CN100464046C - Improved PVC elastic roll floor-board and production method - Google Patents

Improved PVC elastic roll floor-board and production method Download PDF

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Publication number
CN100464046C
CN100464046C CNB2007101189148A CN200710118914A CN100464046C CN 100464046 C CN100464046 C CN 100464046C CN B2007101189148 A CNB2007101189148 A CN B2007101189148A CN 200710118914 A CN200710118914 A CN 200710118914A CN 100464046 C CN100464046 C CN 100464046C
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layer
foaming
elastic roll
wear
pvc elastic
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CN101070728A (en
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金政武
周立杰
刘宇
陈建军
朱惠清
周景龙
王书明
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WEILAINSHUN PLASTIC PRODUCTS CO Ltd BEIJING
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WEILAINSHUN PLASTIC PRODUCTS CO Ltd BEIJING
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Abstract

The invention relates to a flexible membrane modified PVC floor, including wear-resistant surface layer, dense layer, foam layer and dorsal closure layer. The connecting layer is filled in between the wear-resistant suface layer and dense layer. The dense layer consists of glass fiber and the foam layer at least containing two foam layer: the first foam layer and the second foam layer. The invention also associates an improving the elastic membrane PVC flooring production methods. Since the invention will organically combine, conpared to any single craftworks, the invention has better quality, wider adaptability; and greatly reduce costs. Furthermore, the combinative craftwork can reuse all the leftover materal and bad goods, which not only reduces the enterprise 's production costs but also decreases their waste production, and is benefit for the social environment.

Description

A kind of PVC elastic roll floor-board and preparation method thereof
Technical field:
The present invention relates to a kind of PVC elastic roll floor-board and preparation method thereof, more particularly, relate to and a kind ofly adopt calendering technology and be coated with the method that technology combines of scraping, preparation PVC elastic roll floor-board.
Background technology:
The present invention is mainly used in the suitability for industrialized production on PVC floor.At present, to produce the PVC elastic roll floor-board both at home and abroad be rolling process basically and be coated with two kinds of technologies of the method for scraping.But these two kinds of technologies all exist separately advantage and outstanding shortcoming:
The general introduction of calendering technology---calendering technology is meant semiproduct such as producing the used transparent wear of PVC elastic roll floor-board, dense layer (not containing glass), foaming layer, back of the body seal is carried out flowing water production at calender, that is: various raw material mixed at mixer, carry out banburying at banbury, further plastify by rolling turbine, extrude by filter, at calender various semiproduct are pressed into sheet and batch.Again dense layer is taken printing machine printing, at last wearing layer, dense layer (not containing glass), foaming layer, back of the body seal are fitted, foamed at foaming furnace and the technology of producing the PVC elastic roll floor-board.Because most of production finished at calender, therefore be called for short rolling process.
The advantage of calendering technology is:
(1) cost of raw material is low.Calendering technology is employed to be suspension method PVC, is coated with that to scrape technology employed be paste PVC.The employed PVC of calendering technology satisfy under the identical situation of function lower by about 40% than being coated with the method for scraping, i.e. the relation of 6:10.
(2) it is big that product strength is adjusted the space.Producing all kinds of semiproduct at calender can adjust soft durometer according to the requirement of different product between 25PHR-80PHR, adjust the interval generally between 35PHR-80PHR and be coated with the method for scraping.
(3) can produce by pattern how wide in variety.The semiproduct production and the stamp of rolling process are independently finished at calender or printing machine.The time of semiproduct production and printing, speed, batch what do not influence output, speed and the product yield of foaming furnace.Single batch of economic production quantity has only 2000 square metres, relatively is fit to the many kinds of exploitation, multi-color, and the compliance of product is wider.
(4) can make the best use of everything.The leftover pieces that produce in production semiproduct, the finished product process, defective products etc. can reclaim at calender at any time to be produced once more, and no waste of material does not have the rubbish of production.
The shortcoming of calendering technology:
The flattening and the dimensional stability of product are relatively poor, and be relatively more suitable civilian, is difficult to adapt to commercial large-scale place and high-grade place ground decoration.
Be coated with the general introduction of scraping technology---be coated with the method for scraping and be manufacturing process with product and all be coated with and scrape at one, the technology of finishing on the foaming streamline, that is: at batch plant used raw material is mixed with pasty state, be coated with kerf with the foliated glass cloth as base material, scrape basic unit by being coated with, gel, cooling, be coated with again after the upset and scrape, gel, cooling, be coated with again and scrape foaming layer, gel, cooling, be coated with again and scrape back of the body seal gel, cooling, print after the upset, and then be coated with and scrape the laggard foaming furnace of surface layer and foam, cooling, batch the technology of producing the PVC coiled material floor, owing to all finish being coated with on the kerf, therefore be called for short the method for scraping that is coated with.
Be coated with the advantage of scraping technology:
(1) flattening of product and dimensional stability are good, are fit to large commercial place and high-grade place ground decoration.
Time cost was relatively low when (2) single pattern was produced in enormous quantities.
Be coated with the shortcoming of scraping technology:
(1) hardness of product and intensity are influenced by Processes and apparatus, can't satisfy as the requirement of the big place of visitors flowrate such as airport, supermarket, workshop to product hardness.
(2) cost of raw material is higher.Since be coated with and scrape the employed PVC of production technology and stick with paste resin, higher by about 40% than suspension method PVC price.Because the cost height, product competitiveness is relatively poor relatively, is the maximum puzzlement of this explained hereafter product of employing producer.
(3) be coated with and scrape the technology device-restrictive of originally experiencing, must adopt new raw material to produce, leftover pieces that produced and defective products can't recyclings, cause bigger material waste.
(4) being coated with what scrape process using is omnidistance pipelining mode, and pattern of every adjustment or product structure all are to finish on streamline, loss that causes and waste greatly, cost is higher.Therefore, only be fit to few pattern and produce in enormous quantities, general single batch of proper production economic magnitude is 20000m 2More than, so the producer that adopts this kind technology, product category is more single, and pattern is less.
Summary of the invention:
Technical problem to be solved by this invention is, overcomes the defective of above-mentioned prior art and a kind of PVC elastic roll floor-board and preparation method thereof is provided.
For achieving the above object, the present invention takes following design scheme:
A kind of PVC elastic roll floor-board of the present invention, comprise wear-resistant coat, dense layer, foaming layer and back of the body seal, also comprise the wear-resistant coat articulamentum between described wear-resistant coat and the dense layer, described dense layer is the glass dense layer that contains glass fiber, and described foaming layer comprises at least the first foaming layer, second foaming layer.
According to a kind of PVC elastic roll floor-board provided by the invention, also have following attached technical characterictic:
Also include enhancement Layer, described enhancement Layer is the plastic film of thickness 0.15~0.7mm.
Also include the UV processing layer at described wear-resistant coat upside.
Another technical problem to be solved by this invention is, a kind of preparation method of PVC elastic roll floor-board is provided, and comprising:
Preparation wear-resistant coat, enhancement Layer, foaming layer and back of the body seal semiproduct, the raw material of correspondence are put into banbury after high-speed mixer mixes plastify, further plastify through mill again, filter then and extrude, will plastify at last the material of getting well through calendering, traction and cooling, rolling get final product required semiproduct;
Scrape legal system and be equipped with the glass dense layer with being coated with, the PVC thickener is scraped technology fiberglass substrate is applied once or twice through being coated with, again through gel and rolling get final product described glass dense layer;
Described wearing layer, glass dense layer, foaming layer and back of the body seal are heated applying in foaming furnace;
By foaming, embossing, cooling and rolling, obtain the PVC elastic roll floor-board then.
According to its preparation method of a kind of PVC elastic roll floor-board provided by the invention, also have following attached technical characterictic:
Also comprise and carry out the processing of UV coating obtaining the PVC elastic roll floor-board.
Also be included in and carry out heating before the processing of UV coating.
Cooling once more after handling curing through UV.
Described applying step also comprises:
At the foaming furnace leading portion that wear-resistant coat articulamentum and the unification of fiberglass substrate laminating is inferior earlier, the once described enhancement Layer of between fiberglass substrate layer and foaming layer, fitting again simultaneously;
Described back of the body seal and described second foaming layer are fitted at calender, and described first foaming layer and second foaming layer are fitted at calender.
Comprise that also the leading portion applying section with foaming furnace increases more than one at least stock shelf and corresponding laminating apparatus, and/or increase more than one stock shelf and corresponding laminating apparatus at least at the foaming furnace back segment.
Advantage of the present invention is: because the present invention is with the rolling process of prior art be coated with two kinds of technologies of the method for scraping and organically combine, so the product quality that the product of producing is produced than any single technology is more excellent, compliance is wider; And greatly reduce cost, be convenient to promote the use of, be convenient to enterprise and increase economic efficiency; Two kinds of technologies not only help enterprise and reduce production costs, and reduced the production rubbish of enterprise in conjunction with recyclable all leftover pieces and the defective products of utilizing in addition, and the social enviroment protection cause is also benefited.And wear-resistant coat of the present invention is divided into wear-resistant coat, wear-resistant coat articulamentum, has solved problems such as increase adhesive power, applying fastness, surface blistering.Enhancement Layer of the present invention, problems such as can solving the applying fastness, increase peel strength and surface blistering, the back side is wrinkling.Cooling once more the present invention increases heating system and heats once more, solidifies before UV handles after increases product size stability, solves preheating and dries problems such as moisture, coating is even.
Description of drawings:
Fig. 1 is the structural representation of PVC elastic roll floor-board of the present invention;
Fig. 2 is preparation method's of the present invention flow chart.
Specific embodiments:
Referring to Fig. 1, wherein express the preferred embodiment of a kind of PVC elastic roll floor-board of prior art, comprise wear-resistant coat 1, dense layer 2, between described wear-resistant coat 1 and dense layer 2, also comprise wear-resistant coat articulamentum 11; The present invention also comprises foaming layer 3 and back of the body seal 4, described foaming layer 3 comprises first foaming layer 31, second foaming layer 32, wherein, described dense layer 2 is for containing the glass dense layer of glass fiber, the present invention also includes enhancement Layer 5, described enhancement Layer 5 is the plastic film of thickness 0.15~0.7mm, also includes UV processing layer 6 at described wear-resistant coat 1 upside.The present invention is improved to by traditional single wear-resistant coat and is divided into wear-resistant coat 1, wear-resistant coat articulamentum 11, has solved problems such as increase adhesive power, applying fastness, surface blistering; And in product structure, added enhancement Layer 5, problems such as having solved the applying fastness, increase peel strength and surface blistering, the back side is wrinkling.Comprised back of the body seal 4 and foaming layer 3 in the product structure of the present invention, and foaming layer 3 has comprised also and first foaming layer 31, second foaming layer 32 applying at calender has solved the problem that needs sandwich construction because of the not enough product of foaming furnace laminating apparatus again.
Referring to Fig. 2, wherein show the preparation method's of PVC elastic roll floor-board of the present invention flow chart, this method comprises: preparation wear-resistant coat, enhancement Layer, foaming layer and back of the body seal semiproduct, the raw material of correspondence are put into banbury after high-speed mixer mixes plastify, further plastify through mill again, filter then and extrude, will plastify at last the material of getting well through calendering, traction, cooling and rolling get final product required semiproduct; Scrape legal system and be equipped with the glass dense layer with being coated with then, the PVC thickener is scraped technology fiberglass substrate is applied once or twice through being coated with, again through gel, rolling get final product described glass dense layer; Then described wearing layer, glass dense layer, foaming layer and back of the body seal are heated applying in foaming furnace; By foaming, embossing, cooling and rolling, obtain the PVC elastic roll floor-board at last.Method of the present invention also comprises carries out the processing of UV coating with obtaining the PVC elastic roll floor-board, and is carrying out heating cooling once more after UV handles curing again before the processing of UV coating.
Wherein, described applying step also comprises: at the foaming furnace leading portion that wear-resistant coat and the unification of fiberglass substrate laminating is inferior earlier, and the once described enhancement Layer of between fiberglass substrate layer and foaming layer, fitting again simultaneously; Described back of the body seal and described second foaming layer are fitted at calender, and described first foaming layer and second foaming layer are fitted at calender.Method of the present invention has increased heating system before UV handles, cooling once more after heating once more, solidifying can make the size of product increase stability, and has solved problems such as preheating oven dry moisture, coating is even.In addition, the wear-resistant coat behind the press printing of the inventive method, by increasing laminating apparatus at the foaming furnace back segment, the mode that adopts the back to paste has solved problems such as variable color, oil dripping.
In order better to realize transforming the present invention to existing equipment.At present both at home and abroad the net belt type foaming furnace generally is that three laminatings attach together and put, the product that will have glass fibre coating in the production of net belt type foaming furnace, must transform foaming furnace, four or more stock shelf and corresponding laminating apparatus be to transform as in the applying section of foaming furnace, more than one at least stock shelf and corresponding laminating apparatus also will be increased at the foaming furnace back segment.Thereby foaming furnace is transformed into the devices that can carry out five subsides at least.
More specifically, the process of the inventive method is: wear-resistant coat is divided into two-layer, at the foaming furnace leading portion wearing layer (thickness is generally 0.15-0.45mm) and glass substrate layer are fitted once earlier, the one step foaming articulamentum of fitting again between glass substrate layer and foaming layer simultaneously is an enhancement Layer, (thickness can adopt the plastic film of 0.15mm-0.7mm according to the requirement of product) combines foaming layer with enhancement Layer, back of the body seal combines with foaming layer, fit at the foaming furnace leading portion simultaneously and enter foaming furnace, come out of the stove the cooling after once more the heating, wear-resistant coat and the product of coming out of the stove are fitted once more, batch the big volume of harvest after the cooling once more, be generally about 1000m.The present invention is closed the internal construction of rolling process explained hereafter PVC elastic roll floor-board and changes wear-resistant coat, wear-resistant coat articulamentum, glass dense layer, enhancement Layer, first foaming layer, second foaming layer and 7 layers of structure of back of the body seal into by original wear-resistant coat, dense layer (not containing glass), foaming layer and back of the body seal four laminatings.Because foaming furnace has only five laminatings to attach together usually and puts, want to produce the product that seven laminatings close, the back of the body seal and second foaming layer will be fitted at calender, and first foaming layer and second foaming layer are fitted at calender.
The UV coating is carried out in twisting in greatly that method of the present invention will be collected on the surface treating machine, leading portion in coating must be heated, allow product be heated once more, cooling and handle to solidify once more after the coating through UV, product increases substantially through the dimensional stability of product after the heating and cooling once more, obviously be better than national standard and European Union's standard, its every following table that sees for details:
Every rerum natura of PVC elastic roll floor-board of the present invention is as follows:
Figure C200710118914D00091
The foregoing description is only for the usefulness that the present invention is described; and be not to be limitation of the present invention; the those of ordinary skill in relevant technologies field; under the situation that does not break away from the spirit and scope of the present invention; can also make various variations and modification; therefore all technical schemes that are equal to also should belong to category of the present invention, and scope of patent protection of the present invention should be limited by each claim.

Claims (9)

1. PVC elastic roll floor-board, comprise wear-resistant coat (1), dense layer (2), foaming layer (3) and back of the body seal (4), it is characterized in that: also comprise wear-resistant coat articulamentum (11) between described wear-resistant coat (1) and the dense layer (2), described dense layer (2) is for containing the glass dense layer of glass fiber, and described foaming layer (3) comprises first foaming layer (31) and second foaming layer (32).
2. a kind of PVC elastic roll floor-board according to claim 1 is characterized in that: also include enhancement Layer (5), described enhancement Layer (5) is the plastic film of thickness at 0.15~0.7mm.
3. a kind of PVC elastic roll floor-board according to claim 2 is characterized in that: also include UV processing layer (6) at described wear-resistant coat (1) upside.
4. preparation method according to claim 2 or 3 described PVC elastic roll floor-boards comprises:
Preparation wear-resistant coat, enhancement Layer, foaming layer and back of the body seal semiproduct, the raw material of correspondence are put into banbury after high-speed mixer mixes plastify, further plastify through mill again, filter then and extrude, will plastify at last the material of getting well through calendering, traction, cooling and rolling get final product required semiproduct;
Scrape legal system and be equipped with the glass dense layer with being coated with, the PVC thickener is scraped technology fiberglass substrate is applied once or twice through being coated with, again through gel and rolling get final product described glass dense layer;
Described wearing layer, glass dense layer, foaming layer and back of the body seal are heated applying in foaming furnace;
By foaming, embossing, cooling and rolling, obtain the PVC elastic roll floor-board then.
5. the preparation method of a PVC elastic roll floor-board according to claim 4 is characterized in that: also comprise and carry out the processing of UV coating with obtaining the PVC elastic roll floor-board.
6. the preparation method according to claim 4 or 5 described PVC elastic roll floor-boards is characterized in that: also be included in and carry out heating before the processing of UV coating.
7. the preparation method of a PVC elastic roll floor-board according to claim 6 is characterized in that: cooling once more after handling curing through UV.
8. the preparation method of a PVC elastic roll floor-board according to claim 4, it is characterized in that: described applying step also comprises:
At the foaming furnace leading portion that wear-resistant coat articulamentum and the unification of fiberglass substrate laminating is inferior earlier, the once described enhancement Layer of between fiberglass substrate layer and foaming layer, fitting again simultaneously;
Described back of the body seal and described second foaming layer are fitted at calender, and described first foaming layer and second foaming layer are fitted at calender.
9. the preparation method of a PVC elastic roll floor-board according to claim 4, it is characterized in that: comprise that also the leading portion applying section with foaming furnace increases more than one at least stock shelf and corresponding laminating apparatus, and/or increase more than one stock shelf and corresponding laminating apparatus at least at the foaming furnace back segment.
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5177053A (en) * 1988-04-15 1993-01-05 Oji Paper Co., Ltd. Thermal transfer image-receiving sheet
US6268029B1 (en) * 1996-07-18 2001-07-31 Fuji Photo Film Co., Ltd. Package easy-to-open for photosensitive material
CN1487161A (en) * 2003-06-05 2004-04-07 英 宋 High-bright composite PVC foor board
CN2685065Y (en) * 2004-01-06 2005-03-16 田瑞军 Environment protection type composite coiled material
CN2688801Y (en) * 2004-04-30 2005-03-30 刘坤 Polyethylene foaming coiled material leather
CN1970287A (en) * 2005-11-24 2007-05-30 科定企业股份有限公司 Soft cushion structure

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5177053A (en) * 1988-04-15 1993-01-05 Oji Paper Co., Ltd. Thermal transfer image-receiving sheet
US6268029B1 (en) * 1996-07-18 2001-07-31 Fuji Photo Film Co., Ltd. Package easy-to-open for photosensitive material
CN1487161A (en) * 2003-06-05 2004-04-07 英 宋 High-bright composite PVC foor board
CN2685065Y (en) * 2004-01-06 2005-03-16 田瑞军 Environment protection type composite coiled material
CN2688801Y (en) * 2004-04-30 2005-03-30 刘坤 Polyethylene foaming coiled material leather
CN1970287A (en) * 2005-11-24 2007-05-30 科定企业股份有限公司 Soft cushion structure

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