CN100562503C - A kind of artificial emerald jade and manufacture method thereof and purposes - Google Patents
A kind of artificial emerald jade and manufacture method thereof and purposes Download PDFInfo
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- CN100562503C CN100562503C CNB200610034305XA CN200610034305A CN100562503C CN 100562503 C CN100562503 C CN 100562503C CN B200610034305X A CNB200610034305X A CN B200610034305XA CN 200610034305 A CN200610034305 A CN 200610034305A CN 100562503 C CN100562503 C CN 100562503C
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- jade
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
A kind of artificial emerald jade and manufacture method thereof and purposes.This artificial emerald jade contains following composition: SiO
262-71 weight %; Al
2O
34-7 weight %; B
2O
30.1-0.4 weight %; CaO 10-15 weight %; K
2O 0.1-0.2 weight %; BaO 2-3.5 weight %; Na
2O10-13 weight %; MgO 0.1-0.3 weight %; Cr
2O
30-0.3 weight %; CuO 0.2-0.5 weight %; The gross weight sum of each component is 100%.The manufacture method of artificial emerald jade of the present invention comprises following processing step: (1) preparation jade green frit; (2) preparation jadite frit; (3) finished product is made in jade green frit and jadite frit is mixed, heat tracing, cooling.Artificial emerald jade of the present invention exactly likes the natural jadeite jade, can be used for making artwork, jewellery, ornament etc.
Description
Technical field
The present invention relates to a kind of artificial crystallite stone material technical field, particularly a kind of artificial emerald jade and manufacture method and purposes.
Background technology
Artificial headdress and the used jade of technology jewelry are divided into natural jadeite jade and synthetic jade at present.The natural jadeite jade originates in Burma, and price is very expensive.And the jade of synthetic adopts resin bond to form mostly, and its main drawback is a non-refractory, and corrosion resistance is poor, and hardness is low, light specific gravity.
Summary of the invention
An object of the present invention is to provide a kind of artificial emerald jade of imitative natural jadeite jade.
Another object of the present invention provides a kind of method of being made artificial emerald jade by the pure natural inorganic materials.
A further object of the present invention provides the purposes of the artificial sad jade of the present invention.
Technical solution proposed by the invention is such:
The invention provides a kind of artificial emerald jade, it contains following composition (weight percent):
SiO
2 62-71％；
Al
2O
3 4-7％；
B
2O
3 0.1-0.4％；
CaO 10-15％；
K
2O 0.1-0.2％；
BaO 2-3.5％；
Na
2O 10-13％
MgO 0.1-0.3％；
Cr
2O
3 0-0.3％；
CuO 0.2-0.5％；
The gross weight sum of each component is 100%.
The purposes of the artificial jade of the present invention, it is used to make artwork, ornament.
The manufacture method of the artificial jade of the present invention, it comprises following processing step:
(1) is heated to 1400 ℃-1600 ℃ with silica powder, lime powder, Feldspar Powder, barium carbonate, soda ash are mixed, makes the fusion of powdery solid substances, be incubated 1-2 hour, then, be put in the jade green clinker that is cooled to the particle shape in the water;
(2) be heated to 1400 ℃-1600 ℃ with silica powder, lime powder, Feldspar Powder, barium carbonate, soda ash, cupric oxide, chromic oxide are mixed, make the fusion of powdery solid substances, be incubated 1-2 hour, then, be put in the jadite frit that is cooled to the particle shape in the water;
(3) with jade green frit and jadite frit in 6～8: be placed on one after 4～2 ratios are mixed and be heated to 1000-1200 ℃, be incubated after 1-2 hour, naturally cool to the room temperature taking-up and be finished product with in the rebasing steel die of asbestos plate.
Above-mentioned frit raw material contains following composition:
SiO
2The 62-71 weight part;
Al
2O
3The 4-7 weight part;
B
2O
30.1-0.4 weight part;
CaO 10-15 weight part;
K
2O 0.1-0.2 weight part;
BaO 2-3.5 weight part;
Na
2O 10-13 weight part;
MgO 0.1-0.3 weight part;
Cr
2O
30-0.3 weight part;
CuO 0.2-0.5 weight part.
Compared with prior art, the present invention has following unusual effect:
(1) the artificial jade of the present invention adopts the pure natural inorganic materials synthetic, can not volatilize harmful organism, and raw material is inexpensive, production cost is low, has high temperature resistant, acid and alkali-resistance at material and aspect of performance, than heavy, than the 2.7-3.0g/cm that weighs
3, specific refractory power reaches 1.55-1.65, and Rockwell hardness reaches 5.1-5.3, and ultimate compression strength reaches 190-200Mpa.
(2) adopt the double-colored frit of preparation, the mixed agglomerating twice firing mode in back earlier in the manufacture method of the artificial jade of the present invention, make the dichromatism frit in mixed sintering process, can obtain Protean mixing shape, resulting artificial emerald jade inside, cooling back has texture or the cloud wadding or the cloud cluster of jadite, exactly likes the natural jadeite jade.Can be used for making artwork, jewellery, ornament etc.
Embodiment
By following embodiment the present invention is further elaborated.
Embodiment 1
Adopt the silica powder shown in the table 1 composed as follows, lime powder, Feldspar Powder, barium carbonate, soda ash to mix and be heated to 1400-1430 ℃, make the fusion of powdery solid substances, be incubated 1 hour, then, put into the jade green frit that water is cooled to the particle shape.
Adopt the silica powder shown in the table 1 composed as follows, lime powder, Feldspar Powder, barium carbonate, soda ash, cupric oxide, chromic oxide to mix and be heated to 1400-1430 ℃, make the fusion of powdery solid substances, be incubated 1 hour, then, put into the jadite frit that water is cooled to the particle shape.
Each components contents in the raw material of table 1 embodiment 1 and jade green frit, the jadite frit
Jade green frit and jadite frit are placed on one in 7: 3 ratios after mixed are heated to 1000 ℃, be incubated after 1 hour, naturally cool to the room temperature taking-up and be finished product with in the rebasing steel die of asbestos slate.
The proportion of artificial emerald jade finished product is 2.7g/cm
3, specific refractory power is 1.55, and Rockwell hardness is 5.1, and ultimate compression strength is 190Mpa.
With the artificial emerald jade that makes through the moulding of artificial engraving, polish smooth wax be jewellery, artwork etc.
Embodiment 2
Adopt the silica powder shown in the table 2 composed as follows, lime powder, Feldspar Powder, barium carbonate, soda ash to mix and be heated to 1570-1600 ℃, make the fusion of powdery solid substances, be incubated 1.5 hours, then, put into the jade green frit that water is cooled to the particle shape.
Adopt the silica powder shown in the table 2 composed as follows, lime powder, Feldspar Powder, barium carbonate, soda ash, cupric oxide, chromic oxide to mix and be heated to 1570-1600 ℃, make the fusion of powdery solid substances, be incubated 1.5 hours, then, put into the jadite frit that water is cooled to the particle shape.
The raw material of table 2 embodiment 2 and jade green frit, jadite frit content
Jade green frit and jadite frit are placed on one in 8: 2 ratios after mixed are heated to 1100 ℃, be incubated after 1.5 hours, naturally cool to the room temperature taking-up and be finished product with in the rebasing steel die of asbestos slate.
The proportion of artificial emerald jade finished product is 2.8g/cm
3, specific refractory power is 1.6, and Rockwell hardness is 5.2, and ultimate compression strength is 194Mpa.
With the artificial emerald jade that makes through the moulding of artificial engraving, polish smooth wax be jewellery, artwork etc.
Embodiment 3
Adopt the silica powder shown in the table 3 composed as follows, lime powder, Feldspar Powder, barium carbonate, soda ash to mix and be heated to 1480-1510 ℃, make the fusion of powdery solid substances, be incubated 2 hours, then, put into the jade green frit that water is cooled to the particle shape.
Adopt the silica powder shown in the table 1 composed as follows, lime powder, Feldspar Powder, barium carbonate, soda ash, cupric oxide, chromic oxide to mix and be heated to 1480-1510 ℃, make the fusion of powdery solid substances, be incubated 2 hours, then, put into the jadite frit that water is cooled to the particle shape.
Each components contents in the raw material of table 3 embodiment 3 and jade green frit, the jadite frit
Jade green frit and jadite frit are placed on one in 6: 4 ratios after mixed are heated to 1200 ℃, be incubated after 2 hours, naturally cool to the room temperature taking-up and be finished product with in the rebasing steel die of asbestos slate.
The proportion of artificial emerald jade finished product is 3.0g/cm
3, specific refractory power is 1.65, and Rockwell hardness is 5.3, and ultimate compression strength is 200Mpa.
With the artificial emerald jade that makes through the moulding of artificial engraving, polish smooth wax be jewellery, artwork etc.
Claims (4)
1, a kind of artificial emerald jade is characterized in that, it contains following composition, represents with weight percent:
SiO
2 62-71％；
Al
2O
3 4-7％；
B
2O
3 0.1-0.4％；
CaO 10-15％；
K
2O 0.1-0.2％；
BaO 2-3.5％；
Na
2O 10-13％；
MgO 0.1-0.3％；
Cr
2O
3 0-0.3％；
CuO 0.2-0.5％；
The gross weight sum of each component is 100%.
2, artificial emerald jade according to claim 1 is characterized in that: its inside has jadite texture and/or cloud cluster.
3, a kind of purposes of artificial emerald jade as claimed in claim 1 is characterized in that: it is used to make artwork, ornament.
4, a kind of method for preparing artificial emerald jade as claimed in claim 1, it is characterized in that: it comprises following processing step:
(1) is heated to 1400 ℃-1600 ℃ with silica powder, lime powder, Feldspar Powder, barium carbonate, soda ash are mixed, makes the fusion of powdery solid substances, be incubated 1-2 hour, then, be put in the jade green frit that is cooled to the particle shape in the water;
(2) be heated to 1400 ℃-1600 ℃ with silica powder, lime powder, Feldspar Powder, barium carbonate, soda ash, cupric oxide, chromic oxide are mixed, make the fusion of powdery solid substances, be incubated 1-2 hour, then, be put in the jadite frit that is cooled to the particle shape in the water;
(3) with jade green frit and jadite frit in 6～8: be placed on one after 4～2 ratios are mixed and be heated to 1000-1200 ℃, be incubated after 1-2 hour, naturally cool to the room temperature taking-up and be finished product with in the rebasing steel die of asbestos plate;
Above-mentioned frit raw material contains following composition:
SiO
2The 62-71 weight part;
Al
2O
3The 4-7 weight part;
B
2O
30.1-0.4 weight part;
CaO 10-15 weight part;
K
2O 0.1-0.2 weight part;
BaO 2-3.5 weight part;
Na
2O 10-13 weight part;
MgO 0.1-0.3 weight part;
Cr
2O
30-0.3 weight part;
CuO 0.2-0.5 weight part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610034305XA CN100562503C (en) | 2006-03-09 | 2006-03-09 | A kind of artificial emerald jade and manufacture method thereof and purposes |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610034305XA CN100562503C (en) | 2006-03-09 | 2006-03-09 | A kind of artificial emerald jade and manufacture method thereof and purposes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1830855A CN1830855A (en) | 2006-09-13 |
| CN100562503C true CN100562503C (en) | 2009-11-25 |
Family
ID=36993381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200610034305XA Expired - Fee Related CN100562503C (en) | 2006-03-09 | 2006-03-09 | A kind of artificial emerald jade and manufacture method thereof and purposes |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962284B (en) * | 2010-09-17 | 2012-09-12 | 广西大学 | Method for synthesizing composite polycrystalline jadeite |
| CN101966995B (en) * | 2010-09-27 | 2012-04-25 | 广西大学 | Method for synthesizing sodium alumino silicate crystal with jade property |
| CN102442816B (en) * | 2011-10-17 | 2013-12-18 | 王蕴渔 | Synthetic grey-white jade and manufacturing method thereof |
| CN105036559B (en) * | 2015-07-01 | 2017-07-11 | 何涌 | A kind of Gem Grade synthesis jadeite seed material and preparation method thereof |
| CN106220142A (en) * | 2016-07-13 | 2016-12-14 | 深圳市超超科技发展有限公司 | Artificial jade based on granite mine tailing and preparation method thereof |
| CN111333334A (en) * | 2018-12-19 | 2020-06-26 | 佛山市晖锐进出口有限公司 | Raw material formula of nano ivory jade |
| CN109913837B (en) * | 2019-04-18 | 2021-04-13 | 辽宁科技大学 | Preparation method of artificial amorphous jade film |
| CN115710121A (en) * | 2022-12-21 | 2023-02-24 | 咸阳陶瓷研究设计院有限公司 | Preparation method of imitation jadeite ceramic ornament |
-
2006
- 2006-03-09 CN CNB200610034305XA patent/CN100562503C/en not_active Expired - Fee Related
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| CN1830855A (en) | 2006-09-13 |
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Granted publication date: 20091125 Termination date: 20160309 |