CN100551651C - A kind of degreasing method of pine veneer - Google Patents

A kind of degreasing method of pine veneer Download PDF

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Publication number
CN100551651C
CN100551651C CNB2007100357254A CN200710035725A CN100551651C CN 100551651 C CN100551651 C CN 100551651C CN B2007100357254 A CNB2007100357254 A CN B2007100357254A CN 200710035725 A CN200710035725 A CN 200710035725A CN 100551651 C CN100551651 C CN 100551651C
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degreaser
degreasing
pine
pine veneer
veneer
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CN101148051A (en
Inventor
李年存
彭万喜
李晓燕
李海燕
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Guangxi Nanning Luyuan Beilin Wood Industry Co., Ltd.
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LI NIANCUN PENG WANXI LI XIAOYAN LI HAIYAN
LI NIANCUN PENG WANXI LI XIAOY
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Abstract

The invention discloses a kind of degreasing method of pine veneer, comprise the steps: (1), degreaser preparation; (2), pine veneer is got the raw materials ready; (3), ungrease treatment.The present invention can make the pine veneer degreasing rate reach more than 70%, and wood color keeps the fresh wood color of pine, and physico-mechanical properties descends less, can satisfy the requirement of furniture fully.This invention have be easy to realize, easy to operate, production cost is low, this technology does not produce waste water, improves the added value of pine, job-creation helps promoting artificial forest resource and ecological, social harmonious development.

Description

A kind of degreasing method of pine veneer
Technical field
The present invention relates to a kind of degreasing method of pine veneer, specifically, relate to a kind of method that removes rosin in the pine veneer.
Background technology
At present, various pines are because the difference of its wood property, rosin content and inclusion, degreasing method is variant slightly, but current degreasing pinewoods method and technology can be concluded five kinds: (1) alkali lye saponification method, (2) solvent extraction, (3) catalyst polymerization, (4) high temperature drying method, (5) boulton process.
Generally, usually adopt two or more degreasing method to combine, but manufacturer is unsatisfactory in actual applications in order to improve degreasing effect.As the degreasing pinewoods rate of utilizing the alkali lye saponification method to handle is low, easy to change, the gloss dimness, and wastewater problem is not basic yet to be solved, and has hindered the development that the pine wood products is produced.
In sum,, obtained considerable progress, also had problems, can not satisfy the requirement in enterprise and market at aspects such as degreasing rate, the anti-variable color processing of degreasing material and degreasing depth though developed many methods in that degreasing pinewoods is technical at present both at home and abroad.Simultaneously, on present degreasing pinewoods theory and technological development, also there are two problems of obviously being badly in need of research:
At first, related in the timber process of manufacture relevant with degreaser infiltration all is non-steady-state permeation process, and the parameter of promptly describing process is the amount relevant with the time.But model in the past is too idealized, and uses steady-state flow data fitting unstable state infiltration mostly.Therefore, set up a theoretical model that meets timber unstable state degreaser infiltration real process, design suitable unstable state degreaser permeability experimental technique, this is an all very important job in theoretical and production application.
Secondly, because measuring large scale test specimen degreaser infiltration coefficient has any problem in practical operation, and the research about the degreasing infiltration all is based on laboratory scale small size test specimen at present, add that the infiltrative variation of degreaser is very big, small size test specimen degreaser permeability has certain limitation in the application of reality, is difficult to the accurately actual degreaser Penetration Signature of reflection large scale test specimen.Thereby the degreaser saturated model of structure large scale timber test specimen, study its permeability, prediction and estimation large scale timber test specimen degreaser infiltration coefficient, can shorten the gap of experimental study and production practices, more effectively be applied in the relevant production reality of timber industry, avoid " large scale effect " to take place.
Therefore, utilize modern test, analysis means, carry out theory and technological innovation, new technology that research and development low cost, high efficiency, low pollution, wood color are fresh, technology maturation and industrialization level are high and new technology are development trends from now on.Applicant of the present invention carries out system research to the pine veneer degreasing, obtains to utilize the technology of efficient degreasing, and this can change the situation that China's pine poor benefit is utilized, and also the sustainable development to China Forest has crucial meaning.
Summary of the invention
Technical problem to be solved by this invention provides and a kind ofly is easy to realize, the degreasing method of easy to operate, environmental protection, pine veneer that production cost is low.
In order to solve the problems of the technologies described above, the degreasing method of pine veneer provided by the invention comprises the steps:
(1), degreaser preparation: utilize ethanol and benzene, according to volume V Ethanol: V Benzene=1.5~2.5: 1 is made into degreaser;
(2), pine veneer is got the raw materials ready: select the thick pine veneer of 0.05~2.5mm;
(3), ungrease treatment: degreaser is filled the degreasing pond, down auxiliary at ultrasonic wave then, 1~10 pine veneer is fixed on the conveyer belt, from the degreasing pond, transport, require pine veneer under the liquid level of degreaser, pine veneer immerse the degreasing liquid level to the time of exposing the degreasing liquid level be 10~60min.
Pine veneer is handled 60min in degreaser, degreasing rate is lower than at 70% o'clock, changes degreaser, and waste and old degreaser carries out distillating recovering solvent, raffinate and the residue rosin for deviating from from pine veneer.
Pine veneer described in the above-mentioned steps (2) is meant the veneer of rotary-cut or slicing, and breadth does not have specific (special) requirements.
Conveyer belt described in the above-mentioned steps (3) is meant the belt or the steel band of anti-degreaser corrosion.
Described distillation is meant under normal pressure and 75~85 ℃, or under vacuum is 0.01Mpa and 45~55 ℃, the separated from solvent in the waste and old degreaser come out.
Adopt the degreasing method of the pine veneer of technique scheme, be to rely on benzene/alcoholic solution the rosin in the veneer to be deviate to the dissolving of rosin, the present invention can make the pine veneer degreasing rate reach more than 70%, wood color keeps the fresh wood color of pine, physico-mechanical properties descends less, can satisfy the requirement of furniture fully.This invention have be easy to realize, easy to operate, production cost is low, what is more important utilizes this technology not produce waste water, improves the added value of pine, job-creation helps promoting artificial forest resource and ecological, social harmonious development.
In sum, the present invention be a kind ofly be easy to realize, the degreasing method of easy to operate, environmental protection, pine veneer that production cost is low.
The specific embodiment
Can further be expressly understood the present invention by specific embodiments of the invention given below, but following embodiment is not a limitation of the invention.
Embodiment 1:
(1), degreaser preparation: according to volume ratio V Ethanol: V BenzeneMix ethanol and benzene at=1.5: 1, is configured to degreaser;
(2), pine veneer is got the raw materials ready: select the thick slicing pine veneer of 2.5mm, the veneer breadth does not have specific (special) requirements;
(3), ungrease treatment: degreaser is filled the degreasing pond, and down auxiliary at ultrasonic wave then, 1 pine veneer is fixed on the steel band, transports from the degreasing pond, requires pine veneer under the liquid level of degreaser, and the ungrease treatment time is 10min;
(4), degreaser reclaims: handle 60min when pine veneer in degreaser, degreasing rate is lower than at 70% o'clock, changes degreaser; Under normal pressure and 75~85 ℃, the separated from solvent in the waste and old degreaser is come out, raffinate and residue rosin for from pine veneer, deviating from.After the degreasing, the veneer color is new green wood wood color, and the physico-mechanical properties variation is no more than 5%.
Embodiment 2:
(1), degreaser preparation: according to volume ratio V Ethanol: V BenzeneMix ethanol, benzene at=2: 1, is configured to degreaser;
(2), pine veneer is got the raw materials ready: select the thick slicing pine veneer of 0.05mm, the veneer breadth does not have specific (special) requirements;
(3), ungrease treatment: degreaser is filled the degreasing pond, and down auxiliary at ultrasonic wave then, 10 pine veneers are fixed on the belt, transport from the degreasing pond, require pine veneer under the liquid level of degreaser, and the ungrease treatment time is 30min;
(4), degreaser reclaims: handle 60min when pine veneer in degreaser, degreasing rate is lower than at 70% o'clock, changes degreaser; Under vacuum is 0.01Mpa and 45~55 ℃, the separated from solvent in the waste and old degreaser is come out, raffinate and residue rosin for from pine veneer, deviating from.After the degreasing, the veneer color is new green wood wood color, and the physico-mechanical properties variation is no more than 5%.
Embodiment 3:
(1), degreaser preparation: according to volume ratio V Ethanol: V BenzeneMix ethanol, benzene at=2.5: 1, is configured to degreaser;
(2), pine veneer is got the raw materials ready: select the thick rotary-cut pine veneer of 2mm, the veneer breadth does not have specific (special) requirements;
(3), ungrease treatment: degreaser is filled the degreasing pond, and down auxiliary at ultrasonic wave then, 10 pine veneers are fixed on the steel band, transport from the degreasing pond, require pine veneer under the liquid level of degreaser, and the ungrease treatment time is 60min;
(4), degreaser reclaims: handle 60min when pine veneer in degreaser, degreasing rate is lower than at 70% o'clock, changes degreaser; Under normal pressure and 75~85 ℃, the separated from solvent in the waste and old degreaser is come out, raffinate and residue rosin for from pine veneer, deviating from.After the degreasing, the veneer color is new green wood wood color, and the physico-mechanical properties variation is no more than 5%.

Claims (5)

1, a kind of degreasing method of pine veneer is characterized in that comprising the steps:
(1), degreaser preparation: utilize ethanol and benzene, according to volume V Ethanol: V Benzene=1.5~2.5: 1 is made into degreaser;
(2), pine veneer is got the raw materials ready: select the thick pine veneer of 0.05~2.5mm;
(3), ungrease treatment: degreaser is filled the degreasing pond, down auxiliary at ultrasonic wave then, 1~10 pine veneer is fixed on the conveyer belt, from the degreasing pond, transport, require pine veneer under the liquid level of degreaser, pine veneer immerse the degreasing liquid level to the time of exposing the degreasing liquid level be 10~60min.
2, the degreasing method of pine veneer according to claim 1, it is characterized in that: pine veneer is handled 60min in degreaser, and degreasing rate is lower than at 70% o'clock, changes degreaser, waste and old degreaser carries out distillating recovering solvent, raffinate and the residue rosin for deviating from from pine veneer.
3, the degreasing method of pine veneer according to claim 1 is characterized in that: the pine veneer described in the above-mentioned steps (2) is meant the veneer of rotary-cut or slicing, and breadth does not have specific (special) requirements.
4, the degreasing method of pine veneer according to claim 1 is characterized in that: the conveyer belt described in the above-mentioned steps (3) is meant the belt or the steel band of anti-degreaser corrosion.
5, the degreasing method of pine veneer according to claim 2 is characterized in that: described distillation is meant under normal pressure and 75~85 ℃, or under vacuum is 0.01Mpa and 45~55 ℃, the separated from solvent in the waste and old degreaser come out.
CNB2007100357254A 2007-09-12 2007-09-12 A kind of degreasing method of pine veneer Expired - Fee Related CN100551651C (en)

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CN100551651C true CN100551651C (en) 2009-10-21

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102837343B (en) * 2012-08-29 2015-04-08 中南林业科技大学 Degreasing method for pines
CN108943236A (en) * 2018-07-26 2018-12-07 湖州亨力木业有限公司 The degreasing method of maple wood

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