CN108166329A - Preventing atomization aluminium imitates foil transfer paper and preparation method thereof - Google Patents

Preventing atomization aluminium imitates foil transfer paper and preparation method thereof Download PDF

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Publication number
CN108166329A
CN108166329A CN201711428639.XA CN201711428639A CN108166329A CN 108166329 A CN108166329 A CN 108166329A CN 201711428639 A CN201711428639 A CN 201711428639A CN 108166329 A CN108166329 A CN 108166329A
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CN
China
Prior art keywords
aluminium
layer
foil transfer
paper
imitates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711428639.XA
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Chinese (zh)
Inventor
聂志平
叶金鑫
郑召
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Fushi Material Science & Technology Co Ltd
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Hubei Fushi Material Science & Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Fushi Material Science & Technology Co Ltd filed Critical Hubei Fushi Material Science & Technology Co Ltd
Priority to CN201711428639.XA priority Critical patent/CN108166329A/en
Publication of CN108166329A publication Critical patent/CN108166329A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/02Metal coatings
    • D21H19/08Metal coatings applied as vapour, e.g. in vacuum
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/84Paper comprising more than one coating on both sides of the substrate
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • D21H23/52Addition to the formed paper by contacting paper with a device carrying the material
    • D21H23/64Addition to the formed paper by contacting paper with a device carrying the material the material being non-fluent at the moment of transfer, e.g. in form of preformed, at least partially hardened coating
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • D21H23/70Multistep processes; Apparatus for adding one or several substances in portions or in various ways to the paper, not covered by another single group of this main group
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper

Abstract

The invention belongs to field of packaging material, and in particular to a kind of transfer paper and preparation method thereof is mainly used for tobacco and food packaging.Preventing atomization aluminium imitates foil transfer paper, it is characterised in that:It is prepared by aluminium foil transfer membrane, glue-line, paper layer and back of the body rubberised layer, and aluminium foil transfer membrane, glue-line, paper layer, back of the body rubberised layer are combined into one successively;The aluminium foil transfer membrane is made of polyester film, the coating layer of the ultraviolet screener containing antifoggant, molding Information Level and aluminium layer, polyester film, the coating layer of the ultraviolet screener containing antifoggant, molding Information Level, aluminium layer are combined into one successively, and aluminium layer is compound with glue-line.The present invention can natural degradation and again keep pure aluminum foil appearance, metal-like is good, can replace aluminum foil composite paper, also with atomization-preventing function.

Description

Preventing atomization aluminium imitates foil transfer paper and preparation method thereof
Technical field
The invention belongs to field of packaging material, and in particular to a kind of transfer paper and preparation method thereof is mainly used for cigarette Grass and food packaging.
Background technology
With attention of the country to environmental protection, the design of packing material should preferentially select side that is nontoxic, harmless, being easy to degradation Case.And existing tobacco and wine and food packaging, for aesthetic effect, generally use is aluminium foil or aluminizer (metalized film) and paper The composite material that is combined is packed.And this composite material production process is simple, process specifications are low and It is not easy natural degradation, not environmentally.
Invention content
The purpose of the present invention is to provide a kind of preventing atomization aluminium to imitate foil transfer paper and preparation method thereof, can natural degradation and again The appearance of pure aluminum foil is kept, metal-like is good, aluminum foil composite paper can be replaced, also with preventing atomization, anti-ultraviolet function.
To achieve these goals, the technical solution used in the present invention is:Preventing atomization aluminium imitates foil transfer paper, and feature exists In:It by aluminium foil transfer membrane 8, glue-line 5, paper layer 6 and the back of the body rubberised layer 7 be prepared, aluminium foil transfer membrane 8, glue-line 5, paper layer 6, Back of the body rubberised layer 7 is combined into one successively;
The aluminium foil transfer membrane 8 is by polyester film 1, the coating layer 2 of the ultraviolet screener containing antifoggant, molding Information Level 3 It is formed with aluminium layer 4, polyester film 1, the coating layer 2 of the ultraviolet screener containing antifoggant, molding Information Level 3, aluminium layer 4 are compound successively Integrally, aluminium layer 4 and glue-line 5 are compound.
The dosage of the aluminium foil transfer membrane 8 is 14.2g/m2;The material of the glue-line 5 be acrylate adhesive, dosage For 2g/m2;The material of the paper layer 6 be paper, dosage 225g/m2;The material of the back of the body rubberised layer 7 is polyvinyl alcohol, is used It measures as 3g/m2
The dosage of the polyester film 1 is 11g/m2;Being molded Information Level 3 is:Steel rider polishing is processed on moulding press Aluminum foil metal texture effect is impressed on the coating layer of polyester film, forms molding Information Level 3;The dosage of aluminium layer 4 is 2g/m2
The material of the coating layer 2 of the ultraviolet screener containing antifoggant is molding coating, antifoggant and ultraviolet screener Mixture, the dosage for being molded coating are 1g/m2, the dosage of antifoggant is 0.1g/m2, the dosage of ultraviolet screener is 0.1g/m2
It is stearic that Monoolein, sorbitan monopalmitate, sorbitan list can be used in the antifoggant Acid esters or polyethylene oxide (20) glyceryl monostearate.The ultraviolet screener is nano-titanium dioxide or hexichol first copper.
The preventing atomization aluminium imitates the preparation method of foil transfer paper, it is characterised in that it includes the following steps:
1) preparation of aluminium foil transfer membrane 8 includes the following steps:
(1) on coating machine, in the double smearing extrusion material of non-corona one side, antifoggant and the ultraviolet screener of polyester film 1 Mixture, then pass through drying on polyester film formed the ultraviolet screener containing antifoggant coating layer 2;
(2) steel rider is made on moulding press, roller embryo is polished, chromium plating after copper facing is processed into aluminum foil metal texture through polishing, Coated polyester film is molded as mold pressing roll, molding Information Level 3 is formed, obtains the polyester of metal-like Film;
(3) polyester film for having metal-like is fitted into vacuum aluminum-plating machine, aluminize being formed on molding Information Level 3 Aluminium layer 4 obtains aluminium foil transfer membrane;
2) one layer of acrylate adhesive is coated with below the aluminium layer 4 of aluminium foil transfer membrane 8, forms glue-line 5;Glue-line 5 with It is mutually glued above paper layer 6, layer of polyethylene alcohol is coated with below paper layer 6, form back of the body rubberised layer 7;Then it is compound by compounding machine Integrally;
3) and then cure;
4) polyester film 1 is removed after curing, preventing atomization is obtained and imitates aluminium foil transfer paper.
It is cured as in the step 4):It it is 20-40 DEG C in temperature, humidity is to be placed 12 hours in the environment of 30-60% Cured.
The beneficial effects of the invention are as follows:Using the above structure, the present invention is at low cost, keeps the appearance of pure aluminum foil, has strong Strong metal-like, at the same again environmental protection, can natural degradation, also with preventing atomization, anti-ultraviolet function.
Description of the drawings
Fig. 1 is the structure diagram of the present invention.
The preventing atomization that Fig. 2 is the present invention imitates aluminium foil transfer paper and is degraded in the soil respectively with existing aluminum foil composite paper Test the result figure obtained.
In Fig. 1:1- polyester films, the coating layer of 2- ultraviolet screeners containing antifoggant, 3- molding Information Levels, 4- aluminium layers, 5- Glue-line, 6- paper layers, 7- back of the body rubberised layers, 8- aluminium foil transfer membranes.
Specific embodiment
As shown in Figure 1, preventing atomization aluminium imitates foil transfer paper, it is made by aluminium foil transfer membrane 8, glue-line 5, paper layer 6 and back of the body rubberised layer 7 Standby to form, aluminium foil transfer membrane 8, glue-line 5, paper layer 6, back of the body rubberised layer 7 are combined into one successively;
The aluminium foil transfer membrane 8 is by polyester film 1, the coating layer 2 of the ultraviolet screener containing antifoggant, molding Information Level 3 It is formed with aluminium layer 4, polyester film 1, the coating layer 2 of the ultraviolet screener containing antifoggant, molding Information Level 3, aluminium layer 4 are compound successively Integrally, aluminium layer 4 is combined into one with glue-line 5.
The dosage of the aluminium foil transfer membrane 8 is 14.2g/m2;The material of the glue-line 5 be acrylate adhesive, dosage For 2g/m2;The material of the paper layer 6 is by paper (plant fiber is made), dosage 225g/m2;The material of the back of the body rubberised layer 7 For polyvinyl alcohol, dosage 3g/m2
The dosage of the polyester film 1 is 11g/m2;The material of the coating layer 2 of the ultraviolet screener containing antifoggant is mould Extrusion material is (such as:It is prosperous to contain board P-B-Y type transfer lasers coating), the mixture of antifoggant and ultraviolet screener, be molded coating Dosage is 1g/m2, the dosage of antifoggant is 0.1g/m2, the dosage of ultraviolet screener is 0.1g/m2;Being molded Information Level 3 is: Steel rider polishing is processed into aluminum foil metal texture effect on moulding press to be impressed on the coating layer of polyester film, forms molding letter Cease layer 3;The material of aluminium layer 4 is 0.03 μm of aluminium layer, dosage 2g/m2
It is stearic that Monoolein, sorbitan monopalmitate, sorbitan list can be used in the antifoggant Acid esters or polyethylene oxide (20) glyceryl monostearate.The ultraviolet screener is nano-titanium dioxide or hexichol first copper.
The preventing atomization aluminium imitates the preparation method of foil transfer paper, it includes the following steps:
1) preparation of aluminium foil transfer membrane 8 includes the following steps:
(1) it is non-corona one side double smearing extrusion material (i.e. below in Fig. 1) in polyester film 1, antifog on coating machine The mixture of agent and ultraviolet screener (double paintings are exactly to apply 2 times) is then prevented by drying to be formed on polyester film containing antifoggant The coating layer 2 of ultraviolet light agent;
(2) steel rider is made on moulding press, roller embryo is polished, chromium plating (after i.e. first " copper facing " again " chromium plating "), warp after copper facing Polishing is processed into aluminum foil metal texture (surface brightness 22), and coated polyester film is molded (i.e. as mold pressing roll The coating layer 2 of the ultraviolet screener containing antifoggant is molded), molding Information Level 3 is formed, obtains the polyester of metal-like Film;
(3) polyester film for having metal-like is fitted into vacuum aluminum-plating machine, aluminize being formed on molding Information Level 3 Aluminium wire (is heated to 1500 DEG C or so melting evaporations, and the condensation that distils, uniformly steams one layer on molding Information Level 3 by aluminium layer 4 Aluminium layer forms aluminium layer 4), obtain aluminium foil transfer membrane;
2) one layer of acrylate adhesive is coated with below the aluminium layer 4 of aluminium foil transfer membrane 8, forms glue-line 5;Glue-line 5 with It is mutually glued above paper layer 6, layer of polyethylene alcohol is coated with below paper layer 6, form back of the body rubberised layer 7;Then it is compound by compounding machine Integrally;
3) it is and then in temperature 20-40 DEG C, humidity is to place 12 hours to be cured in the environment of 30-60%;
4) polyester film 1 is removed after curing, antifoggant is obtained and imitates aluminium foil transfer paper.
Preferably, in step (1), six section baking oven set temperatures of coating machine are respectively 80~90 DEG C, 100~110 DEG C, It 120~140 DEG C, 120~140 DEG C, 100~115 DEG C, 90~100 DEG C, is coated with, applied using the ceramic anilox roller of 140~165 lines The dry measure of layer of cloth is controlled in 1.0g/m2, coating speed control at 110~120 ms/min, the coating viscosity control 15 of coating~ 25 seconds.
Preferably, in step (2), molding temperature is 145~190 DEG C, and molding speed is 30~60 ms/min.
Preferably, in step (3), vacuum degree of aluminizing is 1.5~3.0 × 100Pa, and speed control of aluminizing is 150~300 M/min.
Aluminium foil transfer paper and existing aluminum foil composite paper is imitated the preventing atomization of the present invention to be degraded in the soil respectively reality It tests to obtain a result and is shown in Table 1.It can be obtained by table 1, preventing atomization imitates aluminium foil transfer paper natural degradation easier than existing aluminum foil composite paper, It is easy to after discarding by soil absorption.It makes discovery from observation, preventing atomization aluminium of the invention imitates foil transfer paper and keeps the outer of pure aluminum foil It sees, metal-like is good.The preventing atomization aluminium of the present invention, which imitates foil transfer paper, can replace aluminum foil composite paper.
Experimental subjects:The preventing atomization of the present invention imitates aluminium foil transfer paper, specimen page size:3cm × 4cm fills the time:3 months, Variation:Base stock rots completely;Surface aluminum layer is rotten, only deposits fragmentary fine-powdered clast.
Experimental subjects:Existing aluminum foil composite paper, specimen page size:3cm × 4cm fills the time:3 months, variation:Base stock It rots completely, surface aluminium foil completely exists.
The present invention preventing atomization aluminium imitate foil transfer paper can effective shield ultraviolet radiation, ultraviolet light cover gear coefficient UPF values More than 50, there is anti-ultraviolet function.The preventing atomization aluminium of the present invention imitates foil transfer paper and does not haze, mist degree (%):≤ 0.3, have Atomization-preventing function.

Claims (8)

1. preventing atomization aluminium imitates foil transfer paper, it is characterised in that:It is by aluminium foil transfer membrane (8), glue-line (5), paper layer (6) and back of the body gluing Layer (7) is prepared, and aluminium foil transfer membrane (8), glue-line (5), paper layer (6), back of the body rubberised layer (7) are combined into one successively;
The aluminium foil transfer membrane (8) is by polyester film (1), the coating layer (2) of the ultraviolet screener containing antifoggant, molding Information Level (3) it is formed with aluminium layer (4), polyester film (1), the coating layer (2) of the ultraviolet screener containing antifoggant, molding Information Level (3), aluminium layer (4) it is combined into one successively, aluminium layer (4) and glue-line (5) are compound.
2. preventing atomization aluminium according to claim 1 imitates foil transfer paper, it is characterised in that:The use of the aluminium foil transfer membrane (8) Amount is 14.2g/m2;The material of the glue-line (5) be acrylate adhesive, dosage 2g/m2;The material of the paper layer (6) is Paper, dosage 225g/m2;The material of the back of the body rubberised layer (7) be polyvinyl alcohol, dosage 3g/m2
3. preventing atomization aluminium according to claim 1 imitates foil transfer paper, it is characterised in that:The dosage of the polyester film (1) For 11g/m2;Being molded Information Level (3) is:Steel rider polishing is processed into aluminum foil metal texture effect on moulding press and is impressed into polyester On the coating layer of film, molding Information Level (3) is formed;The dosage of aluminium layer (4) is 2g/m2
4. preventing atomization aluminium according to claim 1 imitates foil transfer paper, it is characterised in that:The ultraviolet screener containing antifoggant The material of coating layer (2) be the mixture for being molded coating, antifoggant and ultraviolet screener, the dosage for being molded coating is 1g/m2, The dosage of antifoggant is 0.1g/m2, the dosage of ultraviolet screener is 0.1g/m2
5. preventing atomization aluminium according to claim 4 imitates foil transfer paper, it is characterised in that:The antifoggant is glycerine list oil Acid esters, sorbitan monopalmitate, sorbitan monostearate or polyethylene oxide (20) glyceryl monostearate.
6. preventing atomization aluminium according to claim 4 imitates foil transfer paper, it is characterised in that:The ultraviolet screener is nanometer Titanium dioxide or hexichol first copper.
7. preventing atomization aluminium as described in claim 1 imitates the preparation method of foil transfer paper, it is characterised in that it includes the following steps:
1) preparation of aluminium foil transfer membrane (8) includes the following steps:
(1) on coating machine, in the double smearing extrusion material of non-corona one side of polyester film (1), antifoggant and ultraviolet screener Mixture then forms the coating layer (2) of the ultraviolet screener containing antifoggant by drying on polyester film;
(2) steel rider is made on moulding press, roller embryo is polished, chromium plating after copper facing is processed into aluminum foil metal texture through polishing, as Mold pressing roll is molded coated polyester film, forms molding Information Level (3), obtains the polyester film of metal-like;
(3) polyester film for having metal-like is fitted into vacuum aluminum-plating machine, aluminize forming aluminium on molding Information Level (3) Layer (4), obtains aluminium foil transfer membrane;
2) one layer of acrylate adhesive is coated with below the aluminium layer (4) of aluminium foil transfer membrane (8), forms glue-line (5);Glue-line (5) with mutually being glued above paper layer (6), layer of polyethylene alcohol is coated with below paper layer (6), forms back of the body rubberised layer (7);Then by Compounding machine is combined into one;
3) and then cure;
4) polyester film (1) is removed after curing, preventing atomization is obtained and imitates aluminium foil transfer paper.
8. antiultraviolet aluminium according to claim 7 imitates the preparation method of foil transfer paper, which is characterized in that the step 4) In be cured as:It it is 20-40 DEG C in temperature, humidity is to place 12 hours to be cured in the environment of 30-60%.
CN201711428639.XA 2017-12-22 2017-12-22 Preventing atomization aluminium imitates foil transfer paper and preparation method thereof Pending CN108166329A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711428639.XA CN108166329A (en) 2017-12-22 2017-12-22 Preventing atomization aluminium imitates foil transfer paper and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711428639.XA CN108166329A (en) 2017-12-22 2017-12-22 Preventing atomization aluminium imitates foil transfer paper and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108166329A true CN108166329A (en) 2018-06-15

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Country Status (1)

Country Link
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101135128A (en) * 2007-09-20 2008-03-05 江苏金恒新型包装材料有限公司 Process for manufacturing aluminum foil pseudo metal texture transition paper
CN103882782A (en) * 2014-04-06 2014-06-25 湖北富狮材料科技股份有限公司 Ultraviolet-proof three-dimensional cold mounting composite paper
CN103898806A (en) * 2014-04-06 2014-07-02 湖北富狮材料科技股份有限公司 Anti-fogging three-dimensional cold laminating composite paper

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101135128A (en) * 2007-09-20 2008-03-05 江苏金恒新型包装材料有限公司 Process for manufacturing aluminum foil pseudo metal texture transition paper
CN103882782A (en) * 2014-04-06 2014-06-25 湖北富狮材料科技股份有限公司 Ultraviolet-proof three-dimensional cold mounting composite paper
CN103898806A (en) * 2014-04-06 2014-07-02 湖北富狮材料科技股份有限公司 Anti-fogging three-dimensional cold laminating composite paper

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