CN100541305C - A kind of method for preparing non-linear optical organic film - Google Patents
A kind of method for preparing non-linear optical organic film Download PDFInfo
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- CN100541305C CN100541305C CN 200610036395 CN200610036395A CN100541305C CN 100541305 C CN100541305 C CN 100541305C CN 200610036395 CN200610036395 CN 200610036395 CN 200610036395 A CN200610036395 A CN 200610036395A CN 100541305 C CN100541305 C CN 100541305C
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Abstract
The present invention designs the optical thin film preparation field, and purpose is to overcome deficiency of the prior art, and a kind of method and organic solvent thereof that can the easy manufacture non-linear optical organic film be provided.Adopt the repetition spin coating technique that organic dyestuff/organic group membrane material colloidal sol is coated with on substrate.Being applied in the preparation of non-linear optical organic film repeating spin coating technique, is a kind of new application of existing method, greatly reduces cost of manufacture, has improved the quality of product.Described organic solvent adopts the organic solvent of boiling point between 100 ℃～250 ℃.Particularly adopt cyclohexanone to have best effect as organic solvent.
Description
Technical field
The present invention relates to the optical thin film preparation field, say so more specifically a kind of be used to the prepare method of non-linear optical organic film and the solvent of employing thereof.
Background technology
In the optical thin film specimen preparation process, the requirement of its optical property is very high, and the quality of film sample preparation is to photonics and the preparation of optoelectronics functional material and study most important.In recent years, be that the chemical method of representative prepares optical thin film and more and more is subject to people's attention with sol-gel (sol-gel) method, it has developed into the strong rival of conventional physical method plated film.This mainly is that the chemical method plated film has following advantage: 1) preparation technology is a normal temperature and pressure; 2) film purity and optical quality height; 3) device for coating and preparation expense are low; 4) coating process easily transforms to industrialization.The main method that sol-gel process prepares optical thin film has methods such as dipping coating method, spin-coating method, splash coating method, The tape casting, meniscus coating method and coating coating method etc.Spin-coating method is that colloidal sol is added drop-wise on the substrate, is horizontally rotated by the substrate high-speed smooth, and the centrifugal force of rotation is thrown colloidal sol away and uniform spreading film forming on substrate.The spin coating instrument that spin-coating method uses is simple relatively, and from flatness, the compactness extent of filming, the accurate control equal angles of firm degree that film is connected with substrate and film thickness is considered all to have superiority.
Dye adulterated with azo chromophore at present to material of main part, as polymethylmethacrylate (PMMA) organic glass, preparation nonlinear optical film material is a focus of research, to requiring its thickness at tens to more than 100 micrometer ranges under the many situations of the optical thin film of this class, its nonlinear optical effect is stronger.If adopt the prepared optical thin film general thickness of once spin-coating method several to tens micrometer ranges, can't make the satisfactory optical thin film of thickness, therefore optical non-linear effect is very weak or can't show, has influenced preparation and research to optical functional materials.Many research reports are to adopt the casing process film forming to azobenzene polymer, but the smooth smoothness of film surface is not good enough.
The report that the aspect that repeats to film is also arranged in the existing spin-coating technology, such as in order to prepare the nano NiO film of different-thickness, that use in preparation technology is PEG6000/Ni (OH)
2The organic/inorganic complex sol, form solvent with a certain proportion of water and ethanol, behind every coating film bone dry, film again next time, but, therefore do not provide the test result of optical property aspect because the film that makes not is to be used in the nonlinear optics aspect.The results showed, this method is because relatively poor at drying layer (gel) and wet layer (colloidal sol shape) interpenetrating property, the rotation film forming is the formation interface between each layer easily, especially stronger to volatility solvent, to transmission light-scattering layer, thereby light is produced anisotropy, form signal at the bottom of the bigger trimmed book, reduced the processing of light signal and the performance of photoswitch.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, a kind of method that can the easy manufacture non-linear optical organic film is provided.
Further purpose of the present invention provides a kind of organic solvent that is adopted in preparation non-linear optical organic film process.
The method for preparing non-linear optical organic film of the present invention adopts the repetition spin coating technique that organic dyestuff/organic group membrane material colloidal sol is coated with on substrate.In the prior art, the technology that repeats spin coating also shall not be applied in the field of preparation non-linear optical organic film, and it is poor generally to be used for the technology film-formation result of casting in field of non-linear optical organic film, therefore still need be improved.At the present situation of prior art, the present invention will repeat to be a kind of new application of existing method, thereby to have improved the quality of non-linear optical organic film in the preparation that spin coating technique is applied to non-linear optical organic film.
Because existing repetition spin coating technique is not to design at the preparation non-linear optical organic film, so also must do further improvement, repetition spin coating of the present invention prepares non-linear optical organic film and comprises the steps:
1. organic dyestuff/organic group membrane material is dissolved in the organic solvent by a certain percentage, makes organic dyestuff/organic group membrane material sol liquid;
2. with the organic dye/even covering substrate of organic group membrane material sol liquid for preparing, start film applicator and carry out low speed and high speed rotating respectively, make organic dye/organic group membrane material colloidal sol on substrate, form the film of 10 micron dimensions;
3. wait for that organic solvent evaporates into the typing of filming naturally and carries out spin coating next time when dry;
4. according to required preparation organic film thickness, 2.～3. repeating step meets the requirements to film thickness.
The method overcomes the shortcoming of existing spin coating technique to preparation organic optical film, and the thickness of preparation film is tens even more than 100 micrometer range, and is little and present the isotropy of height and the low light level had than high light and learn nonlinear effect to transmission light-scattering layer.3. finalize the design almost behind the dry several hrs of film forming in and not during bone dry in step, the back rete engaging zones under the effect of organic solvent of filming that carries out next time has fused preferably property, therefore causes that the sudden change of film bonding land will reduce greatly because interlayer drying shrinks.The control of this condition is very crucial for the effect of preparation non-linear optical organic film, adopt different organic solvents to cause the interval time of twice spin coating different, do not wait from several seconds to several hrs, the time interval between twice spin coating of strict control is that existing spin coating technique is not available.
Because need the interval time between twice spin coating of strictness control, institute thinks convenient the making, should adopt the more weak organic solvent of volatility, helps the control of time like this, the better effects if of the product of feasible preparation reduces technology difficulty.The present invention is best, and the organic solvent that adopts adopts the organic solvent of boiling point between 100 ℃～250 ℃, and the 3. middle time of waiting for of step is 2.5～3.5 hours.If adopt the organic solvent of high volatility, the time of the bone dry of filming has only several seconds, carries out the spin coating second time in the so short time, and is all very high to the precision requirement of technology and equipment.If a little less than adopting volatility too, wait for that the time of the typing of filming is oversize, then be unfavorable for the batch process of product.The boiling point of the organic solvent that the present invention selects for use is between 100 ℃～250 ℃, the long time interval is arranged between shaping film and bone dry like this, in the control of carrying out spin coating next time, have bigger dynamic role, greatly reduce technology difficulty, and help large batch of production.
Through overtesting, the best of the present invention is to adopt PMMA as organic dyestuff/organic group membrane material, adopts cyclohexanone as organic solvent.PMMA and cyclohexanone are made organic dyestuff/organic group membrane material sol liquid by the mass percent of 0.5wt%～10wt%.Solution is filtered, mix with organic dyestuff/organic group membrane material again and stirred 1～3 hour, next mixed liquor is carried out suction filtration, obtain impure less organic dyestuff/organic group membrane material sol liquid, leave standstill colloidal sol at last and observed deposit-free matter in 15～30 hours.The low speed of film applicator is in the 300-400r/min scope, and the time is 4-6s; In the 1000-1800r/min scope, the time is 5-10s at a high speed.A little less than the cyclohexanone volatility, need to finalize the design almost with the air dry rear film in 3 hours and just can carry out filming next time.
Another object of the present invention provides a kind of organic solvent that is applicable to said method, and described organic solvent adopts the organic solvent of boiling point between 100 ℃～250 ℃.Particularly adopt cyclohexanone to have best effect, generally organic dye/organic group membrane material and cyclohexanone are made organic dyestuff/organic group membrane material sol liquid by the mass percent of 0.5wt%～10wt% as organic solvent.
The present invention has following outstanding substantive distinguishing features and obvious improvement for prior art.
1. the technology that adopt to repeat spin coating prepares non-linear optical organic film, and to have technology simple, in advantages such as the non-linear effect of more than tens to 100 microns of preparation products are good;
2. in the time interval between twice spin coating of strict control, can improve yield rate and product quality;
3. the organic solvent that employing volatility is weak helps the control of time, reduces technology difficulty;
4. adopt PMMA to have best spin coating effect as organic solvent as organic dyestuff/organic group membrane material and cyclohexanone.
Description of drawings
Fig. 1 is the structural representation of film sample photoanisotropy experimental apparatus for testing.
Embodiment
The present invention is described further below in conjunction with accompanying drawing, for advantage of the present invention more specifically is described, has adopted multiple condition and technology to prepare non-linear optical organic film among the embodiment, and its test findings is analyzed.
The present invention mainly is the preparation of nonlinear optics organic film to the research that optical functional film prepares the aspect, and adopts the method for sol-gel and repetition spin-coating film to prepare optical thin film.Polymer-doped material of main part is PMMA, and guest materials is ethyl red Ethyl Red, and it is that (the sailing boat board No.7101), soaked several hours and with deionized water soaking and washing and dry with acetone for the microslide of 1mm-1.2mm that substrate adopts 25.4 * 76.2mm, thickness.Organic solvent is selected methenyl choloride (61.2 ℃ of boiling points) respectively for use, cyclohexanone (boiling point 154-156 ℃).
Being formulated as follows of colloidal sol: at first with PMMA and above-mentioned two kinds of chromophore's material ethyl red 0.6wt%, 0.8wt%, 2wt%, 6wt% weighings by mass percentage respectively, dissolve respectively with above-mentioned several solvents, overanxious to dye solution, mix with PMMA solution again and stirred 2 hours, again PMMA/ dyestuff mixed liquor is carried out suction filtration, obtain impure less PMMA/ dye sols liquid, leave standstill colloidal sol again and observed deposit-free matter in 24 hours.
Earlier colloidal sol is evenly dripped on the microslide and with glass rod during spin-coating colloidal sol is covered microslide, the low speed of film applicator is in the 300-400r/min scope, and the time is 4-6s; In the 1000-1800 scope, the time is 5-10s at a high speed.A general spin-coated thin film thickness is at tens to 20 micrometer ranges.The fused degree that repeats to film between the rete is an emphasis of the present invention, selects different to repeat the time interval of filming, and sees the following form 1.The methenyl choloride high volatility, the caudacoria substantially dry of at every turn filming typing, the time interval that therefore repeats to film influence is less; A little less than the cyclohexanone volatility, filming next time needs to finalize the design almost with the air dry rear film and can carry out in 3 hours.Surface structure from the different solvents film forming of once filming, cyclohexanone is better than methenyl choloride, experimentally the optic test result has also proved this point, simultaneously a little less than the adhesion of methenyl choloride solvent film and microslide, be prone to film and microslide segregation phenomenon, and the cyclohexanone solvent film is strong and the strong adhesion of microslide.Consider a little less than the cyclohexanone volatility, behind the dry several hrs of film forming, finalize the design almost and bone dry not, the back rete engaging zones under the effect of organic solvent of filming that carries out next time has fused preferably property, therefore cause that the sudden change of film bonding land will reduce greatly because interlayer drying shrinks, this is consistent with optic test result in the table 1.Experiment is carried out under chemical laboratory and room temperature 22-25 ℃ condition.
The anisotropy proving installation that transmitted light is produced of film sample as shown in Figure 1, (632.8nm CW) plays inclined to one side transmission film sample through the polarizer to He-Ne laser, again through the analyzer analyzing.The polarizer is vertical mutually with the analyzer polarization direction.The emergent light of analyzer is by photo-detector (Photo detector, form by photodiode and low noise prefix operation amplifier OP07 etc.) detect, again by high-speed data acquisition card (NI5102, America NI company product, software platform Lab View 7.0) makes automatic data collection and by Computer Processing.When not putting into film sample, because the polarizer is vertical mutually with the analyzer polarization direction, so the analyzer emergent light is zero, and photo-detector receives zero light intensity signal, thus with 0 volt of voltage signal as reference light level signal.When putting into film sample, even more and the smooth smoothness of film surface is high more when the film sample inner structure, then the scattering that transmitted light is produced is more little, and it is also just more little that analyzer detects light intensity; When film sample because the inhomogeneous or impurity of inner structure produces anisotropy to the not good enough transmitted light that makes of the smooth smoothness of light scattering and film surface, the relative polarization of incident light direction in the polarization direction of transmitted light changes, therefore to detect light intensity non-vanishing for analyzer, and the size of this light intensity has reflected the size of transmitted light anisotropy degree.Film has a maximum orientation to the relative linearly polarized light of anisotropy that light produces, when being that axle rotates the light intensity variation that sample one Zhou Zeke detects maximum with the incident light, therefore can compare the homogeneity of optical thin film inner structure and the smooth smoothness of film surface by the variation of largest light intensity.Test is selected 4 different points of film to carry out and is got the quality of the maximum data represented film of wherein light intensity variation.Below table 1 be that light intensity is arbitrary unit (a.u) in the table 1 to the result of the part film sample produced test, we have considered that also the difference of thickness, doping content of film is to the influence of test result in the test.
Table 1. film sample optic test result:
| The doped polymer film | Ratio wt% | Solvent | The mode of filming | Repeat the time interval of filming | Film thickness/μ m | Maximum variation/the a.u of transmitted light intensity |
| Ethyl red/PMMA | 0.6 | Methenyl choloride | A spin coating | 13 | 3.5 | |
| Ethyl red/PMMA | 0.6 | Methenyl choloride | A spin coating | 17 | 3.2 | |
| Ethyl red/PMMA | 0.6 | Methenyl choloride | The secondary spin coating | 30s | 34 | 51 |
| Ethyl red/PMMA | 0.6 | Methenyl choloride | The secondary spin coating | 24h | 28 | 56 |
| Ethyl red/PMMA | 0.6 | Methenyl choloride | Three spin coatings | 30s | 50 | 110 |
| Ethyl red/PMMA | 0.8 | Methenyl choloride | A spin coating | 15 | 4.2 | |
| Ethyl red/PMMA | 0.8 | Methenyl choloride | The secondary spin coating | 20s | 36 | 82 |
| Ethyl red/PMMA | 0.8 | Methenyl choloride | The secondary spin coating | 24h | 32 | 88 |
| Ethyl red/PMMA | 2 | Methenyl choloride | Casting | 80 | 210 | |
| Ethyl red/PMMA | 0.8 | Cyclohexanone | A spin coating | 13 | 1.6 | |
| Ethyl red/PMMA | 0.8 | Cyclohexanone | The secondary spin coating | 3h | 28 | 2.0 |
| Ethyl red/PMMA | 0.8 | Cyclohexanone | The secondary spin coating | 36h | 30 | 7.2 |
| Ethyl red/PMMA | 2 | Cyclohexanone | A spin coating | 15 | 1.8 | |
| Ethyl red/PMMA | 2 | Cyclohexanone | The secondary spin coating | 3.5h | 30 | 1.9 |
| Ethyl red/PMMA | 2 | Cyclohexanone | The secondary spin coating | 48h | 35 | 7.8 |
| Ethyl red/PMMA | 6 | Cyclohexanone | A spin coating | 12 | 1.6 | |
| Ethyl red/PMMA | 6 | Cyclohexanone | The secondary spin coating | 3h | 40 | 3.2 |
| Ethyl red/PMMA | 6 | Cyclohexanone | The secondary spin coating | 36h | 38 | 6.8 |
| Ethyl red/PMMA | 6 | Cyclohexanone | Three spin coatings | 3h | 62 | 4.5 |
| Ethyl red/PMMA | 6 | Cyclohexanone | Three spin coatings | 48h | 59 | 10.3 |
| Ethyl red/PMMA | 6 | Cyclohexanone | Four spin coatings | 4h | 84 | 4.6 |
| Ethyl red/PMMA | 6 | Cyclohexanone | Four spin coatings | 48h | 81 | 13.5 |
| Ethyl red/PMMA | 6 | Cyclohexanone | Five spin coatings | 3h | 102 | 4.5 |
| Ethyl red/PMMA | 6 | Cyclohexanone | Six spin coatings | 3h | 121 | 4.6 |
| Ethyl red/PMMA | 6 | Cyclohexanone | Casting | 92 | 62.5 |
The test result of table 1 can obtain following some conclusion:
1) solvent selects for use the influence of counterweight overcoating film quality bigger.The sample that with methenyl choloride is solvent is bigger slightly than the sample (1.6-1.8) with cyclohexanone solvent at its largest light intensity variable quantity (3.2-3.5) of once filming, but both differ big (51-56)/(2.0-6.8) after secondary is filmed, variation difference after filming for three times is just bigger, and the film of cyclohexanone solvent reaches its light intensity of 120 μ m at six coating thicknesses to be changed and still remain on low value (4.6).Therefore, the solvent of high volatility is unfavorable for repeating to film, but the precision of control by improving processing technology and equipment still can remedy this shortcoming.
2) time interval influence that repeats to film has certain influence.The solvent stronger to volatility, because degree dry after the film forming is higher, the time effects that is repeated to film is less, is the sample of solvent as methenyl choloride, film after 30 seconds with 24 hours after film its test light intensity be changed to 51/56, light intensity is changed to 8.9% relatively; To the solvent a little less than the volatility, because degree dry after the film forming is lower, the surperficial difference of shrinking of its film was also bigger when the time interval difference that repeats to film was big, therefore the time effects that is repeated to film is bigger, filming as the sample secondary of cyclohexanone solvent that different time changes after its light intensity is 3.2/6.8, it differs to about 50%, four time its light intensity of filming changes is 4.6/13.5, and it differs and is about 52%.
3) not good with the smooth smoothness on its surface of casing process film forming, optic test its light intensity variable quantity as a result and is difficult for improving by selective solvent the quality on film surface more than 65, and therefore the thicker nonlinear optical film of preparation should adopt the repetition spin-coating method.
The optical thin film of preparation is being made photic birefringence effect and all-optical switch Study on Effect result shows, the film sample of cyclohexanone solvent is better than the film sample that methenyl choloride is a solvent, its reason is the dipole moment=2.87/D of cyclohexanone solvent, and methenyl choloride dipole moment=1.04/D, cyclohexanone belongs to intensive polar solvent, help the orientation reorganization of film molecule under the optical excitation, thereby show stronger optical non-linear effect.
Claims (2)
1. method for preparing non-linear optical organic film is characterized in that adopting and repeats spin coating technique organic dyestuff/organic group membrane material colloidal sol is coated with on substrate, specifically may further comprise the steps:
1. be dissolved in organic dyestuff/organic group membrane material in the organic solvent by a certain percentage, make organic dyestuff/organic group membrane material sol liquid: adopt PMMA as organic dyestuff/organic group membrane material, adopt cyclohexanone as organic solvent, PMMA and cyclohexanone are made organic dyestuff/organic group membrane material sol liquid by the mass percent of 0.5wt%～10wt%;
2. with the organic dye/even covering substrate of organic group membrane material sol liquid for preparing, start film applicator and carry out low speed and high speed rotating respectively, make organic dye/organic group membrane material colloidal sol on substrate, form the film of 10 micron dimensions; Described low speed is in the 300-400r/min scope, and the time is 4-6s; In the 1000-1800r/min scope, the time is 5-10s at a high speed.
3. wait for that organic solvent evaporates into the typing of filming naturally and carries out spin coating next time when dry, the time of wait is 2.5～3.5 hours;
4. according to required preparation organic film thickness, 2.～3. repeating step meets the requirements to film thickness.
2. the method for preparing non-linear optical organic film according to claim 1, it is characterized in that described step concrete steps 1. are that solvent is filtered, mix with organic dyestuff/organic group membrane material again and stirred 1～3 hour, next mixed liquor is carried out suction filtration, obtain impure less organic dyestuff/organic group membrane material sol liquid, leave standstill colloidal sol at last and observed deposit-free matter in 15～30 hours.
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| CN104445988A (en) * | 2014-11-14 | 2015-03-25 | 福建农林大学 | Multilayer titanium oxide antireflection film with long-acting super hydrophilicity and preparation method of antireflection film |
| CN109827850A (en) * | 2019-01-15 | 2019-05-31 | 广东工业大学 | A kind of fexible film stretch bending device |
| CN112195504B (en) * | 2019-10-29 | 2021-07-06 | 天津大学 | Method for growing two-dimensional organic single crystal |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5459232A (en) * | 1992-07-13 | 1995-10-17 | Fujitsu Limited | Nonlinear optical material, process of production of same, and nonlinear optical device and directional coupling type optical switch using same |
| CN1417030A (en) * | 2001-09-04 | 2003-05-14 | 佳能株式会社 | Record unit, image recorder and image recording method |
| CN1441923A (en) * | 2000-05-31 | 2003-09-10 | Fsi国际公司 | Coating method and coating device |
| CN1534378A (en) * | 2003-03-27 | 2004-10-06 | ���﹤ҵ��ʽ���� | Transparent coloured composition and colour filter |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5459232A (en) * | 1992-07-13 | 1995-10-17 | Fujitsu Limited | Nonlinear optical material, process of production of same, and nonlinear optical device and directional coupling type optical switch using same |
| CN1441923A (en) * | 2000-05-31 | 2003-09-10 | Fsi国际公司 | Coating method and coating device |
| CN1417030A (en) * | 2001-09-04 | 2003-05-14 | 佳能株式会社 | Record unit, image recorder and image recording method |
| CN1534378A (en) * | 2003-03-27 | 2004-10-06 | ���﹤ҵ��ʽ���� | Transparent coloured composition and colour filter |
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Application publication date: 20061213 Assignee: Winda Opto-Electronic Co., Ltd. Assignor: Zhanjiang Normal University Contract record no.: 2010440000414 Denomination of invention: Method for preparing non-linear optical organic film and solvent therefor Granted publication date: 20090916 License type: Exclusive License Record date: 20100416 |
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