CN100577082C - Cleaning implement - Google Patents
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- CN100577082C CN100577082C CN200580029805A CN200580029805A CN100577082C CN 100577082 C CN100577082 C CN 100577082C CN 200580029805 A CN200580029805 A CN 200580029805A CN 200580029805 A CN200580029805 A CN 200580029805A CN 100577082 C CN100577082 C CN 100577082C
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Abstract
A dry-type cleaning tool for use indoors having a fibrous base material, which is imparted with an antigenicity reducing composition containing an antigenicity reducing component for reducing the antigenicity of a substance inducing allergy, an oil agent and a surfactant is imparted. The above antigenicity reducing component preferably comprises an extract prepared by extracting a plant belonging to Olive or Privet with water or an organic solvent. The above cleaning tool can reduce the antigenicity of a substance inducing allergy attached thereto.
Description
Technical field
The present invention relates to have the indoor cleaning apparatus of fibrous substrate, more specifically, the present invention relates to reduce antigenic cleaning appliance of the material of cause allergic reaction (Allergie).
Background technology
In recent years, the number of suffering from allergic rhinitis (Allergic rhinitis) or bronchial astehma anaphylactias such as (bronchialasthma) increases steadily.The material that becomes the reason that causes above-mentioned anaphylactia is so-called anaphylactogen (allergen), and the anaphylactogen of having determined is just had an appointment 200 kinds now.The skeleton of a corpse of mite, mite, the hair of pet, pollen etc. are its typical examples, and above-mentioned anaphylactogen brings out various allergic symptoms by contact or enter human body with human body with certain form.
At this moment, cause anaphylactoid mite etc. even kill, also because its corpse still has antigenicity, so can't fundamentally solve anaphylactic disease with medicine etc.Therefore for the symptom that alleviates anaphylactic disease or prevent new allergic reaction (sensitivities), must remove anaphylactogen from the living space fully or by the anaphylactogen sex change being waited reduce antigenicity of the material that (inactivation) cause allergic reaction.
As the antigenic medicament that reduces the above-mentioned material that causes allergic reaction, for example, the anaphylactogen deactivator of being made up of at least a plant that is selected from Oleaceae Olea (Olea europaea) or Ligustrum (Ligustrum) (spy opens 2003-55122 communique patent documentation 1) is disclosed.
In addition, as the medicament that reduces anaphylactogen, disclose the anaphylactogen that can scatter with the state of the aqueous solution or be coated on tatami, carpet, the floor etc. and reduced agent, this medicament is formed (spy opens 2003-334240 communique patent documentation 2) by containing aluminum sulfate and sodium sulphate as the aqueous solution of active ingredient.
Summary of the invention
Rag, mop, the cleaning piece cleaning appliances such as (wiper) used in order to remove indoor dust or grit etc., above-mentioned anaphylactogen sticks on the cleaning appliance in cleaning course, and keeps this state for a long time.Therefore, as mentioned above, for the symptom that alleviates anaphylactic disease or prevent to cause new anaphylactic disease, also must reduce the antigenicity that remains on the anaphylactogen on the cleaning appliance.
But above-mentioned patent documentation 1,2 described medicaments are all by direct distribution or be coated in the place that tatami, carpet, floor, clothing etc. might touch human body and use.Must after coating, wipe or inhale and remove above-mentioned medicament, make troubles to the user with dust catcher.But, for the cleaning of the grit dust of the floor of daily the most frequent cleaning or furniture, the research method of simply removing the material that causes allergic reaction.In addition, because existing method has wet the cleaning object,, do not propose to reduce dry type (drytype) clean method of the material that causes allergic reaction so need the dry time.And, also reduce antigenic research of the material that causes allergic reaction contained in the grit dust that enters dry cleaning apparatus such as mop.
Particularly in the indoor cleaning apparatus, disposablely or removable has the fibrous substrate of laminar or brush and sac like, not contain the dry cleaning apparatus of moisture in fact well received on market.When using above-mentioned dry cleaning apparatus, as the antigenicity reductionization composition (antigenicity-reducing composition) that is endowed, require said composition good, and the transfer to the cleaning object during use is few to the adhesiveness or the impregnation of fibrous substrate.
At this point, in patent documentation 1, the composition of having considered above-mentioned adhesiveness or impregnation is not studied.In addition, the anaphylactogen of patent documentation 2 reduce agent be with the aqueous solution state, be that hygrometric state makes and is used for reducing anaphylactogen, be difficult to use in the dry cleaning apparatus that does not contain moisture in fact.
The present invention obtains in view of above-mentioned subject study, and purpose is to provide and can reduces the antigenic cleaning appliance that sticks to the material that causes allergic reaction on the cleaning appliance.
The inventor etc. have carried out deep repeatedly research in order to solve above-mentioned problem, found that by antigenicity is reduced to change into and give cleaning appliance after branch is made the particular composition that contains finish and surfactant, can solve above-mentioned problem, thereby finish the present invention.More specifically, the invention provides following cleaning appliance.
(1) a kind of cleaning appliance, described cleaning appliance is the cleaning appliance that is used for indoor cleaning, described cleaning appliance has dry type fibrous substrate and the antigenicity reductionization composition that is imparted on the described fibrous substrate, and described antigenicity reductionization composition contains the antigenic antigenicity reduction that reduces the material that causes allergic reaction and changes into branch, finish and surfactant.
Cleaning appliance of the present invention owing to used contains antigenicity and reduces and change into the antigenicity reductionization composition of branch, finish and surfactant, so can easily said composition be given the dry type fibrous substrate.In addition, give by state with above-mentioned composition, can be with the effect of stable status long term maintenance antigenicity reductionization.In addition, the composition amount of giving more after a little while, can prevent in use composition from fibrous substrate one sidesway to cleaning object one side.
Need to prove that among the present invention, " dry type " is meant that the finish proportion is more in the weight rate of finish contained in giving the antigenicity reductionization composition of cleaning appliance and moisture, moisture is to be suitable below 5.0%.Moisture must be dissolved in finish, if finish generation emulsification, then because control of dust ability drop and not preferred.
(2) as (1) described cleaning appliance, wherein, it is water-soluble or hydrophilic component that described antigenicity reduction changes into branch, and in addition, (3) as (1) or (2) described cleaning appliance, wherein, it is the plant extract composition that described antigenicity reduction changes into branch.
According to this scheme, to change into branch be water-soluble or hydrophilic component because the antigenicity of using reduces, and perhaps derives from plant, so safe to human body.
(4) as each described cleaning appliance in (1)～(3), wherein, described antigenicity reduces and changes into that branchs be made up of the extract of the plant gained of water or organic solvent extraction Olea (olea) or Ligustrum (ligustrum).
According to this scheme, water or organic solvent extract the extract that the plant of Olea or Ligustrum obtains (below be also referred to as Fructus Canrii Albi extract), reduce and turn usefulness into owing to have good antigenicity, so even give more on a small quantity, also can reduce antigenicity.In addition, the antigenicity that derives from existing plant reduces and changes into the difference of branch according to kind, and composition itself is coloured, so occur the problem that base material is colored when giving fibrous substrate with it.But the tone of Fructus Canrii Albi extract itself is Huang～yellowish-brown, so it is transparent almost to become colorless when giving fibrous substrate after the Fructus Canrii Albi extract dilution, can prevent that base material is colored.
(5) as each described cleaning appliance in (1)～(4), wherein, described antigenicity reduction changes into and is divided into oleuropein (oleuropein).
The oleuropein that uses in the such scheme is phenol iridoid glycoside (phenolic iridoidglycoside), and content is more in above-mentioned Olea or Ligustrum plant.Contain formoxyl and hydroxyl in this iridoid glycoside, think that the amino that contains in above-mentioned group and the allergen protein combines, thereby performance reduces antigenic effect.
(6) as each described cleaning appliance in (1)～(5), wherein, described glass or plastic containers.
According to this programme, hybrid antigen reduction stably changes into branch and finish.
(7) as each described cleaning appliance in (1)～(6), wherein, described finish is binding dust (dust-adhesive) finish, and
(8) as the cleaning appliance described in (1)～(7) each, wherein, described finish is a mineral oil.
According to this programme, by using binding dust finish, mineral oil as finish, make antigenicity reductionization composition adhere to fibrous substrate easily, and, the antigenicity reductionization composition that can effectively prevent to stick on the fibrous substrate breaks away from, and shifts to cleaning object one side.In addition, the trapping ability raising to dust can prevent to come off once again.
(9) as (8) described cleaning appliance, wherein, the viscosity of described mineral oil under 30 ℃ is 10～200mm
2/ s.
The viscosity of mineral oil under 30 ℃ is preferably 10～200mm
2/ s.15～120mm more preferably
2/ s.The not enough 10mm of viscosity
2During/s, composition is shifted to the cleaning object in a large number, or sticks to the sensation that is clamminess is arranged on hand.Viscosity surpasses 200mm
2During/s, the adsorptivity of dust is bad.
(10) as (4) or (5) described cleaning appliance, wherein, described fibrous substrate is white.
Thus, because the painted degree of above-mentioned Fructus Canrii Albi extract or oleuropein is light, so the problem that fibrous substrate is colored can not occur.Therefore, can use white fiber shape base material, so offer an explanation dust or the grit that adheres to easily same as the prior artly.
(11) as each described cleaning appliance in (1)～(10), wherein, described cleaning appliance contains the described antigenicity reduction of 0.01～10 quality % and changes into branch, the described finish of 50～95 quality %, the described surfactant of 1～50 quality % with respect to described antigenicity reductionization composition in its entirety.
According to this programme,, utilize the binding dust power of fibrous substrate itself and finish, trap dust by being set at the cooperation ratio of above-mentioned scope.And, can utilize antigenicity reductionization composition to reduce the antigenicity that captures the material that causes allergic reaction contained in the thing.
(12) as (11) described cleaning appliance, wherein, the amount of giving of described antigenicity reductionization composition is 1～15 quality % with respect to the fibrous substrate integral body of having given described antigenicity reductionization composition.
The amount of giving by making antigenicity reductionization composition is more than the 1 quality % with respect to fibrous substrate integral body, can obtain sufficient antigenicity reductionization effect.Need to prove, be 0.01～10 quality % because the antigenicity of this moment reduces the adding proportion that changes into branch, can give full play to effect so change into branch by the antigenicity reduction of giving denier.
The amount of giving by making antigenicity reductionization composition is below the 15 quality % with respect to fibrous substrate integral body, can prevent to cause antigenicity reductionization composition to shift to the problem that cleans object because of adhering to superfluous antigenicity reductionizations composition.
(13) as (11) described cleaning appliance, wherein, the amount of giving of described antigenicity reductionization composition is 3～15 quality % with respect to the fibrous substrate integral body of having given described antigenicity reductionization composition.
(14), wherein, make at least a portion of described antigenicity reductionization composition shift to the cleaning object as (13) described cleaning appliance.
According to the scheme of (13) and (14), be more than the 3 quality % by the amount of giving that makes antigenicity reductionization composition with respect to fibrous substrate integral body, can make cleaning appliance have sufficient antigenicity reductionization effect.In addition, can make at least a portion of antigenicity reductionization composition shift to the cleaning object, thus, also can bring into play simultaneously the antigenicity reductionization effect of cleaning object and the effect of waxing (waxing effect) that finish moves generation.The amount of giving by making antigenicity reductionization composition is below the 15 quality % with respect to fibrous substrate integral body, can prevent that composition from shifting to the cleaning object too much or sticking to the sense of being clamminess is arranged on hand.
Thus, the scheme of above-mentioned (13) and (14), owing to can bring into play antigenicity reductionization effect to cleaning appliance, also can bring into play simultaneously to antigenicity the reductionizations effect of cleaning object and to the effect of waxing of floor, so template (floor-type) cleaning appliance with being preferred for the what is called used on the floor.
According to the present invention, can provide and reduce the antigenic cleaning appliance that sticks to the material that causes allergic reaction on the cleaning appliance.
According to accompanying drawing of representing with following Ref. No. and following explanation, foregoing and other objects of the present invention, characteristics, advantage are very clearly.
Description of drawings
Fig. 1 is the side view of one of expression cleaning appliance of the present invention example.
Fig. 2 is the decomposition side view of the fibrous substrate of Fig. 1.
Fig. 3 is the side view of other examples of expression cleaning appliance of the present invention.
Fig. 4 is the side view of other examples of expression cleaning appliance of the present invention.
The specific embodiment
＜antigenicity reductionization composition 〉
The antigenic antigenicity that (a) reduce the material that causes allergic reaction of containing the antigenicity reductionization composition of giving cleaning appliance of the present invention reduces and changes into branch, (b) finish and (c) surfactant.Below, each constituent is described.
[the antigenicity reduction changes into branch]
" the antigenicity reduction changes into branch " used among the present invention suppresses the composition of allergic symptom for reducing the antigenicity of the material that causes allergic reaction, and preferably derives from the composition of plant.Be meant for example inhalant allergens such as cdear pollen (cedar pollen), grass family pollen (grass pollen), mite, house dust (house dust), animal, fungi (mould), insect etc. as the material that causes allergic reaction (anaphylactogen) herein.
Reduce the object lesson that changes into branch as above-mentioned antigenicity, be not particularly limited, can enumerate above-mentioned Fructus Canrii Albi extract, glossy privet (privet) extract, the extract of pomegranate (pomegranate), azadirachta (neem), persimmon (persimmon), tea, bamboo, purple perilla, peppermint (peppermint), Japan cypress (Japanese Hinoki cypress), Thujopsis dolabrata (Hiba arborvitae), eucalyptus (eucalyptus), tea tree (tea tree) etc.As the compound that extraction obtains, can enumerate tannic acid, gallic acid etc.In addition, can also enumerate following material: the poly-macromolecular compound that vinylphenol (poly para vinyl phenol) etc. is had 1 valency or the above phenolic groups of 1 valency at the side chain of the high molecular repetitive of line style, dihydroxy-benzoic acid polymer etc. has the macromolecular compound of 1 bivalent phenol group in repetitive, dodecyl diphenyl ether disulfonic acid disodium (disodium lauryl diphenyl ether disulfonic acid) etc. has the benzene sulfonate more than the divalent of polyoxyethylene chain and/or ethylene chain in molecule, and/or the above sulfate of the divalent that has polyoxyethylene chain and/or ethylene chain in the molecule, 2, hydroxybenzoic acids such as 5-dihydroxy-benzoic acid, aromatic hydroxy compound, alkali-metal carbonate, alum, the lauryl benzene sulfonate, lauryl sulfate, polyoxyethylene lauryl ether sulfate, phosphate, zinc sulfate and/or lead acetate etc.
Wherein, antigenicity reduces and to change into branch and preferably be made up of Fructus Canrii Albi extract." Fructus Canrii Albi extract " of the present invention is made up of the extract of the plant gained of water or organic solvent extraction Olea or Ligustrum.The antigenicity reduction changes into branch and more preferably is oleuropein.Oleuropein is an iridoid glycoside, has formoxyl and hydroxyl in this iridoid glycoside, thinks that above-mentioned group reduces antigenicity by combining with contained amino in the allergen protein.As above-mentioned Fructus Canrii Albi extract, can use above-mentioned patent documentation 1 described Fructus Canrii Albi extract particularly.
In addition, think that tannic acid is that the amino of hydroxyl and allergen protein by polyphenol or peptide bond part combine and reduce antigenicity.
Above-mentioned antigenicity reduces and changes into branch and can be used as separate constituent and be engaged in the antigenicity reductionization composition, also can cooperate with the states such as solution that contain active ingredient such as oleuropein and extract thereof etc. (below be called the agent of antigenicity reductionization).For example, above-mentioned Fructus Canrii Albi extract is one of an antigenicity reductionization agent example, can use the composition that also contains alcohol and water except that oleuropein.
[finish]
" finish " used among the present invention adds for the absorption hold facility that improves dust or grit.Be not particularly limited as above-mentioned finish, preferably contain in mineral oil, artificial oil, silicone oil, the vegetable oil more than at least a kind.As mineral oil, can enumerate alkane, cycloalkane, aromatic hydrocarbon etc.Above-mentioned finish can use separately, also can mix more than 2 kinds and use.
Wherein, when the main component of finish was atoleine, antigenicity reductionization composition sticked on the fibrous substrate easily, and, owing to can effectively prevent to give the antigenicity reductionization composition disengaging on fibrous substrate and shift to cleaning object one side, so preferred.
[surfactant]
Used " surfactant " is in order can easily to give composition cleaning appliance and to make the composition homogenising and add among the present invention.Surfactant preferably uses non-ionic surface active agent.As above-mentioned non-ionic surface active agent, be not particularly limited, as polyoxyethylene alkyl ether, preferred polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene stearyl base ether etc.As sorbitan ester, preferred sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, dehydrated sorbitol mono-fatty acid ester etc.As fatty acid glyceride, preferred single myristic acid glyceride, glycerin monostearate, glyceryl monooleate, single glyceryl isostearate, glyceryl dioleate etc.As vegetable oil, preferred jojoba oil (jojoba oil), avocado oil (avocado oil), olive oil, apricot kernel oil, grape seed oil (grape seed oil), safflower oil (safflower oil), sunflower oil (sunflower oil) etc.As sorbitan trioleate (Sorbitan Trioleate), preferred sorbitan tristearate, sorbitan trioleate etc.As oxirane (EO) addition product of castor oil or rilanit special, preferred Crodaret, laurate Crodaret, single isostearic acid Crodaret etc.Above-mentioned surfactant can be used alone, but also also mix together more than 2 kinds.
[other compositions]
In the used antigenicity reductionization composition of the present invention, can its proterties be taken place in the scope of bigger change, cooperate and remove above-mentioned antigenicity reduction and change into various compositions branch, finish, the surfactant.
[cooperation of antigenicity reductionization composition]
Can mix with existing known method and stir above-mentioned each composition, obtain antigenicity reductionization composition.Antigenicity as above-mentioned essential 3 kinds of compositions reduces the cooperation ratio that changes into branch, finish, surfactant, with respect to antigenicity reductionization composition in its entirety, preferably contain the reduction of 0.01～10 quality % antigenicity and change into branch, 50～95 quality % finishes, 1～50 quality % surfactant.More preferably contain the reduction of 0.02～1 quality % antigenicity and change into branch, 60～80 quality % finishes, 20～40 quality % surfactants.
Change into branch less than 0.01 quality % if antigenicity reduces, then insufficient and not preferred to the antigenicity reduced rate of the dust that captures, if surpass 10 quality %, then the ageing stability of antigenicity reductionization composition is bad and expensive and not preferred.
If finish less than 50 quality %, then insufficient and not preferred by the effect of giving the raising dust class adsorbance that the finish composition obtains, if surpass 95 quality %, then the ageing stability of antigenicity reductionization composition is bad and not preferred.
If surfactant less than 1 quality % then causes the ageing stability of antigenicity reductionization composition bad and not preferred easily,, then, the finish amount that can add reduces, so not preferred because of reducing the adsorbance that causes the dust class if surpass 50 quality %.
[cleaning appliance]
Below, the cleaning appliance of having given above-mentioned antigenicity reductionization composition is described.Cleaning appliance so long as have the fibrous substrate that does not contain moisture in fact the indoor cleaning apparatus, be that so-called dry cleaning apparatus gets final product, be not particularly limited.For example, can also can also can as mop, constitute, also can form by bunch fiber (tow fiber, the aggregate of fiber) for laminar for the strip behind the cut-out thin slice by a large amount of shoestring.The kind of fibrous substrate is not particularly limited, and can be in natural fiber, synthetic fibers, the semisynthetic fibre any.In addition, fibre morphology can be in fabric, braid, the nonwoven any, is not particularly limited.
The example of＜cleaning appliance 〉
One of Fig. 1, the above-mentioned cleaning appliance of 2 expressions example.Fig. 1 is the side view of cleaning appliance, and Fig. 2 is the decomposition side view of the Clean-thin slice of Fig. 1.As shown in Figure 1, this cleaning appliance 10 is so-called handheld (handy type), is made of Clean-thin slice 11 that is equivalent to fibrous substrate of the present invention and holding tool (grasping tool) 12.Need to prove that holding tool 12 can suitably be changed, for example,, the cleaning appliance of Fig. 1 also can be used in eminence or stenosis that hand can't touch by holding tool 22 as shown in Figure 3 is installed.
As shown in Figure 2, Clean-thin slice 11 has begun by forming of being made up of nonwoven the support thin slice 1 of a large amount of strip sheets, the substrate sheet of being made up of nonwoven equally that has formed a large amount of strip sheets 2 from the top, the 1st fibre bundle 3a that is made up of bunch fiber, the 2nd fibre bundle 3b that is made up of bunch fiber, the 3rd fibre bundle 3c that is made up of bunch fiber, the 4th fibre bundle 3d that is made up of bunch fiber, the order of rectangle thin slice 5 that formed a plurality of strip sheets carry out stacked successively.Then, in this embodiment, the 1st fibre bundle 3a, the 2nd fibre bundle 3b, the 3rd fibre bundle 3c and the 4th fibre bundle 3d constitute brush of the present invention portion.Therefore, can more effectively clean by this brush portion.Because as long as give antigenicity reductionization composition, so can more effectively give antigenicity reductionization composition in this brush portion.Herein, " brush portion " is meant and mainly brings into play the part of cleaning function in cleaning appliance of the present invention, can be the part of fibrous substrate, also can be that they are whole.Each layer, only engages at joint line (bonding line) 7 places and supports thin slice 1, substrate sheet the 2, the 1st fibre bundle 3a and the 2nd fibre bundle 3b in conjunction with supporting thin slice 1, substrate sheet the 2, the 1st fibre bundle 3a, the 2nd fibre bundle 3b, the 3rd fibre bundle 3c, the 4th fibre bundle 3d and rectangle thin slice 5 at layer joint line (layer bonding line) 6 places.Thus, supporting to form support space 13 between thin slice 1 and the substrate sheet 2, holding tool 12 can be inserted and installs.In above-mentioned handheld cleaning appliance 10,20, give antigenicity reductionization composition to the brush portion that constitutes by the 1st fibre bundle 3a, the 2nd fibre bundle 3b, the 3rd fibre bundle 3c and the 4th fibre bundle 3d for preferred.
Other examples of＜cleaning appliance 〉
Among Fig. 4, as other examples of cleaning appliance, expression is preferred for cleaning ground template (floor type) cleaning appliance 30 of floor.As shown in Figure 4, Clean-thin slice 31 circumvolutions that will be equivalent to fibrous substrate of the present invention of this cleaning appliance 30 are used to the leading section 32a of grasping tool 32.Need to prove that the positive and negative of Clean-thin slice 31 all is formed with the protuberance 33 that is made of tow, be easy to clean the place that plane cleaning appliances such as ditch part are difficult to clean.Only need make these cleaning appliance 30 contact floors etc., can be by Clean-thin slice 31 trap dust etc.In the above-mentioned ground template cleaning appliance 30, preferably give antigenicity reductionization composition to Clean-thin slice 31 integral body.
The adding method of＜antigenicity reductionization composition 〉
As the method for antigenicity reductionization composition being given above-mentioned cleaning appliance, can enumerate with spray-on process, roller coat (roller coating) method, infusion process etc. and give antigenicity reductionization method for compositions, but be not limited thereto fibrous substrate.
The amount of giving of antigenicity reductionization composition in handheld cleaning appliance as shown in Figure 1, is 1～10 quality % with respect to fibrous substrate integral body preferably.If give quantity not sufficient 1 quality %, then can't remove Powdered dust fully and not preferred.If the amount of giving surpasses 10 quality %, then composition is shifted to the cleaning object in a large number, and sticks to the sense and not preferred of being clamminess being arranged on hand.
For ground template cleaning appliance as shown in Figure 4, preferably give the antigenicity reductionization composition of Duoing slightly than handheld, be 3～15 quality % with respect to fibrous substrate integral body, more preferably give 3～10 quality %.If the amount of giving is in above-mentioned scope, then at least a portion of antigenicity reductionization composition is shifted to cleaning object one side easily.Thus, can bring into play the antigenicity reductionization effect of above-mentioned cleaning appliance, simultaneously, move and remain in the antigenicity reductionization composition of cleaning object one side and also can bring into play antigenicity reductionization effect.Therefore, also can bring into play the antigenicity reductionization effect of cleaning object.In addition, the finish in the antigenicity reductionization composition is also shifted to the cleaning object at this moment, so can bring into play the effect of waxing to floor simultaneously.Therefore, this scheme optimization is used for the floor cleaning appliance of so-called ground template.If give quantity not sufficient 3 quality %, then cleaning appliance can't be removed Powdered dust fully, and in addition, antigenicity reductionization composition is insufficient and not preferred to dividing a word with a hyphen at the end of a line of cleaning object.In addition, if the amount of giving surpasses 15 quality %, then antigenicity reductionization composition is shifted to the cleaning object in a large number, and sticks to and feel on hand to be clamminess and not preferred.
Embodiment
Illustrate in greater detail the present invention with embodiment and comparative example below, but the present invention is not limited to following embodiment.
＜contain the preparation that antigenicity reduces the antigenicity reductionization agent change into branch 〉
(Fructus Canrii Albi extract)
Based on the composition embodiment 3 of patent documentation 1, water extracts the leaf of plant olive and (puts into the fresh leaf of 20g olive in 100g water, pulverize with agitator, and filter with filter paper, obtain filtrate), add ethanol then, be mixed with the liquid that contains 0.6% oleuropein.
(tannic acid)
Water and ethanol dissolving tannic acid (with the pure medicine system of light) are mixed with the liquid that contains 15% tannic acid.
＜antigenicity reductionization preparation of compositions 〉
Use the agent of above-mentioned 2 kinds of antigenicity reductionizations,, obtain the antigenicity reductionization composition of preparation example 1～4 according to the cooperation ratio shown in the table 1.
As finish, use be selected from atoleine, the safflower oil more than a kind.In addition, as surfactant, use be selected from polyoxyethylene alkyl ether, dehydrated sorbitol mono-fatty acid ester, single glyceryl isostearate, sorbitan trioleate, the Crodaret more than a kind, in addition, mixing water also stirs, preparation antigenicity reductionization composition.
Annotate 1) (tannic acid): water and ethanol dissolving tannic acid (with the pure medicine system of light) are mixed with the liquid that contains 15% tannic acid.
(Fructus Canrii Albi extract): extract the leaf of plant olive based on composition embodiment 3 waters of patent documentation 1, add ethanol then, preparation contains the liquid of 0.6% oleuropein.
Notes 2) the EO addition molal quantity of polyoxyethylene alkyl ether is 5 moles, and the carbon number in the alkyl structure is 12～14.
Annotate 3) viscosity under 30 ℃ is 50mm
2/ s.
Notes 4) the EO addition molal quantity of Crodaret is 60 moles.
Notes 5) the EO addition molal quantity of polyoxyethylene alkyl ether is 3 moles, and the carbon number in the alkyl structure is 12～14.
＜give cleaning appliance with antigenicity reductionization composition 〉
Give cleaning appliance shown in Figure 1 (below be called handheld) and cleaning appliance shown in Figure 4 (below be called the ground template) by splash with the composition of the antigenicity reductionization composition of above-mentioned preparation example 1～3 and preparation example 4 then, at all kinds, obtain the cleaning appliance of embodiment 1～3 (having given the cleaning appliance of the composition gained of preparation example 1～3) and comparative example 1 (having given the cleaning appliance of the composition gained of preparation example 4) respectively.
Need to prove that in handheld, the amount of giving of antigenicity reductionization composition is 5 quality % with respect to fibrous substrate (thin slice 11 among Fig. 1) integral body.In addition, in the ground template, the amount of giving of antigenicity reductionization composition is 7.5 quality % with respect to fibrous substrate (thin slice 31 among Fig. 4) integral body.
＜test example 〉
[test example 1: antigenicity reduces the evaluation of voltinism energy]
To the cleaning appliance of embodiment 1,2,3 and comparative example 1, carry out evaluation in the following order to the antigenicity reductionization of cdear pollen and dirt mite (dust mites) genus.Sum up its result in table 2,3.Need to prove, " reduced rate " in the table is according to the value that 100-100 * (having given the amount of allergen that the cleaning appliance of antigenicity reductionization agent is obtained according to the ELISA method)/(not giving the amount of allergen that the cleaning appliance of antigenicity reductionization agent is tried to achieve according to the ELISA method) tries to achieve, the following reduced rate of the symbolic representation in the table.
Zero ... good reduced rate is more than 50%
△ ... difference reduced rate 10～50%
* ... bad reduced rate 0～10%
Handheld: about 0.05g is contained the rubbish of mite allergen (Dermatophagoides) and the vial that about 0.01g cdear pollen is put into the high 17cm of diameter 9cm respectively, and cover lid makes rubbish and cdear pollen be dispersed to whole bottle inwall.Uncap is wiped bottle interior rubbish and cdear pollen with handheld cleaning appliance.From this cleaning appliance, extract anaphylactogen with extract, measure anaphylactogen with ELISA standard measure ground.
Ground template: will about 0.05g contain on the rubbish of mite allergen (Dermatophagoides) and the floor panel (floor panel) that about 0.01g cdear pollen is scattered in 30 * 30cm respectively.Land used template cleaning appliance is wiped this rubbish and cdear pollen.From this cleaning appliance, extract anaphylactogen with extract, measure anaphylactogen with ELISA standard measure ground.
Need to prove,, use phosphate buffer (pH7) as extract.In addition, the ELISA method (enzyme-linked immunosorbent assay: enzyme-linked immunosorbent assay) be the colour developing that in antigen-antibody reaction, utilizes enzyme to material carry out quantitative methods (EIA method (enzyme immunoassay): enzyme immunoassay) a kind of, utilize and clamp material to be checked with 2 kinds of antibody and carry out quantitative sandwich (sandwich) method.
[table 2] cdear pollen-antigen reduced rate
[table 3] mite antigenicity reduced rate
By table 2,3 results verification ground template cleaning appliance use any antigenicity reductionization composition that the reductionization effect is all arranged.Need to prove that the handheld cleaning appliance of embodiment 1 is few because of antigenicity reduces the amount of giving that changes into branch, effect is inadequate slightly.
[test example 2: heating, the postradiation reduction Evaluation on effect of light]
Heat run: at handheld cleaning appliance, only the fibrous substrate with the cleaning appliance of embodiment 2,3 is positioned in the paper container and packing, at ground template cleaning appliance, only the fibrous substrate of the cleaning appliance of embodiment 2,3 is carried out the pillow type with film and packs.This package body is positioned over indoor shady place respectively, places 40 ℃ of thermostats, 50 ℃ of thermostats.Then, just placing the back, measuring anaphylactogen after through 1 month according to the method identical with above-mentioned test example 1.
Test is penetrated in illumination: handheld, the fibrous substrate of template cleaning appliance all do not pack, directly place with the thin slice state.With xenon arc type climatic test chamber (xenon lamp weather meter) irradiation, be equivalent to shine sunshine 1 month, be equivalent to shine sunshine 6 months, measure anaphylactogen according to the method identical with above-mentioned test example 1.
The result is as shown in table 4.Reduced rate in the table and symbolic representation and table 2,3 identical implications.Can determine that any cleaning appliance among the embodiment 2,3 is placed and all keep the reductionization effect after 1 month under heating condition, in addition, after illumination is penetrated, also all keep the reductionization effect.
[table 4] mite antigenicity reduced rate
About the preferred embodiments of the present invention; describe in detail with accompanying drawing; but the present invention is not limited to the embodiment of above-mentioned strictness, and be construed as those skilled in the art do not depart from claim can carry out various changes or improvement in clear and definite protection scope of the present invention.
Claims (9)
1, a kind of cleaning appliance, described cleaning appliance is the clean wiping apparatus that is used for indoor cleaning with dry type fibrous substrate, wherein, described dry type fibrous substrate is the stacked support thin slice of being made up of nonwoven that has formed a large amount of strip sheets, the substrate sheet of forming by nonwoven that has formed a large amount of strip sheets, the fibre bundle of forming by bunch fiber, the rectangle thin slice that has formed a plurality of strip sheets constitutes, on described fibrous substrate, give antigenicity reductionization composition, described antigenicity reductionization composition contains the antigenic antigenicity reduction that reduces the material that causes allergic reaction and changes into branch, finish and surfactant, it is the plant extract composition that described antigenicity reduction changes into branch.
2, cleaning appliance as claimed in claim 1, wherein, it is water-soluble or hydrophilic component that described antigenicity reduction changes into branch.
3, cleaning appliance as claimed in claim 1 or 2, wherein, described antigenicity reduces and changes into that branchs be made up of the extract of the plant gained of water or organic solvent extraction Olea or Ligustrum.
4, cleaning appliance as claimed in claim 1 or 2, wherein, described antigenicity reduction changes into and is divided into oleuropein.
5, cleaning appliance as claimed in claim 1 or 2, wherein, described glass or plastic containers.
6, cleaning appliance as claimed in claim 1 or 2, wherein, described finish is the binding dust finish, is that the viscosity under 30 ℃ is 10～200mm
2The mineral oil of/s.
7, cleaning appliance as claimed in claim 1 or 2 wherein, with respect to described antigenicity reductionization composition in its entirety, contains the described antigenicity reduction of 0.01～10 quality % and changes into branch, the described finish of 50～95 quality %, the described surfactant of 1～50 quality %.
8, cleaning appliance as claimed in claim 7, wherein, the amount of giving of described antigenicity reductionization composition is 1～15 quality % with respect to the fibrous substrate integral body of having given described antigenicity reductionization composition.
9, cleaning appliance as claimed in claim 7, wherein, the amount of giving of described antigenicity reductionization composition is 3～15 quality % with respect to the fibrous substrate integral body of having given described antigenicity reductionization composition.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP262896/2004 | 2004-09-09 | ||
| JP2004262896 | 2004-09-09 | ||
| JP341804/2004 | 2004-11-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101010024A CN101010024A (en) | 2007-08-01 |
| CN100577082C true CN100577082C (en) | 2010-01-06 |
Family
ID=38698017
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200580029805A Expired - Fee Related CN100577082C (en) | 2004-09-09 | 2005-08-10 | Cleaning implement |
| CN200580029970.3A Expired - Fee Related CN101014695B (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
| CN200580029969.0A Expired - Fee Related CN101014694B (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200580029970.3A Expired - Fee Related CN101014695B (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
| CN200580029969.0A Expired - Fee Related CN101014694B (en) | 2004-09-09 | 2005-09-08 | Cleaning implement |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN100577082C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105464415A (en) * | 2015-11-18 | 2016-04-06 | 宁波市鄞州银鑫铝业有限公司 | Swimming pool cleaning tool of picking rod |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6777064B1 (en) * | 1997-05-23 | 2004-08-17 | The Procter & Gamble Company | Cleaning sheets, implements, and articles useful for removing allergens from surfaces and methods of promoting the sale thereof |
| JP4766639B2 (en) * | 2001-08-07 | 2011-09-07 | 住化エンビロサイエンス株式会社 | Anti-allergen composition and allergen inactivation method |
| US20040007251A1 (en) * | 2002-07-10 | 2004-01-15 | Kimberly-Clark Worldwide, Inc. | Cleaners for the control and removal of allergens |
-
2005
- 2005-08-10 CN CN200580029805A patent/CN100577082C/en not_active Expired - Fee Related
- 2005-09-08 CN CN200580029970.3A patent/CN101014695B/en not_active Expired - Fee Related
- 2005-09-08 CN CN200580029969.0A patent/CN101014694B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101014695B (en) | 2012-09-12 |
| CN101010024A (en) | 2007-08-01 |
| CN101014695A (en) | 2007-08-08 |
| CN101014694B (en) | 2012-09-12 |
| CN101014694A (en) | 2007-08-08 |
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