CN100572478C - Adhesive sheet with multi-staged air vent channels - Google Patents

Adhesive sheet with multi-staged air vent channels Download PDF

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Publication number
CN100572478C
CN100572478C CNB2006800000397A CN200680000039A CN100572478C CN 100572478 C CN100572478 C CN 100572478C CN B2006800000397 A CNB2006800000397 A CN B2006800000397A CN 200680000039 A CN200680000039 A CN 200680000039A CN 100572478 C CN100572478 C CN 100572478C
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China
Prior art keywords
raceway groove
air vent
adhesive sheet
vent channels
stage
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Expired - Fee Related
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CNB2006800000397A
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Chinese (zh)
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CN1942547A (en
Inventor
林东勋
南允祐
车炯旻
李康烨
林景嫄
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LG Corp
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LG Chemical Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/40Adhesives in the form of films or foils characterised by release liners
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/40Adhesives in the form of films or foils characterised by release liners
    • C09J7/403Adhesives in the form of films or foils characterised by release liners characterised by the structure of the release feature
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/20Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/204Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive coating being discontinuous

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesive Tapes (AREA)

Abstract

The present invention increases the application that air vent channels improves adhesive sheet by the adhesive surface to adhesive sheet.According to the present invention, formation has the air vent channels of various height and width, make each air vent channels to disappear at a certain time interval, thereby promote the eliminating of air, and the increase bond area reaches the required time of the bounding force of design with shortening, and the increase of bond area has improved the smoothness between adhesive surface and the target surface, so that the figure of air vent channels does not appear on the front surface of adhesive sheet.

Description

Adhesive sheet with multi-staged air vent channels
Technical field
The present invention relates to a kind of tackiness agent fixing adhesive sheet of film on target surface that uses.
Background technology
Use adhesive sheet can be on target surface adhesive film removably because it is easy to use, adhesive sheet is applied to a plurality of fields.The object lesson of adhesive sheet comprises reflecting piece, advertisement film, facing film for building, label, adhesive tape etc.
In order to prepare such adhesive sheet, at first use mode rolling or casting to prepare substrate, tackiness agent is coated on the surface of release liner (release liner), then the coated surface of release liner and the one side of substrate are combined togather.
Release liner is usually by preparing with coated papers such as polyethylene, polypropylene, polyester, and coating handles with silicone-treated or with other method, so that itself and tackiness agent separate easily.
Preparation has the stripper surface of the release liner of good smoothness, so that the tackiness agent that applies has homogeneous thickness.When film adhered on the target surface, because air can be trapped between tackiness agent and the target surface, the film with level and smooth adhesive surface produced relatively poor outward appearance owing to the swelling of film is surperficial.In addition, reduced bond area with target surface owing to be absorbed in the layer of air, thereby caused reducing of bounding force.
In order to address this problem, made such effort: non-adhesive inorganic materials, metal component or glass are placed on the surface of successive bonding coat, with position that can trim plate, thereby make and remove air and become easily, and provide the air can be from the passage of discharging wherein to the surface of bonding coat.
If form discontinuous bonding coat on sheet, can be used as air in the part of the adhesive-free of this sheet can be from the raceway groove of discharging wherein.This discontinuous bonding coat can be on film by print process or spray method arranged in form tackiness agent with island, and dry adhesive island and forming.
Perhaps, change the structure of the silicon treat surface of release liner or film, make this structure can be transferred to the surface of bonding coat, thereby be formed for removing the raceway groove of air.
Europe publication numbers 279579 has disclosed a kind of pressure sensitive adhesion sheet that comprises the continuous bonding coat with irregular adhesive surface.This continuous bonding coat with irregular adhesive surface can be provided at the initial ability and the continuous capability of reorientating sheet on the plurality of target surface when structure.
Japan publication 6-212131 has disclosed by jog is set on the surface of continuous bonding coat and has improved easy degree of removing air and the ability of reorientating sheet.Specifically, the invention that discloses in this publication provides the adhesive sheet of the removable that is used to decorate, and wherein each jog has the height of 10~20 μ m, the bottom width of 50~100 μ m and the last plane width of 50~100 μ m.
U.S. Patent number 5650215 has disclosed the method for the product of a kind of manufacturing such as self adhesive tape or transfer printing coating (transfer coat), this product comprises the continuous pressure-sensitive adhesive layer with microstructure, and this microstructure has a series of depth-width ratios and is approximately 0.1~10 figure.Have microscopic dimensions among this microstructure Ying Zaigao, wide and long at least two, can obtain to reorientate the initial ability of this product such as the product with microstructure of self adhesive tape or transfer printing coating.
In addition, the volume that U.S. Patent number 6524675 has limited the air vent channels that is formed by microstructure is, whenever has the circular area of the tackiness agent of 500 μ m diameters, and this volume is at least 1 * 10 3μ m 3In addition, in order to satisfy above-mentioned condition, the pitch of figure (pitch) is restricted to 400 μ m or littler, so that concaveconvex structure does not appear on the front surface with adherent of target surface.
U.S. Patent number 6630218 has disclosed two processes: application of adhesive and release liner and sheet put together on the release liner of plane, thereby with the two dimensional structure memory on tackiness agent; And remove release liner, and sheet and the release liner with concaveconvex structure are put together, thereby make adhesive surface have concaveconvex structure.When removing release liner, tackiness agent is owing to the elasticity of cross-linked binder is recovered the two dimensional structure of its memory, and concaveconvex structure disappears thus.In addition, under 25 ℃, after 48 hours, obtain at least 92% bond area, thereby the convex-concave pattern that is present in tackiness agent can be presented on the surface of sheet.
U.S. Patent number 6197397 has disclosed the little formation of duplicating adhesive surface that has the microchannel that is used for the fluid discharging and be used to improve the nail of adhesion characteristic.Such minute-pressure line figure has the microchannel that is used for the fluid discharging and finds time, and can place non-adhesive material therein, thereby promotes the discharging of air, improves the ability of reorientating sheet simultaneously.
Summary of the invention
The present invention is the air that is absorbed in when using adhesive sheet in order to remove, improving releasable and to reorientate the ability of sheet, and outward appearance and bounding force after improving it and using.
The present invention will be by addressing the above problem in conjunction with two types of raceway grooves: when the application sheet, the raceway groove of the first kind can be easy to disappear by pressure, and the raceway groove of second type can not disappear after this sheet is used for some time.
An object of the present invention is to provide a kind of adhesive sheet, wherein form air vent channels with various height and width, so that each air vent channels disappears behind the certain hour of interval, thereby promote the discharge and the bond area that increases sharply of air, to shorten the required time of the bounding force that obtains design, and increase bond area improving the slickness between adhesive surface and the target surface, thereby the figure of air vent channels is not appeared on the front surface of sheet.
Description of drawings
By the description of the following preferred implementation that provides in conjunction with the accompanying drawings, above and other objects of the present invention, characteristics and advantage will become apparent, wherein:
Fig. 1 is the sectional view that illustrates according to the air vent channels of bonding coat of the present invention;
Fig. 2 shows the adhesive surface that has the bonding coat of air vent channels according to of the present invention; And
Fig. 3 shows the adhesive surface of the bonding coat with air vent channels of another embodiment according to the present invention.
Embodiment
The invention provides a kind of adhesive sheet and preparation method thereof, wherein, when on the surface of tackiness agent, forming jog with the qualification air vent channels, formation has the raceway groove of different depths, make some raceway grooves under low pressure can disappear, to increase bond area, therefore can reach the design level of the bounding force of tackiness agent in a short time.In addition, during the application of sheet, convex-concave surface can discharge the air that is absorbed between adhesive surface and the target surface, and raceway groove can disappear in a short time and increase the slickness of adhesive surface, thereby the jog that prevents tackiness agent appears on the surface of sheet.
In the present invention, use conventional texturizing method on release liner, to press the inverse structure corresponding with air vent channels.Release liner makes by using such as polyethylene or polyacrylic thermoplastic resin coated paper, so that it can be by heat or pressure and easily deformable.
Embossing roller is heated to is about the fusing point that is coated in the resin on the release liner, give figure on the release liner of this embossing roller nip part between through embossing roller and rubber rollers.At this moment, the temperature of embossing roller is preferably 90~160 ℃.If the temperature of embossing roller is too low, then, can not extrude required figure because thermoplastic resin lacks flowability.On the contrary, if the temperature of embossing roller is too high, the then undue fusion of resin can not extrude required figure.
Have different heights and width by the raceway groove that release liner is carried out on the adhesive surface that embossing forms, and be connected with each other, thereby the air that is absorbed in when making application sheet can be discharged into the outside of sheet.
About the height of raceway groove, as shown in Figure 1, air vent channels comprises highly to be 10 μ m or littler low raceway groove (L) 11 and to be the high raceway groove (H) 12 of 10~30 μ m highly.Shown in Fig. 2 and 3, these raceway grooves are connected with each other.If the height of air vent channels is 10 μ m or littler, then raceway groove is easy to disappear usually, causes the air discharging relatively poor.But, if the length of raceway groove is reduced to 4mm or littler, then before raceway groove disappears, can obtain emission effect, and raceway groove is easy to disappear, thereby increase the contact area of itself and target surface, this be increase bounding force and prevent that figure from appearing on the surface of sheet desirable.At this moment, for air is discharged into the outside of sheet from low raceway groove (L) 11, low raceway groove (L) 11 should link to each other with high raceway groove (H) 12.Because raceway groove (H) 12 is higher than the height of low raceway groove (L) 11,, thereby can discharge the air of collecting by low raceway groove (L) 11 from the outside of sheet so high raceway groove is not easy disappearance.Hereinafter, at first the low raceway groove (L) 11 of Xiao Shiing is called " first step raceway groove ", and high raceway groove (H) 12 is called " second stage raceway groove ".
But preferred even first step raceway groove also has the height of at least 3 μ m.This is to be generally 1~2 μ m because be coated in the variation in thickness of the tackiness agent on the release liner, therefore need to guarantee that the height of raceway groove is greater than variation, the height of raceway groove also can cause that when it contacts with target surface raceway groove disappears immediately less than 3 μ m, thereby even can not reach the air emission effect in a short time.
Have 2mm or littler pattern pitch if the length of first step raceway groove shortens to excessively, then reduce the contact area with target surface, thereby reduce initial adhesion power, when sheet adheres to curved part, can cause immediately and separate.Therefore, the figure of the preferred first step and second stage raceway groove formation has the pitch of 2mm at least.
In order to realize effective air discharging, except the height of raceway groove, also should consider the width of raceway groove.If the width of raceway groove is bigger, even then raceway groove can not disappear, flow into raceway groove yet after sheet adheres on the target surface, and reduced the contact area with target surface thereby be used as fluidic, reduced bounding force.On the contrary, if the width of raceway groove is less, then raceway groove can be when application sheet and the air that is absorbed in is just blocked before being discharged.Therefore, each first step raceway groove (L) preferably has the width of 10~30 μ m, and each second stage raceway groove (H) preferably has the width of 30~60 μ m.
Wish that first step raceway groove (L) obtains the air emission effect at short notice, still at the outward flange of sheet, its air discharge function reduces.Therefore, first step raceway groove preferably forms with second stage raceway groove (H) and is connected, thereby makes it have length less than 4mm.That is to say that second stage raceway groove preferably has the pattern pitch less than 4mm.
The section of each raceway groove can have the geometrical shape such as rectangle, trilateral, pentagon and U-shape, and first step raceway groove can have the section shape different with second stage raceway groove.Even the section shape of raceway groove is not a rectangle, except the unusual situation of section shape, the variation of raceway groove is by the maximum height decision of bottom width and raceway groove.Therefore, hereinafter, the bottom width in term " width " dactylotome road, the maximum height in term " highly " dactylotome road.
Mode by transfer printing on the surface of tackiness agent forms such figure.Specifically, on the surface of release liner, apply and dry fluid binder with embossing figure.Dry back tackiness agent preferably has the thickness of 20~50 μ m.After this, substrate by rolling or the casting mode with substrate and its adhesion, thereby make the finished product.
To the present invention be described in more detail in conjunction with following embodiment.
After using film, to the evaluation test of its outward appearance
The specimen of preparation 20 * 20cm adheres to the mode of extruding and transparent acrylic panel then.After adhering to one day, according to its condition of surface and the emission behaviour of the air that is absorbed in film is estimated, evaluation result is classified as follows.
The discharging of air The film condition of surface
Well All air that are absorbed in have been discharged With the naked eye can not identify the figure that the jog on the adhesive surface causes
Medium Give off the air that is absorbed on a small quantity, but do not give off the air that is absorbed in a large number Find the figure that the jog on the adhesive surface causes slightly
Difference Exist the air that is absorbed in a large number not to be discharged from With the naked eye can identify the figure that the jog on the adhesive surface causes
The evaluation of bounding force
Use tension bounding force method of testing to carry out the evaluation of bounding force.According to KS A1107 method of testing, prepare a specimen, and adhere to target object, adhere to and bounding force was estimated in back 20 minutes and 24 hours.
The height of raceway groove and the measurement of width
Release liner is fixed on the flat glass plate, uses SURFTEST 301 surface roughness testers available from Mitutoyo company.When the probe of tester is mobile on release liner, obtain graphic representation, measure the height and the width of embossed lines, be used separately as the height and the width of raceway groove then by this graphic representation.
Embodiment
Be formed for forming the embossed lines figure of raceway groove on the stripper surface of release liner, its specification is listed in the table below in 1.On release liner, apply and dry acryloid cement, and substrate and release liner put together have the adhesive sheet of 30~35 μ m thickness with formation.Peel off this release liner, sheet and acrylic panel adhere to.After one day, the surface of this sheet is level and smooth.After adhering to 20 minutes, bounding force is lower than the bounding force of comparative example 1.But, adhere to 24 hours after, bounding force is similar to comparative example 1.
Comparative example 1
Except not forming the air vent channels, on the stripper surface of release liner according to preparing adhesive sheet with the essentially identical method of embodiment.As following table 1 as can be known, bounding force is the highest, but because the air that is absorbed in makes the outward appearance after adhering to the poorest.
Comparative example 2
On the stripper surface of release liner, only form a kind of raceway groove, use release liner to form adhesive sheet according to the method identical with embodiment with equal height and width.The detail specifications of this raceway groove is shown in Table 1.In comparative example 2, compare with comparative example 1, can prevent easilier that air is absorbed in, but the convex-concave pattern of tackiness agent on the outside surface of sheet, occur.No matter through how long, its bounding force is all than low about 20% of comparative example 1 after adhering to.
Comparative example 3
Even in this comparative example, also be to form a kind of raceway groove according to the specification shown in the table 1, form adhesive sheet according to the method identical with embodiment.Its bounding force does not reduce, but sheet and acrylic panel have been absorbed in air when adhering to.
Comparative example 3-1
In this comparative example, except increase pattern pitch as shown in table 1, form adhesive sheet according to the method identical with comparative example 3.Its bounding force is good, but grievous injury the discharging of air.
Comparative example 4
In this comparative example, as shown in table 1, form a kind of raceway groove.Increase the width of this raceway groove, form adhesive sheet according to same procedure with embodiment.Its bounding force significantly worsens, and the state on film surface is relatively poor.
Comparative example 4-1
In this comparative example, except the height of increase raceway groove as shown in table 1, form adhesive sheet according to the method identical with comparative example 4.Its bounding force significantly worsens, and the non-constant of the state on film surface.
Comparative example 5
In this comparative example, raceway groove (L) and high raceway groove (H) are hanged down in formation as shown in table 1.The width of raceway groove is bigger relatively than embodiment's.Because its poor adhesion is found in the minimizing of initial adhesion area, and finding the state on film surface, some is poor.
Comparative example 6
Just in this comparative example, raceway groove (L) and high raceway groove (H) are hanged down in formation also as shown in table 1.The aspect ratio embodiment's of raceway groove is big relatively.Its bounding force little deterioration, but find that the film condition of surface is very poor.
Table 1
Figure C20068000003900131
Can find that by these comparative examples shown in the table 1 and other subtest when the height of raceway groove was not more than 10 μ m, air can not be discharged effectively, but can keep bounding force.In addition, after adhesive sheet is attached, identify the figure that is caused by the jog on the adhesive surface in order to prevent naked eyes from the front surface of sheet, the height of raceway groove preferably is not more than 20 μ m.
In an embodiment, according to above-mentioned observed result, form two kinds of raceway grooves.When pattern pitch was 2~4mm, shortcoming was that bounding force is lower in a short time, but after advantage is 24 hours, and its bounding force returns on the level similar to comparative example 1, and finds that the outward appearance of this sheet has improvement.
According to the present invention, formation has than the first step raceway groove of low height and the second stage raceway groove with high height, and be connected with each other, make that first step raceway groove can be used as the air vent channels with shorter length in a short time, disappear then providing bigger contact area, and second stage raceway groove can be used as secular air vent channels, causes the application of adhesive sheet to be improved, and prevent that raceway groove from figure occurring on the front surface of sheet, to improve outward appearance.

Claims (4)

1, a kind of adhesive sheet with multi-staged air vent channels, this adhesive sheet comprises basement membrane and pressure-sensitive adhesive layer,
Wherein said bonding coat has the surfacial pattern that the transfer printing by the jog on the release surface of release liner forms, this surfacial pattern is configured to interconnective at least two kinds of raceway grooves, these at least two kinds of raceway grooves comprise height with 3~10 μ m and 10~30 μ m width first step raceway groove and have the height of 10~20 μ m and the second stage raceway groove of the width of 30~60 μ m, and
Described first step raceway groove is with less being spaced, and described second stage raceway groove is with bigger being spaced,
Thereby after described adhesive sheet and target surface adhesion, described first step raceway groove supplies air vent channels in its disappearance prerequisite, this makes because first step raceway groove disappears, increased the bond area with target surface, even and described second stage raceway groove also provides air vent channels after first step raceway groove disappears.
2, adhesive sheet as claimed in claim 1, wherein, described second stage raceway groove is spaced with 2~4mm's, and with the limitation of length of the air vent channels of described first step raceway groove in this size range.
3, a kind of adhesive sheet with multi-staged air vent channels, this adhesive sheet comprises basement membrane, bonding coat and release liner,
Wherein said bonding coat has the embossed surfaces figure on the release surface of release liner, at least two kinds of embossed lines that this embossed surfaces figure is configured to be connected with each other, these at least two kinds of embossed lines comprise height with 3~10 μ m and 10~30 μ m width first step embossed lines and have the height of 10~20 μ m and the second stage embossed lines of the width of 30~60 μ m, and
Described first step embossed lines is with less being spaced, and described second stage embossed lines is with bigger being spaced,
Thereby when peeling off described release liner from described adhesive sheet also with this sheet and target surface adhesion, corresponding to the first step raceway groove of described first step embossed lines since the rheological characteristics of tackiness agent and disappearance prerequisite for air vent channels, thereby along with first step raceway groove disappears, can increase the bond area with target surface, and after first step raceway groove disappears, provide air vent channels corresponding to the second stage raceway groove of described second stage embossed lines.
4, adhesive sheet as claimed in claim 3, wherein, described second stage embossed lines is spaced with 2~4mm's, and the limitation of length of the air vent channels of described first step raceway groove is in this size range.
CNB2006800000397A 2005-01-28 2006-01-11 Adhesive sheet with multi-staged air vent channels Expired - Fee Related CN100572478C (en)

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