CN101003879A - Hot rolled steel in C-Mn-Ti series with high intensity magnetic induction performance - Google Patents

Hot rolled steel in C-Mn-Ti series with high intensity magnetic induction performance Download PDF

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Publication number
CN101003879A
CN101003879A CN 200710051252 CN200710051252A CN101003879A CN 101003879 A CN101003879 A CN 101003879A CN 200710051252 CN200710051252 CN 200710051252 CN 200710051252 A CN200710051252 A CN 200710051252A CN 101003879 A CN101003879 A CN 101003879A
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China
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hot
magnetic induction
steel
rolled
strength
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CN 200710051252
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Chinese (zh)
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CN100557060C (en
Inventor
郭斌
苏毅
刘昌明
郑琳
谢懋亮
鄢檀力
陈洪伟
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武汉钢铁(集团)公司
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Abstract

This invention relates to a method for producing C-Mn-Ti hot-rolled steel with high strength and high magnetic induction. This invention solves the problems of high cost and serious damage to rolling equipment faced by present techniques. The hot-rolled steel is composed of: C 0.03-0.15 wt.%, Si less than or equal to 0.15 wt.%, Mn 0.50-1.40 wt.%, P less than or equal to 0.025 wt.%, S less than or equal to 0.015 wt.%, Ti 0.05-0.15 wt.%, Al 0.02-0.10 wt.%, N less than or equal to 0.010 wt.%, and Fe. The method comprises: desulfurizing molten iron, smelting in a converter, treating by blowing Ar, casting into raw plates, heating the raw plates to 1230-1280 deg.C primarily hot-rolling (end temperature is greater than or equal to 1100 deg.C), then finely hot-rolling (end temperature is 850-930 deg.C), cooling, and curling at 580-650 deg.C to obtain hot-rolled and curled plates.

Description

C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel and manufacture method thereof
Technical field
The present invention relates to microalloyed steel and make the field, refer to particularly a kind of be adapted to large-sized water turbine generator rotor rim part required possess high strength (ReL 〉=600MPa) and the steel and the manufacture method thereof of high magnetic induction performance.
Background technology
Along with becoming increasingly conspicuous of imbalance between power supply and demand, become the important behave that China solves energy problem as cleanliness without any pollution, reproducible water power.Along with going deep into of China's development of the West Regions, large-scale, the huge hydroelectric project of large quantities of Three Gorges level will put into operation in coming few decades successively, these large-scale, huge hydroelectric projects all need single-machine capacity 70~800,000 other Large Hydroelectric Set of kilowatt level, and this has just proposed the requirement of high strength, high magnetic induction performance with steel to generator amature yoke wherein part.Before the present patent application, the patent No. is that 98800888.2 Chinese invention patent has been put down in writing a kind of " producing the method for the preferable grain orientation electrical sheet with high magnetic flux density based on low temperature slab heating method ", it is longer that its composition and process system weak point are to produce line, be annealed into cold-rolled steel sheet from hot-rolled steel sheet, also need to carry out carbonization treatment at last, production cycle is long, energy consumption is big, and steel plate contains silicon (Si) or a certain amount of copper (Cu) of high level, nickel (Ni), chromium (Cr), boron (B), cost of alloy is higher, and this invention simultaneously relates to kind and do not possess high tensile strength.Application number is that 200480002119.7 Chinese invention patent has been introduced a kind of " ultrahigh strength hot-rolled steel and the method for producing band ", its composition and process system weak point are to contain 0.5%~1.0% chromium (Cr), and need in the production technique rolling temperature is controlled at and be lower than 950 ℃, be cooled to 400 ℃ or low temperature more then, remain on the rate of cooling between 800 ℃ and 700 ℃ therebetween greater than 50 ℃/S, at last at 250 ℃ or more reel under the low temperature, this Capability Requirement for milling train and taking-up equipment is high, and it is bigger to equipment damage, do not have operability, this patent relates to kind and does not possess high magnetic induction performance simultaneously.
Summary of the invention
Higher for solving the existing in prior technology cost, and to problem rolling and that the taking-up equipment infringement is bigger, the invention provides yield strength ReL 〉=600MPa that yoke is partly used in a kind of large-sized water turbine generator rotor that can satisfy high single-machine capacity, high magnetic induction performance steel of C-Mn-Ti series high strength and the manufacture method thereof of magnetic induction performance B50 〉=1.5T.
For achieving the above object, the C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel that the present invention is designed, it is by carbon (C), silicon (Si), manganese (Mn), phosphorus (P), sulphur (S), titanium (Ti), aluminium (Al), nitrogen (N) and iron (Fe), the weight percent of each component is C:0.03%~0.15%, Si :≤0.15%, Mn:0.50%~1.40%, P: S≤0.025% :≤0.015%, Ti:0.05%~0.15%, Al:0.02%~0.10%, N :≤0.010, and all the other inevitably are mingled with for Fe reaches.
The mechanism of action of each alloy ingredient is as follows in the C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel of the present invention:
Carbon of the present invention (C) content is 0.03%~0.15%, carbon is one of element of indispensable raising steel strength in the steel, can form the microalloy carbide with Ti effect in the steel simultaneously, play the precipitation strength effect, the too high meeting of carbon content has influence on the magnetic induction performance of steel.Carbon content is limited to 0.03~0.15%, both can have improved the intensity of steel, guarantee the magnetic induction performance of steel, be fit to production operation again.
Manganese of the present invention (Mn) content is 0.50%~1.40%, can reduce austenitic transformation and become ferritic transformation temperature, enlarges the hot processing temperature zone, helps the refinement ferrite grain size, improves the yield strength and the tensile strength of steel.
Phosphorus of the present invention (P) content≤0.025%, sulphur (S) content≤0.015%, phosphorus have disadvantageous effects such as causing segregation, reduction magnetic induction performance easily in steel.Sulphur easily combines generation MnS and is mingled with manganese, influence the magnetic induction performance and the plasticity of steel.Therefore, the present invention should reduce as far as possible phosphorus, element sulphur to rigidity can disadvantageous effect, by molten iron being carried out means such as dark desulfurization pre-treatment, control phosphorus, sulphur content, thereby alleviate its disadvantageous effect.
Silicon of the present invention (Si) content≤0.15%, silicon has disadvantageous effect to hot continuous rolling coiled sheet surface quality, so the present invention should reduce silicone content in the steel as far as possible.
Titanium of the present invention (Ti) content is 0.08%~0.18%, titanium is a kind of intensive carbide and nitride forming element, in reheating, steel stop austenite crystal to be grown up, TiN and TiC separate out when the roughing of high temperature austenite district, can effectively suppress austenite crystal and grow up, TiN that separates out simultaneously and TiC can effectively improve armor plate strength.
Aluminium of the present invention (Al) content is 0.02~0.10%, and it mainly acts on is the oxygen of sloughing in the molten steel, prevents that titanium is oxidized and loses efficacy.
Nitrogen of the present invention (N) content≤0.01% belongs to normal remaining in the converter steel, can combine formation TiN with titanium in the steel (Ti) and separate out, and plays the inhibition austenite crystal and grows up and the precipitation strength effect.
The manufacture method of above-mentioned C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel is undertaken by following step: a, desulfurizing iron; B, converter top bottom blowing; Blowing argon gas is handled behind c, the stove; D, pour into slab; E, hot continuous mill controlled rolling and controlled cooling.Wherein, described hot continuous rolling controlled rolling and controlled cooling carries out at the hot continuous rolling unit, earlier the prepared slab of steps d is heated to 1230~1280 ℃; Roughing then, roughing end temp are 〉=1100 ℃; Finish rolling then, finishing temperature are 850~930 ℃; Steel plate rolls and batches after the laminar flow cooling is adopted in the back, and coiling temperature is 580~650 ℃, makes hot-rolled sheet coil.
C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel of the present invention does not contain copper (Cu), nickel (Ni), chromium (Cr), boron compositions such as (B), and cost greatly economizes in raw materials; And rolling temperature and coiling temperature are higher, can reduce steel plate deformation drag, and ((ReL 〉=600MPa) reduce machine utilization in the steel process has reduced the infringement to rolling equipment and taking-up equipment to 1.6~5mm) high strength in rolling thin specification.Test shows, the yield strength ReL of C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel of the present invention 〉=600MPa, tensile strength Rm 〉=700MPa, magnetic induction performance B50 〉=1.50T can satisfy the demand of large-sized water turbine generator rotor rim with high strength and magnetic induction property steel.
Embodiment
Below in conjunction with specific embodiment C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel of the present invention and production method thereof are described in further detail:
The chemical ingredients of table 1 steel of the present invention, wt%
Composition ?C ?Si ?Mn ?P ?S ?Ti ?Al ?N
??1 ?0.064 ?0.03 ?0.769 ?0.016 ?0.005 ?0.063 ?0.034 ?0.007
??2 ?0.074 ?0.022 ?0.776 ?0.011 ?0.004 ?0.077 ?0.047 ?0.008
??3 ?0.10 ?0.022 ?0.533 ?0.015 ?0.005 ?0.079 ?0.057 ?0.007
Table 1 has been listed the present invention and can be used for the Chemical Composition of large-sized water turbine generator rotor rim with several specific exampless of steel.
These several high strength and magnetic induction properties are as follows with the manufacture method of steel: at first, adopt the dark desulfurization technology of molten iron, in converter, carry out top bottom blowing, make S≤0.005% in the molten iron, molten steel is behind stove in the blowing argon gas treating processes, carry out microalloying, make Chemical Composition in the steel satisfy the requirement of table 1, surplus is Fe and inevitably is mingled with; Then, the pouring molten steel that satisfies table 1 requirement is become the slab of 200~300mm * 900~1550mm section; At last, the hot continuous rolling production technique with this slab adopts controlled rolling and controlled cooling to handle on hot continuous mill is rolled into hot-rolled sheet with it.
When adopting the hot continuous rolling production technique of controlled rolling and controlled cooling processing, for giving full play to the effect of microalloy element in steel and dimensions, the surface quality of assurance steel plate, utilize high-power milling train (3/4 continous way hot strip mill group, the single chassis peak power is more than the 5000kw) capacity of equipment, reduce rolling pass, improve percentage pass reduction.Earlier slab is heated to 1230~1280 ℃.Roughing accumulative total draft is 80~90%, and the roughing end temp is 〉=1100 ℃.Carry out finish rolling after the roughing, finishing temperature is 850~930 ℃; Batch after the laminar flow cooling, coiling temperature is 550~620 ℃, makes the hot-rolled sheet that thickness of slab is 1.6~5mm.
The processing parameter and the test-results of the hot-rolled sheet of C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel of the present invention see Table 2.
Table 2 steel hot-rolling plate of the present invention preparation method and test-results
Composition Grade of steel Heating temperature ℃ Finishing temperature ℃ Coiling temperature ℃ Thickness mm ?ReL ?MPa ?Rm ?MPa ?A 5?% ?B50 ?T
??1 ??1 ??1260 ??880 ??610 ??2 ?630 ?710 ?22 ?1.587
??2 ??1260 ??890 ??615 ??5 ?600 ?700 ?23 ?1.567
??2 ??3 ??1270 ??870 ??620 ??2 ?670 ?725 ?20 ?1.678
??3 ??4 ??1270 ??885 ??618 ??4 ?625 ?710 ?22 ?1.643
Annotate: the composition 1,2,3 of table 2 and the composition 1,2,3 in the table 1 are corresponding relation.
Embodiment has enumerated the C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel of three kinds of compositions, corresponds respectively to the composition 1,2,3 in the table 1.The hot-rolled sheet explained hereafter press in test, two kinds of specifications thicker and that approach that wherein composition 1 is rolling.From the performance that table 2 reflects, 1.6~5mm hot-rolled sheet of each composition can both satisfy yield strength R EL〉=600MPa, magnetic induction performance B50 〉=1.50T.

Claims (5)

1, C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel, it is characterized in that it is made up of C, Si, Mn, P, S, Ti, Al, N and Fe, the weight percent of each component is C:0.03%~0.15%, Si :≤0.15%, Mn:0.50%~1.40%, P: S≤0.025% :≤0.015%, Ti:0.05%~0.15%, Al:0.02%~0.10%, N :≤0.010%, and all the other are Fe.
2, C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel according to claim 1, the weight percent that it is characterized in that each component is C:0.064%, Si:0.03%, Mn:0.769%, P:0.016%, S:0.005%, Ti:0.063%, Al:0.034%, N:0.007%, and all the other are Fe.
3, C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel according to claim 1, the weight percent that it is characterized in that each component is C:0.074%, Si:0.022%, Mn:0.776%, P:0.011%, S :≤0.004%, Ti:0.077%, Al:0.047%, N:0.008%, all the other are Fe.
4, C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel according to claim 1, the weight percent that it is characterized in that each component is C:0.10%, Si:0.022%, Mn:0.533%, P:0.015%, S:0.005%, Ti:0.079%, Al:0.057%, N: 0.007%, and all the other are Fe.
5,, it is characterized in that it is undertaken by following step: a, desulfurizing iron according to the manufacture method of claim 1,2,3 or 4 described C-Mn-Ti series hot-rolled high strength high magnetic induction performance steels; B, converter top bottom blowing; Blowing argon gas is handled behind c, the stove; D, pour into slab; E, hot continuous mill controlled rolling and controlled cooling.Wherein, described hot continuous rolling controlled rolling and controlled cooling carries out at the hot continuous rolling unit, earlier the prepared slab of steps d is heated to 1230~1280 ℃; Roughing then, roughing end temp are 〉=1100 ℃; Finish rolling then, finishing temperature are 850~930 ℃; Steel plate rolls and batches after the laminar flow cooling is adopted in the back, and coiling temperature is 580~650 ℃, makes hot-rolled sheet coil.
CNB2007100512527A 2007-01-12 2007-01-12 The manufacture method of C-Mn-Ti series hot-rolled high strength high magnetic induction performance steel CN100557060C (en)

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CN102943206A (en) * 2012-12-09 2013-02-27 新余钢铁集团有限公司 High-strength hot rolled steel strip with improved zonal structure by manganese reduction and manufacturing method thereof
CN104011234A (en) * 2011-12-27 2014-08-27 杰富意钢铁株式会社 Hot-rolled steel sheet and process for manufacturing same
CN104962813A (en) * 2015-07-16 2015-10-07 武汉钢铁(集团)公司 CSP production line-based economic high-strength steel with good forming property and production method thereof
CN105420606A (en) * 2015-12-14 2016-03-23 武汉钢铁(集团)公司 High-strength and high-toughness hot rolled magnetic yoke steel with yield strength to be 550MPa grade and production method
CN106319352A (en) * 2016-08-31 2017-01-11 安阳钢铁股份有限公司 Titanium microalloy strengthened pipeline steel hot-rolled coiled plate and production method thereof
CN106636924A (en) * 2016-12-30 2017-05-10 武钢集团昆明钢铁股份有限公司 235 MPa level shock-proof hot-rolled steel plate and steel strip for building structure and preparation method thereof
CN108914008A (en) * 2018-08-10 2018-11-30 武汉钢铁集团鄂城钢铁有限责任公司 A kind of economical high-ductility 360MPa level structure steel plate and its manufacturing method
CN109161639A (en) * 2018-09-29 2019-01-08 中信重工机械股份有限公司 A kind of DT4 magnetic pole of 250MeV superconducting cyclotron main magnet, magnetic yoke steel smelting technique
CN109338216A (en) * 2018-10-24 2019-02-15 辽宁工业大学 A kind of preparation method of high performance generation machine pawl pole steel
CN109576593A (en) * 2017-09-29 2019-04-05 宝山钢铁股份有限公司 A kind of hot rolling magnetic yoke steel and its manufacturing method
CN109576594A (en) * 2017-09-29 2019-04-05 宝山钢铁股份有限公司 A kind of hot rolling magnetic yoke steel and its manufacturing method

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CN104011234A (en) * 2011-12-27 2014-08-27 杰富意钢铁株式会社 Hot-rolled steel sheet and process for manufacturing same
CN104011234B (en) * 2011-12-27 2015-12-23 杰富意钢铁株式会社 Hot-rolled steel sheet and manufacture method thereof
CN102943206B (en) * 2012-12-09 2014-10-22 新余钢铁集团有限公司 High-strength hot rolled steel strip with improved zonal structure by manganese reduction and manufacturing method thereof
CN102943206A (en) * 2012-12-09 2013-02-27 新余钢铁集团有限公司 High-strength hot rolled steel strip with improved zonal structure by manganese reduction and manufacturing method thereof
CN104962813A (en) * 2015-07-16 2015-10-07 武汉钢铁(集团)公司 CSP production line-based economic high-strength steel with good forming property and production method thereof
CN105420606A (en) * 2015-12-14 2016-03-23 武汉钢铁(集团)公司 High-strength and high-toughness hot rolled magnetic yoke steel with yield strength to be 550MPa grade and production method
CN106319352A (en) * 2016-08-31 2017-01-11 安阳钢铁股份有限公司 Titanium microalloy strengthened pipeline steel hot-rolled coiled plate and production method thereof
CN106636924B (en) * 2016-12-30 2018-04-03 武钢集团昆明钢铁股份有限公司 A kind of building structure of 235MPa ranks earthquake-resistant hot rolled steel plate, steel band and preparation method thereof
CN106636924A (en) * 2016-12-30 2017-05-10 武钢集团昆明钢铁股份有限公司 235 MPa level shock-proof hot-rolled steel plate and steel strip for building structure and preparation method thereof
CN109576593A (en) * 2017-09-29 2019-04-05 宝山钢铁股份有限公司 A kind of hot rolling magnetic yoke steel and its manufacturing method
CN109576594A (en) * 2017-09-29 2019-04-05 宝山钢铁股份有限公司 A kind of hot rolling magnetic yoke steel and its manufacturing method
CN108914008A (en) * 2018-08-10 2018-11-30 武汉钢铁集团鄂城钢铁有限责任公司 A kind of economical high-ductility 360MPa level structure steel plate and its manufacturing method
CN109161639A (en) * 2018-09-29 2019-01-08 中信重工机械股份有限公司 A kind of DT4 magnetic pole of 250MeV superconducting cyclotron main magnet, magnetic yoke steel smelting technique
CN109338216A (en) * 2018-10-24 2019-02-15 辽宁工业大学 A kind of preparation method of high performance generation machine pawl pole steel

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