CN100523367C - PTT fiber and protein fiber one-bath dyeing method - Google Patents
PTT fiber and protein fiber one-bath dyeing method Download PDFInfo
- Publication number
- CN100523367C CN100523367C CNB2006101657158A CN200610165715A CN100523367C CN 100523367 C CN100523367 C CN 100523367C CN B2006101657158 A CNB2006101657158 A CN B2006101657158A CN 200610165715 A CN200610165715 A CN 200610165715A CN 100523367 C CN100523367 C CN 100523367C
- Authority
- CN
- China
- Prior art keywords
- grams per
- per liter
- dyeing
- fiber
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Coloring (AREA)
Abstract
The invention discloses PTT and protein fibers one bath process dyeing method. It includes the following steps: using applicable dye to dye protein fiber; adding disperse dyes and carrier PTT fiber in one bath; soaping; dispersant cleaning; neutralizing washing; fixing by fixing agent; mellowing; dehydrating; and drying. The invention solves the problem of blending PTT and protein fibers low temperature one bath process dyeing, and the production problem of no corresponding high temperature pressure dyeing device for enterprise, which is the key of deep processing for blending fiber product, the necessary condition for its market popularization and application.
Description
One, technical field
The present invention relates to the technology of a kind of ptt fiber and protein fiber one-bath dyeing, belong to textile fabric dyeing processing technique field.
Two, background technology
Ptt fiber is a polytrimethylene terephthalate, be by terephthalic acid (TPA) (PTA) and 1,3 one propylene glycol (PD0) obtain through over-churning, polycondensation, and PTT belongs in the polyester family new product of exploitation in recent years, and ptt fiber combines the elasticity, ABRASION RESISTANCE of nylon and fatigue durability preferably; The bulkiness of acrylic fibers, flexibility, dyeability and good COLOR FASTNESS preferably; The wrinkle resistance of terylene, DIMENSIONAL STABILITY and good advantages such as heat resistance have broad application prospects.The PTT polyester fiber is a kind of hydrophobicity chemical fibre, and dyeability is close with the PET polyester fiber, and dyeing temperature is lower than PET polyester fiber, adopts disperse dyeing.And protein fibre is a kind of natural hydrophilic fibre, can adopt hydrophilic dye (comprising ACID DYES, REACTIVE DYES, premetallized dye etc.) dyeing.Blend fibre dyeing for ptt fiber and protein fibre, prior art all needs to adopt DISPERSE DYES and two kinds of dyestuffs of protein fibre suitable dyes, two kinds of fibers of resisdye are not seen bibliographical information ptt fiber and protein fiber one-bath dyeing method at present respectively.
Three, summary of the invention
The purpose of this invention is to provide a kind of ptt fiber and protein fiber one-bath dyeing method.
This and other purpose of the present invention will further be set forth and embody by following detailed description and explanation.
Ptt fiber of the present invention and protein fiber one-bath dyeing method comprise the steps:
A, elder generation protein fibre suitable dyes dsred protein fiber;
B, then with adding DISPERSE DYES and carrier dyeable PTT fiber in bathing;
Soap after C, the dyeing, dispersant cleans, neutralization washing and color-fixing agent fixation;
E, at last blend fibre is carried out soft treatment and dehydration, oven dry obtain finished product.
In ptt fiber of the present invention and protein fiber one-bath dyeing method, in the A step, add protein fibre dyeing assistant and REACTIVE DYES, at 35-45 ℃, walk even, the insulation 3-10 minute, described dyeing assistant is made up of the levelling agent B-01 of 1.5-2.5 weight % and glauber salt and the excess water of 2-4 weight %.
The dyeing carrier and the DISPERSE DYES that in the B step, add dyeing assistant, 0.8-1.2 grams per liter, rise to 98 ℃ with 0.8-1.2 ℃ of/minute speed, be incubated 30-60 minute; bath raio 1:20-30; described dyeing assistant is made up of the bleeding agent of 0.5 grams per liter, the levelling agent T of 2-4 grams per liter and the acetic acid-sodium acetate and the excess water of 1.5-2.5 grams per liter, and regulating PH simultaneously is 5-6.
Add the sodium carbonate of 1.5-2.5 grams per liter and the soaping agent of 1.5-2.5 grams per liter rises to 70 ℃ with 1.5-2.5 ℃ of/minute speed soaping described in the C step, be incubated 20 minutes, in the back of soaping with hot, cold wash.The ammoniacal liquor of adding 1.5-2.5 grams per liter is cleaned in described dispersion and the washing agent of 1.5-2.5 grams per liter rises to 80 ℃ with 1.5-2.5 ℃ of/minute speed, is incubated 20 minutes.The acetic acid that described neutralization washing adds 0.5 grams per liter rises to 45 ℃ with 1.5-2.5 ℃ of/minute speed, is incubated 10 minutes.Described fixation is incubated 20 minutes for the cationic color-fixing agent that adds 2 weight % rises to 80 ℃ with 3-5 ℃ of/minute speed.
, 45 ℃ of insulations 10 minutes, dewater then, dry and obtain finished product for adding the softener VS of 1 weight % in the soft treatment described in the C step.
In the method for the invention, before dyeing, if necessary can carry out pre-treatment to fiber, described pre-treatment rises to 60 ℃ for the ammoniacal liquor of scouring agent, 1-3 grams per liter bleeding agent and the 1-3 grams per liter of adding 1-3 grams per liter with 1.5-2.5 ℃ of/minute speed, be incubated 15-25 minute, lower the temperature, wash, described scouring agent, bleeding agent are anion surfactant.
Dyeing theory of the present invention is:
The first step: with protein fibre suitable dyes and auxiliary agent dsred protein fiber;
Second step: with adding DISPERSE DYES dyeable PTT fiber in bathing, add carrier simultaneously and help and dye, improve the dyeing dye uptake;
The 3rd step: by soap, washing agent cleans, and removes loose colour to guarantee the COLOR FASTNESS of ptt fiber; Use the color-fixing agent fixation again, to guarantee the COLOR FASTNESS of protein fibre;
The 4th step: blend fibre is carried out soft treatment, guarantee its soft hand feeling, in order to road, back weaving process.
Solved blending ptt fiber and azelon low temperature one-bath dyeing problem with method of the present invention, and the style characteristic of two kinds of fibers is maintained also, product is soft, moisture absorption is ventilative and comfortable flexible.Simultaneously also having solved the production problem of the enterprise that does not have corresponding device of high-temperature and high-pressure dyeing, is the key that this kind blend fibre carries out the product deep processing, and this staining technique has been created necessary condition for marketing, the application of this product.
Ptt fiber and azelon (particularly wool fibre) blend fibre reeled yarn is after above-mentioned technology dyeing arrangement, and its product is soft, flexible, the high-class product requirement that the COLOR FASTNESS index is up to state standards.Concrete data see Table 1
Table one
Concentration in all raw material of Shi Yonging and some technologies etc. all is conventional uses in the present invention, can buy from market or this professional skill field technical staff is familiar with.For example in the present invention, operable auxiliary agent and manufacturer are as follows: dyeing carrier POE (Clariant chemical industry), penetrating agent JFC (production of auxiliary reagent factory, Shanghai), soaping agent EKaline F (Clariant Chemical Manufacture), cationic color-fixing agent Sandofix EC and scouring agent LYS (Clariant Chemical Manufacture).In the present invention, refer in particular to as non-, all amount, percentages are unit of weight.
Below in conjunction with embodiment the present invention is carried out concrete description.As known by the technical knowledge, the present invention can realize by other the embodiment that does not break away from its spiritual essence or essential feature.Therefore, following embodiment with regard to each side, all just illustrates, and is not only.All within the scope of the present invention or the change that is equal in the scope of the present invention all be included in the invention.
Four, the specific embodiment
Embodiment 1: hank dyeing
Raw material: ptt fiber and wool blended yarn, 2/48NM, PTT50%/SW50%
Look number: P001 black
Dyeing installation: overflow hank-dyeing machine
Pre-treatment: the scouring agent (LYS), the 2.5 grams per liter bleeding agents that in dye bath, add 1.5 grams per liters
(JFC) and the ammoniacal liquor of 1 grams per liter rise to 60 ℃ with 2.0 ℃ of/minute speed, be incubated 15 minutes, lower the temperature again, wash;
Dyeing: in dye bath, add protein fibre dyeing assistant and REACTIVE DYES (hair reactive black A-CG) 2.0 weight %, at 35 ℃, walk even, the insulation 10 minutes, dyeing assistant is made up of the levelling agent B-01 of 1.5 weight % and glauber salt and the excess water of 2.5 weight %.The dyeing carrier (dyeing carrier POE) and the DISPERSE DYES that add dyeing assistant, 0.8 grams per liter then (are disperseed black TXD 5.0 weight %, dispersed ruby TX0.5 weight %), rise to 98 ℃ with 1.0 ℃ of/minute speed, be incubated 40 minutes; bath raio 1:20; dyeing assistant is made up of the penetrating agent JFC of 0.5 grams per liter, the levelling agent T of 2.5 grams per liters and the acetic acid-sodium acetate and the excess water of 1.5 grams per liters, and regulating PH simultaneously is 5.5.
Post processing: the sodium carbonate that soaping after the dyeing adds 1.5 grams per liters and the soaping agent (EKaline F) of 1.5 grams per liters rise to 70 ℃ with 1.5 ℃ of/minute speed, are incubated 20 minutes, in back heat, the cold wash of soaping; The ammoniacal liquor of adding 2.5 grams per liters is cleaned in the dispersion of carrying out then and the washing agent of 2.5 grams per liters rises to 80 ℃ with 1.5 ℃ of/minute speed, is incubated 20 minutes; The acetic acid that the washing that neutralizes again adds 0.5 grams per liter rises to 45 ℃ with 1.5 ℃ of/minute speed, is incubated 10 minutes.The fixation of carrying out is incubated 20 minutes for the cationic color-fixing agent (Sandofix EC) that adds 2 weight % rises to 80 ℃ with 3.5 ℃ of/minute speed at last.
Soft treatment: after fixation, add the softener VS of 1 weight %, 45 ℃ of insulations 10 minutes, dewater then, dry and obtain finished product.
Embodiment 2: hank dyeing
Raw material: ptt fiber and wool blended yarn, 2/48NM, PTT60%/SW40%
Look number: P001 black
Dyeing installation: overflow hank-dyeing machine
Pre-treatment: the ammoniacal liquor that adds scouring agent (LYD), 1.5 grams per liter penetrating agent JFCs and 2.5 grams per liters of 2.0 grams per liters in dye bath rises to 60 ℃ with 2.5 ℃ of/minute speed, is incubated 20 minutes, lowers the temperature, washes;
Dyeing: in dye bath, add protein fibre dyeing assistant and REACTIVE DYES (hair reactive red A-BG) 2.0 weight %, at 40 ℃, walk even, be incubated 6 minutes, dyeing assistant is made up of the levelling agent B-01 of 2.0 weight % and glauber salt and the excess water of 3 weight %.The dyeing carrier POE and DISPERSE DYES (the disperse red HXD4.0 weight % that add dyeing assistant, 1.0 grams per liters then, disperse black AX0.8 weight %), rise to 98 ℃ with 0.8 ℃ of/minute speed, be incubated 50 minutes; bath raio 1:25; dyeing assistant is made up of the bleeding agent of 0.5 grams per liter, the levelling agent T of 4 grams per liters and the acetic acid-sodium acetate and the excess water of 2.5 grams per liters, and regulating PH simultaneously is 6.
Post processing: the sodium carbonate that soaping after the dyeing adds 2.5 grams per liters and the soaping agent (washing powder) of 2.0 grams per liters rise to 70 ℃ with 2.0 ℃ of/minute speed, are incubated 20 minutes, in back heat, the cold wash of soaping; The ammoniacal liquor of adding 1.5 grams per liters is cleaned in the dispersion of carrying out then and the washing agent of 1.5 grams per liters rises to 80 ℃ with 2.0 ℃ of/minute speed, is incubated 20 minutes; The acetic acid that the washing that neutralizes again adds 0.5 grams per liter rises to 45 ℃ with 1.5-2.5 ℃ of/minute speed, is incubated 10 minutes.The fixation of carrying out is incubated 20 minutes for the cationic color-fixing agent Sandofix EC that adds 2 weight % rises to 80 ℃ with 4 ℃ of/minute speed at last.
Soft treatment: after fixation, add the softener VS of 1 weight %, 45 ℃ of insulations 10 minutes, dewater then, dry and obtain finished product.
Claims (6)
1, a kind of ptt fiber and protein fiber one-bath dyeing method is characterized in that comprising the steps:
A, add protein fibre dyeing assistant and REACTIVE DYES, at 35-45 ℃, walked even, insulation 3-10 minute, described dyeing assistant is made up of the levelling agent B-01 of 1.5-2.5 weight % and glauber salt and the excess water of 2-4 weight %;
The dyeing carrier and the DISPERSE DYES of B, adding dyeing assistant, 0.8-1.2 grams per liter rise to 98 ℃ with 0.8-1.2 ℃ of/minute speed, are incubated 30-60 minute, bath raio 1:20-30; Described dyeing assistant is made up of the bleeding agent of 0.5 grams per liter, the levelling agent T of 2-4 grams per liter and the acetic acid-sodium acetate and the excess water of 1.5-2.5 grams per liter, and regulating pH simultaneously is 5-6;
Soap after C, the dyeing, dispersant cleans, neutralization washing and color-fixing agent fixation;
D, at last blend fibre is carried out soft treatment and dehydration, oven dry obtain finished product.
2, ptt fiber according to claim 1 and protein fiber one-bath dyeing method, it is characterized in that the described sodium carbonate that adds the 1.5-2.5 grams per liter and the soaping agent of 1.5-2.5 grams per liter soaped rises to 70 ℃ with 1.5-2.5 ℃ of/minute speed, is incubated 20 minutes.
3, ptt fiber according to claim 1 and protein fiber one-bath dyeing method, it is characterized in that described dispersant cleans the ammoniacal liquor of adding 1.5-2.5 grams per liter and the washing agent of 1.5-2.5 grams per liter rises to 80 ℃ with 1.5-2.5 ℃ of/minute speed, be incubated 20 minutes.
4, ptt fiber according to claim 1 and protein fiber one-bath dyeing method is characterized in that the acetic acid that described neutralization washing adds 0.5 grams per liter rises to 45 ℃ with 1.5-2.5 ℃ of/minute speed, is incubated 10 minutes.
5, ptt fiber according to claim 1 and protein fiber one-bath dyeing method is characterized in that the cationic color-fixing agent that described fixation adds 2 weight % rises to 80 ℃ with 3-5 ℃ of/minute speed, is incubated 20 minutes.
6, ptt fiber according to claim 1 and protein fiber one-bath dyeing method is characterized in that described soft treatment is for adding the softener VS of 1 weight %, 45 ℃ of insulations 10 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101657158A CN100523367C (en) | 2006-12-14 | 2006-12-14 | PTT fiber and protein fiber one-bath dyeing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101657158A CN100523367C (en) | 2006-12-14 | 2006-12-14 | PTT fiber and protein fiber one-bath dyeing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1978782A CN1978782A (en) | 2007-06-13 |
| CN100523367C true CN100523367C (en) | 2009-08-05 |
Family
ID=38130075
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101657158A Expired - Fee Related CN100523367C (en) | 2006-12-14 | 2006-12-14 | PTT fiber and protein fiber one-bath dyeing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100523367C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104005220A (en) * | 2014-05-04 | 2014-08-27 | 广东都市丽人实业有限公司 | Dyeing method for silkworm pupa protein composite fiber |
| CN104831559B (en) * | 2014-10-27 | 2017-01-11 | 苏州市云帆刺绣工艺品有限公司 | Dyeing method of silk thread |
| CN107354774B (en) * | 2017-08-08 | 2019-10-01 | 浙江嘉名染整有限公司 | A kind of dyeing and finishing technology improving the blended mutual dyefastness of brushed fabrics spliced together |
-
2006
- 2006-12-14 CN CNB2006101657158A patent/CN100523367C/en not_active Expired - Fee Related
Non-Patent Citations (2)
| Title |
|---|
| PTT纤维的染整加工（三）. 杨栋樑.印染，第32卷第3期. 2006 |
| PTT纤维的染整加工（三）. 杨栋樑.印染，第32卷第3期. 2006 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1978782A (en) | 2007-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100489188C (en) | PTT fiber and cellulose fiber one-bath dyeing method | |
| CN104711874B (en) | Dyeing process of nylon fiber | |
| CN103938446B (en) | A kind of nice and cool crease-resistant soft treatment technique of fibre blending yarn | |
| CN104695239B (en) | A kind of colouring method of aramid fiber | |
| CN102978980B (en) | Polyester cotton one bath process dye | |
| CN110344262B (en) | One-bath one-step processing method for dyeing and waterproof finishing of polyester fabric | |
| CN104746369A (en) | Acid dye dyeing process for acrylic fiber | |
| CN101413207B (en) | Dyeing and finishing process for sea silk fabric | |
| CN106192478A (en) | A kind of colouring method of non-shrinkable wool fabric | |
| CN108708190A (en) | A kind of dyeing of Cationic Dyeable Pet | |
| CN100523367C (en) | PTT fiber and protein fiber one-bath dyeing method | |
| CN1285799C (en) | Soybean fiber loose-stock dyeing and processing method | |
| CN111910446A (en) | Polyester-cotton blended yarn dyeing process | |
| CN108049202A (en) | A kind of dyeing of covering yarn | |
| CN104278558A (en) | Active dye applied to wool and wool dyeing method | |
| CN104831560A (en) | Chinlon cationic dyeing process | |
| CN104762828A (en) | Direct dyeing process for chemical fiber | |
| CN100434592C (en) | Color deepening agent for fiber and method for deepening color of fiber using same | |
| CN110106690A (en) | A kind of cellulose fibre-dacron interweaved fabric dyeing and finishing processing method | |
| CN111005239B (en) | Dyeing and finishing process for reducing strength reduction of PLA-PHBV, tencel and cotton interwoven fabric in dyeing | |
| CN109505170B (en) | Reactive dye homochromatic dyeing method for real silk/shrink-proof (mercerized) wool interwoven fabric | |
| CN103382667A (en) | Dyeing method for blended and interwoven fabric of cotton fiber, linen fiber and wool fiber | |
| CN102127872B (en) | Method for dyeing nylon-containing silver-plated fiber interwoven shell fabric | |
| CN113863034A (en) | Method for short-flow pre-treatment dyeing of polyester-cotton knitted fabric | |
| KR20210063545A (en) | Method for manufacturing antimicrobial towel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: QUANZHOU HAITIAN MATERIAL SCINENCE + TECHNOLOGY CO Free format text: FORMER OWNER: WANG QIMING Effective date: 20100805 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 362000 NO.107, GUITAN LANE, LICHENG DISTRICT, QUANZHOU CITY, FUJIAN PROVINCE TO: 362000 HAITIAN INDUSTRY PARK, JIANGNAN DEVELOPMENT ZONE, QUANZHOU CITY, FUJIAN PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20100805 Address after: Haitian Industrial Park Jiangnan Development Zone in Quanzhou City, Fujian province 362000 Patentee after: QUANZHOU HAITIAN MATERIAL TECHNOLOGY Corp. Address before: 362000, 107, GUI Tan alley, Licheng District, Fujian, Quanzhou Patentee before: Wang Qiming |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090805 Termination date: 20211214 |