CN100545275C - From aluminium plastic composite material, extract the method for aluminium - Google Patents

From aluminium plastic composite material, extract the method for aluminium Download PDF

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Publication number
CN100545275C
CN100545275C CNB2006100696812A CN200610069681A CN100545275C CN 100545275 C CN100545275 C CN 100545275C CN B2006100696812 A CNB2006100696812 A CN B2006100696812A CN 200610069681 A CN200610069681 A CN 200610069681A CN 100545275 C CN100545275 C CN 100545275C
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China
Prior art keywords
aluminium
composite material
plastic composite
separating agent
heating tank
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Expired - Fee Related
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CNB2006100696812A
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Chinese (zh)
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CN101121964A (en
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于福寿
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Individual
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to a kind of method of from aluminium plastic composite material, extracting aluminium.By the aluminium plastic composite material fragment is mixed the back pyroprocessing with organic solvent, make dissolving plastic in the aluminium plastic composite material in organic solvent, the last again aluminium foil that reclaims the pulverizing forms aluminium powder and is used.This method rate of recovery height, production efficiency height.

Description

From aluminium plastic composite material, extract the method for aluminium
Technical field
The present invention relates to a kind of method of from aluminium plastic composite material, extracting aluminium.
Background technology
Plastic-aluminum, aluminium paper compound package material be owing to have excellent performance and be widely used, and all have significantly every year and increase progressively.Application Areas relates to the packing and decorating of industries such as food, medicine, tobacco, advertisement, chemical industry, and modern architecture material such as al-plastics composite pipe.But when the aluminium plastic composite material consumption increases substantially, the aluminium plastic composite material leftover bits and the waste that produce in production and the life also increase with surprising rapidity, because aluminium and plastics all are the materials that is difficult to degrade, if do not handled, these waste materials and waste meeting long-term existence also cause serious environmental to pollute.Though aluminium and plastics all are can be by the material of processing second stage employ, aluminium is in the same place with plastic hybrid in aluminium plastic composite material, brings difficulty to regeneration.Plastics in the aluminium plastic composite material can be burnt by the method for burning, stay wherein nonflammable aluminium, but the waste gas that so produces has caused new environmental pollution, the high temperature that produces when burning simultaneously also can bring difficulty to regeneration with aluminaization.
Summary of the invention
The purpose of this invention is to provide a kind of efficient height, the method for from aluminium plastic composite material, extracting aluminium simple to operation.
For achieving the above object, the present invention adopts following technical scheme:
The method of extracting aluminium from aluminium plastic composite material of the present invention is characterized in that comprising the steps:
A) with the particle of aluminium plastic composite material and separating agent according to 15: put into heating tank after ratio of weight and number (1-8) mixes and heat;
B) controlled temperature is opened the vertical valve of heating tank at 100 ℃-400 ℃, will reclaim after the condensation of separating agent steam introducing cooling tower;
C) when the separating agent in the heating tank all volatilizees, no longer include condensed separating agent in the cooling tower when flowing out, stop, to be cooledly extract being taken out during to normal temperature the heating tank heating.
After above-mentioned steps C takes out extract, with pulverizer extract is pulverized again, sieve, remove Powdered impurity wherein, leave and take wherein granular aluminium powder.
Above-mentioned separating agent be water and organic solvent according to 1: the mixed product of ratio of weight and number (0.5-1.5).
Above-mentioned separating agent is become to be grouped into by following ratio of weight and number:
Water 1000
Organic solvent 500-1500
Soda ash 5-15.
Above-mentioned separating agent be water and kerosene according to 1: the mixed product of ratio of weight and number (0.5-1.5).
Above-mentioned separating agent is become to be grouped into by following ratio of weight and number:
Water 1000
Kerosene 500-1500
Soda ash 5-15.
After adopting such scheme, heat by heating tank, plastics in the aluminium plastic composite material can be by organic solvent dissolution, stay undissolved aluminium and small amount of impurities, the later recovery that is condensed again of organic solvent volatilization, the yield of aluminium is higher in the production process, and the aluminium in the aluminium plastic composite material can all extract, dissolving plastic wherein is in organic solvent, and what can be used as other industry closes matter oil.
Embodiment
Embodiment 1:
Put in the heating tank after the fragment, water, kerosene of getting aluminium-plastic composite paper mixes according to 15: 2: 2 ratio of weight and number and heat, when treating that temperature reaches 260 ℃, controlled temperature, make it be stabilized in 260 ℃, open the vertical valve of heating tank simultaneously, reclaim after steam is introduced the cooling tower condensation, because the fragment proportion of aluminium-plastic composite paper is bigger, heating tank can reach 260 ℃ under normal pressure, guaranteed that promptly production safety has reduced production cost again; When the water in the heating tank with kerosene all volatilizees, no longer include condensed oil in the cooling tower when flowing out, stop the heating tank heating, to be cooledly extract is taken out during to normal temperature.
This moment, the main component of extract was an aluminium, was Powdered surface attached to aluminium foil after having the plastics additive that is insoluble to kerosene on a small quantity to be heated.With pulverizer aluminium foil is pulverized again, sieved, remove Powdered impurity wherein, leave and take the wherein bigger aluminium powder of particle.Owing to lost sticking power after the heating, the plastics additive powder can nature comes off in crushing process, as long as handle a little or sieve and it can be removed.
What condensed oil can be used as other industry from cooling tower closes matter oil.What present embodiment finally can be obtained the aluminium powder of about 3 weight parts and 5 weight parts closes matter oil, and economic benefit and social benefit are considerable.
Embodiment 2:
Put in the heating tank after the fragment, water, kerosene of getting aluminium plastic composite material mixes according to 15: 0.2: 0.8 ratio of weight and number and heat, when treating that temperature reaches 150 ℃, controlled temperature makes it be stabilized in 150 ℃, open the vertical valve of heating tank simultaneously, reclaim after steam is introduced the cooling tower condensation; When the water in the heating tank with kerosene all volatilizees, no longer include condensed oil in the cooling tower when flowing out, stop the heating tank heating, to be cooledly extract is taken out during to normal temperature.
Embodiment 3:
Put in the heating tank after the fragment, water, kerosene of getting aluminium plastic composite material mixes according to 15: 4: 4 ratio of weight and number and heat, when treating that temperature reaches 400 ℃, controlled temperature makes it be stabilized in 400 ℃, open the vertical valve of heating tank simultaneously, reclaim after steam is introduced the cooling tower condensation; When the water in the heating tank with kerosene all volatilizees, no longer include condensed oil in the cooling tower when flowing out, stop the heating tank heating, to be cooledly extract is taken out during to normal temperature.
Embodiment 4:
Put in the heating tank after the fragment, water, kerosene of getting aluminium plastic composite material mixes according to 15: 3: 3 ratio of weight and number and heat, when treating that temperature reaches 300 ℃, controlled temperature makes it be stabilized in 300 ℃, open the vertical valve of heating tank simultaneously, reclaim after steam is introduced the cooling tower condensation; When the water in the heating tank with kerosene all volatilizees, no longer include condensed oil in the cooling tower when flowing out, stop the heating tank heating, to be cooledly extract is taken out during to normal temperature.
Embodiment 5:
Get to put in the heating tank after the fragment of aluminium plastic composite material and kerosene mix according to 15: 5 ratio of weight and number and heat, when treating that temperature reaches 150 ℃, controlled temperature makes it be stabilized in 150 ℃, open the vertical valve of heating tank simultaneously, reclaim after steam is introduced the cooling tower condensation; When the water in the heating tank with kerosene all volatilizees, no longer include condensed oil in the cooling tower when flowing out, stop the heating tank heating, to be cooledly extract is taken out during to normal temperature.
In the various embodiments described above, in order to improve the dissolving power of plastics, can also add an amount of soda ash in heating tank, the ratio of weight and number of aluminium plastic composite material fragment and soda ash is 1000: (0.5-1.5).

Claims (4)

1, from aluminium plastic composite material, extracts the method for aluminium, it is characterized in that comprising the steps:
A) with the particle of aluminium plastic composite material and separating agent according to 15: put into heating tank after the ratio of weight and number of 1-8 mixes and heat;
B) controlled temperature is opened the vertical valve of heating tank at 100 ℃-400 ℃, will reclaim after the condensation of separating agent steam introducing cooling tower;
C) when the separating agent in the heating tank all volatilizees, no longer include condensed separating agent in the cooling tower when flowing out, stop, to be cooledly extract being taken out during to normal temperature the heating tank heating;
D) with pulverizer with step C) extract obtained pulverizes, and sieves, and removes Powdered impurity wherein, leaves and takes wherein granular aluminium powder.
2, the method for extracting aluminium from aluminium plastic composite material according to claim 1 is characterized in that: described separating agent be water and kerosene according to 1: the mixed product of the ratio of weight and number of 0.5-1.5.
3, the method for from aluminium plastic composite material, extracting aluminium according to claim 1, it is characterized in that: described separating agent is become to be grouped into by following ratio of weight and number:
Water 1000
Kerosene 500-1500
Soda ash 5-15.
4, the method for extracting aluminium from aluminium plastic composite material according to claim 1, it is characterized in that: described separating agent is a kerosene.
CNB2006100696812A 2006-08-09 2006-08-09 From aluminium plastic composite material, extract the method for aluminium Expired - Fee Related CN100545275C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006100696812A CN100545275C (en) 2006-08-09 2006-08-09 From aluminium plastic composite material, extract the method for aluminium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2006100696812A CN100545275C (en) 2006-08-09 2006-08-09 From aluminium plastic composite material, extract the method for aluminium

Publications (2)

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CN101121964A CN101121964A (en) 2008-02-13
CN100545275C true CN100545275C (en) 2009-09-30

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103397188B (en) * 2013-07-22 2015-01-21 南南铝业股份有限公司 Organic scrap-containing aluminum regeneration method
CN105420513B (en) * 2015-11-13 2017-08-25 惠州市富济电子材料有限公司 A kind of inorganic agent separated for aluminum alloy resin complex

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
废铝塑分离回收铝技术. 李金钟.农村新技术,第10期. 2002
废铝塑分离回收铝技术. 李金钟.农村新技术,第10期. 2002 *
废铝塑片的回收和利用. 马新起,李明静,张希兰,王玉兰.河南化工,第8期. 1995
废铝塑片的回收和利用. 马新起,李明静,张希兰,王玉兰.河南化工,第8期. 1995 *
聚乙烯铝塑复合包装材料的一种回收与利用技术. 王崇臣,王鹏.北京建筑工程学院学报,第21卷第4期. 2005
聚乙烯铝塑复合包装材料的一种回收与利用技术. 王崇臣,王鹏.北京建筑工程学院学报,第21卷第4期. 2005 *

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