CN100508715C - Novel electromagnetic shielding composite material and preparation method thereof - Google Patents
Novel electromagnetic shielding composite material and preparation method thereof Download PDFInfo
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- CN100508715C CN100508715C CNB2006100811647A CN200610081164A CN100508715C CN 100508715 C CN100508715 C CN 100508715C CN B2006100811647 A CNB2006100811647 A CN B2006100811647A CN 200610081164 A CN200610081164 A CN 200610081164A CN 100508715 C CN100508715 C CN 100508715C
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- composite material
- electromagnetic shielding
- powder
- ferrite
- phase composite
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- 239000002131 composite material Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 26
- 239000002033 PVDF binder Substances 0.000 claims abstract description 20
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims abstract description 20
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 11
- 238000007731 hot pressing Methods 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims description 13
- 238000000465 moulding Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 229910010272 inorganic material Inorganic materials 0.000 claims description 4
- 239000011147 inorganic material Substances 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 15
- 239000002245 particle Substances 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 6
- 230000005291 magnetic effect Effects 0.000 abstract description 5
- 239000003302 ferromagnetic material Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 23
- 238000012216 screening Methods 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 6
- 238000011161 development Methods 0.000 description 4
- 230000005294 ferromagnetic effect Effects 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 229910001053 Nickel-zinc ferrite Inorganic materials 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000006249 magnetic particle Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
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- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a composite material formed by conductive stuff and ferromagnetic material, belonging to the electromagnetic shield material, and relative preparation. Wherein, it uses four three-phase composite systems as Ba3Co2Fe23O41-Ni-PVDF as the experiment object; according to volume formula, mixing hexagonal ferrite, metal nickel particles, and polyvinylidene fluoride uniformly, to be arranged in mould; at 180-220Deg. C and the pressure as 10-15MPa, hot pressing them for 15-20mins to be molded; its total shield effect is 30-50dB at 8.2-12.4GHz; and it can avoid the secondary pollution of electromagnetic wave, with better frequency stability of total shield effect. The invention combines the electric shield and magnetic shield, to mainly adsorb the electromagnetic wave, with wider application.
Description
Technical field
The invention belongs to the electromagnetic shielding material field, particularly by conductive filler and ferromagnetic filler are formed, preparation temperature is low, technology is easy a kind of novel electromagnetic shielding composite material and preparation method thereof.
Background technology
Along with the develop rapidly of wireless communication technique, electromagnetic interference, electromagnetic information is revealed, and problems such as electromagnetic environment pollution also become more and more serious.At present, nearly all electronics and the electric equipment interference that all inevitably is subjected to the signal of telecommunication and magnetic signal.Therefore, the problem of electromagnetic interference is subjected to paying close attention to widely, and the research of electromagnetic shielding material also becomes a focus, has great importance for the strategy of sustainable development of national economy.With respect to traditional metal species shielding material, present electromagnetic shielding material develops towards direction light, thin, easily processing, to adapt to the development of passive device in the microelectronics industry.
In recent years, the research of electromagnetic shielding composite material aspect concentrated on two class materials.The first kind mainly is to add conductive particle in polymer, as silver, and copper, nickel, iron or carbon nano-tube etc. improve the conductivity of polymer by formation conductive path in polymeric matrix, thereby improve electromagnet shield effect.The main problem of this type shielding material is, then needs higher cost if arrive higher screening effectiveness, only have the function of single electric screen simultaneously, and reflection loss is too big, causes the secondary electromagnetic interference easily.
The second type shielding material mainly is soft magnetic material to be added to realize electromagnetic shielding in the polymer.For example, nickel-zinc ferrite, hexad ferrite particle or other magnetic-particles are added in the polymer.Because it is higher to add the resistance of particle, the conductivity of composite material is not ideal enough, makes that the screening effectiveness of this type shielding material is not ideal enough.
Recently, there is the people that conductive particle and magnetic-particle are added to simultaneously and prepared the composite material that a class has both electric screen and magnetic screen in the polymer.For example nickel particle and carbonyl iron or nickel particle and nickel-zinc ferrite are added in the polymer, but this class material can only be in low-frequency range shielding electromagnetic wave preferably.Mechanics of communication to the trend of higher frequency development press for development higher frequency more also can shielding electromagnetic wave in the wide region shielding material.
We constitute novel three-phase composite material with hexad ferrite phase, metal phase and organic polymer component among the present invention, have developed a series of electromagnetic shielding composite material.In this class material, high-resistance hexad ferrite not only plays the effect of insulation phase, and the nickel particle that high electricity is led is isolated, and has reduced eddy current effect effectively to the ferromagnetic influence of composite material, and play ferromagnetic effect, improved the magnetic of composite material significantly.Simultaneously, the applying frequency scope of this class material improves greatly, and in the 8.2-12.4GHz scope, total electromagnet shield effect has good application prospects between 30-70dB.
Summary of the invention
The invention provides a kind of novel electromagnetic shielding composite material and preparation method thereof.It is characterized in that: described novel electromagnetic shielding composite material comprises inorganic material: hexad ferrite is [as Z type plane hexad ferrite (Ba
3Co
2Fe
23O
41, Ba
3Co
2Fe
24O
41) or Y type plane hexad ferrite (Ba
2Co
2Fe
115O
22, Ba
2Co
2Fe
2O
22)], conducting metal nickel powder (Ni), and polymeric material: Kynoar (PVDF).Its prescription volume ratio is: nickel 7.5～45%, hexad ferrite 5～42.5%, Kynoar 50%.The granularity of described inorganic material is: nickel 2～3 μ m, hexad ferrite 10～30 μ m.
Technological process of the invention process is as follows:
1) volume batching: get the hexad ferrite powder 5～42.5% of nickel powder 7.5～45%, 10～30 μ m of 2～3 μ m, Kynoar 50% by above-mentioned volume prescription.
2) join sample: nickel powder, Kynoar and ferrite powder are stirred according to aforementioned proportion, mix.
3) moulding: the powder that mixes is placed on the powder compressing machine, is 180～220 ℃ in temperature, and pressure is under the condition of 10～15MPa, hot pressing 15～20min moulding.
The invention has the beneficial effects as follows: by simple composite action, ferromagnetic particle and conductive particle are filled in the polymeric matrix according to certain volume ratio, make composite material have the good electric screen and the characteristic of magnetic screen simultaneously, obtain Ba
3Co
2Fe
23O
41-Ni-PVDF and Ba
3Co
2Fe
24O
41Total screening effectiveness of-Ni-PVDF system is 30～70dB in the 8.2-12.4GHz scope; Ba
2Co
2Fe
11.5O
22-Ni-PVDF, and Ba
2Co
2Fe
12O
22Total screening effectiveness of-Ni-PVDF system is 30～50dB in the 8.2-12.4GHz scope.Above-mentioned four kinds of three-phase composite systems adopt simple heat pressing process to carry out forming materials, have shortened preparation time, have obtained well behaved electromagnetic shielding composite material at short notice.
Description of drawings
Fig. 1: total the screening effectiveness of three-phase composite material with the Changing Pattern of frequency, wherein Fig. 1 (a)～(d) is respectively Ba
3Co
2Fe
23O
41-Ni-PVDF, Ba
3Co
2Fe
24O
41-Ni-PVDF, Ba
2Co
2Fe
12O
22-Ni-PVDF, and Ba
2Co
2Fe
11.5O
22-Ni-PVDF three-phase composite system.The unit of screening effectiveness is dB.
Fig. 2: total the screening effectiveness of three-phase composite material, reflecting barrier usefulness and absorption screening effectiveness are with the Changing Pattern of nickel/(nickel+ferrite) volume ratio.
Embodiment
The purpose of this invention is to provide a kind of novel electromagnetic shielding composite material and preparation method thereof.With Ba
3Co
2Fe
23O
41-Ni-PVDF, Ba
3Co
2Fe
24O
41-Ni-PVDF, Ba
2Co
2Fe
11.5O
22-Ni-PVDF, and Ba
2Co
2Fe
12O
22Four kinds of three-phase composite systems of-Ni-PVDF are as experimental subjects.After according to prescription three kinds of powders being mixed earlier, hot-forming at low temperatures.
Technological process of the invention process is as follows:
1) volume batching: get the hexad ferrite powder 5～42.5% of nickel powder 7.5～45%, 10～30 μ m of 2～3 μ m, Kynoar 50% by above-mentioned volume prescription.
2) join sample: nickel powder, Kynoar and ferrite powder are stirred according to aforementioned proportion, mix.
3) moulding: the powder that mixes is placed on the powder compressing machine, is 180～220 ℃ in temperature, and pressure is under the condition of 10～15MPa, hot pressing 15～20min moulding.
Below exemplifying embodiment is further specified the present invention.
Embodiment 1
Take by weighing an amount of nickel powder, Y type hexad ferrite and 0.416g Kynoar according to listed prescription in the table one and mix and be placed in the mould, in 200 ℃, hot pressing 15min moulding can obtain a series of samples under the 15MPa.
Table one embodiment 1 component prescription
| Numbering | Ni | Ba 2Co 2Fe 11.5O 22 |
| Vol％ | Vol％ | |
| A1 | 17.5 | 32.5 |
| A2 | 35.0 | 15.0 |
| A3 | 42.5 | 7.5 |
Illustrate: all contain 50vol%PVDF in each composite material, weight is 0.416g
Embodiment 2
Take by weighing an amount of nickel powder, Y type hexad ferrite and 0.416g Kynoar according to listed prescription in the table two and mix and be placed in the mould, in 200 ℃, hot pressing 15min moulding can obtain a series of samples under the 15MPa.
Table two embodiment 2 component prescriptions
| Numbering | Ni | Ba 2Co 2Fe 12O 22 |
| Vol％ | Vol％ | |
| A1 | 7.5 | 42.5 |
| A2 | 15.0 | 35.0 |
| A3 | 45.0 | 5.0 |
Illustrate: all contain 50vol%PVDF in each composite material, weight is 0.416g.
Embodiment 3
Take by weighing an amount of nickel powder, Z type hexad ferrite and 0.416g Kynoar according to listed prescription in the table three and mix and be placed in the mould, in 200 ℃, hot pressing 15min moulding can obtain a series of samples under the 15MPa.
Table three embodiment 3 component prescriptions
| Numbering | Ni | Ba 3Co 2Fe 23O 41 |
| Vol％ | Vol％ | |
| A1 | 15.0 | 35.0 |
| A2 | 25.0 | 25.0 |
| A3 | 40.0 | 10.0 |
Illustrate: all contain 50vol%PVDF in each composite material, weight is 0.416g.
Embodiment 4
Take by weighing an amount of nickel powder, Z type hexad ferrite and 0.416g Kynoar according to listed prescription in the table four and mix and be placed in the mould, in 200 ℃, hot pressing 15min moulding can obtain a series of samples under the 15MPa.
Table four embodiment 4 component prescriptions
| Numbering | Ni | Ba 3Co 2Fe 24O 41 |
| Vol％ | Vol％ | |
| A1 | 20.0 | 30.0 |
| A2 | 30.0 | 20.0 |
| A3 | 45.0 | 5.0 |
Illustrate: all contain 50vol%PVDF in each composite material, weight is 0.416g.
Claims (4)
1. novel electromagnetic shielding three-phase composite material, it is characterized in that: comprise inorganic material in the described electromagnetic shielding three-phase composite material: hexad ferrite, conducting metal nickel powder and Kynoar PVDF, its volume ratio is: nickel 7.5～45%, ferrite 5～42.5%, Kynoar 50%.
2. according to the described novel electromagnetic shielding three-phase composite material of claim 1, it is characterized in that: the granularity of inorganic material is in the described electromagnetic shielding three-phase composite material: nickel 2～3 μ m, hexad ferrite 10～30 μ m.
3. according to the described novel electromagnetic shielding three-phase composite material of claim 1, it is characterized in that: described hexad ferrite is Z type plane hexad ferrite: Ba
3Co
2Fe
23O
41, Ba
3Co
2Fe
24O
41Or Y type plane hexad ferrite: Ba
2Co
2Fe
11.5O
22, Ba
2Co
2Fe
2O
22
4. the preparation method of the described electromagnetic shielding three-phase composite material of claim 1 is characterized in that: described electromagnetic shielding three-phase composite material adopts the heat pressing process preparation, and its flow process is:
1) volume batching: get the hexad ferrite powder 5～42.5% of nickel powder 7.5～45%, 10～30 μ m of 2～3 μ m, Kynoar 50% by above-mentioned volume ratio;
2) join sample: nickel powder, Kynoar and ferrite powder are stirred according to aforementioned proportion, mix;
3) moulding: the powder that mixes is placed on the powder compressing machine, is 180～220 ℃ in temperature, and pressure is under the condition of 10～15MPa, hot pressing 15～20min moulding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100811647A CN100508715C (en) | 2006-05-23 | 2006-05-23 | Novel electromagnetic shielding composite material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100811647A CN100508715C (en) | 2006-05-23 | 2006-05-23 | Novel electromagnetic shielding composite material and preparation method thereof |
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|---|---|
| CN1867243A CN1867243A (en) | 2006-11-22 |
| CN100508715C true CN100508715C (en) | 2009-07-01 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100811647A Expired - Fee Related CN100508715C (en) | 2006-05-23 | 2006-05-23 | Novel electromagnetic shielding composite material and preparation method thereof |
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|---|---|
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101807744A (en) * | 2010-03-26 | 2010-08-18 | 西南交通大学 | Planar inverted-F antenna based on Z-type hexaferrite |
| CN105062417B (en) * | 2015-07-15 | 2017-07-21 | 北京新怡源环保科技有限公司 | A kind of organo-mineral complexing nanometer microwave absorbing material and preparation method thereof |
| CN106633547B (en) * | 2016-12-15 | 2018-11-27 | 陕西科技大学 | A kind of Z- type ferrite flaky powder/PVDF Wave suction composite material and preparation method thereof |
| CN107835628A (en) * | 2017-11-17 | 2018-03-23 | 桂林电子科技大学 | A kind of Fe/Y ferrites composite wave-suction material and preparation method thereof |
| CN110570977B (en) * | 2019-09-30 | 2021-08-10 | 江苏亨通线缆科技有限公司 | High electromagnetic shielding heat-resistant cable |
| CN110660502B (en) * | 2019-09-30 | 2021-06-04 | 江苏亨通线缆科技有限公司 | High-strength electromagnetic shielding cable |
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2006
- 2006-05-23 CN CNB2006100811647A patent/CN100508715C/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN1867243A (en) | 2006-11-22 |
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