CN100506703C - Method of preparing titanium dioxide, tin dioxide and doping composite fiber material thereof - Google Patents
Method of preparing titanium dioxide, tin dioxide and doping composite fiber material thereof Download PDFInfo
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- CN100506703C CN100506703C CNB2007100110552A CN200710011055A CN100506703C CN 100506703 C CN100506703 C CN 100506703C CN B2007100110552 A CNB2007100110552 A CN B2007100110552A CN 200710011055 A CN200710011055 A CN 200710011055A CN 100506703 C CN100506703 C CN 100506703C
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Abstract
This invention relates to a method for preparing fiber TiO2, SnO2 and its doped compound material characterizing in utilizing a fiber material as a template, taking TBT, titanium tetrahalide, tin tetrachloride or a mixture as a precursor, which is carried by nitrogen or argon and enters into a reactor with a gas containing ammonia for chemical gaseous phase deposition, in which, the gas flow, deposition temperature and the sinter atmosphere and temperature are controlled, the inert gas is heated to get load-type fiber material to be sintered under the atmosphere of oxidation and reaction to remove the fiber template and form an oxide fiber material, and utilize the active carbon fiber template and ignition process to form porous fiber or tubular fiber material.
Description
Technical field
The invention belongs to technical field of nano material, it is a kind of method for preparing nano material, be specifically related to utilize activated carbon fiber as template, in conjunction with the method for atmospheric cryochemistry vapour deposition preparation (cannulated) fibrous titanium dioxide, tindioxide and doped and compounded material thereof.
Background technology
Titanium dioxide nano material is because plurality of advantages such as inexpensive, nontoxic, spectrochemical property is stable, transforms at memory by using, the photoelectricity of sun power, obtained widespread use aspect the photochromic and photochemical catalysis.The preparation method of titanic oxide material has vapour deposition process
[1-9], sol-gel method etc., wherein the vapour deposition fado uses than higher temperature, as more than 300 ℃, common is 500～600 ℃.Utilize the reaction or the pyrolysis of presoma and oxygen under the high temperature to form oxide compound
[6 7]Be the common method of preparation film-type or coating material, can also introduce multiple composition and particle be carried out surface modified as deposit carbon composition or carbon nanotube
[4], nitrating handles, vapour deposition silver
[9]Perhaps iron, nickel etc.This method temperature of reaction height does not need sintering processes.The pyrolysis of organometallic precursor, oxidizing reaction, muriatic hydrolysis or oxidation form metal oxide.But high temperature reacts down and the sedimentation velocity ratio is very fast, and producing particle diameter may be bigger.The effect that is unfavorable for forming the bigger material of porosity or keeps template.Can not use matrix or (template) material of non-refractory.
Be the specific surface area and convenient recycling that increase titanium dioxide, the preparation research of the titanium dioxide of nanotube form and fiber pattern comes into one's own.
Titanium dioxide (little) nanotube is a kind of one dimension (little) the nanotube-shaped material of size in (little) nanometer range, makes it have more outstanding use value.The preparation method of titania nanotube has template, hydrothermal synthesis method, sol-gel method, chemical Vapor deposition process, electrochemical process etc.These methods respectively have its relative merits.Hydrothermal synthesis method can obtain the nanotube of reduced size, but the reaction needed high-temperature and high-pressure conditions, and the reaction times is long.Sol-gel method equipment is simple, but the processing requirement strictness.Utilize template to prepare the titania nanotube of nanotube, ordered arrangement, simple to operate, need not high-tension apparatus, be easy to control, but synthetic nanotube caliber is general bigger.
By the literature search of prior art being found template prepares the employed template of titania nanotube at present, be the nano-form, polycarbonate leaching film etc. of porous anodic alumina films (PAA), photoengraving preparation mostly.Be that the report that template prepares titania nanotube is not a lot of with the activated carbon fiber, and adopt the activated carbon fiber direct impregnation more in TiO 2 sol that the template action of activated carbon fiber can not embody well.And adopt the low temperature chemical vapor deposition method, be that the method that template prepares the titanium dioxide Nano/micro tube is not appeared in the newspapers with the activated carbon fiber.
The method for making of bibliographical information titania fiber has: 1. solvent heat treatment
[10]: carbon fiber immerses in the organic solution of presoma, behind the ultra-sonic dispersion after the nitric acid treatment, solvent heat treatment 180 ℃ of 24 hours (dehydrated alcohol, toluene) or supercritical carbon dioxide treatment (150 ℃ 20mpa handle 2 hours), sintering is removed carbon fiber (600 ℃ 5 hours) in oxygen atmosphere afterwards; Utilize CO 2 supercritical to handle the titania fiber specific surface area that obtains and to reach 180m
2/ g; 2. sol-gel method: load colloidal sol is on matrix fiber as (carbon fiber
[11], the PVDF tubular fibre
[12]), sintering removes body material and forms tubular fibre or microtubule then.3. ion exchange method preparation
[13]4. directly obtain by electrospinning silk way
[14]5. directly adopt polymer-based carbon titanium precursor body, dry-spinning obtains macrofiber
[15,16,17], hydro-thermal activation heat treatment or sintering processes then.Fiber generally is solid, does not have hollow structure.Also report does not utilize the preparation of chemical vapor deposition way that the titania fiber of middle hole is arranged.Tindioxide also is a kind of photocatalyst material and electro-conductive material.Its powder preparation method and titanium dioxide are similar, and fibrous preparation methods research is few
[18,19]
Reference:
1.Koichi?Nakasoa，Kikuo?Okuyamaa；*，Manabu?Shimadaa，Sotiris?E.Pratsinisb，Ef?f?ect?of?reaction?temperature?on?CVD-made?TiO2?primary?particle?diameter，Chemical?Engineering?Science?58(2003)3327-3335
2.Zhe?Ding?a，Xijun?Hub，*，Po?L.Yueb，Gao?Q.Lua，Paul?F.Greenfield，Synthesis?ofanatase?TiO2?supported?on?porous?solids?by?chemical?vapor?deposition，CatalysisToday?68(2001)173-182
3.Seung?Yong?Leea，b，Jaehyeon?Parka，b，Hyunku?Joo，Visible?light-sensitizedphotocatalyst?immobilized?on?beads?by?CVD?in?a?fluidizing?bed，Solar?EnergyMaterials?&?Solar?Cells?90(2006)1905-1914
4.Silvia?Orlanducci?a，Vito?Sessa?a，Maria?Letizia?Terranova?a，*，Giovanni?A.Battiston?b，Simone?Battiston?b，Rosalba?Gerbasi，Nanocrystalline?TiO2?on?singlewalled?carbon?nanotube?arrays：Towards?the?assembly?of?organized?C/TiO2nanosystems，Carbon?44(2006)2839-2843
5.V.P.Godbole1，Young-Soon?Kim，Gil-Sung?Kim，M.A.Dar，Hyung-Shik?Shin，Synthesis?of?titanate?nanotubes?and?its?processing?by?different?methods，Electrochimica?Acta?52(2006)1781-1787
6.M.G.Nolan?a，M.E.Pemble?b，D.W.Sheel?a，H.M.Yates，One?step?process?forchemical?vapour?deposition?of?titanium?dioxide?thin?films?incorporating?controlledstructure?nanoparticles，Thin?Solid?Films?515(2006)1956-1962
7.Chien-Sheng?Kuo，Yao-Hsuan?Tseng，Chia-Hung?Huangb，Yuan-Yao?Li，Carbon-containing?nano-titania?prepared?by?chemical?vapor?deposition?and?itsvisible-light-responsive?photocatalytic?activity，Journal?of?Molecular?Catalysis?A：Chemical?270(2007)93-100
8.Ireneusz?Piwon′ski，Aneta?Ilik，Vapor?phase?modification?of?sol-gel?derivedtitania(TiO2)surfaces，Applied?Surface?Science?253(2006)2835-2840
9.L.A.Brook，P.Evans，H.A.Foster，M.E.Pemble，A.Steele，D.W.Sheel，H.M.Yates，Highly?bioactive?silver?and?silver/titania?composite?films?grown?by?chemicalvapour?deposition，Journal?of?Photochemistry?and?Photobiology?A：Chemistry?187(2007)53-63
10.Rusheng?Yuan，Xianzhi?Fu，Ping?Liu?and?Xuxu?Wang，Influence?of?solvents?onmorphology?of?TiO2?fibers?prepared?by?template?synthesis，Scripta?Materialia?55(2006)1003-1006
11.P.Gibot，C.Vix-Guterl，TiO2?and[TiO2/_-SiC]microtubes?prepared?from?anoriginal?process，，Journal?of?the?European?Ceramic?Society?27(2007)2195-2201
12.Haiqiang?Lu，Lixiong?Zhang，Weihong?Xing，Huanting?Wang，Nanping?Xu，Preparation?of?TiO2?hollow?fibers?using?poly(vinylidene?fluoride)hollow?fibermicrofiltration?membrane?as?a?template，Materials?Chemistry?and?Physics?94(2005)322-327
13.Yumin?Liu，Tao?Qi，Yi?Zhang，Synthesis?of?hexatitanate?and?titanium?dioxidefibers?by?ion-exchange?approach，Materials?Research?Bulletin?42(2007)40-45
14.Sudha?Madhugiri?a，Bo?Sun?b，Panagiotis?G.Smirniotis?b，John?P.Ferrarisa，Kenneth?J.BalkusJr.Electrospun?mesoporous?titanium?dioxide?fibers，Microporous?and?Mesoporous?Materials?69(2004)77-83
15. Chinese invention patent: Bao Nan; Zhang Feng; Zhang Chenglu; Sun Jian; Ma Dong, preparation method's 200510104390.8 application numbers of photocatalytic titania fiber material
16. Chinese invention patent: Liu Heyi; Xu Dong; Bao Nan; Zhao Xiangjin; Hou Xianqin; Wang Yanling; Du Wei; Zhang Guanghui; Wang Xinqiang; Lv Mengkai; Yuan Duorong, 200410024265 application numbers. preparation method 17. Lee of titania fiber are from lifting Zhai Guojun, Fu Zhongyu, Wang Peijie, Chang Min, Li Xiaoning, the preparation of nano fiber non-woven fabric and Photocatalytic Performance Study, Chinese Journal of Inorganic Chemistry, 2006,22 (11), 2061-2065
18. yellow at silver, Chai Chunfang, Wu Jian etc., SnO2 nano belt water assisting growth is in characterizing Chinese Journal of Inorganic Chemistry, 2006,22 (11), 2037-2041
19.Qin?Kuang，Song-Fei?Li，Zhao-Xiong?Xie*，Shui-Chao?Lin，Xian-HuaZhang，Su-Yuan?Xie，Rong-Bin?Huang，Lan-Sun?Zheng，Controllable?fabrication?ofSnO2-coated?multiwalled?carbon?nanotubes?by?chemical?vapor?deposition，Carbon?44(2006)1166-1172
Summary of the invention
The purpose of this invention is to provide a kind of solvent that do not use, utilize the low temperature vapor deposition method, preparation has the method for (irregular hollow tube) titanium dioxide, tindioxide and the doping composite fiber material thereof of catalysis and adsorpting characteristic.
Technical scheme of the present invention is to use the low temperature chemical vapor deposition method, with the filamentary material is template, as natural and regenerated fiber, charcoal fiber etc., former material precursor that carries by the gas phase carrier gas such as titanium tetrachloride, tetrabutyl titanate, titanium isopropylate (perhaps being called the titanium tetraisopropylate acid esters), aqueous vapor (containing ammoniacal liquor gas) reactive ingredients, the after chemical reaction deposition oxide, sintering processes afterwards obtains the load filamentary material under inert atmosphere.Sintering processes in oxidisability and the atmosphere reactive is removed fibrous template, obtains keeping the materials such as titanium dioxide of fibrous template constitutional features.Utilize activated carbon fiber to make template, control deposition sintering condition, the material of (tubulose in the middle irregular hole) fiber characteristics that obtained to have unique pattern.With charcoal fiberoptic fiber template dipping dopant ion solution, the oven dry back is as the dopant ion mould material, and process deposition and sintering thermal treatment obtain the oxide fibre material of adulterated metal titanium, tin.If the raw fibre template exists with paper or felted, can obtain the nano micron fibre material of paper shape or felted after the deposition sintering processes.Nano material keeps the constitutional features of mould material on the microcosmic.
Concrete steps of the present invention are as follows:
(1) earlier will (gac) fiber clean, dry, activate, standby;
(2) conditioned reaction actuator temperature is between 5～280 ℃;
(3) respectively precursor titanium tetrachloride or organic titanate and ammoniacal liquor 0.01～10M are respectively charged in the bubbler, feed rare gas elementes such as nitrogen or argon gas and be written in the reactor, the ventilation deposition reaction time is at 1～180min;
(4) flow of adjusting precursor, linear velocity is between 0.01～120cm/min;
(5) after deposition reaction finishes, regulate heat-up rate (0.1～50 ℃/min) and the thermal treatment sintering temperature between 100～900 ℃, agglomerating atmosphere is rare gas elementes such as nitrogen, argon gas or air, oxygen water vapour isoreactivity gas, and sintering time is between 0.1～6h.
Effect and benefit of the present invention are: the titania fiber of preparation, have good shapes and structure, the tubular structure that under scanning electron microscope, shows hollow, opening, tubular nanometer material as a kind of special construction and function has a wide range of applications at aspects such as photochemical catalysis, transmitters.Advantage of the present invention is the deficiency that overcomes in existing nano titanium oxide/tindioxide and compound (pipe) fiber production technology thereof: do not use solvent, the reaction times is short, conservation, and reaction is relatively gentleer, simple to operate, reduces cost.This preparation method can be widely used in filamentary material finishing and functionalization, makes material have cleaning, hydrophilic and photocatalytic activity or conduction property.Activated carbon fiber-loaded titanium, tin oxide materials catalyzer or fiber (pipe) shape titanium dioxide, tin (doping) material (catalyzer), have than bigger serface, as absorption and catalytic purification material, very big purposes is arranged in water body and purifying air and pollution detection field.Has important practical value.
Description of drawings
Fig. 1 is the preparation facilities synoptic diagram of filamentary material.
Among the figure: 1,2 are material temperature control and air-lift device, 3 reactors, 4 heating temperature control unit, 5 vent gas treatment and circulation device, the 6th, nitrogen or other rare gas element carrier gas sources of the gas.
Fig. 2 amplifies 1000 times titania fiber scanning of materials Electronic Speculum figure.
Fig. 3 amplifies 5000 times titania fiber scanning of materials Electronic Speculum figure.
Embodiment
Provide specific embodiment below, the present invention will be further described, rather than limit the scope of application of the present invention.
The preparation of embodiment 1 titania fiber
Activated carbon fiber surface deposition: put into activated carbon fiber in the reactor in filamentary material preparation facilities synoptic diagram as shown in Figure 1, logical nitrogen carries preset temperature at 5～70 ℃ titanium tetrachloride vapors and ammonia soln, enter reactor with certain linear velocity 0.01～120cm/min, the temperature maintenance of reactor is at 5～280 ℃.The reactive deposition time was at 1～180 minute.Be warmed up to 100～900 ℃ of heating 0.1～6 hour afterwards in the air, remove template, obtain, have the irregular pore texture filamentary material in centre of nano-anatase or rutile ore constructional feature shown in 3 as Fig. 2.The analysis revealed titania is a nanoscale, and its fiber has the feature of nano material one dimension pipe simultaneously, also has three-dimensional spatial disposition feature.Its Pyrogentisinic Acid's adsorptive power is higher.If heat treated is carried out under inert atmosphere, then titania fiber is in the same place with the charcoal fiber composite.
The preparation of embodiment 2 dioxide composite tin and titania fiber
In reactor, put into activated carbon fiber, feed the precursor gas composition of tin tetrachloride and titanium in proportion, simultaneously intermittently alternately feed the aqueous vapor composition, in the pore texture that enter hydrolysis reaction that presoma takes place in the reactor, is deposited on activated carbon fiber and on the surface.The temperature range of reactor is at 5～280 ℃, the temperature of presoma is at 5～70 ℃, and linear flow rates is at 0.01～120cm/min, sintering in the air, 100～900 ℃ of temperature and time range 1～6 hour obtain different ratios titanium dioxide tindioxide compound (tubulose) fiber.
The preparation of embodiment 3 tindioxide fibers:
Carbon fiber surface deposition: in the reactor of filamentary material preparation facilities as shown in Figure 1, put into activated carbon fiber, logical nitrogen carries preset temperature at 5～70 ℃ tin tetrachloride steam and ammonia soln, enter reactor with certain linear velocity 0.01～120cm/min, the temperature maintenance of reactor is at 5～280 ℃.The reactive deposition time was at 1～180 minute.In air, be warmed up to 100～900 ℃ of heating 0.1～6 hour afterwards, remove template, irregular pore texture tindioxide filamentary material in the middle of can obtaining.If utilize sintering under nitrogen atmosphere or the inert gas atmosphere, do not remove template, obtain the tindioxide of compound charcoal fiber.
The nano material preparation of embodiment 4 doping type titanium oxide or stannic oxide
With a certain amount of salt that contains the different metal composition of activated carbon fiber raw material dipping,, put into reactor after the oven dry, low temperature chemical vapor deposition burning titanium titanium dioxide or tindioxide or titanium tin composite oxides as the nitrate of silver, cerium, lanthanum etc.Carry out sintering processes can obtain the to mix fibre composite of different metal composition afterwards.
The preparation of the nano composite material of embodiment 5 doping nitrogen elemental compositions such as (fluorine phosphorus sulphur).
Charcoal fiber absorption is contained the different compounds that contains nitrogen, fluorine, phosphorus, element sulphur, nitrogenous compound as trolamine, amino acid etc., react after drying, stay in the fiber.Fiber is put into reactor carry out low temperature chemical vapor deposition, gained deposition oxide material obtains nitrogen, the adulterated oxide composite of (fluorine phosphorus, sulphur) part after sintering processes subsequently.
Embodiment 7 puts into reactor with fibrous template such as polyester cloth, utilizes TiO 2 precursor and steam to carry out the cryochemistry deposition according to the condition among the embodiment, and thermal treatment afterwards obtains the cloth titanium dioxide of loading type and the mixture of polyester.
Claims (5)
1, a kind of preparation titanium dioxide, the method of tindioxide and doping composite fiber material thereof, it is characterized in that, in reaction, utilize fiber to be template, with titanium tetrachloride or tetrabutyl titanate, titanium tetraisopropylate acid esters organic precursor, perhaps tin tetrachloride, the compound of tin tetrachloride and aforementioned titanium is a presoma, carry presoma and contain ammoniacal liquor gas and enter reactor by nitrogen or argon gas rare gas element, utilize 5～280 ℃ low temperature to carry out aumospheric pressure cvd, deposition precursor body on template is handled the acquisition titanium oxide through follow-up sintering, stannic oxide and doping composite fiber material thereof.
2, a kind of method for preparing titanium dioxide, tindioxide and doping composite fiber material thereof according to claim 1 is characterized in that the depositing temperature that sets is 5～280 ℃, and deposition back sintering processes temperature is 100～900 ℃.
3, a kind of method for preparing titanium dioxide, tindioxide and doping composite fiber material thereof according to claim 1 is characterized in that sintering processes obtains the loading type filamentary material under the inert atmosphere; Sintering processes under oxidisability and the atmosphere reactive is removed fibrous template, forms the oxide fibre material.
4, a kind of method for preparing titanium dioxide, tindioxide and doping composite fiber material thereof according to claim 3, it is characterized in that with the activated carbon fiber being fibrous template, sintering processes atmosphere is oxidisability and atmosphere reactive, obtain the multiporous fiber shape material of burn off charcoal fiber, filamentary material has irregular tubular fibre tubulose structure.
5, a kind of method for preparing titanium dioxide, tindioxide and doping composite fiber material thereof according to claim 1, it is characterized in that pre-soaked doping nitrogen element or the metal ion solution of containing of activated carbon fiber, adsorb the oven dry of saturated back, put into reactor, carry out low temperature chemical vapor deposition and follow-up sintering processes, the oxide fibre of obtain mixing nitrogen element or metal ion.
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Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101763917B (en) * | 2010-03-04 | 2011-07-27 | 长春理工大学 | Method for preparing tin dioxide and titanium dioxide nano cable |
| CN101817552B (en) * | 2010-03-25 | 2012-05-09 | 山东大学 | Titanium dioxide micron tube material and preparation method thereof |
| CN102125826B (en) * | 2010-12-08 | 2012-10-10 | 中国科学院新疆生态与地理研究所 | Photocatalyst material diaphragm and preparation method thereof |
| US9433933B2 (en) * | 2012-01-18 | 2016-09-06 | Nitto Denko Corporation | Titania photocatalytic compounds and methods of making the same |
| CN102992271A (en) * | 2012-12-18 | 2013-03-27 | 安徽工程大学 | Method for preparing metallic oxide micro-tube |
| CN103451852B (en) * | 2013-08-31 | 2015-09-23 | 中国人民解放军国防科学技术大学 | A kind of TiO 2the preparation method of nanometer rods/SiC composite fibrofelt |
| CN103803490B (en) * | 2014-02-27 | 2015-02-25 | 北京化工大学 | Carbon nanofiber material and preparing method and application of carbon nanofiber material |
| CN104045110B (en) * | 2014-07-04 | 2016-05-18 | 西北师范大学 | The preparation method of titanium dioxide nanofiber material |
| CN105129903A (en) * | 2015-07-09 | 2015-12-09 | 常州大学 | Titanium dioxide sieve for photocatalytic treatment of phenol-containing wastewater |
| CN106311196B (en) * | 2016-07-19 | 2019-01-01 | 天津大学 | Tubular structure nano titanium dioxide photocatalyst and preparation method |
| CN106591935A (en) * | 2016-11-29 | 2017-04-26 | 上海师范大学 | Method for preparing mesoporous monocrystal TiO2 with renewable fiber template |
| CN106621807B (en) * | 2017-02-15 | 2020-02-04 | 中南大学 | Flue gas treatment method for catalytic reduction, desulfurization and denitrification of titanium dioxide nanotube array loaded with lanthanum-cerium oxide |
| CN108732187B (en) * | 2017-04-20 | 2020-06-23 | 北京大学 | Rapid assessment method for cleanliness of large-area graphene |
| CN109576733B (en) * | 2018-11-22 | 2020-10-27 | 太原理工大学 | Preparation method of carbon fiber loaded chlorine evolution catalytic electrode |
| CN109607602A (en) * | 2018-12-19 | 2019-04-12 | 云南锡业集团（控股）有限责任公司研发中心 | A kind of preparation method of stannic oxide |
| CN109713137A (en) * | 2018-12-30 | 2019-05-03 | 华北电力大学 | Element gas phase doping method for perovskite solar cell transport layer |
| CN112892474B (en) * | 2021-01-15 | 2022-10-28 | 神美科技有限公司 | Multifunctional industrial water treatment agent and preparation method thereof |
| CN113135768B (en) * | 2021-03-19 | 2022-06-03 | 西安理工大学 | Preparation method of hollow porous SiC fibers |
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