CN100515546C - 惰性阳极组件 - Google Patents
惰性阳极组件 Download PDFInfo
- Publication number
- CN100515546C CN100515546C CNB2003801040824A CN200380104082A CN100515546C CN 100515546 C CN100515546 C CN 100515546C CN B2003801040824 A CNB2003801040824 A CN B2003801040824A CN 200380104082 A CN200380104082 A CN 200380104082A CN 100515546 C CN100515546 C CN 100515546C
- Authority
- CN
- China
- Prior art keywords
- anode
- electrolysis unit
- limiting material
- bath
- solid limiting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 87
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims description 55
- 239000007787 solid Substances 0.000 claims description 29
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- 229910052782 aluminium Inorganic materials 0.000 claims description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 21
- 239000004411 aluminium Substances 0.000 claims description 19
- 239000013078 crystal Substances 0.000 claims description 17
- 239000003792 electrolyte Substances 0.000 claims description 17
- 230000000670 limiting effect Effects 0.000 claims description 16
- 239000004568 cement Substances 0.000 claims description 12
- 238000005507 spraying Methods 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims 1
- 239000011343 solid material Substances 0.000 abstract description 10
- 229910001610 cryolite Inorganic materials 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 11
- 230000035939 shock Effects 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 238000009413 insulation Methods 0.000 description 8
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 101100165186 Caenorhabditis elegans bath-34 gene Proteins 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 238000003287 bathing Methods 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 229910016569 AlF 3 Inorganic materials 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 235000013024 sodium fluoride Nutrition 0.000 description 4
- 239000011775 sodium fluoride Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- -1 sodium aluminum fluoride Chemical compound 0.000 description 3
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical group FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000011195 cermet Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- KOPBYBDAPCDYFK-UHFFFAOYSA-N caesium oxide Chemical compound [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 1
- 229910001942 caesium oxide Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PPPLOTGLKDTASM-UHFFFAOYSA-A pentasodium;pentafluoroaluminum(2-);tetrafluoroalumanuide Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3] PPPLOTGLKDTASM-UHFFFAOYSA-A 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Nonmetallic Welding Materials (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US42881802P | 2002-11-25 | 2002-11-25 | |
US60/428,818 | 2002-11-25 | ||
US10/713,798 | 2003-11-13 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1917933A CN1917933A (zh) | 2007-02-21 |
CN100515546C true CN100515546C (zh) | 2009-07-22 |
Family
ID=35052368
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003801040824A Expired - Lifetime CN100515546C (zh) | 2002-11-25 | 2003-11-19 | 惰性阳极组件 |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP2688130B1 (ru) |
CN (1) | CN100515546C (ru) |
ES (1) | ES2644864T3 (ru) |
NO (1) | NO20052924D0 (ru) |
RU (1) | RU2293143C1 (ru) |
SI (1) | SI2688130T1 (ru) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101709485B (zh) * | 2009-12-18 | 2012-07-04 | 中国铝业股份有限公司 | 一种采用惰性阳极生产原铝的铝电解槽 |
CN101942677A (zh) * | 2010-09-30 | 2011-01-12 | 中南大学 | 一种铝电解惰性阳极用保温包覆材料及其应用 |
EP3786314B1 (en) * | 2014-09-08 | 2022-07-20 | Elysis Limited Partnership | Anode apparatus |
WO2017132353A1 (en) | 2016-01-26 | 2017-08-03 | Alcoa Usa Corp. | Insulation assembly for electrolysis cell |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5098530A (en) * | 1988-11-17 | 1992-03-24 | Verenigte Aluminium-Werke Ag | Carbon electrode with gastight, temperature stable protective globe |
US20010035344A1 (en) * | 2000-01-13 | 2001-11-01 | D'astolfo Leroy E. | Retrofit aluminum smelting cells using inert anodes |
US20030209426A1 (en) * | 2000-12-08 | 2003-11-13 | Slaugenhaupt Michael L. | Insulating lid for aluminum production cells |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH579155A5 (ru) * | 1971-11-16 | 1976-08-31 | Alusuisse | |
US4057480A (en) * | 1973-05-25 | 1977-11-08 | Swiss Aluminium Ltd. | Inconsumable electrodes |
GB2062862B (en) | 1979-11-08 | 1984-03-14 | Sumitomo Metal Ind | Fully automatic ultrasonic flaw detection apparatus |
IN169360B (ru) * | 1987-12-22 | 1991-09-28 | Savoie Electrodes Refract | |
US5279715A (en) | 1991-09-17 | 1994-01-18 | Aluminum Company Of America | Process and apparatus for low temperature electrolysis of oxides |
GB9511692D0 (en) | 1995-06-09 | 1995-08-02 | Fosbel Int Ltd | A process for forming a refractory repair mass |
US6423195B1 (en) | 1997-06-26 | 2002-07-23 | Alcoa Inc. | Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals |
US5865980A (en) | 1997-06-26 | 1999-02-02 | Aluminum Company Of America | Electrolysis with a inert electrode containing a ferrite, copper and silver |
US6372119B1 (en) | 1997-06-26 | 2002-04-16 | Alcoa Inc. | Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals |
US6217739B1 (en) | 1997-06-26 | 2001-04-17 | Alcoa Inc. | Electrolytic production of high purity aluminum using inert anodes |
BR0108693B1 (pt) | 2000-02-24 | 2012-01-24 | método para retroajuste de uma célula de fusão de alumìnio. |
-
2003
- 2003-11-19 ES ES13183888.0T patent/ES2644864T3/es not_active Expired - Lifetime
- 2003-11-19 EP EP13183888.0A patent/EP2688130B1/en not_active Expired - Lifetime
- 2003-11-19 RU RU2005120002/02A patent/RU2293143C1/ru active
- 2003-11-19 SI SI200332555T patent/SI2688130T1/en unknown
- 2003-11-19 CN CNB2003801040824A patent/CN100515546C/zh not_active Expired - Lifetime
-
2005
- 2005-06-15 NO NO20052924A patent/NO20052924D0/no not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5098530A (en) * | 1988-11-17 | 1992-03-24 | Verenigte Aluminium-Werke Ag | Carbon electrode with gastight, temperature stable protective globe |
US20010035344A1 (en) * | 2000-01-13 | 2001-11-01 | D'astolfo Leroy E. | Retrofit aluminum smelting cells using inert anodes |
US20030209426A1 (en) * | 2000-12-08 | 2003-11-13 | Slaugenhaupt Michael L. | Insulating lid for aluminum production cells |
Also Published As
Publication number | Publication date |
---|---|
EP2688130A1 (en) | 2014-01-22 |
ES2644864T3 (es) | 2017-11-30 |
SI2688130T1 (en) | 2018-06-29 |
RU2293143C1 (ru) | 2007-02-10 |
EP2688130B1 (en) | 2017-07-26 |
NO20052924L (no) | 2005-06-15 |
CN1917933A (zh) | 2007-02-21 |
NO20052924D0 (no) | 2005-06-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20170711 Address after: American Pennsylvania Patentee after: ALCOA USA Corp. Address before: American Pennsylvania Patentee before: Alcoa Inc. |
|
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20090722 |