CN100534574C - Technics of preparing sparse oil porous ceramic filtering material - Google Patents
Technics of preparing sparse oil porous ceramic filtering material Download PDFInfo
- Publication number
- CN100534574C CN100534574C CNB2007100526341A CN200710052634A CN100534574C CN 100534574 C CN100534574 C CN 100534574C CN B2007100526341 A CNB2007100526341 A CN B2007100526341A CN 200710052634 A CN200710052634 A CN 200710052634A CN 100534574 C CN100534574 C CN 100534574C
- Authority
- CN
- China
- Prior art keywords
- ceramic filter
- filter material
- curing agent
- diluent
- filtering material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Filtering Materials (AREA)
Abstract
The lipophobic filtering material preparing process includes the following steps: 1. washing ceramic filter ball of 3-5 mm granularity in water and stoving to obtain ceramic filter material; 2. compounding modifying solution with no-benzene eco-friendly paint, curing agent and diluent in the volume ratio of 1 to 0.5-0.8 to 0.6-1, and through mixing; and 3. soaking the ceramic filter material inside the modifying solution through stirring at room temperature and drying naturally to obtain the lipophobic filtering material. Thus obtained lipophobic filtering material has the features of high oil eliminating rate, easy cleaning, high mechanical strength and long service life.
Description
Technical field
The present invention relates to a kind of preparation technology of oleophobic property filtrate.
Background technology
Oily waste water treatment process commonly used is at present: oil removal-coagulation (air supporting)-filtration.Wherein air supporting is to utilize particular device, under certain pressure with air dissolves in water, preparation meets the dissolved air water of air supporting requirement; In oily waste water, feed the dissolved air water that contains a large amount of micro-bubbles again, utilize micro-bubble to catch and adhere in the waste water and take off steady little oil droplet, form whole proportion less than the buoyancy aid of water and rely on buoyancy to float to obtain to the water surface oil, moisture from a kind of method, but conventional press dissolved air flotation treating apparatus is scraped the slag residue extraction mechanism and is constituted by air compressor, pressure air-dissolving jar, decompression release device, flotation tank, machinery, equipment is many, long flow path, volume is big.
Summary of the invention
The object of the present invention is to provide that a kind of deoiling effect is good, the preparation technology of the sparse oil porous ceramic filtering material of easy cleaning, mechanical strength height, long service life.
To achieve these goals, technical scheme of the present invention is: a kind of preparation technology of sparse oil porous ceramic filtering material is characterized in that it comprises the steps:
1) be that the enviroment protective ceramic filter bulb of 3～5mm is scrubbed with clear water with particle diameter, then 100～110 ℃ of oven dry down, pretreated ceramic filter material;
2) preparation modified solution: press no benzene ecological paint: curing agent: no benzene ecological paint, curing agent and diluent are chosen in the volume ratio of diluent=1: 0.5～0.8: 0.6～1, curing agent is mixed with no benzene ecological paint, add diluent after stirring again, after fully stirring once more, get modified solution; Described curing agent is PIC or polyamide, and described diluent is butyl acetate or acrylate monomer;
3) pretreated ceramic filter material is joined in the modified solution, the addition of pretreated ceramic filter material is as the criterion so that pretreated ceramic filter material is just wetting, at room temperature stirs, and spreads out then, after the air dry, gets sparse oil porous ceramic filtering material.
Described ceramic filtration ball is a Chinese invention patent number: ZL200310111209.7 (inventor: Wu Jianfeng) the enviroment protective ceramic filter bulb of manufacturing.Particular content is as follows:
The manufacture method of enviroment protective ceramic filter bulb comprises the steps:
1). batching: by weight percentage, alumina laterite 15～30, flyash 20～40, gangue 10～30, clay 10～15, pore former 20～40, high temperature adhesive 3～6;
2). pulverize: with ball mill pulverizing, mix, 100～180 orders that sieve then are standby with above-mentioned raw materials;
3). balling-up: before the balling-up, low temperature binder and water are made into mixed liquor with 1: 2 weight ratio in entry, spray into gradually in the blank of nodulizer again, reach water content 3～8%, adopt the nodulizer balling-up then;
3). drying: 80～120 ℃ of dryings 4～5 hours;
4). fire: above-mentioned dried ball is burnt till at 1100 ℃～1250 ℃;
Described high temperature adhesive is any or the mixing more than two kinds in nepheline orthoclase, spodumene or the potassic feldspar, is any proportioning during mixing more than two kinds;
Described low temperature binder is any or the mixing more than two kinds in carboxymethyl cellulose, waterglass or the aluminium dihydrogen phosphate, is any proportioning during mixing more than two kinds.
Described pore former is any or the mixing more than two kinds in sawdust or the dolomite, is any proportioning during mixing more than two kinds.
Described drying is: will become good ball to put into the dry drawer of the dry base car of drawer type, and push the dry base car of drawer type, 80～120 ℃ of dryings 4～5 hours.
Described fire for: above-mentioned dried ball is reinstalled in the pallet saggar of pallet saggar car.
The invention has the beneficial effects as follows: by to hydrophilic ceramic filtration ball (Chinese invention patent number: the enviroment protective ceramic filter bulb of ZL200310111209.7 manufacturing) carry out modification, make hydrophilic ceramic filtration ball become oleophobic property filtrate (being sparse oil porous ceramic filtering material).The sparse oil porous ceramic filtering material of the present invention's preparation is applied to the coarse of oily waste water, one side can be agglomerated into big particle diameter oil droplet with the dispersed oil of oil emulsion through taking off steady (polyaddition aluminium chloride) processing and small particle diameter and remove, thereby increase the clearance (clearance that does not have the ceramic filtration ball of modification under same experiment condition is 22.8%, and the oil removal rate of the sparse oil porous ceramic filtering material after the modification is 66.67%) of oil; Tackle the suspension of big particle diameter on the other hand by machinery, thereby alleviated the load of follow-up technology of fine filtering effectively.[use the clear water backwash, intensity is 20L/ (m to the sparse oil porous ceramic filtering material easy cleaning simultaneously
2S), the backwash time is 15min], mechanical strength higher (crushing strength is 18.2MPa), long service life (minimum) more than 1 year.
The coarse technology of using the sparse oil porous ceramic filtering material of the present invention's preparation and forming, technology is simple, and is applied widely, all can adopt oily waste water.
The specific embodiment
In order to understand the present invention better, further illustrate content of the present invention below in conjunction with embodiment, but content of the present invention not only is confined to the following examples.
Embodiment 1:
A kind of preparation technology of sparse oil porous ceramic filtering material, it comprises the steps:
1) press Chinese invention patent number: ZL200310111209.7 (inventor: Wu Jianfeng), make enviroment protective ceramic filter bulb (abbreviation ceramic filtration ball), ceramic filtration ball; The ceramic filtration ball that with particle diameter is 3～5mm is scrubbed (until washing out water not till the displaing yellow, so that pollutant and dust that the flush away filter material surface adheres to) with clear water, then 105 ℃ of oven dry down, pretreated ceramic filter material;
2) preparation modified solution: by no benzene ecological paint: curing agent: the volume ratio of diluent=1: 0.7: 0.8 is chosen no benzene ecological paint, curing agent and diluent, curing agent is mixed with no benzene ecological paint, add diluent after stirring again, after fully stirring once more, get modified solution; Described curing agent is a PIC; Described diluent is a butyl acetate;
3) pretreated ceramic filter material is joined in the modified solution, the addition of pretreated ceramic filter material be as the criterion so that pretreated ceramic filter material surface is just wetting (generally cannot see obvious modified solution between ceramic filter material for well), at room temperature stir, stir 5～10mmin; Then ceramic filter material is poured on the galvanized iron sheet ceramic filter material particle is separated,, after the air dry, get sparse oil porous ceramic filtering material in case it bonds mutually.
The sparse oil porous ceramic filtering material of using this preparation technology's preparation has carried out operation processing continuously in three months (coarse jar employing upward flow to certain oil field through the coagulation pretreatment recovered water, leave certain parking space above the filtrate, so that floating, coalescent big particle diameter oil droplet discharges) from oil drain out, experimental result shows that oil removal rate reaches 60～70%, to the suspended substance removal rate is that 40～95% (concentration of suspension according to the coagulation water outlet is decided, go out the water concentration height, the clearance height; It is low to go out water concentration, and clearance is low), for follow-up technology of fine filtering has alleviated load, thereby can guarantee that oil, concentration of suspension, total concentration of iron in the fine filtering effluent quality can satisfy A1 standard among the SY/T5329-94.To with sparse oil porous ceramic filtering material sampling the carrying out ESEM and the infrared spectrum analysis of crossing, confirm that the oleophobic coating is not damaged, this shows the oleophobic coating and matrix bond is firm, wear-resisting, corrosion resistant.
Embodiment 2:
A kind of preparation technology of sparse oil porous ceramic filtering material, it comprises the steps:
1) press Chinese invention patent number: ZL200310111209.7 (inventor: Wu Jianfeng), make the enviroment protective ceramic filter bulb, ceramic filtration ball; The ceramic filtration ball that with particle diameter is 3～5mm is scrubbed (until washing out water not till the displaing yellow, so that pollutant and dust that the flush away filter material surface adheres to) with clear water, then 100 ℃ of oven dry down, pretreated ceramic filter material;
2) preparation modified solution: by no benzene ecological paint: curing agent: the volume ratio of diluent=1: 0.5: 0.6 is chosen no benzene ecological paint, curing agent and diluent, curing agent is mixed with no benzene ecological paint, add diluent after stirring again, after fully stirring once more, get modified solution; Described curing agent is a PIC, and described diluent is a butyl acetate;
3) pretreated ceramic filter material is joined in the modified solution, the addition of pretreated ceramic filter material is as the criterion so that pretreated ceramic filter material surface is just wetting, at room temperature stir, stir 5～10mmin, spread out then and (ceramic filter material is poured on the galvanized iron sheet ceramic filter material particle is separated, in case it bonds mutually), after the air dry, get sparse oil porous ceramic filtering material.
Embodiment 3:
A kind of preparation technology of sparse oil porous ceramic filtering material, it comprises the steps:
1) press Chinese invention patent number: ZL200310111209.7 (inventor: Wu Jianfeng), make the enviroment protective ceramic filter bulb, ceramic filtration ball; The ceramic filtration ball that with particle diameter is 3～5mm is scrubbed (until washing out water not till the displaing yellow, so that pollutant and dust that the flush away filter material surface adheres to) with clear water, then 110 ℃ of oven dry down, pretreated ceramic filter material;
2) preparation modified solution: by no benzene ecological paint: curing agent: the volume ratio of diluent=1: 0.8: 1 is chosen no benzene ecological paint, curing agent and diluent, curing agent is mixed with no benzene ecological paint, add diluent after stirring again, after fully stirring once more, get modified solution; Described curing agent is a polyamide, and described diluent is an acrylate monomer;
3) pretreated ceramic filter material is joined in the modified solution, the addition of pretreated ceramic filter material is as the criterion so that pretreated ceramic filter material surface is just wetting, at room temperature stir, stir 5～10mmin, spread out then and (ceramic filter material is poured on the galvanized iron sheet ceramic filter material particle is separated, in case it bonds mutually), after the air dry, get sparse oil porous ceramic filtering material.
Claims (1)
1. the preparation technology of a sparse oil porous ceramic filtering material is characterized in that it comprises the steps:
1) be that the enviroment protective ceramic filter bulb of 3～5mm is scrubbed with clear water with particle diameter, then 100～110 ℃ of oven dry down, pretreated ceramic filter material;
2) preparation modified solution: press no benzene ecological paint: curing agent: no benzene ecological paint, curing agent and diluent are chosen in the volume ratio of diluent=1: 0.5～0.8: 0.6～1, curing agent is mixed with no benzene ecological paint, add diluent after stirring again, after fully stirring once more, get modified solution; Described curing agent is PIC or polyamide, and described diluent is butyl acetate or acrylate monomer;
3) pretreated ceramic filter material is joined in the modified solution, the addition of pretreated ceramic filter material is as the criterion so that pretreated ceramic filter material is just wetting, at room temperature stirs, and spreads out then, after the air dry, gets sparse oil porous ceramic filtering material;
The manufacture method of enviroment protective ceramic filter bulb comprises the steps:
1). batching: by weight percentage, alumina laterite 15～30, flyash 20～40, gangue 10～30, clay 10～15, pore former 20～40, high temperature adhesive 3～6;
2). pulverize: with ball mill pulverizing, mix, 100～180 orders that sieve then are standby with above-mentioned raw materials;
3). balling-up: before the balling-up, low temperature binder and water are made into mixed liquor with 1: 2 weight ratio in entry, spray into gradually in the blank of nodulizer again, reach water content 3～8%, adopt the nodulizer balling-up then;
3). drying: 80～120 ℃ of dryings 4～5 hours;
4). fire: above-mentioned dried ball is burnt till at 1100 ℃～1250 ℃;
Described high temperature adhesive is any or the mixing more than two kinds in nepheline orthoclase, spodumene or the potassic feldspar, is any proportioning during mixing more than two kinds;
Described low temperature binder is any or the mixing more than two kinds in carboxymethyl cellulose, waterglass or the aluminium dihydrogen phosphate, is any proportioning during mixing more than two kinds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100526341A CN100534574C (en) | 2007-07-04 | 2007-07-04 | Technics of preparing sparse oil porous ceramic filtering material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100526341A CN100534574C (en) | 2007-07-04 | 2007-07-04 | Technics of preparing sparse oil porous ceramic filtering material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101081343A CN101081343A (en) | 2007-12-05 |
| CN100534574C true CN100534574C (en) | 2009-09-02 |
Family
ID=38911263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100526341A Expired - Fee Related CN100534574C (en) | 2007-07-04 | 2007-07-04 | Technics of preparing sparse oil porous ceramic filtering material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100534574C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103230705B (en) * | 2013-04-28 | 2015-02-04 | 武汉理工大学 | Modified ceramic filter material and applications thereof |
| CN105924212B (en) * | 2016-05-04 | 2018-08-14 | 山东理工大学 | The method for preparing light porous ceramic with red mud and aluminium dihydrogen phosphate |
| CN112274979B (en) * | 2020-09-30 | 2021-12-14 | 倍杰特集团股份有限公司 | Pre-filter for resin oil removal equipment, water treatment filtering system and method |
| CN112843865A (en) * | 2021-01-19 | 2021-05-28 | 盐城庆达新材料有限公司 | Modified vapor sealing material for automobile filter |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1364743A (en) * | 2002-02-09 | 2002-08-21 | 中国科学院上海硅酸盐研究所 | Process for preparing biological active tabular spar ceramics |
| EP1412064A1 (en) * | 2000-05-12 | 2004-04-28 | Aaflowsystems GmbH & Co. KG | Discoid filtration body |
| CN1528491A (en) * | 2003-10-08 | 2004-09-15 | 武汉理工大学 | Method for manufacturing environmental-protection ceramic filter ball |
| JP2004330117A (en) * | 2003-05-09 | 2004-11-25 | Tokyo Yogyo Co Ltd | Silicon carbide catalyst carrier |
| CN1923333A (en) * | 2006-04-17 | 2007-03-07 | 株式会社宫尾 | Filter |
-
2007
- 2007-07-04 CN CNB2007100526341A patent/CN100534574C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1412064A1 (en) * | 2000-05-12 | 2004-04-28 | Aaflowsystems GmbH & Co. KG | Discoid filtration body |
| CN1364743A (en) * | 2002-02-09 | 2002-08-21 | 中国科学院上海硅酸盐研究所 | Process for preparing biological active tabular spar ceramics |
| JP2004330117A (en) * | 2003-05-09 | 2004-11-25 | Tokyo Yogyo Co Ltd | Silicon carbide catalyst carrier |
| CN1528491A (en) * | 2003-10-08 | 2004-09-15 | 武汉理工大学 | Method for manufacturing environmental-protection ceramic filter ball |
| CN1923333A (en) * | 2006-04-17 | 2007-03-07 | 株式会社宫尾 | Filter |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101081343A (en) | 2007-12-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100534574C (en) | Technics of preparing sparse oil porous ceramic filtering material | |
| CN102101689B (en) | Technological method for producing high-purity low-iron aluminum sulfate by using coal ash and comprehensively utilizing coal ash | |
| CN100515536C (en) | Technics of preparing lipophilic porous ceramic filtering material | |
| CA2639513A1 (en) | Modified biogenic silica and method for purifying a liquid | |
| CN102963953A (en) | Method for treating coal washing wastewater | |
| CN112551537A (en) | Method and device for obtaining valuable substances from bauxite residues | |
| CN101522577B (en) | Process for separating off carbon black from a wastewater stream | |
| El-Awady et al. | Removal of heavy metals by cement kiln dust | |
| CN101293768A (en) | Biological filter material and preparation method | |
| JP4578121B2 (en) | Sewage sludge treatment method by sludge-coal-oil coagulation method | |
| Guo et al. | Effects of agricultural waste-based conditioner on ultrasonic-aided activated sludge dewatering | |
| Fuadi et al. | Review study for activated carbon from palm shell used for treatment of waste water | |
| CN101612550B (en) | Preparation method and application of filter aid for purifying and solid-liquid separation of industrial sewage | |
| CN106423112B (en) | Heavy metal ion adsorbent and preparation method thereof | |
| CN102951697A (en) | Method for treating electroplating wastewater | |
| CN103771422B (en) | A kind of oil refining waste catalyst combines the method preparing white carbon black and polymerization aluminum chloride | |
| CN107056236B (en) | Method for preparing ceramic brick with air purification function and compound fertilizer by using sludge | |
| CN105771884A (en) | Molecular sieve composite material for adsorbing heavy metal in water and method for preparing molecular sieve composite material | |
| FR2643628A1 (en) | METHOD FOR FIXING DILUTED AQUEOUS SLUDGE USING POUZZOLANIC MATERIAL | |
| CN101955285A (en) | Pretreatment method before ammonia distillation of coking wastewater | |
| JP7184622B2 (en) | Method for recovering gypsum dihydrate from waste gypsum board | |
| CN104860437B (en) | Heavy metal polluted wastewater treatment method | |
| CN111453782B (en) | Steel plant water treatment filter material and application thereof | |
| EP0555826A1 (en) | Process for utilisation of draff, used kieselguhr containing filter aids and paper products | |
| KR20180037500A (en) | Dehydration Processing Method of Bio-sludge |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090902 Termination date: 20110704 |