CN100513586C - Process and device for producing spheroidal graphite cast iron tube - Google Patents
Process and device for producing spheroidal graphite cast iron tube Download PDFInfo
- Publication number
- CN100513586C CN100513586C CNB2007100250628A CN200710025062A CN100513586C CN 100513586 C CN100513586 C CN 100513586C CN B2007100250628 A CNB2007100250628 A CN B2007100250628A CN 200710025062 A CN200710025062 A CN 200710025062A CN 100513586 C CN100513586 C CN 100513586C
- Authority
- CN
- China
- Prior art keywords
- molten iron
- iron
- spheroidization
- magnesium
- production technique
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Landscapes
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Abstract
The invention discloses a manufacturing technique of a nodulargraphitecrystal cast-iron pipe and a device thereof. The invention comprises the processes of: melting iron process, spheroidization process, pouring process, annealing process, finishing process and packing process. In the spheroidization process, a spheroidization agent is added into a reaction chamber positioned at the upper part of a horizontal labiate ladle; the molten iron is poured into the labiate ladle under the temperature of 1410-1530 DEG C; then the labiate ladle is turned over to ensure the reaction time of the molten iron and the spheroidization agent to be not less than 3 minutes; the product is obtained. Compared with the prior art, a pure magnesium block is chosen as the spheroidization agent in the invention, the process cost of spheroidization agent is low and the absorptivity of magnesium is above the average of 60 percent, thus, the spheroidization technology has low cost, low energy consumption and low resources consumption. Meanwhile, the special arrangement of the labiate ladle reaction chamber ensures magnesium steam during the spheroidization process to be contacted with molten iron from the most bottom of the labiate ladle, and the function of wallop when boiloff ensures the molten iron to be stirred sufficiently and facilitates the spheroidization reaction to be more complete and sufficient, which is suitable for water-cooling metal mold centrifugal casting technology which demands high quality on molten iron.
Description
Technical field:
The invention belongs to the production technique of ductile iron pipe and install this technical field, belong to especially with centrifuging and prepare the production technique of ductile iron pipe and install this technical field.
Background technology:
Though the history in existing hundreds of years of the production of cast iron pipe and application, ductile iron pipe causes people's extensive concern with its good intensity, toughness, corrosion resistance nature and plurality of advantages such as saving metal, reliability height after coming out, and obtains fast-developing.Usually the operation of ductile iron pipe comprises smelting iron water conservancy project preface, nodularization operation, cast operation, annealing operation, finishing procedure, packaging process, and the nodularization operation is to make the performance of cast iron pipe produce the qualitative leap important means.The main spheroidizing mode of spheroidal graphite cast iron pours method, lid bag method, subcontracts method, inner type spheroidization method, feeds pompon method, pressure of magnesium adding method, seal flow method etc.What present domestic use was more is to feed the silk method, promptly adopts the mixture of steel band parcel passivated magnesium particle and silico-calcium, rare earth alloy to make heart yearn (the magnesium powder is than 1:1.5), again by wire feeder constant speed, quantitative input molten iron, spheroidizing reacion is carried out at the bag end.The magnesium absorption rate of this spheriodizing technique is at present average about 50%, and anti-interference decaying spheroidisation ability is better, the nodularization effect stability.Feed that the environmental pollution of pompon metallization processes is little, labour intensity is low, technology adjustment and organization of production very flexibly, be easy to adjust, can obtain stable nodularization molten iron composition easily, be suitable for continuous production.But because pure magnesium and alloy must coat with steel band, the mass consumption steel band, and also the magnesium grain will pass through multiple working procedures such as pulverizing, screening, passivation, coating and processes the cost of manufacture height.
Subcontract the spheriodizing technique casting industry precedent that early has success to be used to produce ductile iron pipe abroad, but the data about subcontracting nodularization that can find has just been done simple introduction to technological process, without any processing parameter that can be for reference.Simultaneously because this technological operation control is quite loaded down with trivial details meticulous, rhythm of production is slow, upset and transportation that the foundry that spheriodizing technique is subcontracted in external use generally all uses special-purpose fork truck to finish and subcontracts are moved, each is subcontracted and joins a fork truck, subcontract reinforced, connect iron, nodularization, the action of converting iron all finishes on fork truck, can not large scale continuous prod.
Summary of the invention:
Content to be solved by this invention provides a kind of production technique and production equipment of subcontracting method continuous production ductile iron pipe.
The technical scheme of technical solution problem of the present invention is a kind of production technique of ductile iron pipe, comprise smelting iron water conservancy project preface, nodularization operation, cast operation, annealing operation, finishing procedure, packaging process, described nodularization operation is for being added to subcontracting in the top reaction compartment of horizontal positioned with nodulizing agent earlier, molten iron poured into subcontract, the temperature of molten iron is controlled to be 1410~1530 ℃; To subcontract upset again and make molten iron and nodulizing agent reaction be not less than 3 minutes, get final product,
Described nodulizing agent is the mixture of magnesium, ferrosilicon, calcium chloride, molten iron: the weight ratio of magnesium, ferrosilicon, calcium chloride is 1000:1-1.5:0.001-0.005:0.01-0.05.
Since magnesium during with compound high temperature that sulphur, oxidation symphysis become chemical stability relatively poor, in the middle of placement, the sulphur phenomenon can take place back in molten iron, that is:
2(MgS)+02f2(MgO)+2[S]
After the spheroidizing, magnesium also can continue evaporation with 0.001~0.004%/min in the molten iron stop process, and the two all can cause abnormal nodularizing.
And pure magnesium poor anti jamming capability, be subjected to the influence of tension-active elements such as S, Bi, Pb, Sb, Ti, As big, because blast furnace feeding raw material structure, the place of production more complicated of China, part disturbs the contents of heavy metal elements of nodularization to fluctuate easily, very easily causes " segregation " phenomenon of foundry goods nodularization effect under the situation that does not have effective measure control along with the segregation of interference element in foundry goods.
Above-mentioned two kinds of situations cause the decline of nodularization easily, in order to prevent the decline of nodularization, can also add silico-calcium, rare earth cerium in nodulizing agent, and the weight ratio of silico-calcium, rare earth cerium and magnesium is 1:1.5-3:2-8.
Good stability, the inactive Characteristics Control reversion of chemical property when adding sulfide that silico-calcium can utilize calcium, oxide high-temperature; Add the rare earth cerium and can suppress the tension-active element effect.
For fear of the sticking iron of reaction chamber charging opening, before the nodularization operation, subcontract temperature and be not less than 700 degree.
In order to reduce the slag that produces in the nodularization operation, the purity of magnesium is not less than 99%.
In order to make is that the ductile iron pipe mechanical property is better, prepared molten iron in the described smelting iron water conservancy project preface, and the concentration expressed in percentage by weight of various compositions is: carbon 3.65-3.95%; Silicon: 0.8-1.8%, sulphur: 0.006-0.025%, phosphorus: below 0.08%, manganese: 0.1-0.35%.
In subcontracting, the molten iron aspect ratio is 1:1.25~1.75, the high 1m~1.4m of molten iron liquid level;
Described cast operation is centrifugal casting.
A kind of production equipment that is used for ductile iron pipe nodularization operation, comprise subcontract, switching mechanism, dedusting mechanism, described switching mechanism is for being the hydro-cylinder of center of turning circle with near be positioned at the inclusion top reaction compartment turning axle, one end of hydro-cylinder links to each other with the outside of subcontracting the bottom by the bag frame that is hinged on its piston outer end, and the other end of hydro-cylinder is fixed in carrier base.
Subcontract the more steady of upset in order to make, described turning axle is positioned at the carrier base corresponding recesses
Describedly subcontract the cylinder-packing that internal surface is provided with refractory matter, one side of inclusion is provided with opening for feed, opening for feed and inclusion removably connect, the opposite side of inclusion is provided with the reaction chamber of protrusion, the reaction chamber cap is positioned at the top of reaction chamber, by the sealing of gripping mechanism and reaction chamber, reaction chamber passes through the foraminous dividing plate with inclusion to be separated, the rear and front end of inclusion be positioned at discharge port near be provided with hanging axis.
In order to make in the spheroidizing reacion in the reaction chamber molten iron circulation smooth more, avoid molten iron overstand in reaction chamber, it is excessive to lower the temperature, and dividing plate is provided with the through hole more than 2, and the diameter of dividing plate top through hole is greater than the through hole of the lower partition.
Described dedusting mechanism comprises dust excluding hood, is fixed on the clad of dust excluding hood inside, the cleaning shaft of fixedlying connected with dust excluding hood, and cleaning shaft links to each other with the dust excluding hood seat by the dust excluding hood turning axle that is positioned at dust excluding hood base top.
In order to reduce the sticking iron that local cooling causes, near the material the clad axle center is the insulating refractory graphite brick.
The reaction process of subcontracting operation is: subcontract turn over turn 90 degrees after, with the bottom of reaction chamber as for bag, molten iron enters reaction chamber by the reacting hole of reserving on the reaction chamber dividing plate, MAG block begins vaporization after running into high temperature liquid iron, form the magnesium vapour pressure in reaction chamber, magnesium steam is overflowed from the aperture on reaction chamber top and is entered molten iron, is absorbed by molten iron in the bubble uphill process, simultaneously molten iron is carried out violent stirring, all run out of until magnesium.Spheroidizing reacion finishes, and subcontracts reverse flip to horizontality, can skim, sampling, thermometric, convert iron.
The present invention compared with prior art, spheriodizing technique uses pure MAG block as nodulizing agent, the nodulizing agent tooling cost is low, feed the silk cost depletions that method has been saved steel band relatively, and the specific absorption of magnesium is higher, and is average more than 60%, and high energy reaches 70%, can reduce the consumption of nodulizing agent, be the spheriodizing technique of a kind of low cost, less energy-consumption, low consumption of resources.Simultaneously, magnesium steam contacts with molten iron from the bottommost of bag in the time of can making spheroidizing owing to the special setting of subcontracting reaction chamber, wallop during vaporization can fully stir molten iron, make that spheroidizing reacion carries out more fully thoroughly, and can not have the floating potentially dangerous that causes molten iron nodularization inequality of nodulizing agent, be more suitable for water-cooled metal mould centrifugal casting technique to molten steel quality requirement harshness.
Description of drawings:
Fig. 1 is the structural representation of the present invention when overturning.
Fig. 2 is the used structural representation of subcontracting of the present invention.
Fig. 3 is the structural representation of clad of the present invention.
In Fig. 1, Fig. 2, Fig. 3,1 for subcontract, 2 for hydro-cylinder, 3 for the bag frame, 4 for turning axle, 5 for clad, 6 for dust excluding hood, 7 for the dust excluding hood pipeline, 8 for the dust excluding hood turning axle, 9 for the dust excluding hood base, 10 for carrier base, 11 for opening for feed, 12 for hanging axis, 13 for cylinder-packing, 14 for inclusion, 15 for dividing plate, 16 for reaction chamber, 17 for the reaction chamber cap, 18 for locking latches, 19 for the insulating refractory graphite brick.
Embodiment:
Below in conjunction with Fig. 1, Fig. 2, Fig. 3 the present invention is described in detail.
Embodiment 1:
As shown in the figure, the device of subcontracting of the present invention, comprise and subcontract 1, switching mechanism, subcontract the corresponding dedusting mechanism in upset back, described switching mechanism is for being the hydro-cylinder 2 of center of turning circle with near the turning axles 4 inclusion 14 top reaction compartment 16, hydro-cylinder 2 links to each other with the outside of subcontracting 1 bottom by the bag frame 3 that is hinged on its piston outer end, subcontracts 1 and is fixed in the corresponding recesses of carrier base 10.
Subcontract the cylinder-packing 13 that 1 internal surface is provided with refractory matter, one side of inclusion 14 is provided with opening for feed 11, opening for feed 11 and inclusion 14 link together by flange, the opposite side of inclusion 14 is provided with the reaction chamber 16 of protrusion, reaction chamber cap 17 is positioned at the top of reaction chamber 16, by gripping mechanism 18 and reaction chamber 17 sealings, reaction chamber 16 separates by foraminous dividing plate 15 with inclusion 14, dividing plate 15 is provided with 2 through holes, the diameter of dividing plate 15 top through holes is greater than the through hole of the lower partition, and the rear and front end of inclusion 14 is provided with hanging axis 12 near being positioned at discharge port 11
Described dedusting mechanism comprises dust excluding hood 6, is fixed on the clad 5 of dust excluding hood 6 inside, the cleaning shaft 7 of fixedlying connected with dust excluding hood 6, and cleaning shaft 7 links to each other with dust excluding hood seat 9 by the dust excluding hood turning axle 8 that is positioned at dust excluding hood base 9 tops.
In order to reduce the sticking iron that local cooling causes, near the material clad 5 axle center is an insulating refractory graphite brick 19
The present invention is the hydro-cylinder 2 of center of turning circle by being positioned near inclusion 14 top reaction compartment 15 turning axles 4, make and subcontract 1 and overturn, when the axis of inclusion was vertical with the face of land, the opening end of opening for feed 11 and clad 5 formed running fit, and reactant gases is discharged by dedusting mechanism.For fear of the sticking iron of reaction chamber charging opening, before the nodularization operation, subcontract temperature and be not less than 700 degree.Too violent for fear of spheroidizing reacion, in subcontracting, the molten iron aspect ratio is 1:1.25~1.75, the high 1m~1.4m of molten iron liquid level.
Embodiment 2:
A kind of production technique of ductile iron pipe comprises smelting iron water conservancy project preface, nodularization operation, cast operation, annealing operation, finishing procedure, packaging process:
Smelting iron water conservancy project preface:
The concentration expressed in percentage by weight of various compositions is in the control molten iron: carbon 3.65%; Silicon: 0.8%, sulphur: 0.006%, phosphorus: 0.08%, manganese: 0.1%.
The nodularization operation:
Earlier nodulizing agent is added to subcontracting in the top reaction compartment of horizontal positioned, subcontracting temperature is 700 degree, melted molten iron is poured into to subcontract again, utilizes overhead traveling crane to be put on the switching mechanism, and the temperature of molten iron is 1410 ℃; To subcontract upset again molten iron and nodulizing agent were reacted 3 minutes, get final product;
Described nodulizing agent is that purity is the mixture of 99% magnesium, ferrosilicon, calcium chloride, and molten iron: the weight ratio of magnesium, ferrosilicon, calcium chloride is 1000:1:0.001:0.01.
The cast operation:
The molten iron centrifugal casting that nodularization is good.
The existing technology of the cast tube that centrifugal casting is good is annealed, finishing, packing get final product.
Embodiment 3:
A kind of production technique of ductile iron pipe comprises smelting iron water conservancy project preface, nodularization operation, cast operation, annealing operation, finishing procedure, packaging process:
Smelting iron water conservancy project preface:
The concentration expressed in percentage by weight of various compositions is in the control molten iron: carbon 3.75%; Silicon: 1.2%, sulphur: 0.015%, phosphorus: 0.06%, manganese: 0.25%.
The nodularization operation:
Earlier nodulizing agent is added to subcontracting in the top reaction compartment of horizontal positioned, subcontracting temperature is 900 degree, melted molten iron is poured into to subcontract again, utilizes overhead traveling crane to be put on the switching mechanism, and the temperature of molten iron is 1480 ℃; To subcontract upset again molten iron and nodulizing agent were reacted 5 minutes, get final product;
Described nodulizing agent is that purity is the mixture of 99.8% magnesium, ferrosilicon, calcium chloride, and molten iron: the weight ratio of magnesium, ferrosilicon, calcium chloride is 1000:1.2:0.003:0.03.
The cast operation:
The molten iron centrifugal casting that nodularization is good.
The existing technology of the cast tube that centrifugal casting is good is annealed, finishing, packing get final product.
Embodiment 4:
A kind of production technique of ductile iron pipe comprises smelting iron water conservancy project preface, nodularization operation, cast operation, annealing operation, finishing procedure, packaging process:
Smelting iron water conservancy project preface:
The concentration expressed in percentage by weight of various compositions is in the control molten iron: carbon 3.95%; Silicon: 1.8%, sulphur: 0.025%, phosphorus: 0.03%, manganese: 0.35%.
The nodularization operation:
Earlier nodulizing agent is added to subcontracting in the top reaction compartment of horizontal positioned, subcontracting temperature is 1000 degree, melted molten iron is poured into to subcontract again, utilizes overhead traveling crane to be put on the switching mechanism, and the temperature of molten iron is 1530 ℃; To subcontract upset again molten iron and nodulizing agent were reacted 6 minutes, get final product;
Described nodulizing agent is that purity is the mixture of 99.99% magnesium, ferrosilicon, calcium chloride, and molten iron: the weight ratio of magnesium, ferrosilicon, calcium chloride is 1000:1.5:0.005:0.05.
The cast operation:
The molten iron centrifugal casting that nodularization is good.
The existing technology of the cast tube that centrifugal casting is good is annealed, finishing, packing get final product.
Embodiment 5:
Remove and add silico-calcium, rare earth cerium in nodulizing agent, the weight ratio of silico-calcium, rare earth cerium and magnesium is outside the 1:1.5:2, and all the other are identical with embodiment 3.
Embodiment 6:
Remove and add silico-calcium, rare earth cerium in nodulizing agent, the weight ratio of silico-calcium, rare earth cerium and magnesium is outside the 1:3:8, and all the other are identical with embodiment 3.
The specific absorption of subcontracting nodularization molten iron magnesium of embodiment 1-6 is on average 59%, sulphur content 0.00977-0.00871%, and average tensile strength is 452.96, particularly embodiment 5,6, the phenomenon of decaying spheroidisation in batches occurs.
Claims (6)
1, a kind of production technique of ductile iron pipe, comprise smelting iron water conservancy project preface, nodularization operation, cast operation, annealing operation, finishing procedure, packaging process, it is characterized in that: described nodularization operation is for being added to subcontracting in the top reaction compartment of horizontal positioned with nodulizing agent earlier, molten iron poured into subcontract, the temperature of molten iron is controlled to be 1410~1530 ℃; To subcontract upset again and make molten iron and nodulizing agent reaction be not less than 3 minutes,
Described nodulizing agent is the mixture of magnesium, ferrosilicon, calcium chloride, molten iron: magnesium: ferrosilicon: the weight ratio of calcium chloride is 1000:1-1.5:0.001-0.005:0.01-0.05.
2, the production technique of a kind of ductile iron pipe according to claim 1 is characterized in that: add silico-calcium, rare earth cerium in nodulizing agent, the weight ratio of silico-calcium, rare earth cerium and magnesium is 1:1.5-3:2-8.
3, the production technique of a kind of ductile iron pipe according to claim 1 is characterized in that: before the nodularization operation, subcontract temperature and be not less than 700 degree.
4, the production technique of a kind of ductile iron pipe according to claim 1 is characterized in that: the purity of magnesium is not less than 99%.
5, the production technique of a kind of ductile iron pipe according to claim 1 is characterized in that: prepared molten iron in the described smelting iron water conservancy project preface, and the concentration expressed in percentage by weight of various compositions is: carbon 3.65-3.95%; Silicon: 0.8-1.8%, sulphur: 0.006-0.025%, phosphorus: below 0.08%, manganese: 0.1-0.35%.
6, the production technique of a kind of ductile iron pipe according to claim 5 is characterized in that: in subcontracting, the molten iron aspect ratio is 1:1.25~1.75, the high 1m~1.4m of molten iron liquid level.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2007100250628A CN100513586C (en) | 2007-07-04 | 2007-07-04 | Process and device for producing spheroidal graphite cast iron tube |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2007100250628A CN100513586C (en) | 2007-07-04 | 2007-07-04 | Process and device for producing spheroidal graphite cast iron tube |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101113482A CN101113482A (en) | 2008-01-30 |
CN100513586C true CN100513586C (en) | 2009-07-15 |
Family
ID=39022009
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2007100250628A Active CN100513586C (en) | 2007-07-04 | 2007-07-04 | Process and device for producing spheroidal graphite cast iron tube |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100513586C (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SI2251443T1 (en) * | 2009-05-06 | 2012-01-31 | Foseco Int | Treatment ladle |
CN102312034A (en) * | 2011-07-28 | 2012-01-11 | 徐州胜海机械制造科技有限公司 | Method of producing wind power casting from blast furnace molten iron |
CN102489690A (en) * | 2011-12-16 | 2012-06-13 | 十堰市泰祥实业有限公司 | Method for as-cast non-alloying production for QT500-7 main bearing cap of gasoline engine |
CN103909236A (en) * | 2013-01-09 | 2014-07-09 | 广西玉柴机器股份有限公司 | Iron liquid vermicularizing treating method and rotation ladle |
CN103469053B (en) * | 2013-08-28 | 2016-06-22 | 于佩 | A kind of Spheroidal graphite cast iron foundation pile pipe and preparation technology thereof |
CN104480382B (en) * | 2015-01-23 | 2017-01-18 | 四川省川建管道有限公司 | Method for preparing centrifugal nodular cast iron pipe |
CN108386622B (en) * | 2018-04-20 | 2020-07-07 | 广东北晟益通实业有限公司 | Nodular cast iron pipe, preparation process of nodular cast iron pipe for town high-pressure gas pipeline and nodular cast iron pipe for town high-pressure gas pipeline |
CN110453139B (en) * | 2019-09-16 | 2021-11-30 | 黄石新兴管业有限公司 | Device and process method for spheroidizing molten iron by pressing-in method |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3747912A (en) * | 1971-04-23 | 1973-07-24 | Fischer Ag Georg | Converter for treatment of molten ductile cast iron with vaporizable additives |
US4684109A (en) * | 1984-10-16 | 1987-08-04 | Asea Aktiebolag | Melt-transfer device for the protected tapping of molten metal from one vessel to another |
-
2007
- 2007-07-04 CN CNB2007100250628A patent/CN100513586C/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3747912A (en) * | 1971-04-23 | 1973-07-24 | Fischer Ag Georg | Converter for treatment of molten ductile cast iron with vaporizable additives |
US4684109A (en) * | 1984-10-16 | 1987-08-04 | Asea Aktiebolag | Melt-transfer device for the protected tapping of molten metal from one vessel to another |
Non-Patent Citations (4)
Title |
---|
常用的球化处理方法. 王成铎等.现代铸铁. 2004 |
常用的球化处理方法. 王成铎等.现代铸铁. 2004 * |
球墨铸铁球化处理的现状与展望. 王洪新等.辽宁工学院学报,第24卷第6期. 2004 |
球墨铸铁球化处理的现状与展望. 王洪新等.辽宁工学院学报,第24卷第6期. 2004 * |
Also Published As
Publication number | Publication date |
---|---|
CN101113482A (en) | 2008-01-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100513586C (en) | Process and device for producing spheroidal graphite cast iron tube | |
CN101698895B (en) | Low-cost preparation method for high-elongation ductile iron castings | |
CN109576567B (en) | Preparation process of nodular iron casting for heavy axle main speed reducer shell | |
CN102069157A (en) | Method for preparing high-aluminum steel | |
CN101177755A (en) | Method for smelting high-speed steel by employing oxide ore | |
JPS6386830A (en) | Method for casting aluminum alloy ingot | |
CN104928486B (en) | A kind of method of divided silicon and alusil alloy | |
CN103433471A (en) | Spheroidizing method of nodular cast iron | |
CN105886788A (en) | Method and device for preparing titanium-silicon-iron alloy by smelting reduction of hot charged titanium-containing slag | |
CN105886765A (en) | Method for producing ferrosilicon | |
CN111218557B (en) | Casting method of ferrovanadium alloy | |
CN108342577B (en) | The green circulatory of failure platinum catalyst utilizes method | |
CN1218059C (en) | Vermiculizer for disposing high sulfur melted iron in vermicular cast iron production | |
CN110396637A (en) | The technique of low cost, short route, high efficiency production SPHC | |
CN101565792B (en) | Method for smelting boron steel | |
TW202248435A (en) | Ferrosilicon vanadium and/or niobium alloy, production of a ferrosilicon vanadium and/or niobium alloy, and the use thereof | |
CN106086411A (en) | Red mud is utilized to prepare the method and system of ferrosilicon | |
CN101191172A (en) | Producing method for preventing aluminum-manganese-iron alloy pulverizing | |
CN218811861U (en) | Production of casting nodulizer inoculant is with rushing into formula upset package | |
CN105177213A (en) | Pretreatment method of hot charged molten iron for casting | |
CN109468427A (en) | A kind of cast iron pretreating agent and preparation method thereof | |
CN100412215C (en) | Copper-nickel-silicon-ferroalloy | |
CN110331317A (en) | A kind of alumal and preparation method thereof | |
CN112981222B (en) | Method for improving purity of molten iron in nodular cast iron smelting | |
CN112251653B (en) | Aluminum-silicon alloying method for rapidly melting silicon in vacuum bag |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |