CN100519725C - Foam-generating kit containing a foam-generating dispenser and a composition containing a high level of surfactant - Google Patents

Foam-generating kit containing a foam-generating dispenser and a composition containing a high level of surfactant Download PDF

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Publication number
CN100519725C
CN100519725C CNB2004800051760A CN200480005176A CN100519725C CN 100519725 C CN100519725 C CN 100519725C CN B2004800051760 A CNB2004800051760 A CN B2004800051760A CN 200480005176 A CN200480005176 A CN 200480005176A CN 100519725 C CN100519725 C CN 100519725C
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Prior art keywords
foam
composition
generating
alkyl
preferred
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CN1753986A (en
Inventor
G·H·S·S·屈勒伦
H·D·赫顿三世
R·L·芒然
A·塔内科
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Procter and Gamble Co
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Procter and Gamble Co
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C11D17/0021—Aqueous microemulsions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1087—Combination of liquid and air pumps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/0018—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam
    • B05B7/0025—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/0018—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam
    • B05B7/0025—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply
    • B05B7/0031—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns
    • B05B7/0037—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns including sieves, porous members or the like
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C11D3/188—Terpenes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2037—Terpenes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Medicinal Preparation (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Materials For Medical Uses (AREA)
  • Closures For Containers (AREA)

Abstract

A foam-generating kit contains a non-aerosol container with a foam-generating dispenser and a high surfactant composition, preferably within the container. The high surfactant composition comprises, by weight of the high surfactant composition, at least 20 % of a surfactant system. When the foam-generating dispenser is employed with the high surfactant composition, the foam-generating dispenser generates a foam having a foam to weight ratio of greater than about 2 ml/g.

Description

Comprise foam-generating dispenser and the foam-generating kit that comprises the high level of surfactant composition
Invention field
The present invention relates to cleaning compositions and container thereof.Specifically, the present invention relates to comprise the cleaning compositions and the container thereof of high level of surfactant.The present invention also relates to foam-generating dispenser usually.
Background of invention
The composition (high surfactant composition) that comprises high level of surfactant, as spissated platter washing composition, hand soaps composition, shampoo Compositions, clothes washing composition, abrasive cleaning composition etc. is to know, and the typical case provides with liquid, gel or paste.Though liquid and paste can be used for various situations, these physical form are no longer thought novel and infusive.In addition, be desirable though novelty and interesting physical form are provided, the use above-mentioned composition typically is limited to these liquid, gel and paste coating or is precoated on the substrate, also will be applied directly on the required surface then.
Though use foam-generating dispenser to generate low surfactant content composition foam (promptly, comprise health washing composition greater than 12% tensio-active agent) be known, but this method is not successfully used to the high surfactant composition as yet, because the typical case has directly related property between the viscosity of the surfactant content that increases and increase.Specifically, the rheological characteristics of high surfactant composition makes it be difficult to obtain the foam of satisfaction when not having extreme turbulent flow and violent flow characteristics.Because these turbulence characteristics need apply too high physical force usually or need high pressure vessel, so actual result is exactly that formulator need reduce their product viscosity usually, so that satisfy the limitation of existing foam-generating dispenser on the market.Therefore, generate foam if desired, this method has freely added constraint artificial, material to what formulator obtained top performance and/or least-cost combination thing.
In addition, need a kind ofly can from the high surfactant composition, generate the foamy foam-generating dispenser.Further need a kind of like this foam-generating dispenser, it can generate this foam, and does not need to apply too high physical force and/or do not need to use aerosol propellants.
Summary of the invention
The present invention relates to foam-generating kit, described external member comprises non-aerosol container and the high surfactant composition (preferably in this container) that has foam-generating dispenser.The high surfactant composition comprises surfactant system at least about 20% by described high surfactant composition weight meter.When this high surfactant composition used foam-generating dispenser, this foam-generating dispenser generated the foam of foam (that is volume) weight ratio greater than about 2mL/g.
The combination that has now found that foam-generating dispenser and high surfactant composition can provide satisfied foaming simultaneously and need not to apply too high physical force and do not use aerosol propellants.Be not bound by theory, it is believed that when generating more and more the turbulent passage, even can make the high surfactant composition generate satisfied foam.
In addition, it is better and/or cleaning faster than the same composition that distributes in other mode to it is believed that the cleaning compositions that distributes can generate from foam-generating dispenser as described in the present invention.Be not bound by theory, it is believed that the generation of physical foam forces the high surfactant composition to be in the state of the total surface area with increase.Because great majority cleaning interaction such as oily emulsive speed and thoroughness are directly related with the surface-area of covering, so we believe that form of the present invention can significantly improve total clean power.In addition, under the situation of micro emulsion and/or former micro emulsion, find that shockingly the present invention has obtained the beneficial effect attractive in appearance of physical foam by forcing physics to generate foam, and the tensio-active agent at not chemical constraint air-water interface place.On the contrary,, compare with the situation that the mixing of water makes by usual method such as tensio-active agent with foam even there is foam, but have bigger per-cent the tensio-active agent chemical be connected on dust, the wet goods.
For a person skilled in the art, by reading the disclosure of the specification and appended claims, these and other feature of the present invention, aspect, advantage and change and described embodiment will become apparent, and be included in the scope of these claims.
Summary of drawings
Though this specification sheets with particularly point out and clearly claimed claims of the present invention it is believed that by following the description of the drawings and will understand the present invention better that identical reference number is represented identical parts in the described accompanying drawing as conclusion, and wherein:
Fig. 1 is the sectional view of the preferred embodiment of foam-generating dispenser;
Fig. 2 is top perspective, the sectional view of the preferred embodiment of moulding applicator; With
Fig. 3 is perspective, the sectional view of the preferred embodiment of moulding applicator.
The accompanying drawing of this paper is not necessarily drawn in proportion.
Detailed Description Of The Invention
Except as otherwise noted, all per-cents of this paper, ratio and ratio are all by the weight of final high surfactant composition.Except as otherwise noted, the unit of all temperature be degree centigrade (℃).
Term used herein " comprises " and is meant other steps, composition, the key element that do not influence net result that can add, or the like.This term comprise term " by ... form " and " basically by ... composition ".
Term used herein " dish " be meant any contacting foodstuff, be used for the food set-up procedure and/or have a dinner before or after the dish, tableware, cooker, glass wares, cutter, knife plate, foodstuffs preparation equipment etc. of washing.
Term used herein " foam " and " foaming " are used alternatingly, and are meant the discrete gas foam that is surrounded and be suspended in by liquid phase in the liquid phase.
Term used herein " micro emulsion " is meant a kind of O/w emulsion, and it has the ability that oil is emulsified into invisible droplet.The maximum diameter that these invisible droplet typical cases have less than about 100 dusts (
Figure C200480005176D0005085318QIETU
), preferably less than about 50
Figure C200480005176D0005085318QIETU
, described diameter is measured by means known in the art, as measure the ISO 7027 of turbidity at wavelength 880nm place.Turbidimetry equipment easily available from, for example, Omega Engineering, Inc., Stamford, Connecticut, U.S.A.
Term used herein " former micro emulsion " is meant that dilutable water forms the composition of micro emulsion.
Container
Can be used for container of the present invention is the non-aerosol container, and the typical case comprises a ducted body and holds the high surfactant composition, preferred platter washing composition, and the most normally by plastics, glass and/or metal, bottle that preferred polymers or resin such as polyethylene, polypropylene, polyethylene terephthalate, polycarbonate, polystyrene, ethyl vinyl alcohol, polyvinyl alcohol, thermoplastic elastomer and their combination are made or jar are although other material known in the art also can use.These containers typically will hold about 100mL to about 2L liquid, and preferably about 150mL is about 1.2L liquid extremely, 200mL about 1L liquid extremely more preferably from about, and know and can be used for the receiving fluids consumer's goods.These containers can be extensively available from many packing suppliers.
Directly or indirectly be operably connected on the container is to be used to generate the foamy foam-generating dispenser.When being activated, this foam-generating dispenser generates foam, and distributes blistered composition simultaneously from container.This foam-generating dispenser can be configured to and the container one, or separates with container.If separately make, foam-generating dispenser can be connected on the container by methods known in the art, as screw thread convex-concave member, pressurization and non-pressurised sealing, locking and snap-on parts and/or other method known in the art by use transition plate, correspondence.Preferably, foam-generating dispenser is connected on the container by means of transition plate and/or the easy corresponding screw thread convex-concave member of replacing of use.
Foam-generating dispenser can interact so that generate foam, as chemical reaction, enzyme reaction and/or mechanical effect with the high surfactant composition by any method.Yet, mechanical effect is preferred at this paper, and the typical case relates to mechanism, and described mechanism is directly given gas such as air, nitrogen, carbonic acid gas etc. or is mixed in the platter washing composition in the turbulent flow mode in minute timing, so that physically forms foam.Preferably, this foam-generating dispenser comprises that gas gives mechanism with by means of forming foam with lower member from air: air injection piston, foam generate hole, impact surfaces, reticulation or net, pump and/or atomizer, more preferably air injection piston, pump, impact surfaces, a plurality of reticulation or net and/or air is injected or is imparted to the atomizer of platter washing composition from atmosphere.In a highly preferred embodiment, foam-generating dispenser uses at least three, preferred three to five reticulations, wherein high surfactant composition Continuous Flow through these reticulations so that generate foam.Be not bound by theory, it is believed that by Continuous Flow through above-mentioned reticulation, the high surfactant composition mixes with air turbulence repeatedly, increase the foam that surpasses any single reticulation and generate effect thereby make foam generate effect.When the per-cent of surfactant system in the high surfactant composition increases, can add additional reticulation so that required foaming height and/or foam volume to be provided.
Foam-generating dispenser also typically comprises starter, the preferred manual starter, such as for instance, triggering device, pressure-activated suction mechanism, button and/or slide block, button that a more preferably available finger starts and/or pressure-activated suction mechanism.It is highly preferred that this starter is designed to following starter: when human consumer's hand was wet and/or sliding, as in manual dish washing process the time, they can start it like a cork.This starter should allow the volume of easily also convenient control dispensing rate of user and distribution.For some applications, as the purposes in industry or public the setting, other starter may be helpful, as electronic starter, computer control starter, electronic eyes or infrared detection starter, manual lever auxiliary actuator etc.Can be used for foam-generating dispenser of the present invention and generate foam wt than greater than about 2mL/g, more preferably from about 3mL/g is to about 10mL/g, even the 4mL/g foam of about 8mL/g extremely more preferably from about.In addition, can be used for the every mL platter washing composition of foam-generating dispenser of the present invention and generate at least about the 2mL foam, preferably about 3mL is to about 10mL, and more preferably from about 4mL is to about 8mL foam." emulsus " and " smooth " foam that fine foam is evenly dispersed in wherein relatively may be especially preferred because of their aesthetic feeling and/or performance.In some cases, preferred foam is to surpass 3 fens clock times significantly not to be degenerated to those of liquid.Specifically, be assigned to the glass surface of cleaning (as, PYREX when foam TMDish) go up after, it was placed 3 minutes in 25 ℃, should be only as seen less than the liquid of 1mm.Preferably, can't see liquid at the foamy edge after 3 minutes.Yet, in other cases, also found certain amount of fluid (promptly, non-foam liquid) also be preferred, because this liquid infiltrates in the applicator (as, sponge) subsequently, thereby when it is used to for example clean dish, can further expand the contact range of high surfactant composition.
Fig. 1 is the sectional view of preferred embodiment that has the foam-generating dispenser 10 of nozzle 12, and the platter washing composition after the foaming distributes from nozzle 12.Platter washing composition enters foam-generating dispenser by soaking material pipe 14, and the ball 16 of flowing through then enters in the cylinder l8.Stopper 20 prevents ball 16 effusions, and also supports wind spring 22 and interior bar 24.Liquid piston 26 is packaged into siphon, and this siphon was inhaled ball 16 and stopper 20 with platter washing composition, enters in the liquid chamber 28, thereby makes foam-generating dispenser 10 prepare to start.Simultaneously, wind box 30 and air piston 31 are also prepared to start, when starter 32 is pressed, air that comes out from wind box 30 and the platter washing composition that comes out from liquid chamber 28 all by turbulent flow push mixing section 34, and through first reticulation 36 and second reticulation 38, these two reticulations are all kept in position by reticulation fixer 40.When turbulent air/platter washing composition mixture is pushed over first reticulation 36, generate initial fluffy and disorderly foam, this fluffy and disorderly foam becomes thinner and more even after through second reticulation 38 and the 3rd reticulation 41.These reticulations can have identical or different aperture.In addition, also can use additional reticulation as required.
In preferred embodiments, foam-generating dispenser is included in the foam-generating dispenser or connects thereon sponge, or except one or more reticulations, also comprises sponge therein or sponge is connected thereon.When the high surfactant composition was forced to the open-celled structure of turbulent flow process sponge, sponge also generated foam.This sponge can be included in the inside of foam-generating dispenser and/or also can be positioned at nozzle end as required.Be not bound by theory, find, be positioned at nozzle slightly and or the additional reticulation and/or the sponge of nozzle end especially can be used for the present invention because they are used for directly generating foam before distributing.Therefore, when foam during through last turbulent area or at its through last turbulent area subsequently, the user sees required foam, froth quality is in best condition simultaneously, and in its significantly degraded and/or before in other words quality changes.
Fig. 1 also shows end cap 42, and it is fixed to the foaming divider on the container 44 that holds the high surfactant composition.
Can be used for preferred foams generation divider of the present invention comprises: available from Afa-Polytek, and Helmond, the T8900 of The Netherlands, OpAd FO, 8203 and 7512 serial frothing machines; Available from Airspray International, Inc., Alkmaar, TheNetherlands or North Pompano Beach, Florida, the T1 of U.S.A., F2 and WR-F3 series frothing machine; Available from Saint-Gobain Calmar, Inc., Cityof Industry, California, the TS-800 of U.S.A. and Mixor series frothing machine; Available from Daiwa Can Company, Tokyo, the suction frothing machine of Japan and crushed foam producer; Available from Guala Dispensing USA, Inc., Hillsborough, New Jersey, the TS1 of U.S.A. and TS2 series frothing machine; With available from YoshinoKogyosho Co., Ltd., Tokyo, the YT-87L-FP of Japan, YT-87L-FX and YT-97 series frothing machine.In addition, referring to Japanese publication " Food ﹠amp; Package ", (2001) the 42nd volumes, the 10th phase, 609-13 page or leaf, " Food ﹠amp; Package ", (2001) the 42nd volumes, o. 11th, 676-79 page or leaf and " Food ﹠amp; Package ", (2001) the 42nd volumes, the 12nd phase, the foam-generating dispenser that the 732-35 page or leaf is discussed.The change of existing foam-generating dispenser and improvement especially can be used for the present invention, especially by adjusting air piston: product piston volume ratio, mesh/net sizes, collision angle etc., and cylinder, bar, the size of soaking material pipe, nozzle etc. and the optimization of size.
Though the trigger-type foam-generating dispenser can be preferred for some embodiment of this paper, the pump of finger and/or palm startup formula (referring to, as, Fig. 1) normally preferred because of aesthetic reasons.Especially under the situation that foam-generating kit is distinguished from " coarse " image of typical hard surface cleaning device and similar durable products.
Height is shown and surfactant composition
The high surfactant composition of this paper typically is selected from cleaning compositions, polishing composition, moisture-keeping composition and/or dye/tint composition, preferred platter washing composition, hair care composition, clothes washing composition, body care composition and/or hard surface cleaning composition are more preferably hand-washed platter washing composition, clothes washing composition, skin care composition and/or shampoo Compositions.Therefore this high surfactant composition comprises surfactant system, and typically comprises solvent and the known optional member of one or more cleaning applications such as dyestuff, enzyme, spices, thickening material, pH control agent, reduction or oxidative bleaching agent, odor control agent, antioxidant and free radical inhibitors and their mixture.
The surfactant system typical case of this paper comprises anion surfactant, amphoterics, cats product, nonionogenic tenside, zwitterionics or their mixture, the derivative of preferred alkyl vitriol, alkoxy sulfate, alkylsulfonate, alkoxyl group sulfonate, alkylaryl sulphonate, amine oxide, trimethyl-glycine or aliphatic series or the heterocycle second month in a season and tertiary amine, quaternary ammonium surfactant, amine, list or polyalkoxylated alcohol, alkyl polyglycoside, fatty acid amide surfactant, C 8-C 20Glutamine, a glycollic amide, diglycollic amide, isopropanol amide, polyhydroxy fatty acid amide and their mixture.The mixture of negatively charged ion and nonionogenic tenside is especially preferred.Can be used for tensio-active agent of the present invention can further be side chain and/or straight chain, replacement or unsubstituted according to needs.Also can be referring to " SurfaceActive Agents and Detergents " (volume I and II, author Schwartz, Perry and Berch).
Be used for anion surfactant of the present invention and comprise that chemical formula is ROSO 3The water-soluble salt of M or acid, wherein R is preferably C 6-C 20The alkyl of straight or branched preferably has C 10-C 20The alkyl of alkyl component or hydroxyalkyl, more preferably C 10-C 14Alkyl or hydroxyalkyl, and M is H or positively charged ion, as alkali metal cation or ammonium or replacement ammonium, but preferred sodium and/or potassium.
Other the suitable anion surfactant that can be used for this paper is that chemical formula is RO (A) mSO 3M water-soluble salt or acid, wherein R is the C of unsubstituted straight or branched 6-C 20Alkyl or hydroxyalkyl, it has C 10-C 20Alkyl component, preferred C 12-C 20Alkyl or hydroxyalkyl, more preferably C 12-C 14Alkyl or hydroxyalkyl, A are oxyethyl group or propoxy-unit, and m is greater than zero, and typically between about 0.5 and about 5, more preferably between about 0.5 and about 2, and M is H or positively charged ion, and it can be, for example, and the ammonium cation of metallic cation, ammonium or replacement.(this paper is abbreviated as C to alkyl ethoxylated sulfate X-YE mS, wherein X-Y represents the length of alkyl chain, and m is same as described above) and the alkyl propoxylated sulphates be that this paper is preferred therefore.The tensio-active agent of example is C 10-C 14Alkyl polyethoxylated (1.0) vitriol, C 10-C 14Polyethoxylated (1.0) vitriol, C 10-C 14Alkyl polyethoxylated (2.25) vitriol, C 10-C 14Polyethoxylated (2.25) vitriol, C 10-C 14Alkyl polyethoxylated (3.0) vitriol, C 10-C 14Polyethoxylated (3.0) vitriol and C 10-C 14Alkyl polyethoxylated (4.0) vitriol, C 10-C 18Polyethoxylated (4.0) vitriol.In preferred embodiments, anion surfactant is an alkoxylate, the mixture of preferred ethoxylation and non-oxyalkylated sulfate surfactant.In this preferred embodiment, preferred average degree of alkoxylation is about 0.4 to about 0.8.
Other the especially suitable anion surfactant that can be used for this paper is alkylsulfonate and alkylaryl sulphonate, comprises that chemical formula is RSO 3The water-soluble salt of M or acid, wherein R is C 6-C 20Straight or branched, saturated or undersaturated alkyl or aryl, preferred C 10-C 20Alkyl or aryl, more preferably C 10-C 14Alkyl or aryl, and M is H or positively charged ion, for example, alkali metal cation (as, sodium, potassium, lithium) or the ammonium of ammonium or replacement (as, methyl-, dimethyl-and trimethyl ammonium positively charged ion and quaternary ammonium cation, as tetramethyl-ammonium and lupetidine positively charged ion and quaternary ammonium cation, derived from alkylamine such as ethamine, diethylamine, triethylamine and their mixture, etc.).It is highly preferred that straight chain and branch-alkylbenzene sulfonate equally, and more preferably linear alkylbenzene sulfonate.
In a further preferred embodiment, the carbochain of anion surfactant comprises one or more alkyl, preferred C 1-4The alkyl branches unit.In this case, greater than about 30%, more preferably from about 35% to about 80% by the weight of described anion surfactant for the average percent of anion surfactant collateralization, and most preferably from about 40% to about 60%.The average percent of this collateralization can obtain by PME is prepared with one or more anion surfactants, and all surface promoting agent all is preferably greater than about 30% side chain, and more preferably from about 35% to about 80%, and most preferably from about 40% to about 60%.Available and more preferably, described PME can comprise the combination of branched anionic surfactants and straight chain anion surfactant, make the average side chain per-cent of total anion surfactant combination greater than about 30%, more preferably from about 35% to about 80%, and most preferably from about 40% to about 60%.
The amphoterics of this paper is the tensio-active agent of electric charge according to the pH variation of PME (if being suitable for) or ME, and is preferably selected from various amine oxide tensio-active agents.Amine oxide is the semi-polarity tensio-active agent, comprises the water-soluble amine oxide compound, and this amine oxide comprises that containing has an appointment 10 is selected to moieties of about 18 carbon atoms and two and comprises about 1 part to the alkyl and the hydroxyalkyl of about 3 carbon atoms; The water soluble oxidized phosphine comprises that containing has an appointment 10 is selected to moieties of about 18 carbon atoms and two and comprises about 1 part to the alkyl and the hydroxyalkyl of about 3 carbon atoms; Water-soluble sulfoxide comprises that containing has an appointment 10 is selected to moieties of about 18 carbon atoms and one and comprises about 1 part to the alkyl and the hydroxyalkyl of about 3 carbon atoms.
The following amine oxide of chemical formula preferably:
Figure C200480005176D00101
R wherein 1Be C 10-14Alkyl, and R 2And R 3Be methyl or ethyl and be described in February 23 nineteen eighty-two and authorize the United States Patent (USP) 4,316,824 of Pancheri; Authorized the United States Patent (USP) 5,075,501 of Borland and Smith on December 24th, 1991; With in the United States Patent (USP) 5,071,594 of authorizing Borland and Smith on December 10th, 1991 those.
Preferred amine oxide tensio-active agent has following formula:
Figure C200480005176D00111
R wherein 3Be to contain have an appointment 8 alkyl, hydroxyalkyl, alkyl phenyl or their mixture to about 22 carbon atoms; R 4Be to contain 2 alkylidene group or hydroxyl alkylidene group or their mixtures of having an appointment to about 3 carbon atoms; X is 0 to about 3; Each R 5Be to contain 1 alkyl or the hydroxyalkyl of having an appointment, or contain 1 the polyethylene oxide base of having an appointment to about 3 Oxyranyles to about 3 carbon atoms.R 5Group can be interconnection, for example by Sauerstoffatom or nitrogen-atoms, forms ring texture.Preferred amine oxide tensio-active agent comprises C 10-C 18Base dimethyl amine oxide compound and C 8-C 12Alkoxyethyl dihydroxyl amine oxides.
Same what be fit to is the amine oxide of propylamine oxide compound for example, is expressed from the next:
Figure C200480005176D00112
R wherein 1Be alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl or 3-alkoxyl group-2-hydroxypropyl, wherein alkyl and alkoxyl group contain respectively and have an appointment 8 to about 18 carbon atoms, R 2And R 3Each is methyl, ethyl, propyl group, sec.-propyl, 2-hydroxyethyl, 2-hydroxypropyl or 3-hydroxypropyl naturally, and n is 0 to about 10.
The kind of also suitable amine oxide semi-polarity surface-active agents comprises the compound that meets following formula and the mixture of compound:
Figure C200480005176D00113
R wherein 1Be alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl or 3-alkoxyl group-2-hydroxypropyl, wherein alkyl and alkoxyl group contain respectively and have an appointment 8 to about 18 carbon atoms, R 2And R 3Each is methyl, ethyl, propyl group, sec.-propyl, 2-hydroxyethyl, 2-hydroxypropyl or 3-hydroxypropyl naturally, and n is 0 to about 10.
Other suitable non-limiting examples of the spendable amphoterics of the present invention comprise the derivative of amido propyl betaine and aliphatic series or heterocyclic secondary and tertiary amine, wherein aliphatic series part can be straight chain or side chain, wherein one of aliphatic substituting group contains and has an appointment 8 to about 24 carbon atoms, and has at least an aliphatic substituting group to contain the anionic water solubilizing group.
Also the embodiment of the amphoterics of Shi Heing is disclosed in " Surface ActiveAgents and Detergents " (volume I and II, author Schwartz, Perry and Berch).
Can be used for cats product of the present invention and comprise having at least one C 10-C 14Alkyl chain, with the quaternary ammonium salt of negatively charged ion (as chlorion) charge balance.Preferred cationic surfactants comprises ammonium surfactant such as alkyl dimethyl ammonium halide and has those tensio-active agents of following chemical formula:
[R 2(OR 3) y][R 4(OR 3) y] 2R 5N +X -
R wherein 2Be to have about 8 alkyl or alkyl benzyls, each R in the alkyl chain to about 18 carbon atoms 3Be selected from-CH 2CH 2-,-CH 2CH (CH 3)-,-CH 3CH (CH 2OH)-,-CH 2CH 2CH 2-, and their mixture; Each R 4Be selected from C 1-C 4Alkyl, C 1-C 4Hydroxyalkyl, benzyl, by two R 4The ring structure that group is connected to form ,-CH 2CHOHCHOHCOR 6CHOH-CH 2OH, wherein R 6Be molecular weight less than about 1000 any hexose or hexose polymkeric substance, and when y is not 0, be hydrogen; R 5With R 4Identical or R wherein 2Add R 5The total number of carbon atoms be not more than about 18 alkyl chain; Each y is 0 to about 10, and the summation of y value is 0 to about 15; And X is any compatible negatively charged ion.
Other can be used for the U.S.4 that cats product of the present invention also is described in the Cambre that announced on October 14th, 1980, in 228,044.The ammonium salt of one alkoxylate and dialkoxyization also can be used for this paper, and usually available from such as Clariant Corporation, Charlotte North Carolina, USA and Akzo Nobel nv, Arnhem, the supplier of theNetherlands.
Zwitterionics also can be used for the present invention, and can roughly be described as the derivative of secondary amine and tertiary amines derived thing, heterocyclic secondary and tertiary amines derived thing or quaternary ammonium, quaternary phosphonium or uncle's sulfonium compound.The embodiment of relevant zwitterionics sees also in the people's such as Laughlin that announced on December 30th, 1975 the United States Patent (USP) 3,929,678, from 19 hurdles, 38 row to 22 hurdles, 48 row.Especially can be used for zwitterionics of the present invention and comprise common available beet alkali surface activator, especially lauryl amido propyl betaine, C 12-C 16Cocoamidopropyl and their mixture.
The PME of this paper also comprises less than about 10%, and preferred about 0% to about 10%, and more preferably from about 0% to about 5%, even 0% to about 3% nonionogenic tenside more preferably from about.Can be used for nonionogenic tenside of the present invention and generally be disclosed in the people's such as Laughlin that announced on December 30th, 1975 United States Patent (USP) the 3,929,678, the 13rd volume 14 row to the 16th volume 6 row.Can be used for other nonionogenic tensides of the present invention, comprise that fatty alcohol is with about 1 mole of condensation product to about 25 moles of ethylene oxide.The alkyl chain of fatty alcohol can be straight or branched, primary alkyl or secondary alkyl, and contains usually and have an appointment 8 to about 22 carbon atoms.Particularly preferably be to contain and have an appointment 10 to the alkyl alcohol of about 20 carbon atoms and the condensation product of oxyethane (every mol of alcohol and about 2 moles of extremely about 18 moles of ethylene oxide condensations).The embodiment of the commercially available nonionogenic tenside of this class comprises 15-S-9 (C 11-C 15The condensation product of linear secondary and 9 moles of ethylene oxide), 24-L-6NMW (C 12-C 14The condensation product of the oxyethane of primary alconol and 6 moles of narrow molecular weight distributions), these two products are all sold by Union CarbideCorporation;
Figure C200480005176D00133
45-9 (C 14-C 15The condensation product of straight chain alcohol and 9 moles of ethylene oxide),
Figure C200480005176D00134
23-6.5 (C 12-C 13The condensation product of straight chain alcohol and 6.5 moles of ethylene oxide), sell by Shell Chemical Company and
Figure C200480005176D00135
EOB (C 13-C 15The condensation product of alcohol and 9 moles of ethylene oxide), by The Procter ﹠amp; Gamble Company, Cincinnati, Ohio, U.S.A sells.Other commercially available ionic surfactant pack are drawn together the commercially available DOBANOL by Shell Chemical Co.
Figure C200480005176D00136
With commercially available by Hoechst
Figure C200480005176D00137
This class nonionogenic tenside is commonly called " alkylethoxylate ".
Also can be used for nonionogenic tenside of the present invention and be selected from alkyl polyglycoside tensio-active agent, fatty acid amide surfactant, C 8-C 20Glutamine, a glycollic amide, diglycollic amide, isopropanol amide, and their mixture.These nonionogenic tensides are known in the art, and are commercially available.Can be used for especially preferred nonionogenic tenside of the present invention is available from Cognis Corp.USA, Cincinnati, the C of OH 9-C 12Alkyl polyglycoside.Preferred alkyl polyglycoside has following chemical formula:
R 2O (C nH 2nO) t(glycosyl) x,
R wherein 2Be selected from alkyl, alkyl phenyl, hydroxyalkyl, hydroxyalkyl phenyl and their mixture, wherein alkyl comprises 10 to 18, preferred 12 to 14 carbon atoms; N is 2 or 3, preferred 2; T is 0 to 10, preferred 0; And x is 1.3 to 10, and is preferred 1.3 to 3, most preferably 1.3 to 2.7.Described glycosyl is preferably derived from glucose.In order to prepare these compounds, at first form alcohol or alkyl polyethoxye alcohol, with glucose or source of glucose reaction, form glucoside (being connected the 1-position) then.Then, other glycosyl units can be connected their the 1-position and 2-, 3-, 4-and/or the 6-position of aforementioned glycosyl units, preferably mainly in the 2-position.
Fatty acid amide surfactant comprises those with following chemical formula:
Figure C200480005176D00141
R wherein 6Be the alkyl that comprises about 7 to about 21 (preferred about 9 to about 17) carbon atoms, and each R 7Be selected from hydrogen, C 1-C 4Alkyl, C 1-C 4Hydroxyalkyl and-(C 2H 4O) xH, wherein x changes to about 3 scope about 1.
Preferred acid amides is C 8-C 20Glutamine, a glycollic amide, diglycollic amide and isopropanol amide.
This paper composition can comprise reach about 20%, preferred about 2% to about 10% polyhydroxy fatty acid amide surfactant.If present, the polyhydroxy fatty acid amide surfactant component typically is chemical formula:
Figure C200480005176D00142
R wherein 1Be H, C 1-C 4Alkyl, 2-hydroxyethyl, 2-hydroxypropyl, or their mixture, preferred C 1-C 4Alkyl, more preferably C 1Or C 2Alkyl, even more preferably C 1Alkyl (that is methyl); And R 2Be C 5-C 31Alkyl, preferred straight chain C 7-C 19Alkyl or alkenyl, more preferably straight chain C 9-C 17Alkyl or alkenyl, even more preferably straight chain C 11-C 15Alkyl or alkenyl, or their mixture; And Z is a polyhydroxy alkyl, and it comprises and has at least 3 straight-chain alkyl chains that directly are connected the hydroxyl on the chain, perhaps their alkoxy derivative (preferred ethoxylation or propoxylation).R 2-C (O)-N＜be preferably selected from coconut oleoyl amine, stearylamide, oleylamide, laurylamide, myristamide, decyl amide, palmitic amide, butter acid amides and their mixture.Z is preferably obtained by reduction amination by reducing sugar; More preferably Z is the sugar alcohol base.Suitable reducing sugar comprises glucose, fructose, maltose, lactose, semi-lactosi, seminose and wood sugar.Can use high glucose maize treacle, high-fructose corn syrup and high malt sugar maize treacle and top listed various sugar as raw material.These maize treacle can generate the sugar component mixture that is used for Z.Should know that this never is to want to get rid of other proper raw material.Z preferably will be selected from-CH 2-(CHOH) n-CH 2OH ,-CH (CH 2OH)-(CHOH) N-1-CH 2OH ,-CH 2-(CHOH) 2(CHOR ') (CHOH)-CH 2OH and their alkoxy derivative, wherein n is 3 to 5 integer (containing 3 and 5), and R ' is H or ring-type or aliphatic monose.Even more preferably wherein n be 4 sugar alcohol base, especially-CH 2-(CHOH) 4-CH 2OH.
The high surfactant composition comprises by described high surfactant composition weight meter at least about 20% surfactant system; Preferred about 20% to about 100% surfactant system; More preferably from about 30% to about 99% surfactant system; Even more preferably from about 35% to about 98% surfactant system; Also even more preferably from about 40% to about 98% surfactant system.
Can be used for solvent of the present invention and typically be selected from water, alcohol, ethylene glycol, ether alcohol and their mixture, more preferably water, ethylene glycol, ethanol, glycol ether and their mixture, even more preferably propylene carbonate, propylene glycol, tripropylene glycol positive propyl ether, Diethylene Glycol n-butyl ether, water and their mixture.Solubleness is counted at least about 12% by solution weight in the water that this paper solvent preferably has, more preferably at least about 50%.
Can reduce product viscosity and/or give shear-thinning or non newtonian rheology feature for composition solvent can exist at this paper, but be not preferred because these solvents typical case is expensive, and do not provide significant non-shearing relevant beneficial effect.Therefore, in a preferred embodiment, when being used for foam-generating dispenser the high surfactant composition of this paper in whole relevant shear scope as Newtonian fuid.
The preferred solvent of the present invention that can be used for of giving Newtonian behavior comprises one, two and polyhydroxy-alcohol, ether and their mixture.Alkyl carbonate such as propylene carbonate also are preferred.
Can be used for enzyme of the present invention and comprise cellulase, hemicellulase, peroxidase, proteolytic enzyme, glucoamylase, amylase, lipase, at, polygalacturonase, zytase, reductase enzyme, oxydase, phenol oxidase, lipoxygenase, ligninase, Starch debranching enzyme, tannase, pentosanase, malanase, beta-glucanase, arabinase and their mixture.Preferred combination is a detergent composition, and it contains the mixture of conventional enzyme applicatory such as proteolytic enzyme, amylase, lipase, at and/or cellulase.By weight, enzyme typically exists with about 0.0001% amount to about 5% organized enzyme.Preferred protease is selected from (Novo Industri A/S), BPN ', protease A and proteolytic enzyme B (Genencor) and their mixture.Proteolytic enzyme B more preferably.Preferred amylase comprises With people such as authorizing Antrim be published on August 18th, 1994 (transferring Genencor International) WO 94/18314 A1 and authorize Svendsen and
Figure C200480005176D0015115523QIETU
-Frantzen also is published in the amylase described in WO 94/02597 A1 on February 3rd, 1994 (transferring NovoNordisk A/S).The further non-limiting example of preferred enzyme is disclosed in people such as authorizing Vinson and is published among WO 99/63034 A1 on December 9th, 1999.
Micro emulsion or former micro emulsion composition, and especially platter washing composition also the typical case comprise low water-soluble oil, its solubleness in water by described low water solubility weight of oil less than about 5,000ppm, preferred about 1/1000000th (0ppm) is to about 1,500ppm, more preferably from about 1/1st to about 100ppm.Can be used for that preferred low water-soluble oil of the present invention comprises terpenes, isoparaffin, other has the oil of above-mentioned solubleness, and their mixture.
Under the situation without foam-generating dispenser, effective foaming dilution range that the platter washing composition typical case of this paper has is for less than about 50%, and preferred about 0% to about 40%, more preferably from about 0% to about 35% dilution range.Yet, in an embodiment of this paper invention, when using foam-generating dispenser, be at least about 50% in effective foaming dilution range that platter washing composition has, preferred about 50% to about 100%, more preferably from about 75% to about 100%, even 85% to about 100% dilution range more preferably from about.The effectively following calculating of foaming dilution range: the foam formation curve of figure I obtains by the extent of dilution of testing various platter washing compositions with the foamy column method of testing of this paper.This curve can use maybe need not be assigned in the post from foam-generating dispenser and obtain." effectively foam " is defined as being generated by given platter washing composition according to the foam formation curve foam of half (50%) at least of foamy maximum volume at this paper.Therefore, in figure I, when not using foam-generating dispenser, about 28% to about 2% product concentration forms effective foam, and it converts effective foaming dilution range to is 26% (that is, 28%-2%).Yet, when same platter washing composition uses (that is, distributing certainly) foam-generating dispenser, can find out that effective foam is created on distribution point (100% product concentration) until the product concentration that reaches about 3%.This is because described dish dishwashing kit generates the foamy platter washing composition extent of dilution of water to be different from the extent of dilution that forms the maximum foam volume according to the foamy column method of testing fully.Therefore, the effective foaming dilution range the when platter washing composition of figure among the I distributes from the foaming divider be 97% (, 100%-3%).
Figure C200480005176D00171
Figure I
Can be used for platter washing composition of the present invention has an oily solubility curve, and described curve is formed by oily dissolution test method defined herein." effective oily solubleness " is defined as according to depicting the oily solubility curve of product concentration (that is, solubleness) function as at this paper, is at least 20% the oily solubleness that is dissolved in the maximum oil mass of given platter washing composition.Therefore, in figure I, the maximum oil mass of dissolved is about 4.7 during 70% product concentration, and therefore effective oily solubleness is at least about 0.94 amount.Effective oily solubleness appears at about 96% to about 42% solubility range, and it is convertible into about 54% effective oily solubility range.
Can find out the I from figure, overlapping without almost not having between the foam formation curve of foam-generating dispenser and the effective oily solubilization dilution range.Similarly, can find out between effective foaming dilution range (28% to 2%) and effective oily solubilization dilution range (42% to 96%), do not have overlapping without foam-generating dispenser.On the contrary, when using foam-generating dispenser, the dilution range of effectively bubbling (3% to 100%) is overlapping with effective oily solubilization dilution range (42% to 96%) complete (100%).In a preferred embodiment, effectively foaming dilution range and effective oily solubilization dilution range are overlapping, preferred effectively foaming dilution range and effective oily solubilization dilution range are overlapping at least about 10%, more preferably from about 25% to about 100%, even more preferably from about 50% to about 100%, especially under the situation of micro emulsion or former micro emulsion.In addition, it is highly preferred that effective foaming extent of dilution be overlapped in oily solubility curve oil the solubleness maximum a bit.Therefore, thus the present invention encourages the user to make the optimized concentration/product dilution of cleaning use this product with dissolving oil more effectively.
The present invention has approved this platter washing composition, and it is next more effective at oily solubility curve that especially micro emulsion and former micro emulsion platter washing composition need the foam-generating dispenser of container and this paper, and preferred maximum extent of dilution obtains the desirable foaming of human consumer down.Therefore, preferably when platter washing composition uses container and foam-generating dispenser, the foam formation curve when effectively the dilution factor that generates of foam significantly is different from unused container and foam-generating dispenser.
Can be used for hand dishwashing composition of the present invention, cleaning compositions, former micro emulsion composition and micro emulsion composition are known in the art, as for example authorizing Farnworth and Martin and being published in WO 96/01305 A1 on January 18th, 1996, authorize people such as Blum and be published in the United States Patent (USP) 5 on December 29th, 1998,854,187, authorize people such as Robbins and be published in the United States Patent (USP) 6 on November 14th, 2000,147,047, authorize people such as Robbins and be published in WO 99/58631 A1 on November 18th, 1999, authorize Matta and be published in the United States Patent (USP) 4 on April 16th, 1985,511,488, authorize people such as Loth and be published in the United States Patent (USP) 5 on December 24th, 1991,075,026, authorize people such as Loth and be published in the United States Patent (USP) 5 on December 31st, 1991,076,954, authorize people such as Loth and be published in the U.S. Pat 05082584 on January 21st, 1992, authorize people such as Loth and be published in the United States Patent (USP) 5 on April 28th, 1992,108,643, be filed in the common unsettled U.S. Patent application/451064 (P﹠amp on February 28th, 2003 for " Protomicroemulsion; Cleaning Implement Containing Same, And Method Of Use Therefor " with the title of authorizing people such as Ford; G Case # AA614FP), the title of authorizing people such as Ford is filed in the common unsettled U.S. Patent application 60/472941 (P﹠amp on May 23rd, 2003 for " Protomicroemulsion; Cleaning Implement ContainingSame, And Method Of Use Therefor "; G Case # AA614P2), the title of authorizing people such as Ford be filed in for " Protomicroemulsion; Cleaning ImplementContaining Same, And Method Of Use Therefor " _ _ _ _ _ _ _ _ _ common unsettled Application No. _ _ _ _ _ _ _ _ _ _ _ _ (P﹠amp; G Case #AA614P3) and authorize Hutton and Foley title and be filed in for " Protomicroemulsion; Cleaning Implement Containing Same, And Method Of UseTherefor " _ _ _ _ _ _ _ _ _ common unsettled Application No. _ _ _ _ _ _ _ _ _ _ _ (P﹠amp; G Case # AA633FP).The platter washing composition of mentioning in the above-mentioned reference or the change of above-mentioned composition are especially preferred to be used jointly with container as herein described and foam-generating dispenser.
The viscosity that this paper high surfactant composition typical case has is at least about 0.05Pa*s, preferred about 0.05Pa*s is to about 10Pa*s, more preferably from about 0.1Pa*s is to about 7Pa*s, in addition more preferably from about 0.2Pa*s to about 5Pa*s, and even 0.3Pa*s about 4Pa*s extremely more preferably from about.
Though the high surfactant composition is preferably sold as individual articles in container, this is not essential, because this paper has imagined restock thing and separate components in the same external member.
The moulding applicator
Find that further the moulding applicator is compared with common applicator significantly improved result can be provided surprisingly and be easy to and used.The moulding applicator is designed and makes the size that is easy to hand, and to be used for blistered platter washing composition is applied in surface to be cleaned be dish.Find, if blistered platter washing composition is applied on the flat applicator, follow blistered platter washing composition rapidly by wiping on first dish of contact, and a small amount of blistered platter washing composition will be retained on the flat applicator to be used to clean the dish of back.Make like this and use blistered platter washing composition not only expensive (because the composition contact range significantly reduces) but also effort (new foaming platter washing composition being applied on the flat applicator) because often need.On the contrary, comprise the moulding applicator that the foaming platter washing composition holds district's (as protection breach and/or bag) and will be for a long time more effectively hold and distribute blistered platter washing composition.
Because the moulding applicator will be often used in scouring, so preferably its at least one surface comprises lapped face.The moulding applicator typically is selected from porous material such as natural or synthetic sponge, brush, the metal swab, textile materials, non-woven material, abrasive material, plastic material, textile material, the primitive fiber cleaning material, polymeric material, resin material, elastomeric material or their mixture, preferred natural or synthetic sponge, brush, the metal swab, abrasive material, foam rubber material, function absorbing material (FAM), polyurethane foam and their mixture, more preferably natural or synthetic sponge, brush, abrasive material, foam rubber material and their mixture, all open-celled structure types be highly preferred.These moulding applicators are available from a plurality of commercial source, as Minnesota Mining and Manufacturing Company (3M), St.Paul, Minnesota, U.S.A..If the moulding applicator is made by flimsy relatively material or the material torn easily, so preferred this material partially or completely permeable more robust materials of water such as non-woven material covers.Same available be by plastics or polymeric material (as available from for example Minnesota Mining and Manufacturing Company (3M), St.Paul, Minnesota, U.S.A. and based on for example Scotch-Brite TMGeneral scouring pad) surface of making.
Preferably, the receptivity that can be used for FAM of the present invention by the weight of FAM greater than about 20g H 2O/g, more preferably 40g H 2O/g.This preferred FAM is described in people such as authorizing DesMarais and is published in the United States Patent (USP) 5,260,345 on November 9th, 1993 or authorizes people such as Dyer and be published in the United States Patent (USP) 5,889,893 on May 4th, 1999.The embodiment of optimization polyurethane is described in people such as authorizing Thoen and is published in the United States Patent (USP) 5 on February 18th, 1992,089,534, authorize people such as Milovanovic-Lerik and be published in the United States Patent (USP) 4 on December 6th, 1988,789,690, authorize Kao Corporation and be published in the Japanese patent publication 10-182780 on July 7th, 1998, authorize Yokohama Gum and be published in the Japanese patent publication 9-30215 on February 4th, 1997, authorize The Dow Chemical Company and be published in the Japanese patent publication 5-70544 on March 23rd, 1993 and authorize TheBridgestone Company and be published among the Japanese patent publication 10-176073 on June 30th, 1998.
Preferably, the moulding applicator is not hard, but have at least one elastic anchor is arranged, and preferably by what lapped face covered elastic anchor is arranged.This choosing wantonly has elastic anchor to allow the user to change contact amount, pressure etc. between scrub surfaces and the dish.Therefore blistered platter washing composition preferably be applied directly in the moulding applicator by foam-generating dispenser or on.
See Fig. 2 again, this figure shows top perspective, the sectional view of the preferred embodiment of this paper moulding applicator 12, and sponge kind moulding applicator 12 comprises and holds district 50, and blistered platter washing composition is applied to this so that use.Hold district 50 therefore the typical case surrounded by wall 52, it prevents that blistered composition from promptly being wiped from moulding applicator 12.Hold the district and be preferably the interior concave indentation of moulding applicator, it can be Any shape and the pattern that keeps the foaming platter washing composition to contact with the moulding applicator.In a preferred embodiment, hold the district comprise steep relatively concave wall or when the typical case uses, effectively blistered washing composition is retained in hold in the district and distribution for a long time other structure.Typically, hold the district and can hold about 1mL to about 200mL, preferably about 2mL is to about 150mL, and more preferably from about 5mL is to the foaming platter washing composition of about 100mL.
In Fig. 2, moulding applicator 12 further comprises a plurality of lapped faces 54 to clean dish.It is highly preferred that at least one lapped face is provided on the moulding applicator.
Fig. 3 shows perspective, the sectional view of the preferred embodiment of moulding applicator 12, and described moulding applicator is made into sponge kind moulding applicator 12, and it has a bag shape and holds district 50, and its interior dimensions is indicated by dotted line.Blistered platter washing composition through port 56 is added to hold to be distinguished in 50, and this mouth can forever open wide as required but also can close.The lapped face 54 basic whole outsides of moulding applicator 12 that cover are to assist in removing the dirt on the dish.
Testing method
This paper viscosity is in 20 ℃ of measurements in model on the Brookfield viscometer of # LVDVII+.The rotor that is used for these measurements is the S31 rotor, uses suitable speed to measure the product of different viscosity; For example, measure the product of viscosity with 1rad/s (12rpm) greater than 1Pa*s; Measure the product of viscosity between 0.5Pa*s and 1Pa*s with 3rad/s (30rpm); Measure the product of viscosity with 6.3rad/s (60rpm) less than 0.5Pa*s.
In order to measure dissolving power, 10.0g product to be measured (if test, this amount comprises water) is placed the 25mL scintillation vial under concrete extent of dilution.Wherein add (the mixture of SOLVENT RED 24 CAS# 85-83-6 and SOLVENTRED 26 CAS# 4477-79-6 at this with 0.045%Pylakrome RED-LX1903, available from Pylam Products, Tempe, Arizona, U.S.A.) the 0.1g food grade canola oil of dyeing covers little bottle cap then.Acutely shook this bottle 5 seconds with hand, allow it leave standstill then, become clarification (through ISO 7027 turbidity testing method) up to it, or up to past 5 minutes, with being as the criterion of at first occurring in two kinds of situations.ISO 7027 methods with as available from Omega Engineering, Inc., Stamford, Connecticut, the turbidimetry equipment of U.S.A. is in wavelength 880nm place measurement turbidity.If bottle becomes clarification, the incremental change with 0.1g adds more oil so, can't become clarification at the appointed time up to bottle.Oil dissolving per-cent note work is successfully dissolved the oil of (that is, bottle is clarification) by the 10.0g product maximum.Preferably, when testing with 75% product concentration, the platter washing composition of this paper dissolves at least about the 1g dyed canola oil, more preferably at least about the 3g dyed canola oil, even more preferably at least about the 4g dyed canola oil.
The foaming feature can record by using foamy column tester (SCT) and using data to draw the foam formation curve.This SCT has 4 posts of a cover.The long 30cm of each post typical case, diameter is 10cm.The thick 0.5cm of post jamb, and the thick 1cm in column bottom.SCT measures the foamy height then with the test soln in the post (typically a plurality of clear plastic post) of the speed rotation sealing of about 2.2rad/s (per minute 21 change) 2 minutes.Dirt can be added in the test soln then, stir once more, and then measure the foam height of gained.Because more dirt is introduced from the surface of washing, this test can be used to the initial foaming feature of imitation composition, and its foaming feature when using.
The foaming characteristic test is as follows:
1. prepare the cylinder of a cover cleaning, drying, calibration, and the water hardness is that 136.8ppm (every liter 2.1 grain) and temperature are 25 ℃ water.
2. add an amount of test composition in each cylinder, adding the total amount that entry makes composition+water in each cylinder then is 500mL.
3. seal above-mentioned cylinder, be placed in the SCT then.
4. connect SCT, and rotated this cylinder 2 minutes.
5. in 1 minute, measure the foamy height, unit is centimetre.
6. bubbling is characterized as the foamy center line average that is generated by composition, and unit is cm.
Composition preferably has the foaming profile maxima and is at least about 2cm as described in the present invention, more preferably at least about 3cm, even 4cm more preferably from about.
Foam wt is than being that every gram product generates measuring of foamy mL number.Foam wt is as follows than measuring: volumetric measuring device of weighing such as graduated cylinder obtain tare weight.Then, use foam-generating dispenser (if applicable) in graduated cylinder, is pushed product dispensing several times for discontinuous distribution device, then distributes for some time for the continuous dispensing device.To discontinuous device (pump, atomizer) by 10 times or continuous apparatus is distributed 10 seconds is the time length of recommending.Dispensing rate during test should be consistent with the dispensing rate under the normal service condition.For example, the trigger-type sprayer per minute is by 120 times, or palm pump per minute is by 45 times.
Use volumetric measuring device to measure the volume of foam that generates, unit is mL.
Weighing comprises the volumetric measuring device of institute's dispensing product, and unit is gram.From then on deduct the tare weight of this volumetric measuring device in the weight.The result is the gram number of institute's dispensing product.At last, foam wt is than (Unit/g) is by calculating divided by the weight (g of unit) of institute's dispensing product with generating volume of foam (Unit).
The foam wt of mL/g is than the foam mL number that is easy to be converted to every mL product by the density that multiply by the high surfactant composition.
Describe embodiments of the invention with way of example below, but not be intended to limit by any way the present invention.These embodiment may not be interpreted as limitation of the present invention, therefore under the condition that does not deviate from spirit and scope of the invention, can carry out many changes to it.
Embodiment 1
Foam-generating kit comprises that 300mL is filled with the hollow plastic container of micro emulsion platter washing composition, incidental T1 series available from Airspray, is similar to frothing machine shown in Figure 1.This T1 frothing machine is adjusted to and comprises the 3rd reticulation that is positioned at nozzle end 41 places as shown in Figure 1.Also comprise moulding applicator as described in Figure 3.When a minute timing, the foam wt ratio that blistered platter washing composition has is about 3mL/g, and foam has emulsus, uniform outward appearance and feel.Penetrate by nozzle in the mouth of moulding applicator, press starter then, blistered platter washing composition is assigned to the pocket type moulding applicator from the foaming divider foam-generating dispenser.When using as mentioned above, this dish dishwashing kit the excellent contact scope is provided and the foam that in whole normal use, continues with the cleaning dish.Yet if do not use foam-generating dispenser (that is, only platter washing composition being poured out) in container, the dilution range of effectively bubbling and effective oily solubilization dilution range are significantly not overlapping.
Embodiment 2
The described radical ion micro emulsion as following chemical formula A-G is provided, packs with the foam-generating dispenser of embodiment 1.Prescription F is a gel, and other prescription is liquid.
A B C D E F G
C 12Alkyl ethoxy 0.6Sodium sulfate 35 40 35 35 28 30 26
C 12-14Alkyl dimethyl amine oxide 8.5 9.6 8.5 8.5 6.3 7.3 6
C 8The alcohol ethoxylate nonionogenic tenside 3.9 4.4 3.9 3.9 3 3.4 3
Poly-(dimethylaminomethyl CALCIUM ACRYLATE) 0.2 0.3 0.2 0.2 0.2 0.2 0.2
1, two (the methylamine)-hexanaphthenes of 3- 0.6 0.7 0.6 0.6 0.5 0.6 0.6
Enzyme (amylase/proteolytic enzyme) 0.1 -- -- 0.1 0.1 -- --
OrganismIsoparaffin limonene terpinol 4 -- -- 4 -- -- -- -- 8 -- 6 -- -- 10 -- 20 -- -- -- -- --
SolventEthanol propylene glycol tripropylene glycol n-propyl ether one glycollic amide propylene carbonate water 10--------surpluses 6--------surpluses 2 14------surpluses 10--------surpluses 12 -- -- -- 8 bal. ----10 5--surplus 8--------surpluses
Thickening materialThe pyrogenic silica xanthan gum -- -- -- -- -- -- -- -- -- -- 2.5 2.5 -- --
Embodiment 3
Made the 1 described foam-generating kit as embodiment, different is, and the T1 frothing machine is adjusted to the top is sponge, rather than the 3rd reticulation.This sponge is the viscose sponge, and it is cut into shape, and is securely fixed in the inside that is right after of nozzle.The foam that generates is an emulsus, and from attractive in appearance be pleasant.The relevant portion of all documents of quoting in detailed Description Of The Invention is incorporated herein by reference; It is to its approval as prior art of the present invention that the quoting of any document not can be regarded as.
Although illustrated and described the present invention with specific embodiments, it will be apparent to those skilled in the art that and to make many other variation and modifications in the case of without departing from the spirit and scope of protection of the present invention.So all such changes and modifications that in additional claims, are included in the scope of the present invention consciously.

Claims (6)

1. foam-generating kit, described external member comprises:
A. comprise the non-aerosol container that is used to generate the foamy foam-generating dispenser, this foam-generating dispenser comprises air injection piston; With
B. high surfactant composition, described composition is micro emulsion or former micro emulsion, and the surfactant system that comprises 35%-98% by the weight of described high surfactant composition, described surfactant system comprises at least a tensio-active agent that is selected from alkyl-sulphate, alkoxy sulfate, alkylsulfonate, alkoxyl group sulfonate, alkylaryl sulphonate and their mixture
Wherein when using with described high surfactant composition, described foam-generating dispenser generates foam wt than the foam greater than 2mL/g.
2. foam-generating kit as claimed in claim 1, wherein said foam-generating dispenser comprises at least three reticulations, wherein said high surfactant composition Continuous Flow through described three reticulations so that generate foam.
3. foam-generating kit as claimed in claim 1, wherein said high surfactant composition is a Newtonian fuid.
4. foam-generating kit as claimed in claim 1, wherein said high surfactant composition also comprises enzyme.
5. foam-generating kit as claimed in claim 1, described external member also comprises the moulding applicator.
6. foam-generating kit as claimed in claim 1, wherein said high surfactant composition is a platter washing composition.
CNB2004800051760A 2003-02-28 2004-03-01 Foam-generating kit containing a foam-generating dispenser and a composition containing a high level of surfactant Expired - Fee Related CN100519725C (en)

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US45106303P 2003-02-28 2003-02-28
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US47294103P 2003-05-23 2003-05-23
US60/472,954 2003-05-23
US60/472,941 2003-05-23
US50266803P 2003-09-12 2003-09-12
US50267303P 2003-09-12 2003-09-12
US60/502,673 2003-09-12
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EP1599569A1 (en) 2005-11-30
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JP2006515380A (en) 2006-05-25

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