Background technology
Such leakproof tank is well-known.
For example US Patent 3,973,719 and 3,988,185 disclose a container assemblies, and this container assemblies comprises the composite tube body with an outside roll extrusion top margin, and tubular body has an asymmetric sheet film type sealing arrangement sealing and is fixed in roll extrusion edge and metal bottom, come metal is sealed by the bottom end that is crimped to tubular body, above-mentioned patent discloses its manufacture method simultaneously.Yet, because the bottom of this container assemblies is a metal, a lot of difficult problems are proposed for relevant manufacturing, weight, cost and recycle, therefore this container assemblies and unsatisfactory.
The such existing clad vessel of appreciiable typically utilizes well-known suturing skill (double seaming) airtight by metal end in a side on the market.But, because metal end accounts for the major part of the whole weight of container, so needs energy big in the manufacturing process, and produce a large amount of radiation.And in many countries, based on the consideration of recycling, metal end need separate with other parts of packing, and this causes user and waste recovery to utilize the inconvenience of mechanism.
As everyone knows, such metal end or bottom have been limited this kind packing and can not be used for micro-wave oven.For making it possible to add the heat-sealing product in container itself, thereby convenient user and can expand the range of use of these kinds packings should replace with metal end the material of anti-microwave.
For overcome these problems as far as possible; EP-A-0 352 127 discloses a kind of oxygen barrier layer laminated structure; be applicable to the ne-leakage container of impermeable oxygen; this container comprises the structural matrix with mechanical stability; heat sealable polymeric material skin; filleting polymer resin ground floor; the oxygen barrier material (comprising aluminium foil) that can in greater range of materials, select; has extrusion coating protection and can inner heat-sealing and the polymeric material that can contact with product; and the second filleting polymer interlayers; the polymer resin layer of anti-unreasonable use; the 3rd filleting polymer resin is all with this order coextru-lamination on the inside face of oxygen barrier material layer.But, the heat sealable polymeric material skin of its use has defective, because this material the time often decolours and misplaces in heat-sealing, that is is adhered on the heat seal tool, and this instrument is used to and reaches the required lead aircraft tool cycle and under the necessary hot conditions.
Described a kind of compound end sealing element that is used for clad vessel in GB-A-2 176 457 patents, its body comprises at least one wild card flaggy, and one is covered in in-to-in equally intercepts paper tinsel (as aluminium foil), an inner sealable plasticity capping.The sealing arrangement of sealing element comprises an optional layer of tearing with inner salable plasticity capping, the profound bottom that the sealing parts are prepared, after filling, comprise that at least one clamp layer, a metal intercept paper tinsel and place its interior salable plasticity capping, this bottom and its edge upwards and outwards stretch and surpass the tubular body end face, portion seals with outside and described tubular body within it, wherein bottom metal intercepts paper tinsel and is arranged in clamp layer inside, itself be positioned at plasticity capping the same side, wherein should bottom and tubular body sealing by high-frequency induction.
Statement of requirement carries out diathermic heating and compare to the identical Machine cycle of known vessel with sheet tin bottom to provide in the course of processing.When use one comprises that bottom, the metal obstruct paper tinsel and of at least one clamp layer place its in-to-in sealing plasticity capping, it also specifically refers to seal by the heat of only being supplied with by the outside, therefore be not to provide by high-frequency induction, high-frequency induction only is used for the unsafty situation of long period.
But, utilize electronic heating that this compound bottom sealing arrangement is sealed not only machine and operating cost and unsatisfactory, and it requires to intercept paper tinsel and have certain thickness, this has limited its essential variation.
And, surpass the tubular body end face when upwards and outwards stretching, when this compound end seal assembly is connected with the pipe portion of tubular body, intercepts paper tinsel and can produce pin hole, otch or breach by bottom margin, this causes container to lose its leakproofness, thereby makes barrier properties invalid.This brings a particular problem when packing solid friable food product, and friable food product not only is easy to go bad under the humidity effect, and will degrade when aerobic exists, and therefore intercepts paper tinsel if produce pin hole, otch or breach, will cause product seriously rotten in storage process.When packaged products is transported under the different pressures condition, this influence will increase, this is to increase owing to the bigger climatic conditions of variation will make internal tank contact with surrounding environment, and these climatic conditions comprise for example high temperature and low temperature, high humidity and low humidity, high height above sea level and low height above sea level.Such condition can cause tangible container external and internal pressure poor.Since this pressure, container material, barrier layer will be under pressure then, and this pressure may be very big so that form pin hole or breach, or exist under the situation of pin hole or breach after the processing, causes this perforation to increase, thereby make its barrier properties of packing forfeiture.
And because sealing characteristics is packaged in high altitude region and can has high interior the pressure, this may cause packing to be heaved.The shape that depends on packing, this outside heave can cause being packaged in be unstable state (as swinging and shake) on the shelf, thereby whether the user is bought this product have a negative impact.
In addition, the existing composite material that is used to process this clad vessel and bottom also must have following characteristic: allow the lead aircraft device cycle, this cycle comprise with sheet form provide and transmit composite materials to and time of passing machine, this machine is used for cutting, deep-draw and transports compound bottom etc.; The requirement material can bear this condition and can not cause machine run to be interrupted, and interruption can make composite laminates adhesion or slippage cause because of the thermoplastic material external coating.
In addition, after the cutting bottom, the surplus material of composite material (being so-called knitmesh) need be transferred among the cutting equipment and/or outside, in this transmission course, the composite material that is used to form tubular tubular body often easily breaks, and causes obstruction, thereby influences the reliability of system.
Equally, the forming process in compound bottom is also included within the transmission course, and friction is important factor.Friction is excessive in (the being deep-draw) process that is shaped causes barrier layer to break or produces pin hole.Also depend on employed transmission system such as air transfer, excessive the causing of finding to rub stops up.In heat-seal operation, need material is folded, and with net shape heating and pressurization, so that should packing shaping and sealing.The excessive material that causes of friction outer and that heat between the back part is folding improper with sealing, thus perturbation operation and leak free quality and reliability.On the other hand, the young pathbreaker that rubbed is because composite material can go wrong from the machine part slippage that is used for it is processed, and this also can cause the course of processing to be interrupted, and especially makes us being difficult to accepting when the machine cycle of operation is short.
And, only using the outside heat that provides to carry out in the process of heat-seal operation, material may decolour, even produces the burning trace on the resinous coat outside, is necessary to protect the container skin not to be subjected to invasions such as humidity, dust, and its skin can be printed user profile.But, in dispensing, storage and the use of this container, importantly container can bear the humidity of certain magnitude, and stops it to draw the dirt dust, and this is necessary for acceptance level that improves the user and user's comfort feature.
Summary of the invention
The object of the present invention is to provide aforesaid leakproof tank, it has improved the characteristic of deep-draw bottom; Its permission seals by the tubular bodies of hot-pressing tool with described bottom and container, produces pin hole, otch or breach and can not make on the barrier layer of base material; This container can provide necessary stability in the course of processing or after the processing, prevent that container from differing under bigger weather (as temperature, humidity and the pressure etc.) condition, heaves in the process of transporting and storing or leaks; And, by making its surface friction with sufficient intensity, optimization and heat stability, make container can obtain the lead aircraft device cycle.
Another target of the present invention provides a kind of manufacture method of this leakproof tank.
It is found that, by using a particular composite that is used for container bottom can realize above-mentioned target, this bottom has a laminar structure that limits, it comprises that an outer card plate surface has the over lacquer layer, can obtain a specific friction coefficient, and provide the oxygen barrier layer of enhancing carrier layer with anti-unreasonable use, such combination can prevent that barrier layer from forming pin hole in the course of processing, otch or breach, even when bottom margin being made progress and the outwardly-bent tubular body end face that surpasses, and storing and transporting in the process, even when at high temperature applying big pressure, also be like this.And coating strengthens carrier layer can make interlayer extremely thin as the evaporated metal layer that is preferably aluminium as oxygen barrier layer.
Particularly, in one aspect of the invention, a kind of leakproof tank is provided, leakproof tank, it is used to pack the solid food to humidity sensitive, described leakproof tank comprises the tubular body of being made by composite material (1), and described composite material comprises external coating (12), at least one wild card flaggy (11), covers described clamp layer in-to-in oxygen barrier layer (10), and the heat sealable internal coating (9) of thermoplastic material; Sealing arrangement (2), its form are the internally coated peelable diaphragm seal that comprises oxygen barrier layer and the heat sealable material of themoplasticity; And the deep-draw of making by composite material bottom (3), described composite material comprises the over lacquer layer, at least one clamp layer, cover described clamp layer in-to-in oxygen barrier layer, and the internal coating of heat sealable thermoplastic material, the bottom upwards and outwards stretches with its edge and surpasses the end face of described tubular body (1), inside and outside heat-sealing with described tubular body (1), the composite material that it is characterized in that described bottom (3) has laminar structure, described laminar structure comprises from outside to inside: heat resistanceheat resistant over lacquer layer (4), the clamp surface that it provides coating, the friction coefficient on clamp surface that utilizes the described coating that the Instron instrument measures according to ASTM method D 1894-00 is between 0.10 to 0.45; At least one clamp layer (5); Oxygen barrier layer (6); Enhancing carrier layer (7) as the anti-unreasonable use of interlayer between described clamp layer (5) and the described oxygen barrier layer (6); And the heat sealable internal coating of thermoplastic material (8); It is characterized in that anti-decolouring of described over lacquer layer (4) and anti-dislocation under applied heat seal condition.
In another aspect of the present invention, a kind of manufacture method of leakproof tank is provided, described leakproof tank is made by composite material, be used to pack solid food to humidity sensitive, described container comprises tubular body (1), it is by at least one wild card flaggy (9), covering described clamp layer in-to-in oxygen barrier layer (7), and the heat sealable internal coating (6) of thermoplastic material is made; Also comprise sealing arrangement (2), its form is the internally coated peelable diaphragm seal that comprises oxygen barrier layer, the heat sealable material of themoplasticity; And deep-draw bottom (3), it comprises the over lacquer layer, at least one clamp layer, cover described clamp layer in-to-in oxygen barrier layer, the internal coating of heat sealable thermoplastic material, the bottom upwards and outwards stretches with its edge and surpasses described tubular body (1) end face, and with the inside and outside heat-sealing of described tubular body (1), it is characterized in that sealing the composite material of described bottom (3), described bottom (3) has laminar structure, described laminar structure comprises from outside to inside: heat resistanceheat resistant over lacquer layer (4), it provides coated surfaces, and the friction coefficient that utilizes the coated surfaces that the Instron instrument measures according to ASTM method D 1894-00 is between 0.10 to 0.45; At least one clamp layer (5); Oxygen barrier layer (6); Enhancing carrier layer (7) as the anti-unreasonable use of interlayer between described clamp layer (5) and the described oxygen barrier layer (6); And the heat sealable internal coating (8) of thermoplastic material; By being heated above 300 ℃ operated pressing tool, via the external coating (12) of described heat sealable internal coating (8) conduction heating heat sealable internal coating (9) and described tubular body (1).
The appended legend of following reference describes in detail the present invention.
The specific embodiment
As shown in Figure 1; the film type sealing device (2) that aforementioned clad vessel comprises composite tube body (1) with outside roll extrusion top margin, is sealedly and fixedly connected with the roll extrusion top margin; make the sealing arrangement peripheral part in that radially the upwards annular region with hoop and roll extrusion ring is consistent; protecting described film and attached lid (14), and not shown bottom sealing arrangement.The bottom sealing arrangement (3) of this container generally includes a metal base plate, and it is connected with this tubular body by crimping.Tear film (2) and can comprise a plectrum, so that described film is removed from tubular body (1) top, the tubular body opening after this can be by lid (14) closure.
In the prior art container, the tubular body of container of the present invention (1) not only can be cylinder shown in Figure 1, also can be non-circular cross sections, as triangle, quadrangle, pentagon, hexagon etc., and can be made by composite material spiral or vertical the winding.As shown in Figure 2, the composite material that is used to make preferred cylindrical tubular body comprises that an external coating (12), at least one wild card flaggy (11), cover clamp layer in-to-in oxygen barrier layer (10), and the heat sealable internal coating of a thermoplastic material (9).Container contents can be printed for information about in the tubular body outside.
Sealing arrangement (2) generally includes a film, and it comprises one or more layers paper, oxygen barrier layer (preferably maybe aluminium lamination evaporation pet film thereon can be made by aluminium foil), and the heat sealable material internal coating of a themoplasticity.If necessary, can between paper, oxygen barrier layer and heat sealable internal coating, provide bonding coat.
Thereby main body of the present invention is the leakproof tank that is used to pack to the solid food of humidity sensitive, it comprises that tubular body (1), at least one wild card flaggy (11), made by the composite material that comprises external coating (12) cover clamp layer in-to-in oxygen barrier layer (10), and the heat sealable internal coating of a thermoplastic material (9); Also comprise a sealing arrangement (2), its form is for comprising an oxygen barrier layer, the heat sealable internally coated peelable diaphragm seal of a themoplasticity; And the deep-draw of making by composite material bottom (3), it comprises the over lacquer layer, at least one clamp layer, one covers clamp layer in-to-in oxygen barrier layer, and inner heat sealable material internal coating, the bottom makes progress and is pulled outwardly with its edge and extends on the terminal film of tubular body (1), inside and outside heat-sealing with described tubular body (1), the composite material that it is characterized in that described bottom (3) has laminar structure, be respectively from outside to inside: the clamp surface of the coating that a thermal resistance over lacquer layer (4) provides, utilize the Instron instrument to measure the friction coefficient on the clamp surface of coating according to ASTM method D 1894-00, make it between about 0.10 and 0.45, be preferably between about 0.20 and 0.30, also comprise at least one clamp layer (5), one oxygen barrier layer (6), the enhancing carrier layer (7) of one anti-unreasonable use, carrier layer is used between clamp layer (5) and the oxygen barrier layer (6), and the heat sealable internal coating of a thermoplastic material (8).
It is found that, when clear coat finish (4) covers the clamp surface of this deep-draw bottom (3) in addition, make the clamp surface of coating have the friction coefficient of above-mentioned qualification, and connecting the enhancing carrier layer (7) that is used for the anti-unreasonable use between described clamp layer (5) and the described oxygen barrier layer (6), the problem of all above-outlined can be very easy to and solve satisfactorily.That is to say, even do not comprise the aluminium foil that an intensity is bigger, and only comprise that one strengthens carrier layer (7), and under the situation that continuous impermeability evaporation aluminium foil is provided on the carrier layer, also can prevent to form in the oxygen barrier layer pin hole, otch or breach in oxygen barrier layer.
Astoundingly, this laminar structure allows to make container just under study for action, wherein bottom and edge thereof upwards and outwards stretch and surpass the tubular body end face, and utilize a heating tool that institute's heat requirement and pressure can be provided, and its inside with described tubular body is sealed with outside.Heat that is provided and pressure not only make it form the prefabricated tubular body of deep-draw around bottom margin of tubular body (1), and necessary heat-sealing can be provided, and can adopt with production market on the existing corresponding to machine cycle of container with metal bottom.
In addition, the specific friction coefficient that is provided by the over lacquer layer not only can prevent adsorbed moisture, dirt or dust, allows required painted and/or application literal or pattern, also can guarantee the smoothing processing of described material in the manufacturing process of flaky material.This manufacturing process comprises punching press, cutting, deep-draw, and removes the surplus material after the punching press, promptly so-called knitmesh and transporting in used delivery system thereof.In addition, when using such clear coat finish, can prevent the decolouring and the dislocation of tubular body (1) external coating (12), even when being used for of using operates bottom and tubular body edge bonded assembly operated pressing tool under the following conditions, also be like this, operating conditions is: surpass 300 ℃ of high temperature, machine cycle is very short, thereby does not allow container cooling and bottom processing.
Airtight or the leak tightness of container of the present invention is defined as to make and keeps O in the container
2-level characteristics is corresponding to less than 0.0002ml O
2Every day every sq cm vessel surface average total oxygen transmission rates, this average total oxygen transmission rates is under air, 23 ℃, the environmental conditions of 50% relative humidity and do not have between described external container and the inside to record under the absolute pressure reduction.
As described in the preferred embodiment of the invention, under applied heat seal condition, anti-decolouring of the over lacquer layer (4) shown in Fig. 2 scheme drawing and anti-dislocation.This means for heat seal step, can not produce the burning trace, varnish can not take place yet be connected with used tool or bonded assembly situation.Described heat seal condition comprises that length of the halt is 1.0 to 4.0s, is preferably 1.6 to 3.0s, and temperature is 120 ℃ to 280 ℃, is preferably 170 ℃ to 260 ℃, and the pressure of heat seal tool is 1 to 22MPa.
Preferably, over lacquer layer (4) can be by the heat resistanceheat resistant seal coat, and being preferably the acrylic resin base paint provides.Described priming paint can by spray, method such as printing, dip-coating, curtain coating obtains.More preferably, the acrylic resin base paint comprises the styrene acrylic resin.Preferably, this kind varnish comprises the water reducing composition, and it comprises the styrene acrylic resin that is scattered in the liquid dielectric, and liquid dielectric comprises softening water, n-propyl acetate alcohol, and if necessary, can comprise antifoam and emulsifying agent.
The solar heat protection seal coat pigmentable of described over lacquer layer (4) and/or adding pigment also can have the information that methods such as printing of utilizing or laser engraving provide on its surface.
Preferably, the over lacquer layer (4) that can a single or multiple lift mode applies, gross dry weight are 0.6 to 1.8g/m
2, be preferably 0.8 to 1.2g/m
2, be positioned on the clamp layer (5).
As described in another embodiment preferred of the present invention, oxygen barrier layer (6,10) and the oxygen barrier layer that provided of aluminium matter sealing arrangement (2) be manufactured from aluminium, aluminium foil or be on the carrier layer more preferably coated with the form of aluminized coating, as carrier layer (7) or be used to form the carrier layer of the composite material of tubular body (1).This aluminium foil preferred thickness is 6 to 12 μ m, is preferably 7 to 9 μ m.
Requiring under the stability-enhanced situation of laminar structure, between the aluminium foil and its surrounding layer of oxygen barrier layer (6,10), wherein surrounding layer is preferably carrier layer (7) and clamp layer (12), and a bonding coat preferably is provided.Bonding coat preferably includes poly-vinyl resin, is preferably ldpe resin, comprises the modified polyvinyl resin of vinyl acetate, acrylate and/or methacrylate monomers and/or the ethene copolymer with grafted functional group.
Preferably, the enhancing carrier layer (7) of anti-unreasonable use is made by tough and tensile high strength polymeric, the tensile strength that according to ISO 1924 standards at relevant heat-sealing temperature is this material of recording under 100 to 220 ℃ the condition is 200 to 500N/15mm, is preferably 350 to 450N/15mm.This " being correlated with " heat-sealing temperature is the temperature with the polymeric material heat-seal process.
Carrier layer (7) is preferably made by polyamide, as one of multiple nylon section bar material, or alkide resin, be preferably polyethylene terephthalate or ethylene-vinyl alcohol copolymer.
Clamp layer (5,11) can comprise an individual layer or by the one or more sublayers of one or more bonding coat bonded assemblys.Preferably, the total area weight of the clamp layer (5) of bottom (3) is 150 to 450g/m
2, more preferably 180 to 340g/m
2, wherein the total area weight of the clamp layer (11) of outer tubular body (1) is 200 to 600g/m
2, more preferably 360 to 480g/m
2
Be used for heat sealable coating (8,9) heat sealable with the thermoplastic material of sealing arrangement (2), its heat-sealing temperature is 90 ℃ to 200 ℃, preferably include an ionomer type resin, or be preferably the salt that is selected from following material, preferred sodium or zinc salt: ethylene/methacrylic acid, ethylene/acrylic acid copolymer, ethylene, ethylene/methyl acrylate copolymer, ethylene/methyl acrylate copolymer, vinyl graft copolymer and composition thereof.
The external coating (12) and the sealing arrangement (2) of tubular body (1) can comprise low density polyethylene (LDPE), linear low density polyethylene, medium density polyethylene or their compound.
Fig. 3 is the scheme drawing of the composite material one preferred laminar structure that is used to make deep-draw bottom (3).This structure comprises a clamp layer (5), and it can comprise an individual layer or by the one or more sublayers of one or more bonding coat bonded assemblys, this clamp layer (5) preferably includes the 280g/m that externally has moisture barrier (4) and cover lacquer coat outward
2Paper, it covers any marking that described surface provides.Under clamp layer (5), bonding coat (13) is provided, it is made by ldpe resin, and its enhancing carrier layer (7) with the anti-unreasonable use of being made by polyethylene terephthalate is connected.The oxygen barrier layer of being made by aluminium foil (6) is connected with another surface that strengthens carrier layer (7), and oxygen barrier layer aluminium foil inside face has the aforesaid heat sealable internal coating of ionomer type resin (8).If desired, can between oxygen barrier layer (6) and heat sealable internal coating (8), add bonding coat.
Another embodiment of the invention comprises the manufacture method of leakproof tank, and this container is made by composite material, is used to pack the food compositions to humidity sensitive.This container comprises tubular body (1), covering clamp layer in-to-in oxygen barrier layer (7) and the heat sealable internal coating of being made by at least one wild card flaggy (9) of thermoplastic material (6); Also comprise a sealing arrangement (2), it comprises sealing and the internally coated peelable film of the heat sealable material of themoplasticity that comprises oxygen barrier layer; An and deep-draw bottom (3), it comprises an over lacquer layer, at least one clamp layer, one covers clamp layer in-to-in oxygen barrier layer, an and heat sealable thermoplastic material internal coating, the bottom makes progress with its edge and is pulled outwardly the end face that extends tubular body (1), inside and outside heat-sealing with described tubular body (1), it is characterized in that and can the composite material of described bottom (3) be sealed, this bottom has laminar structure, be respectively from outside to inside: the clamp surface of the coating that heat insulation over lacquer layer (4) provides, utilize the Instron instrument to measure the friction coefficient of coated surfaces between about 0.10 to 0.45 according to ASTM method D 1894-00, preferably between about 0.20 to 0.30, also comprise at least one clamp layer (5), one oxygen barrier layer (6), one enhancing carrier layer (7) as the anti-unreasonable use of interlayer between clamp layer (5) and the oxygen barrier layer (6), and the inner heat sealable coating (8) of a thermoplastic material, when instrument was heated above 300 ℃ of temperature, it utilized induction heat to process through described heat sealable internal coating (8) to the external coating (12) of heat sealable internal coating (9) and described tubular body (1) by operated pressing tool.
Preferably, described method comprises heat-sealing, and its dwell time is 1.0 to 4.0s, is preferably 1.6 to 3.0s, and temperature is 120 ℃ to 280 ℃, is preferably 170 ℃ to 260 ℃, and pressure is 1 to 22MPa.
Airtight or the leak tightness of the container of the inventive method preparation is defined as and keeps being in the container O
2The characteristic of-level is corresponding to less than 0.0002ml O
2Every day every sq cm vessel surface average total oxygen transmission rates, this average total oxygen transmission rates is under air, 23 ℃, the environmental conditions of 50% relative humidity and do not have between described external container and the inside to record under the absolute pressure reduction.
Over lacquer layer (4) is provided as anti-decolouring and anti-dislocation under applied heat seal condition as the preferred embodiment of this statement method.
Varnish finish under heat seal condition (4) coating is for anti-decolouring (promptly as preventing to burn trace) and anti-dislocation (promptly, prevent and the surperficial bonding of employed heat seal tool or combination), this heat seal condition comprises that the dwell time is 1.0 to 4.0s, be preferably 1.6 to 3.0s, temperature is 120 ℃ to 280 ℃, be preferably 170 ℃ to 260 ℃, the pressure of heat seal tool is 1 to 22MPa.
Preferably, over lacquer layer (4) comprises the heat resistanceheat resistant seal coat, is preferably the acrylic resin base paint or is preferably the priming paint that comprises the styrene acrylic resin.The preferred varnish of the type comprises a kind of water reducing composition, and it comprises the styrene acrylic resin, is scattered in to comprise softening water, n-propyl acetate alcohol, and comprises if necessary in the liquid dielectric of antifoam and emulsifying agent.
Clear coat finish pigmentable and/or comprise pigment and maybe can have by printing or the laser engraving literal or the pictorial information that form.
According to a preferred embodiment of the invention, will be used for the dry weight of bottom on (3) laminar structure is 0.6 to 1.8g/m
2, be preferably 0.8 to 1.2g/m
2Outside clear coat finish (4) place on the clamp layer (5).
Preferably, the oxygen barrier layer of used composite material (6,10) is made of aluminum, more preferably the aluminium foil on carrier layer (7) or the coating of aluminizing.The aluminum foil thickness of oxygen barrier layer (6,10) and sealing arrangement (2) is 6 to 12 μ m, is preferably 7 to 9 μ m.
As described in another preferred embodiment of the present invention, laminar structure can be used for making profound bottom (3), and it comprises the aluminium foil and the bonding coat between the carrier layer (13) of an oxygen barrier layer (6); Or the bonding coat between the aluminium foil of oxygen barrier layer (10) and the wild card flaggy (11); Described bonding coat can comprise poly-vinyl resin, is preferably ldpe resin, comprises modified polyvinyl resin, acrylate and/or the methacrylate monomers of vinyl acetate and/or comprises the ethene copolymer of grafted functional group.
Preferably, the laminar structure of bottom (3) comprises the enhancing carrier layer (7) of the anti-unreasonable use of being made by tough and tensile high strength polymeric, is that the material tensile strength that records under 100 to 220 ℃ of conditions is 200 to 500N/15mm according to ISO 1924 standards at heat-sealing temperature, be preferably 350 to 450N/15mm.Should " being correlated with " heat-sealing temperature be the temperature that polymeric material is stood in heat seal process.
More preferably, described carrier layer (7) is made by polyamide or alkide resin, and preferably by polyethylene terephthalate or poly-terephthalic acids butanediol ester, or ethylene-vinyl alcohol copolymer is made.
Clamp layer (5,11) can comprise an individual layer or the one or more sublayers that are formed by connecting by one or more bonding coats.Preferably, clamp layer (5) total area weight of bottom (3) is 150 to 450g/m
2, more preferably 180 to 340g/m
2, and the total area weight of the clamp layer (11) of outer tubular body (1) is 200 to 600g/m
2, more preferably 360 to 480g/m
2
As described in the preferred embodiment of the invention, the heat sealable material of themoplasticity is heat sealable under 90 to 200 ℃ of conditions at heat-sealing temperature, and comprises ionomer type resin.Preferred ionomer type resin is selected from the salt of following material, preferred sodium or zinc salt: ethylene/methacrylic acid, ethylene/acrylic acid copolymer, ethylene, ethylene/methyl acrylate copolymer, ethylene/methyl acrylate copolymer, vinyl graft copolymer and composition thereof.
Preferably, tubular body (1) used in the inventive method comprises an external coating (12), is made by low density polyethylene (LDPE), linear low density polyethylene, medium density polyethylene or their compound.
Therefore the present invention provides leakproof tank, be used to pack solid food to humidity or oxygen sensitivity, be preferably the friable food product of frangible glycosyl with salt, as the potato fast food of potato chips, processing, nut etc., and it is differing under the bigger different climatic conditions, under high temperature and low temperature, high humidity and low humidity, high pressure and low pressure situation, all provide required leakproofness.This container can be as method as described in this claim with easy low cost method manufacturing, and this method relates to common conduction heating technique and common processing and operates machines.This container has the following advantages: high structural stability, and in light weight, be easy to recycle, cause environmental pollution less.
Under normal conditions, container of the present invention is made as in advance and comprises sealing arrangement (2), and its form is the film with loam cake (14) covering, and is full of by the open bottom side.Subsequently deep-draw bottom (3) and tubular body (1) sealing are provided the seam of container bottom.