 2008-07-03 2012-10-03 陈晓鹏 Fibre pad for removing indoor air pollution and method of producing the same
CN105219539A (en) * 2015-09-17 2016-01-06 广州佳伲思抗菌材料有限公司 A kind of antimildew and antibacterial cleansing cream and preparation method thereof and application
CN107185399A (en) * 2017-05-24 2017-09-22 黄丽英 Except formaldehyde articles for use
CN107199034A (en) * 2017-05-24 2017-09-26 黄丽英 The photocatalyst product of formaldehyde can be removed
CN107858826A (en) * 2017-11-17 2018-03-30 程林 Decomposability environmental protection cloth for cleaning
CN109847527A (en) * 2019-03-29 2019-06-07 天津清科材慧环保科技有限公司 A kind of wet tissue and preparation method thereof with except aldehyde function

Families Citing this family (1)

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Publication number Priority date Publication date Assignee Title
CN102660197B (en) * 2012-04-20 2014-11-05 上海皇宇科技发展有限公司 Leather brightening agent and leather brightening wet wiper

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Publication number Priority date Publication date Assignee Title
CN1059549A (en) * 1990-09-04 1992-03-18 李辉 Cleaning-polishing towel for leather products
AT404548B (en) * 1996-02-23 1998-12-28 Karl Zeilinger DEVICE FOR CLEANING FOOTWEAR
CN2464247Y (en) * 2001-02-26 2001-12-12 陈修定 Disposable leather cleaning paper bag

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101314100B (en) * 2008-07-03 2012-10-03 陈晓鹏 Fibre pad for removing indoor air pollution and method of producing the same
CN101828897A (en) * 2010-05-04 2010-09-15 江西生成卫生用品有限公司 Leather shoes wiper
CN105219539A (en) * 2015-09-17 2016-01-06 广州佳伲思抗菌材料有限公司 A kind of antimildew and antibacterial cleansing cream and preparation method thereof and application
CN107185399A (en) * 2017-05-24 2017-09-22 黄丽英 Except formaldehyde articles for use
CN107199034A (en) * 2017-05-24 2017-09-26 黄丽英 The photocatalyst product of formaldehyde can be removed
CN107858826A (en) * 2017-11-17 2018-03-30 程林 Decomposability environmental protection cloth for cleaning
CN109847527A (en) * 2019-03-29 2019-06-07 天津清科材慧环保科技有限公司 A kind of wet tissue and preparation method thereof with except aldehyde function

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