CN100570243C - Adopt the adsorption refrigerating device of liquid-storing cartridge heater - Google Patents

Adopt the adsorption refrigerating device of liquid-storing cartridge heater Download PDF

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Publication number
CN100570243C
CN100570243C CNB2008100117185A CN200810011718A CN100570243C CN 100570243 C CN100570243 C CN 100570243C CN B2008100117185 A CNB2008100117185 A CN B2008100117185A CN 200810011718 A CN200810011718 A CN 200810011718A CN 100570243 C CN100570243 C CN 100570243C
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China
Prior art keywords
adsorbent
liquid
inner bag
cartridge heater
storing cartridge
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Expired - Fee Related
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CNB2008100117185A
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Chinese (zh)
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CN101285626A (en
Inventor
金继伟
杨家勇
金柏华
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62Absorption based systems

Abstract

The invention belongs to the refrigerator technical field, particularly a kind of adsorption refrigerating device that adopts liquid-storing cartridge heater comprises high pressure valve, two absorbing cylinders, high pressure line, liquid-storing cartridge heater, the high pressure delivery valve, condenser, reservoir, choke valve, multi-tube evaporator, feed liquor valve, boiler and blower fan, absorbing cylinder is by the absorption urceolus, the adsorbent inner bag, and heating tube and the adsorbent that is contained in this adsorbent inner bag are formed.Contain liquid ammonia in the liquid-storing cartridge heater inner bag.Adsorbent is a compound adsorbent, selects several composition the in calcium chloride, strontium chloride, manganese chloride, nickel chloride, activated carbon fiber, silica gel, graphite powder, graphite lath, active carbon, the aluminium oxide for use.The preparation method of compound adsorbent: each component, graphite lath and tubule with holes are placed in the adsorbent inner bag extrusion forming again.The present invention utilizes the chemisorbed principle, and the heat energy of external heat and the heat energy of chemisorbed heat are mutually combined, and carries out the high temperature heating and cooling, energy-conserving and environment-protective.

Description

Adopt the adsorption refrigerating device of liquid-storing cartridge heater
Technical field
The invention belongs to the refrigerator technical field, particularly a kind of adsorption refrigerating device that adopts liquid-storing cartridge heater.
Background technology
Along with The development in society and economy, increasing to the demand of the energy, power-saving technology also develops rapidly thereupon." absorption type refrigerating " book has been introduced operation principle, device structure and the applicable cases of absorption type refrigerating.The problem of being found in the practical application is that adsorption rate is low, heat time heating time length, complex structure, bulky, involve great expense, therefore be difficult to realize commercialization production.
Utility model patent 20052C091675.8 provides a kind of heat pipe tumbling barrel formula concentration difference energy heat-storing device, belongs to absorption energy storage heating and cooling and generating integration device, because exist smoke emissioning pollution to be difficult to apply with the generating excessive problem of noise.
Summary of the invention
The purpose of this invention is to provide a kind of chemisorbed principle of utilizing, the heat energy of external heat and the heat energy of chemisorbed generation are mutually combined, carry out the adsorption refrigerating device of the employing liquid-storing cartridge heater of high temperature heating and cooling.
The objective of the invention is to realize by following technical proposals:
Adsorption refrigerating device according to employing liquid-storing cartridge heater of the present invention, it is characterized in that comprising two absorbing cylinders that are connected by high pressure valve, by two liquid-storing cartridge heaters that absorbing cylinder is connected of high pressure line and this, by two condensers that absorbing cylinder is connected of high pressure delivery valve and this, the reservoir that is connected of condenser therewith, by the choke valve multi-tube evaporator that is connected of reservoir therewith, this reservoir is connected with described liquid-storing cartridge heater with the feed liquor valve by this choke valve, by the water outlet pipeline, return piping is the boiler that is connected of liquid-storing cartridge heater and by air line and described two blower fans that absorbing cylinder is connected therewith, described absorbing cylinder is by the absorption urceolus, be arranged on the adsorbent inner bag in this absorption urceolus, be arranged on one group of inner bag heating tube in this adsorbent inner bag and be contained in this adsorbent inner bag adsorbent and form, described liquid-storing cartridge heater is by the heating urceolus, be arranged on the storage liquid inner bag in this heating urceolus, the one group of inner bag heating tube that is arranged in this storage liquid inner bag is formed.
Storage liquid inner bag one side of described liquid-storing cartridge heater is connected with described adsorbent inner bag by the high pressure admission valve, and the feed liquor valve that the opposite side of described storage liquid inner bag passes through is connected with described choke valve.
Described one group of inner bag heating tube is evenly distributed in the described attached dose of inner bag, and the mouth of pipe of each inner bag heating tube is connected with urceolus.
Be provided with water pump in described and the back with water inlet line that boiler is connected.
Described boiler is waste heat boiler, electric heat water tank or solar water heater, and described inner bag heating tube is a heat pipe.
The return piping of described boiler also can be simultaneously be connected with two absorption urceolus by valve, described return piping by liquid-storing cartridge heater through two absorption urceolus therewith boiler be connected.
Described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Calcium chloride 20-40%
Strontium chloride 20-40%
Activated carbon fiber 15-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
Described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Magnesium chloride 40-60%
Manganese chloride 15-25%
Nickel chloride 15-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
Described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Active carbon 65-85%
Aluminium oxide 5-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
A kind of preparation method of compound adsorbent of adsorption refrigerating device of described employing liquid-storing cartridge heater is characterized in that:
1) the preparation diameter is the tubule with holes of 6mm,
2) be that the tubule with holes of 6mm evenly is placed in the described adsorbent inner bag with described graphite lath and 2-20 root diameter,
3) simultaneously other each component of adsorbent of described percentage by weight is put into described adsorbent inner bag,
4) will pack into again each component of adsorbent and tubule with holes extrusion forming together in the adsorbent inner bag.
Use the job step of the adsorption refrigerating device of employing liquid-storing cartridge heater of the present invention to be:
In boiler and embodiment that liquid-storing cartridge heater is connected, at first make to be full of liquid ammonia in the liquid-storing cartridge heater, and make the adsorbent in the adsorbent inner bag be filled ammonia;
85 ℃ hot water of reusable heat water tank is heated to 85 ℃ with the liquid ammonia in the liquid-storing cartridge heater, and pressure reaches 13.7Mpa;
These 85 ℃, the ammonia of 13.7Mpa are entered in the adsorbent inner bag of the full ammonia of absorption in advance through the high pressure admission valve, 85 ℃, the ammonia of 13.7Mpa and the adsorbed ammonia of adsorbent in this adsorbent inner bag carry out isobaric desorption, make the ammonia temperature in this adsorbent inner bag reach 160 ℃, pressure reaches 14.7Mpa;
14.7Mpa the ammonia of pressure enters condenser through high pressure delivery valve and distribution pressure pipeline, through blower fan the hot blow of hot ammonia is walked, be condensed into liquid ammonia, this liquid ammonia enters in the surge drum, liquid ammonia in this surge drum enters multi-tube evaporator after the throttling action of choke valve, evaporation is gasified and produced cold air;
Low pressure gas in the multi-tube evaporator enters in another adsorbent inner bag through appendix and turnover pressure valve, and the compound adsorbent that is placed in this adsorbent inner bag is adsorbed, prepares to enter the next refrigeration cycle;
After cycle time, open the feed liquor valve a refrigeration, the liquid ammonia in the surge drum enters in the liquid-storing cartridge heater inner bag through choke valve and feed liquor valve, enters the next refrigeration cycle.Refrigeration is even read in circulation and so forth.
Adopting two adsorbent inner bags is to move continuously in order to carry out alternate cycles, and when promptly an adsorbent inner bag heated, another adsorbent inner bag cooled off.
In boiler and embodiment that two absorbing cylinders are connected, to send in advance the adsorbent inner bag of the full ammonia of absorption respectively from 85 ℃ hot water of 85 ℃ of liquid-storing cartridge heater, the ammonia of 13.7Mpa and boiler and neutralize in another absorbing cylinder, carry out the isothermal and isobaric desorption.
In the component of compound adsorbent, silica gel, graphite powder, these three kinds of components of graphite lath are indispensable, and all the other components can be selected for use according to local resources.
When the compacting compound adsorbent, adopt the compound adsorbent after tubule with holes can make moulding to have air permeability and good, promote the suction-operated and the isobaric desorption of compound adsorbent.
A kind of adsorption refrigerating device that adopts liquid-storing cartridge heater of the present invention is a kind of high adsorption rate, efficient, energy-conservation high-quality refrigerator, and is simple in structure, cheap, the scope of application is extensive, is specially adapted to the waste heat heating and cooling of automobile, boats and ships.
Description of drawings
Fig. 1 is a flowage structure schematic diagram of the present invention.
The specific embodiment
Below in conjunction with description of drawings the specific embodiment of the present invention.
As shown in Figure 1, adsorption refrigerating device according to employing liquid-storing cartridge heater of the present invention, it is characterized in that comprising two absorbing cylinders 3 that are connected by high pressure valve 13, the liquid-storing cartridge heater 11 that is connected by two absorbing cylinders of high pressure line and this, the condenser 5 that is connected by two absorbing cylinders of high pressure delivery valve 4 and this, the reservoir 8 that is connected of condenser 5 therewith, by choke valve 9 multi-tube evaporator 10 that is connected of reservoir 8 therewith, this reservoir 8 is connected with described liquid-storing cartridge heater 11 with feed liquor valve 7 by this choke valve 9, by the water outlet pipeline, return piping is the boiler 17 that is connected of liquid-storing cartridge heater 11 and the blower fan 1 that is connected with described two absorbing cylinders by air line therewith, described absorbing cylinder is by absorption urceolus 16, be arranged on the adsorbent inner bag 15 in this absorption urceolus 16, be arranged on the one group of inner bag heating tube 14 in this adsorbent inner bag 15 and be contained in this adsorbent inner bag adsorbent and form, described liquid-storing cartridge heater 11 is by the heating urceolus, be arranged on the storage liquid inner bag in this heating urceolus, the one group of inner bag heating tube that is arranged in this storage liquid inner bag is formed.Label 6 among the figure is a fan.
Storage liquid inner bag one side of described liquid-storing cartridge heater 11 is connected with described adsorbent inner bag 15 by high pressure admission valve 2, and the feed liquor valve 7 that the opposite side of described storage liquid inner bag passes through is connected with described choke valve 9.
Described one group of inner bag heating tube 14 is evenly distributed in the described adsorbent inner bag, and the mouth of pipe of each inner bag heating tube 14 is connected with urceolus.
Be provided with water pump 12 in described and the water outlet pipeline that boiler 17 is connected.
Described boiler 17 is waste heat boiler, electric heat water tank or solar energy hot water tank, and described inner bag heating tube 14 is a heat pipe.
The return piping of described boiler also can be simultaneously be connected with two absorption urceolus by valve, described return piping by liquid-storing cartridge heater through two absorption urceolus therewith boiler be connected.
Described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Calcium chloride 20-40%
Strontium chloride 20-40%
Activated carbon fiber 15-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
Described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Magnesium chloride 40-60%
Manganese chloride 15-25%
Nickel chloride 15-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
Described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Active carbon 65-85%
Molecular sieve 5-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
A kind of preparation method of compound adsorbent of adsorption refrigerating device of described employing liquid-storing cartridge heater is characterized in that:
1) the preparation diameter is the tubule with holes of 6mm,
2) be that the tubule with holes of 6mm evenly is placed in the described adsorbent inner bag with described graphite lath and 2-20 root diameter, the quantity of tubule with holes depends on the specification of refrigerator, and refrigerator is big more, required tubule with holes
3) simultaneously other each component of adsorbent of described percentage by weight is put into described adsorbent inner bag,
4) will pack into again each component of adsorbent and tubule with holes extrusion forming together in the adsorbent inner bag.
A kind of adsorption refrigerating device that adopts liquid-storing cartridge heater of the present invention is a kind of high adsorption rate, efficient, energy-conservation high-quality refrigerator, and is simple in structure, cheap, the scope of application is extensive, is specially adapted to the waste heat heating and cooling of automobile, boats and ships.

Claims (8)

1, a kind of adsorption refrigerating device that adopts liquid-storing cartridge heater, it is characterized in that comprising two absorbing cylinders that are connected by high pressure valve, by two liquid-storing cartridge heaters that absorbing cylinder is connected of high pressure line and this, by two condensers that absorbing cylinder is connected of high pressure delivery valve and this, the reservoir that is connected of condenser therewith, by the choke valve multi-tube evaporator that is connected of reservoir therewith, this reservoir is connected with described liquid-storing cartridge heater with the feed liquor valve by this choke valve, by the water outlet pipeline, return piping is the boiler that is connected of liquid-storing cartridge heater and by air line and described two blower fans that absorbing cylinder is connected therewith, described absorbing cylinder is by the absorption urceolus, be arranged on the adsorbent inner bag in this absorption urceolus, be arranged on one group of inner bag heating tube in this adsorbent inner bag and the adsorbent that is contained in this adsorbent inner bag and form, described liquid-storing cartridge heater is by the heating urceolus, be arranged on the storage liquid inner bag in this heating urceolus, the one group of inner bag heating tube that is arranged in this storage liquid inner bag is formed.
2, the adsorption refrigerating device of employing liquid-storing cartridge heater according to claim 1, storage liquid inner bag one side that it is characterized in that described liquid-storing cartridge heater is connected with described adsorbent inner bag by the high pressure admission valve, and the feed liquor valve that the opposite side of described storage liquid inner bag passes through is connected with described choke valve.
3, the adsorption refrigerating device of employing liquid-storing cartridge heater according to claim 1 is characterized in that being provided with water pump in described and the back with water inlet line that boiler is connected.
4, the adsorption refrigerating device of employing liquid-storing cartridge heater according to claim 1 is characterized in that described boiler is waste heat boiler, electric heat water tank or solar water heater, and described inner bag heating tube is a heat pipe.
5, the adsorption refrigerating device of employing liquid-storing cartridge heater according to claim 1, the water outlet pipeline that it is characterized in that described boiler is connected with two absorption urceolus by valve simultaneously, described return piping by liquid-storing cartridge heater through two absorption urceolus therewith boiler be connected.
6, the adsorption refrigerating device of employing liquid-storing cartridge heater according to claim 1 is characterized in that described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Calcium chloride 20-40%
Strontium chloride 20-40%
Activated carbon fiber 15-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
7, the adsorption refrigerating device of employing liquid-storing cartridge heater according to claim 1 is characterized in that described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Magnesium chloride 40-60%
Manganese chloride 15-25%
Nickel chloride 15-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
8, the adsorption refrigerating device of employing liquid-storing cartridge heater according to claim 1 is characterized in that described adsorbent is a compound adsorbent, and this compound adsorbent is made up of the component of following weight percentage:
Active carbon 65-85%
Molecular sieve 5-25%
Silica gel 1-3%
Graphite powder 2-4%
Graphite lath 4-6%.
CNB2008100117185A 2008-06-10 2008-06-10 Adopt the adsorption refrigerating device of liquid-storing cartridge heater Expired - Fee Related CN100570243C (en)

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CN100570243C true CN100570243C (en) 2009-12-16

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102744037B (en) * 2012-07-11 2015-09-16 中国第一汽车股份有限公司 Porous storage ammonia mixture sample block containing carbon fiber and preparation method thereof
CN103673376B (en) * 2013-12-24 2015-07-15 金继伟 Heat conversion device with heating and adsorption heat combined

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2679632A1 (en) * 1991-07-26 1993-01-29 Faiveley Sa Installation for producing cold by solid/gas reaction, the reactor including heating means
CN1242227C (en) * 2003-09-18 2006-02-15 上海交通大学 Marine afterheat driven physically adsorbing ice maker

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2679632A1 (en) * 1991-07-26 1993-01-29 Faiveley Sa Installation for producing cold by solid/gas reaction, the reactor including heating means
CN1242227C (en) * 2003-09-18 2006-02-15 上海交通大学 Marine afterheat driven physically adsorbing ice maker

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