CN100575605C - Process for manufacturing aluminum foil pseudo metal texture transition paper - Google Patents

Process for manufacturing aluminum foil pseudo metal texture transition paper Download PDF

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Publication number
CN100575605C
CN100575605C CN200710132937A CN200710132937A CN100575605C CN 100575605 C CN100575605 C CN 100575605C CN 200710132937 A CN200710132937 A CN 200710132937A CN 200710132937 A CN200710132937 A CN 200710132937A CN 100575605 C CN100575605 C CN 100575605C
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film
paper
aluminum foil
coated
mold pressing
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CN101135128A (en
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魏立勤
徐正琴
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JIANGSU JINHENG NEW STYLE PACKAGE MATERIAL CO Ltd
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JIANGSU JINHENG NEW STYLE PACKAGE MATERIAL CO Ltd
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Abstract

The present invention relates to a kind of production technology of tobacco and wine wrapping paper, be a kind of process for manufacturing aluminum foil pseudo metal texture transition paper, may further comprise the steps: coating: on arbitrary of bidirectional stretching polypropylene film, biaxially oriented polyester film or heat sealing type biaxial-tension polypropylene film, singly be coated with or two transfer coatings that is coated with; Mold pressing: make special mold pressing roll film is carried out mold pressing; Aluminize: on film, carry out vacuum aluminum-coated; Compound: with film and 30~250g/m 2It is compound that paper use glue carries out wet method; Slaking: is 35~55 ℃ with film in temperature, and humidity is to put in 30~60% the environment to carry out slaking in 24~48 hours; Stripping: film is peeled off.Aluminum foil pseudo metal texture transfer paper through explained hereafter of the present invention has strong metal-like, and is very approximate in appearance with aluminum foil composite paper, better than common metallization transfer paper visual effect, but environmental protection natural degradation again simultaneously.

Description

Process for manufacturing aluminum foil pseudo metal texture transition paper
Technical field
The present invention relates to a kind of production technology of tobacco and wine wrapping paper, a kind of specifically process for manufacturing aluminum foil pseudo metal texture transition paper.
Background technology
The packing of the existing tobacco and wine and the cosmetics of super quality, gift is in order to reach effect noble attractive in appearance, and what adopt usually is that aluminium foil or metalized film (being commonly called as aluminizer) are packed with the composite that paper is composited.Along with the attention of western countries to environmental protection; the difficulty or ease that reclaim according to packaging material of German Duale System Deutschland (DSD) in 1994 and the degree of environmental pollution; and the principle of packaging material saving earth resource degree, non-environment-friendly type packaging material are implemented heavy taxation.And China is also more and more paying attention to the saving of environmental protection and resource in recent years, as the 20th regulation of the Law of the People's Republic of China on Promoting Clean Production: the design of product and packing material, should consider its influence in life cycle to human health and environment, preferentially select nontoxic, harmless, be easy to the scheme of degrading or being convenient to recycle.Enterprise should carry out reasonable packing to product, reduces excessively using and the generation of packing property refuse of packaging material.
The production technology of existing tobacco and wine class packing composite aluminium foil paper, aluminizer composite sheet and the transfer paper of aluminizing is as follows respectively:
The production technology of composite aluminium foil paper is: with pure aluminum foil and the 30~250g/m of 0.006~0.007mm 2Paper to carry out wet type compound, aluminium foil and paper are fit together, form composite aluminium foil paper.The composite aluminium foil paper production process is simple, the technology requirement is low, and product specification is lower, and is difficult for natural degradation, not environmental protection.
The production technology of aluminizer composite sheet is: with bidirectional stretching polypropylene film (being called for short BOPP) or the biaxially oriented polyester film (being called for short BOPET) and 100~250g/m of 12~25 μ m 2It is compound that paper carries out wet type, and aluminizer and paper are fit together, and forms the aluminizer composite sheet.Aluminizer composite sheet production process is also simpler, and technology requires low, but the surface brightness height, product also is difficult for natural degradation, not environmental protection.
The production technology of the transfer paper of aluminizing is: with BOPP or BOPET and the 30~250g/m of 12~25 μ m 2It is compound that paper carries out wet type, aluminizer and paper are fit together, and be 35~55 ℃ in temperature again, humidity is to put in 30~60% the environment to carry out slaking in 24~48 hours, again OPP or PET film are stripped down after the slaking, only stay aluminium coated on paper, form the transfer paper of aluminizing.The easy natural degradation of transfer paper produces though aluminize, the product environmental protection, and its operation is many, and technology requires high, and production cost is high relatively.
An importance of packaging material economy principle is to composite product " 95% " principle, that is: a kind of material composition in the composite product can be divided into homogenous material greater than 95%.Vacuum directly plate or the transfer paper aluminium lamination very thin, only be 0.03~0.04 μ m (aluminum layer thickness of aluminum foil composite paper is 6~7 μ m), therefore be called as homogenous material, and be degradable material through test, therefore by approval in the world for being wrapping paper with barrier property environment-friendly and green.Therefore aluminum foil composite paper and aluminizer composite sheet are being metallized paper (being commonly called as vacuum aluminium-plated paper or vacuum aluminum-coated transferring paper) gradually and are replacing.But the use of the non-environment-friendly type aluminum foil composite paper of China is quite general at present, and this material has been deep into the consumer at heart, will cause tremendous loss to cigarette industry if immediate cancel is used.In order to solve such cigarette-brand problem with paper environmental protection and outward appearance two aspects, how on the basis of metallization transfer paper, make the metal-like effect of aluminium foil, meeting the environment-friendly degradable requirement simultaneously is the key of dealing with problems.
Summary of the invention
But the objective of the invention is to propose a kind of natural degradation, maintain pure aluminum foil outward appearance natural texture, metal-like is good, can replace the process for manufacturing aluminum foil pseudo metal texture transition paper of aluminum foil composite paper, aluminizer composite sheet and vacuum aluminium-plated paper.
Purpose of the present invention can be achieved through the following technical solutions:
Process for manufacturing aluminum foil pseudo metal texture transition paper may further comprise the steps:
Coating: on arbitrary of bidirectional stretching polypropylene film (be called for short BOPP), biaxially oriented polyester film (being called for short BOPET) or heat sealing type biaxial-tension polypropylene film, singly be coated with or two transfer coatings that is coated with;
Mold pressing: make steel rider by equipment requirement roller footpath size on moulding press, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminum foil pseudo metal texture effect through polishing, as mold pressing roll film is carried out mold pressing;
Aluminize: on film, carry out vacuum aluminum-coated;
Compound: with film and 30~250g/m 2It is compound that paper use glue carries out wet method;
Slaking: is 35~55 ℃ with film in temperature, and humidity is to put in 30~60% the environment to carry out slaking in 24~48 hours;
Stripping: film is peeled off.
Purpose of the present invention can also further realize by following technical measures:
Aforesaid process for manufacturing aluminum foil pseudo metal texture transition paper, carry out in regular turn according to the following steps:
1. on arbitrary of the non-corona of the bidirectional stretching polypropylene film of 12~25 μ m (being called for short BOPP) or biaxially oriented polyester film (being called for short BOPET), singly be coated with or two transfer coatings that is coated with;
2. make steel rider by equipment requirement roller footpath size on moulding press, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminum foil pseudo metal texture effect through polishing, as mold pressing roll BOPP film or the BOPET film that is coated with transfer coatings is carried out mold pressing;
3. on BOPP film after the mold pressing or BOPET film, carry out vacuum aluminum-coated;
4. BOPP film or BOPET film and the 30~250g/m with coating, mold pressing, after aluminizing 2It is compound that paper use glue carries out wet method;
5. be 35~55 ℃ with the film after compound in temperature, humidity is to put in 30~60% the environment to carry out slaking in 24~48 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
Aforesaid process for manufacturing aluminum foil pseudo metal texture transition paper if adopt the bidirectional stretching polypropylene film of heat-sealing type, also can be adjusted technology, carries out according to the following steps in regular turn:
1. make steel rider by equipment requirement roller footpath size on moulding press, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminum foil pseudo metal texture effect through polishing, as mold pressing roll the heat cover of the heat sealing type biaxial-tension polypropylene film of 12~25 μ m is carried out mold pressing;
2. on the heat sealing type biaxial-tension polypropylene film after the mold pressing, carry out vacuum aluminum-coated;
3. the face of aluminizing of the heat sealing type biaxial-tension polypropylene film after aluminizing is coated with material for transfer;
4. heat sealing type biaxial-tension polypropylene film and the 30~250g/m with mold pressing, after aluminizing, being coated with 2It is compound that paper use glue carries out wet method;
5. be 35~55 ℃ with the film after compound in temperature, humidity is to put in 30~60% the environment to carry out slaking in 24~48 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
The production technology of aforesaid imitative aluminium foil transfer paper, the transfer coatings of wherein said coating is the oiliness transfer coatings, or aqueous transfer coating, it and BOPP or BOPET are covering insecure, and with the vacuum aluminum-coated fastness that combines, play release, in conjunction with, the effect of duplicating the aluminium foil texture, the coating dry measure is 1~2g/m 2
The production technology of aforesaid imitative aluminium foil transfer paper, the surface brightness of wherein said pressure roller are 20~45 (measuring with Minolta CR-321 colour photometer).
The production technology of aforesaid imitative aluminium foil transfer paper, wherein said vacuum aluminum-coatedly in the take-up type vacuum aluminum-spraying machine, carry out, thickness of coating is 300~400 dusts.
Advantage of the present invention is: through the aluminum foil pseudo metal texture transfer paper of explained hereafter of the present invention, has strong metal-like, very approximate in appearance with aluminum foil composite paper, better than common metallization transfer paper visual effect, but environmental protection natural degradation again simultaneously.
The production material of the present invention and existing tobacco and wine wrapping paper composite aluminium foil paper, aluminizer composite sheet and the transfer paper of aluminizing and pluses and minuses are to such as table 1:
Table 1
Figure C20071013293700081
The present invention adopts vacuum aluminum-coated, and vacuum aluminium-plated paper and aluminum foil composite paper are carried out the experiment of aqueous slkali solubility property respectively and in the experiment of degraded in soil speed, draw table 2 and table 3:
Table 2
Experimental subjects The specimen page size Alkaline concentration The aqueous slkali consumption Dissolve required time fully
Vacuum aluminium-plated paper 40mm×40mm 10%NaOH 30ml 8min
Vacuum aluminium-plated paper 40mm×40mm 2%NaOH 30ml 10min
Aluminum foil composite paper 40mm×40mm 10%NaOH 30ml 30min
Aluminum foil composite paper 40mm×40mm 2%NaOH 30ml 120min
Table 3
Experimental subjects The specimen page size The meadow landfill The landfill time Change behind the landfill
Vacuum aluminium-plated paper 40mm * 40mm The grass hole is dark: 200mm area: 200mm * 200mm 3 months 1, the specimen page base stock is rotten fully; 2, surperficial aluminium lamination rots, and only deposits fragmentary fine-powdered chip, is difficult to collect weigh.
Aluminum foil composite paper 40mm * 40mm The grass hole is dark: 200mm area: 200mm * 200mm 3 months 1, the specimen page base stock is rotten fully; 2, the complete existence of surperficial aluminium foil.
Can draw by table 2 and table 3: when adopting vacuum aluminum-coated vacuum aluminium-plated paper of the present invention to recycle as package paper, its aluminium lamination dissolution process required time is short, and vacuum aluminium-plated paper is easy to be absorbed by soil after abandoning than aluminum foil composite paper easily biological-degradable.
The specific embodiment
Embodiment one
A kind of process for manufacturing aluminum foil pseudo metal texture transition paper, carry out in regular turn according to the following steps:
1. singly be coated with the oiliness transfer coatings on arbitrary of the non-corona of the BOPP film of 22 μ m, the coating dry measure is 1g/m 2
2. make steel rider by equipment requirement roller footpath size on moulding press, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminium foil surface metal effect through polishing, and surface brightness is 20, and the BOPP film that will be coated with transfer coatings with roller on moulding press carries out mold pressing;
3. carry out vacuum aluminum-coatedly in the take-up type vacuum aluminum-spraying machine at the BOPP film after the mold pressing, thickness of coating is 300 dusts.
4. BOPP film and the 30g/m with coating, mold pressing, after aluminizing 2It is compound that paper use glue carries out wet method;
5. be 35 ℃ with the film after compound in temperature, humidity is to put in 30% the environment to carry out slaking in 24~48 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
Embodiment two
A kind of process for manufacturing aluminum foil pseudo metal texture transition paper, carry out in regular turn according to the following steps:
1. twoly on arbitrary of the non-corona of the BOPP film of 25 μ m be coated with aqueous transfer coating, the coating dry measure is 1.5g/m 2
2. make steel rider by equipment requirement roller footpath size on moulding press, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminium foil surface effect through polishing, and surface brightness is 35, and the BOPP film that will be coated with transfer coatings with roller on moulding press carries out mold pressing;
3. carry out vacuum aluminum-coatedly in the take-up type vacuum aluminum-spraying machine at the BOPP film after the mold pressing, thickness of coating is 350 dusts.
4. BOPP film and the 100g/m with coating, mold pressing, after aluminizing 2It is compound that paper use glue carries out wet method;
5. be 40 ℃ with the film after compound in temperature, humidity is to put in 45% the environment to carry out slaking in 35 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
Embodiment three
A kind of process for manufacturing aluminum foil pseudo metal texture transition paper, carry out in regular turn according to the following steps:
1. singly be coated with aqueous transfer coating on arbitrary of the non-corona of the BOPET film of 15 μ m, the coating dry measure is 2g/m 2
2. make steel rider by equipment requirement roller footpath size on moulding press, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminium foil surface effect through polishing, and surface brightness is 45, and the BOPET film that will be coated with transfer coatings with roller on moulding press carries out mold pressing;
3. advance vacuum aluminum-coated row at the BOPET film after the mold pressing in the take-up type vacuum aluminum-spraying machine, thickness of coating is 400 dusts.
4. BOPET film and the 250g/m with coating, mold pressing, after aluminizing 2It is compound that paper use glue carries out wet method;
5. be 55 ℃ with the film after compound in temperature, humidity is to put in 60% the environment to carry out slaking in 48 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
Embodiment four
Process for manufacturing aluminum foil pseudo metal texture transition paper, carry out in regular turn according to the following steps:
1. on moulding press, make steel rider by equipment requirement roller footpath size, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminium foil surface effect through polishing, surface brightness is 20, with roller the heat cover of the heat sealing type biaxial-tension polypropylene film of 22 μ m is carried out mold pressing on moulding press;
2. advance vacuum aluminum-coated row at the heat sealing type biaxial-tension polypropylene film after the mold pressing in the take-up type vacuum aluminum-spraying machine, thickness of coating is 300 dusts;
3. singly be coated with the oiliness transfer coatings on arbitrary of the non-corona of the heat sealing type biaxial-tension polypropylene film after aluminizing, the coating dry measure is 1g/m 2
4. heat sealing type biaxial-tension polypropylene film and the 30g/m with mold pressing, after aluminizing, being coated with 2It is compound that paper use glue carries out wet method;
5. be 35 ℃ with the film after compound in temperature, humidity is to put in 30% the environment to carry out slaking in 24 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
Embodiment five
Process for manufacturing aluminum foil pseudo metal texture transition paper, carry out in regular turn according to the following steps:
1. on moulding press, make steel rider by equipment requirement roller footpath size, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminium foil surface effect through polishing, surface brightness is 35, with roller the heat cover of the heat sealing type biaxial-tension polypropylene film of 25 μ m is carried out mold pressing on moulding press;
2. advance vacuum aluminum-coated row at the heat sealing type biaxial-tension polypropylene film after the mold pressing in the take-up type vacuum aluminum-spraying machine, thickness of coating is 350 dusts;
3. singly be coated with or two oiliness transfer coatings or aqueous transfer coating of being coated with on arbitrary of the non-corona of the heat sealing type biaxial-tension polypropylene film after aluminizing, the coating dry measure is 1.5g/m 2
4. heat sealing type biaxial-tension polypropylene film and the 150g/m with mold pressing, after aluminizing, being coated with 2It is compound that paper use glue carries out wet method;
5. be 40 ℃ with the film after compound in temperature, humidity is to put in 45% the environment to carry out slaking in 35 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
Embodiment six
Process for manufacturing aluminum foil pseudo metal texture transition paper, carry out in regular turn according to the following steps:
1. on moulding press, make steel rider by equipment requirement roller footpath size, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminium foil surface effect through polishing, surface brightness is 45, with roller the heat cover of the heat sealing type biaxial-tension polypropylene film of 25 μ m is carried out mold pressing on moulding press;
2. advance vacuum aluminum-coated row at the heat sealing type biaxial-tension polypropylene film after the mold pressing in the take-up type vacuum aluminum-spraying machine, thickness of coating is 400 dusts;
3. singly be coated with or two oiliness transfer coatings or aqueous transfer coating of being coated with on arbitrary of the non-corona of the heat sealing type biaxial-tension polypropylene film after aluminizing, the coating dry measure is 2g/m 2
4. heat sealing type biaxial-tension polypropylene film and the 250g/m with mold pressing, after aluminizing, being coated with 2It is compound that paper use glue carries out wet method;
5. be 55 ℃ with the film after compound in temperature, humidity is to put in 60% the environment to carry out slaking in 48 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
The present invention can also have other embodiment, and the technical scheme that equal replacement of all employings or equivalent transformation form all drops within the scope of protection of present invention.

Claims (5)

1. process for manufacturing aluminum foil pseudo metal texture transition paper is characterized in that: may further comprise the steps:
Coating: on arbitrary of bidirectional stretching polypropylene film or biaxially oriented polyester film, singly be coated with or two transfer coatings that is coated with;
Mold pressing: make steel rider by equipment requirement roller footpath size on moulding press, with the polishing of roller embryo, copper facing chromium plating is processed into the aluminum foil pseudo metal texture effect through polishing, as mold pressing roll film is carried out mold pressing;
Aluminize: on film, carry out vacuum aluminum-coated;
Compound: with film and 30~250g/m 2It is compound that paper use glue carries out wet method;
Slaking: is 35~55 ℃ with film in temperature, and humidity is to put in 30~60% the environment to carry out slaking in 24~48 hours;
Stripping: film is peeled off.
2. process for manufacturing aluminum foil pseudo metal texture transition paper as claimed in claim 1 is characterized in that: carry out according to the following steps in regular turn:
1. on arbitrary of the non-corona of the bidirectional stretching polypropylene film of 12~25 μ m or biaxially oriented polyester film, singly be coated with or two transfer coatings that is coated with;
2. on moulding press, make steel rider by equipment requirement roller footpath size, the roller embryo is polished, copper facing chromium plating is processed into the aluminum foil pseudo metal texture effect through polishing, as mold pressing roll bidirectional stretching polypropylene film or the biaxially oriented polyester film that is coated with transfer coatings is carried out mold pressing;
3. on bidirectional stretching polypropylene film after the mold pressing or biaxially oriented polyester film, carry out vacuum aluminum-coated;
4. bidirectional stretching polypropylene film or biaxially oriented polyester film and the 30~250g/m with coating, mold pressing, after aluminizing 2It is compound that paper use glue carries out wet method;
5. be 35~55 ℃ with the film after compound in temperature, humidity is to put in 30~60% the environment to carry out slaking in 24~48 hours;
6. after the slaking film is peeled off, obtained the aluminum foil pseudo metal texture transfer paper.
3. process for manufacturing aluminum foil pseudo metal texture transition paper as claimed in claim 1 or 2 is characterized in that: the transfer coatings of described coating is the oiliness transfer coatings, or aqueous transfer coating, and the coating dry measure is 1~2g/m 2
4. process for manufacturing aluminum foil pseudo metal texture transition paper as claimed in claim 1 or 2 is characterized in that: the surface brightness of described pressure roller is 20~45.
5. process for manufacturing aluminum foil pseudo metal texture transition paper as claimed in claim 1 or 2 is characterized in that: described vacuum aluminum-coatedly carry out in the take-up type vacuum aluminum-spraying machine, thickness of coating is 300~400 dusts.
CN200710132937A 2007-09-20 2007-09-20 Process for manufacturing aluminum foil pseudo metal texture transition paper Expired - Fee Related CN100575605C (en)

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CN102864684B (en) * 2012-08-21 2015-03-11 湖南中烟工业有限责任公司 Preparation process of aqueous silvery vacuum aluminized paper and transfer coating used for preparation process
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CN103343493B (en) * 2013-07-12 2015-12-23 常德市武陵金德镭射科技有限公司 A kind of preparation method shifting paperboard
CN108130814A (en) * 2017-12-22 2018-06-08 湖北富狮材料科技股份有限公司 Aluminium imitates foil transfer paper and preparation method thereof
CN108166328A (en) * 2017-12-22 2018-06-15 湖北富狮材料科技股份有限公司 Anti-aging aluminium imitates foil transfer paper and preparation method thereof
CN108166326A (en) * 2017-12-22 2018-06-15 湖北富狮材料科技股份有限公司 Antiultraviolet aluminium imitates foil transfer paper and preparation method thereof
CN108166329A (en) * 2017-12-22 2018-06-15 湖北富狮材料科技股份有限公司 Preventing atomization aluminium imitates foil transfer paper and preparation method thereof
CN108166327A (en) * 2017-12-22 2018-06-15 湖北富狮材料科技股份有限公司 Durable aluminum imitates foil transfer paper and preparation method thereof
CN110356138A (en) * 2019-08-09 2019-10-22 金石包装(嘉兴)有限公司 A kind of aluminum plastic film printing layer and the solvent-free compound method of middle layer
CN113481759A (en) * 2021-05-17 2021-10-08 南京金陵金箔集团股份有限公司 Production process of lining paper for packaging
CN113550174A (en) * 2021-08-03 2021-10-26 新郑市吉龙包装材料有限公司 Production process of golden common silver transfer paper

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