JP5281065B2 - Cleaning tool - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cleaning tool reducing antigenicity of an allergy causing substance attached to the cleaning tool. <P>SOLUTION: The cleaning tool is for indoor cleaning and has a dry fibrous base material. The fibrous base material is added with an antigenicity reducing composition containing an antigenicity reducing component for reducing antigenicity of an allergy causing substance, oil solution, and a surfactant. The antigenicity reducing component is tannic acid. <P>COPYRIGHT: (C)2011,JPO&amp;INPIT

Description

  The present invention relates to an indoor cleaning tool having a fibrous base material, and more particularly to a cleaning tool that can reduce the antigenicity of substances that cause allergies.

  In recent years, the number of people with allergic diseases such as allergic rhinitis and bronchial asthma has been increasing. Substances that cause these allergic diseases are so-called allergens, and there are about 200 kinds of allergens that are currently identified. Tick, mite carcass, pet hair, pollen and the like are typical examples, and various allergic symptoms are induced when these allergens contact or enter the human body in some form.

  In this case, even if ticks that cause allergies are killed by a drug or the like, the dead insects also have antigenicity, and thus do not lead to a fundamental solution of allergic diseases. Therefore, in order to reduce symptoms of allergic diseases or prevent new sensitization, allergens are completely removed from the living space or allergens are denatured to reduce (inactivate) the antigenicity of substances that cause allergies. It will be necessary.

  As an agent for reducing the antigenicity of a substance that causes allergies, for example, an allergen inactivating agent comprising at least one plant selected from the genus Oleaceae or Genus genus is disclosed (see Patent Document 1).

Moreover, an allergen reducing agent comprising an aqueous solution containing aluminum sulfate and sodium sulfate as active ingredients is disclosed as an agent that can be sprayed or applied to tatami mats, carpets, floors, etc. in the form of an aqueous solution (see Patent Document 2). ).
JP 2003-55122 A JP 2003-334240 A

  In cleaning tools such as dust cloths, mops, and wipers used for the purpose of removing dust and dirt in the room, the allergen is attached to the cleaning tool by cleaning, and is kept in this state for a long time. . For this reason, as described above, in order to reduce the symptoms of allergic diseases or prevent the development of new allergic diseases, it is necessary to reduce the antigenicity of the allergen retained in the cleaning tool.

  However, all of the agents disclosed in Patent Documents 1 and 2 are used by directly spraying or applying to the places where there is a possibility of touching the human body, such as tatami mats, carpets, floors, and clothes. These need to be wiped off after application or vacuumed, which is cumbersome. However, methods for easily removing allergenic substances have not been studied with regard to cleaning of dust and dust on floors and furniture that are cleaned most frequently every day. In addition, since the conventional method wets an object, it takes time to dry, and no dry type cleaning method capable of reducing substances that cause allergies has been proposed. In addition, no studies have been made to reduce the antigenicity of substances that cause allergies contained in dust / dust collected in dry-type cleaning tools such as mops.

  In particular, in the case of indoor cleaning tools, disposable and replaceable, having a sheet-like or brush-like fibrous base material, and a dry type that does not substantially contain moisture is popular in the market. Expo. In the case of such a dry-type cleaning tool, as the antigenicity-reducing composition to be applied, the composition is excellent in adhesion or impregnation to the fibrous base material, and in use, is transferred to an object. Is required to be low.

  In this regard, Patent Document 1 does not investigate a composition that takes into account the above-described adhesion and impregnation properties. Further, the allergen reducing agent of Patent Document 2 is used in a so-called wet state in the form of an aqueous solution, and is difficult to apply to a dry-type cleaning tool that does not substantially contain moisture.

  This invention is made | formed in view of the above subjects, and it aims at providing the cleaning tool which can reduce the antigenicity of the substance which causes the allergy adhering to the cleaning tool.

  As a result of intensive research to solve the above problems, the present inventors have given the antigenicity-reducing component to a cleaning tool as a specific composition containing an oil agent and a surfactant. As a result, the present invention has been completed. More specifically, the present invention provides the following.

  (1) An indoor cleaning wipe having a dry type fibrous base material, wherein the fibrous base material includes an antigenicity-reducing component that reduces the antigenicity of a substance that causes allergies, and an oil agent. And a surfactant, and a cleaning tool, wherein the antigenicity-reducing component is tannic acid.

  According to the cleaning tool of the present invention, since the antigenicity-reducing composition containing the antigenicity-reducing component, the oil agent, and the surfactant is used, this composition is used as a dry type fibrous substrate. It can be easily given. Moreover, the effect of antigenicity reduction can be maintained in the state stabilized for a long time by providing in such a composition state. Moreover, when there is little composition provision amount, the transfer of the composition from the fibrous base material side to the cleaning object side can be prevented during use. Tannic acid is considered to reduce antigenicity by binding the hydroxyl group of polyphenol to the amino group or peptide part of allergen protein. Tannic acid is inexpensive and easily available. Furthermore, since it is derived from a plant, safety to the human body is high.

  In the present invention, the “dry type” means that the oil is more in the weight ratio of the oil agent and the water contained in the antigenicity-reducing composition to be given to the cleaning tool, and the amount of water is 5. 0% or less is appropriate. It is necessary that water is solubilized in the oil agent, and when the oil agent is emulsified, the dust collecting power is reduced, which is not preferable.

  (2) The cleaning tool according to (1), wherein the surfactant is a nonionic surfactant.

  According to this aspect, the antigenicity-reducing component and the oil agent can be stably mixed.

  (3) The oil agent is a cleaning tool according to (1) or (2), which is a dust oil agent, and (4) the oil agent is mineral oil according to any one of (1) to (3) Cleaning tool.

  According to this aspect, by using a dusting oil material or mineral oil as the oil agent, the antigenicity-reducing composition can be easily attached to the fibrous base material, and the antigen once applied to the fibrous base material. It is possible to effectively prevent the property reducing composition from desorbing and shifting to the cleaning target side. Further, the dust collecting power is increased, and re-dropping can be prevented.

(5) The cleaning tool according to (4), wherein the mineral oil has a viscosity at 30 ° C. of 10 to 200 mm ² / s.

The viscosity of the mineral oil at 30 ° C. is preferably 10 to ²⁰⁰ mm ² / s. More preferably, it is 15-120 mm < ² > / s. When the viscosity is less than 10 mm ² / s, it may move to the surface to be cleaned in large quantities or may adhere to the hand and feel sticky. When it exceeds 200 mm ² / s, the adsorptivity of dust becomes poor.

  (6) 0.01 to 10% by mass of the antigenicity reducing component, 50 to 95% by mass of the oil agent, and 1 to 50% by mass of the surfactant with respect to the whole antigenicity reducing composition. The cleaning tool as described in (1) to (5).

  According to this aspect, by setting the blending ratio in the above range, dust is collected by the fibrous base material itself and the dusting force of the oil agent. Furthermore, the antigenicity of the substance causing the allergy contained in the collected material can be reduced by the antigenicity-reducing composition.

  (7) The cleaning according to (6), wherein the antigenicity-reducing composition is applied so as to be 1 to 15% by mass with respect to the entire fibrous base material to which the antigenicity-reducing composition is applied. Tools.

  According to this aspect, a sufficient antigenicity reducing effect can be obtained by applying the antigenicity-reducing composition to the entire fibrous base material in an amount of 1% by mass or more. In addition, since the addition ratio of the antigenicity-reducing component in this case is 0.01 to 10% by mass, the effect can be sufficiently exerted by applying a very small amount of the antigenicity-reducing component.

  On the other hand, by applying the antigenicity-reducing composition to the entire fibrous base material in an amount of 15% by mass or less, transfer of the antigenicity-reducing composition to the object to be cleaned due to the adhesion of the excess antigenicity-reducing composition. Can be prevented.

  ADVANTAGE OF THE INVENTION According to this invention, the cleaning tool which reduces the antigenicity of the substance which causes the allergy adhering to the cleaning tool can be provided.

<Antigenicity-reducing composition>
The antigenicity-reducing composition applied to the cleaning tool of the present invention comprises (a) an antigenicity-reducing component that reduces the antigenicity of a substance that causes allergies, (b) an oil agent, and (c) a surfactant. And. Hereinafter, each component will be described.

[Antigenicity-reducing component]
The “antigenicity-reducing component” used in the present invention is a plant-derived component that suppresses allergic symptoms by reducing the antigenicity of a substance that causes allergy. Here, allergen-causing substances (allergens) include, for example, inhalable allergens such as mites, house dust, animals, fungi (molds), insects, cedar, grass pollen and the like.

  In the present invention, tannic acid is used as the antigenicity-reducing component. As such tannic acid, tannic acid described in JP-B-2-16731 can be used. Tannic acid is considered to reduce antigenicity by binding the hydroxyl group of polyphenol to the amino group or peptide part of allergen protein.

  The antigenicity-reducing component may be blended as a single component in the antigenicity-reducing composition, and in a state of a solution containing the active ingredient and its extract (hereinafter referred to as an antigenicity-reducing agent). You may mix | blend.

[Oil agent]
The “oil agent” used in the present invention is added in order to enhance the ability to adsorb dust and dust. Although it does not specifically limit as such an oil agent, It is preferable to contain at least 1 sort (s) or more among mineral oil, synthetic oil, silicone oil, and vegetable oil. Examples of mineral oils include paraffinic hydrocarbons, naphthenic hydrocarbons, and aromatic hydrocarbons. These oil agents may be used alone or in combination of two or more.

  In particular, when the main component of the oil agent is liquid paraffin, the antigenicity-reducing composition is easily attached to the fibrous base material, and the antigenicity-reducing composition once applied to the fibrous base material It is preferable because it can be effectively prevented from detaching and moving to the cleaning target side.

[Surfactant]
The “surfactant” used in the present invention is added to facilitate application to a cleaning tool and to homogenize the composition. As the type of surfactant, it is preferable to use a nonionic surfactant. Such a nonionic activator is not particularly limited, but polyoxyethylene alkyl ether is preferably polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene stearyl ether or the like. As the sorbitan ester, sorbitan lauric acid monoester, sorbitan palmitic acid monoester, sorbitan stearic acid monoester, sorbitan oleic acid monoester and the like are preferable. As the glycerin fatty acid ester, glyceryl monomyristate, glyceryl monostearate, glyceryl monooleate, glyceryl monoisostearate, glyceryl dioleate and the like are preferable. Preferred vegetable oils are jojoba oil, avocado oil, olive oil, apricot oil, grape seed oil, safflower oil, sunflower oil and the like. As sorbitan trioleate, sorbitan stearic acid triester, sorbitan oleic acid triester and the like are preferable. As an EO adduct of castor oil or hydrogenated castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil laurate, polyisoethylene hydrogenated castor oil monoisostearate and the like are preferable. These surfactants may be used alone or in combination of two or more.

[Other ingredients]
In the antigenicity-reducing composition used in the present invention, various components other than the above-mentioned plant-derived antigenicity-reducing components, oils, and surfactants are blended within a range that does not greatly change the properties thereof. Also good.

[Formulation of antigenicity-reducing composition]
Each of the above components can be mixed and stirred by a conventionally known method to obtain an antigenicity-reducing composition. Here, as a blending ratio of the antigenicity-reducing component, the oil agent, and the surfactant, which are the essential three components, the antigenicity-reducing component is 0.01 to 10% by mass with respect to the whole antigenicity-reducing composition. The oil agent is preferably contained in an amount of 50 to 95% by mass and the surfactant in an amount of 1 to 50% by mass. More preferably, the antigenicity-reducing component is 0.02-1% by mass, the oil agent is 60-80% by mass, and the surfactant is 20-40% by mass.

  If the antigenicity-reducing component is less than 0.01% by mass, the antigenicity-reducing rate for the collected dust cannot be said to be sufficient, and if it exceeds 10% by mass, the antigenicity-reducing composition may be reduced. It is not preferable because the day stability becomes poor and the cost becomes high.

  If the amount of oil is less than 50% by mass, improvement in the amount of adsorbed dust due to the addition of the oil component is not preferable, and if it exceeds 95% by mass, the stability over time in the antigenicity-reduced composition is poor. It is not preferable.

  If the surfactant is less than 1% by mass, the stability over time of the antigenicity-reducing composition tends to be poor, which is not preferable. If it exceeds 50% by mass, the amount of oil that can be added decreases, so that the adsorption of dusts Since the amount is reduced, it is not preferable.

<Cleaning tools>
Next, the cleaning tool to which the above antigenicity-reducing composition is applied will be described. The cleaning tool is not particularly limited as long as it is an indoor cleaning tool having a fibrous base material that does not substantially contain moisture, that is, a so-called dry type cleaning tool. For example, it may be a sheet shape, a strip shape obtained by cutting a sheet, may be composed of a number of string-like bodies like a mop, and is formed of tow fibers (aggregates of fibers). It may be. The kind of fibrous base material is not particularly limited, and any of natural fiber, synthetic fiber, and semi-synthetic fiber may be used. The fiber form may be any of a woven fabric, a knitted fabric, and a non-woven fabric, and is not particularly limited.

<Examples of cleaning tools>
An example of such a cleaning tool is shown in FIGS. 1 is a perspective view of the cleaning tool, and FIG. 2 is an exploded perspective view of the cleaning sheet in FIG. As shown in FIG. 1, the cleaning tool 10 is a so-called handy type, and includes a cleaning sheet 11 corresponding to a fibrous base material in the present invention and a gripping tool 12. Note that the gripping tool 12 can be replaced as appropriate. For example, the gripping tool 22 shown in FIG. 3 can be used so that the cleaning tool of FIG. it can.

  As shown in FIG. 2, the cleaning sheet 11 is, in order from the top, a holding sheet 1 made of a nonwoven fabric and formed with a large number of strips, and a substrate sheet 2 formed of a nonwoven fabric and formed with a large number of strips, A first fiber bundle 3a made of tow fibers, a second fiber bundle 3b made of tow fibers, a third fiber bundle 3c made of tow fibers, a fourth fiber bundle 3d made of tow fibers, and a plurality of strips are formed The strip sheets 5 are stacked in this order. And in this embodiment, the 1st fiber bundle 3a, the 2nd fiber bundle 3b, the 3rd fiber bundle 3c, and the 4th fiber bundle 3d comprise the brush part in this invention. Therefore, cleaning can be performed more effectively by the brush portion. And since an antigenicity-reduced composition should just be provided only to this brush part, an antigenicity-reduced composition can be provided more effectively. Here, the “brush portion” is a portion that mainly exhibits the cleaning function in the cleaning tool according to the present invention, and may be a part or all of the fibrous base material. In each layer, the holding sheet 1, the base sheet 2, the first fiber bundle 3 a, the second fiber bundle 3 b, the third fiber bundle 3 c, the fourth fiber bundle 3 d, and the strip sheet 5 are joined at the all-layer joining line 6. Thus, only the holding sheet 1, the base sheet 2, the first fiber bundle 3 a, and the second fiber bundle 3 b are joined at the joining line 7. Thereby, the holding space 13 is formed between the holding sheet 1 and the base sheet 2, and the gripping tool 12 can be inserted and mounted. In such a handy-type cleaning tool 10, 20, only the brush portion composed of the first fiber bundle 3a, the second fiber bundle 3b, the third fiber bundle 3c, and the fourth fiber bundle 3d is used. It is preferable to apply an antigenicity-reducing composition.

<Other examples of cleaning tools>
FIG. 4 shows a floor-type cleaning tool 30 suitable for cleaning the floor as another example of the cleaning tool. As shown in FIG. 4, in this cleaning tool 30, a cleaning sheet 31 corresponding to the fibrous base material in the present invention is wound around a distal end portion 32 a of a gripping tool 32 and used. In addition, the convex part 33 which consists of tows is formed in the front and back of the sheet | seat 31 for cleaning, and it becomes easy to clean the location which is hard to clean with planar things, such as a groove part. The dust can be collected by the cleaning sheet 31 only by touching the floor surface with the cleaning tool 30. In such a floor-type cleaning tool 30, it is preferable to apply the antigenicity-reducing composition to the entire cleaning sheet 31.

<Method for Applying Antigenicity-Reducing Composition>
Examples of the method of applying the antigenicity-reducing composition to the cleaning tool include a method of applying the antigenicity-reducing composition to the fibrous base material by a spraying method, a roller coating method, a dipping method, or the like. It is not limited.

  In the handy type cleaning tool as shown in FIG. 1, the application amount of the antigenicity-reducing composition is preferably 1 to 10% by mass with respect to the entire fibrous base material. If it is 1% by mass or less, powdery dust cannot be removed, and if it is 10% by mass or more, it may move to the object to be cleaned in a large amount or may stick to the hand and feel sticky. On the other hand, in the floor-type cleaning tool as shown in FIG. 4, it is preferable to apply 3 to 15% by mass with respect to the entire fibrous base material, slightly more than the handy type. If it is 3% by mass or less, powdered dust cannot be removed, and if it is 15% by mass or more, it may move to the object to be cleaned or may adhere to the hand and feel sticky.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail using an Example and a comparative example, this invention is not limited to a following example.

<Production of antigenicity reducing agent containing antigenicity reducing component>
(Tannic acid)
This is a liquid prepared by dissolving tannic acid (manufactured by Wako Pure Chemical Industries, Ltd.) in water and ethanol so as to be 15% tannic acid.

<Production of antigenicity-reducing composition>
Using the antigenicity-reducing agent containing tannic acid as the antigenicity-reducing component, the antigenicity-reducing compositions of Production Examples 1 to 3 were obtained at the blending ratios shown in Table 1.

  As the oil, at least one selected from liquid paraffin and safflower oil was used. Further, as the surfactant, at least one selected from polyoxyethylene alkyl ether, sorbitan oleic acid monoester, glyceryl monoisostearate, sorbitan oleic acid triester, polyoxyethylene hydrogenated castor oil is used, and water is also used. Mixing and stirring were performed to prepare an antigenicity-reducing composition.

Note 1) (Tannic acid): A solution prepared by dissolving tannic acid (manufactured by Wako Pure Chemical Industries, Ltd.) in water and ethanol to a concentration of 15% tannic acid.
Note 2) The polyoxyethylene alkyl ether has 5 moles of EO addition and 12 to 14 carbon atoms in the alkyl group.
Note 3) Viscosity at 30 ° C. is 50 mm ² / s.
Note 4) The number of moles of EO added to polyoxyethylene hydrogenated castor oil is 60 moles.
Note 5) The polyoxyethylene alkyl ether has 3 moles of EO addition and 12 to 14 carbon atoms in the alkyl group.

<Granting Antigenicity-Reducing Composition to Cleaning Tool>
Next, the antigenicity-reducing composition of Production Examples 1 and 2 and the composition of Production Example 3 were combined with a cleaning tool as shown in FIG. 1 (hereinafter referred to as a handy type) and as shown in FIG. It is applied to a cleaning tool (hereinafter referred to as a floor type) by spraying, and for each type of Examples 1 and 2 (Production Examples 1 and 2 provided) and Comparative Example 1 (Production Example 3 provided). A cleaning tool was obtained.

  In addition, in the handy type, it provided so that it might become 5 mass% with respect to the whole fibrous base material (sheet | seat 11 in FIG. 1). Moreover, in the floor type, the antigenicity-reducing composition was applied so as to be 7.5% by mass with respect to the entire fibrous base material (sheet 31 in FIG. 4).

<Test example>
[Test Example 1: Evaluation of antigenicity reduction performance]
About the cleaning tool of Example 1, 3 and the comparative example 1, the antigenicity reduction with respect to a cedar pollen and leopard mites was evaluated in the following procedures. The results are summarized in Tables 2 and 3. The “reduction rate” in the table is 100-100 × (amount of allergen by ELISA of the cleaning tool provided with the antigenicity reducing agent) / (amount of allergen by ELISA of the cleaning tool not provided with the antigenicity reducing agent) ), And the symbols in the table indicate the following reduction rate.
○ ・ ・ ・ Good Reduction rate 50% or more Δ ・ ・ ・ Inferior Reduction rate 10-50%
× ・ ・ ・ Defect reduction rate 0 to 10%

  Handy type: About 0.05 g of mite allergen (leopard mite) and about 0.01 g of cedar pollen are placed in a glass bottle with a diameter of 9 cm and a height of 17 cm. Pollen was dispersed. The lid was removed, and the trash and cedar pollen in the bottle were wiped off with a handy type cleaning tool. The allergen was extracted from the cleaning tool with an extract, and the allergen was quantitatively measured by ELISA.

  Floor type: Garbage containing about 0.05 g mite allergen (Leopard mite) and about 0.01 g of cedar pollen were each dispersed on a 30 × 30 cm floor panel. The garbage and cedar pollen were wiped off with a floor-type cleaning tool. The allergen was extracted from the cleaning tool with an extract, and the allergen was quantitatively measured by ELISA.

  A phosphate buffer solution (pH 7) was used as the extract. The ELISA method (enzyme-linked immunosorbent assay) is a method of quantifying a substance using enzyme color development in an antigen-antibody reaction (EIA method (enzyme immunoassay)). This is a sandwich method in which a substance to be detected is sandwiched between two types of antibodies and quantified.

  From the results of Tables 2 and 3, the floor type cleaning tool was confirmed to have a reducing effect in any antigenicity reducing composition. In addition, in the handy-type cleaning tool of Example 1, the application amount of the antigenicity-reducing component was small, and the effect was slightly insufficient.

[Test Example 2: Evaluation of reduction effect after heating and light irradiation]
Heating test: Only the fibrous base material of the cleaning tool of Example 2 was packaged with the handy cleaning tool housed in a paper container, and the floor type cleaning tool was pillow-wrapped with a film. This package was left in the indoor shade, 40 ° C. thermostat, and 50 ° C. thermostat. And allergen was measured by the method similar to said test example 1 immediately after leaving and after one month progress.
Light irradiation test: Handy type and floor type cleaning tools fibrous base materials were not packaged and left as they were. Allergens were measured by the same method as in Test Example 1 by irradiating sunlight equivalent to 1 month and equivalent to 6 months with a xenon lamp weather meter.

  The results are shown in Table 4. The reduction ratios and symbols in the table have the same meaning as in Tables 2 and 3. It was confirmed that the cleaning tool of Example 2 maintained the reduction effect even after being heated for one month, and also maintained the reduction effect after light irradiation.

  The present invention can be suitably used as an indoor cleaning tool having a fibrous base material.

It is a perspective view which shows an example of the cleaning tool of this invention. It is a disassembled perspective view of the fibrous base material in FIG. It is a perspective view which shows the other example of the cleaning tool of this invention. It is a perspective view which shows the further another example of the cleaning tool of this invention.

DESCRIPTION OF SYMBOLS 1 Holding sheet 2 Base material sheet 3 Fiber bundle (brush part)
3a 1st fiber bundle 3b 2nd fiber bundle 3c 3rd fiber bundle 3d 4th fiber bundle 5 Strip sheet 6 Full-layer joining line 7 Joining line 10, 20, 30 Cleaning tool 11, 31 Cleaning sheet (fiber Substrate)
12, 22, 32 Gripping tool 13 Holding space 32a Tip portion 33 Convex portion

Claims (7)

A base sheet;
A holding sheet that forms a holding space capable of holding the gripping tool by inserting the gripping tool between the base material sheet, and
With fiber bundles,
The holding sheet, the base sheet, the fiber bundle, is of laminated in this order,
Only the fiber bundle is attached with an antigenicity-reducing composition that reduces the antigenicity of substances that cause allergies,
Cleaning tool.   The cleaning tool according to claim 1, wherein the antigenicity-reducing composition comprises an antigenicity-reducing component, an oil agent, and a surfactant.   The cleaning tool according to claim 1 or 2, wherein a strip sheet is laminated on a side of the fiber bundle opposite to the base sheet.   The cleaning tool according to any one of claims 1 to 3, wherein the fiber bundle is a toe fiber.   The cleaning tool according to any one of claims 1 to 4, wherein the main component of the oil agent is paraffin.   The cleaning tool according to any one of claims 1 to 5, wherein the antigenicity-reducing composition further contains water. In the weight ratio of the oil and water contained in the antigenicity-reducing composition,
The cleaning tool according to any one of claims 1 to 6, wherein the moisture content is 5.0% or less, and the moisture is solubilized in the oil agent.

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