CN100459277C - Dynamic electrolyte for lithium ion battery - Google Patents
Dynamic electrolyte for lithium ion battery Download PDFInfo
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- CN100459277C CN100459277C CNB2006101222620A CN200610122262A CN100459277C CN 100459277 C CN100459277 C CN 100459277C CN B2006101222620 A CNB2006101222620 A CN B2006101222620A CN 200610122262 A CN200610122262 A CN 200610122262A CN 100459277 C CN100459277 C CN 100459277C
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
This invention relates to dynamic lithium ion battery electrolyte and to one safe dynamic high capacity lithium ion electrolyte and discloses the following components: w/w carbonic acid esters agent composed of vinylene carbonate less than 40 percentage; propylene carbonate less than 20 percentage; methyl propionate less than 40 percentage; propylene carbonate less than 40 percentage; lithium salt 10-16 percentage to prevent additive agent phenylcyclohexyl, p-methyl peroxide, phthalandione or fluoride content less than 12 percentage or combustion inhibitor less than 10 percentage and film addictive agent less than 5 percentage.
Description
Technical field
The present invention relates to the electrolyte that lithium ion battery is used, specifically a kind of safe power type high-capacity lithium ion cell electrolyte.
Background technology
Lithium ion battery has operating voltage height, specific energy height, has extended cycle life, with characteristics such as environmental friendliness and memory-less effect, obtained development rapidly, be widely used on the portable electronics.What conventional liquid lithium ionic cell used is the lithium salt solution of organic carbonate, has easy-to-leak liquid and incendive potential safety hazard, and overcharge blast easily when battery is abused, and this has had a strong impact on the development of lithium ion battery to the power type direction.
Solve the simple of lithium ion battery safety problem and valid approach is a development all solid state lithium ion battery, because all solid state lithium ion battery room temperature and poor performance at low temperatures now have a lot of technology to remain to be broken through.Polymer gel attitude lithium ion battery also can be alleviated the safety problem of liquid lithium ionic cell to a certain extent, but its big shortcoming of polarization when having poor performance at low temperatures, big electric current equally.
(in＜5Ah) the lithium ion battery, the content of electrolyte is fewer, and battery can comparatively fast distribute at the time heat that produces of short circuit, generally situation about can not blast in low capacity; Under the state of overcharging, because the input of external electric energy is arranged, battery can cause blast by persistent fever, if in electrolyte, add anti-overcharge additive such as biphenyl, cyclohexyl benzene etc., polymerization takes place under a certain current potential, open circuit in inside battery formation, battery is in a safe condition, can improve or solve the safety problem that overcharges of battery.Yet the ambient temperature that power-type lithium ion battery uses is than higher (40～90 ℃) and capacity height, and the heat of battery moment generation can not get in time distributing during short circuit, and the temperature meeting of battery sharply raises, and the interior voltage rise height of battery explodes, burns thereby produce.If in electrolyte, add fire retardant and anti-overcharge additive simultaneously, just can prevent the short circuit of battery or the safety problem when overcharging.But the affiliation that adds of these two kinds of additives influences battery capacity and useful life.
Summary of the invention
The purpose of this invention is to provide a kind of novel power-type lithium ion battery electrolyte, its amount by selecting carbonate solvent to add, and functional additive, when keeping this lithium-ion electrolyte cell high-capacity, improve high-temperature behavior, solve the safety problem of battery, make battery have the good life-span that recycles.
The technology of the present invention solution is that electrolyte is made up of following various materials, and content of material is represented to account for the heavy w/w of total liquid:
A, carbonate solvent main component comprise that ethylene carbonate content is not more than 40%, and the propylene carbonate ester content is not more than 20%, and carbonic acid first propyl ester content is not more than 40%, and dipropyl carbonate content is not more than 40% mixed liquor;
B, contain lithium salts 10～16%;
C, anti-overcharge additive comprise cyclohexyl benzene, terephthaldehyde's ether, and one or more in the fluoro thing of perhaps 1,2-dimethoxy benzene, or above material, content is not more than 12%;
D, fire retardant comprise tributyl phosphate, the trifluoromethyl phosphate, or 2,2, one or more in the 2-trifluoroethyl phosphate, content is not more than 10%;
E, film for additive comprise halogenated ethylene carbonate, halo propene carbonate, vinylene carbonate, vinylethylene carbonate, 1,3-sulfonic acid propiolactone, 1,4-sulfonic acid butyrolactone, ethylene sulfite, or in the propylene sulfite one or more, content is not more than 6%.
More than carbonate solvent of the present invention comprise gamma-butyrolacton 0～40%, dimethyl carbonate 0～15%, methyl ethyl carbonate 0～40%, diethyl carbonate 0～50%, carbonic acid first isopropyl ester 0～40%.
More than lithium salts of the present invention be selected from LiPF
6, LiBOB, LiSO
3CF
3, LiBF
4, LiAsF
6, Li (CF
3SO
2)
2N, LiC (CF
3SO
2)
3In one or more, addition is 11～13%.
Its addition of anti-overcharge additive of the present invention is 6～8%.
More than fire retardant of the present invention comprise trimethyl phosphate, triethyl phosphate, triphenyl phosphate, tributyl phosphate, trifluoromethyl phosphate, or 2,2, one or more in the 2-trifluoroethyl phosphate, its addition is 5～8%.
Film for additive addition of the present invention is 2～4%.
The high boiling dicyandiamide solution of employing of the present invention makes electrolyte highly stable under hot conditions, and decomposition reaction does not take place, and can not produce higher vapour pressure at inside battery.In electrolyte, add phosphate flame retardant, the phosphate of preferably fluoridizing, both can improve lithium salts thermal stability in the electrolyte, improve the security performance of battery when thermal shock, battery is burnt at the Shi Buhui of accident blast, because the phosphate viscosity of fluoridizing is lower, can not influence battery performance simultaneously.Another aspect that improves the electrolyte security performance is to use anti-overcharge additive in electrolyte, guarantees the safety of battery under the state of overcharging.The use of these additives in the capacity and the useful life that can influence battery in varying degrees, therefore adds film for additive in electrolyte, at the preferential passivation protection film that forms good thermal stability in the both positive and negative polarity surface of battery.The present invention to the selection of dicyandiamide solution and above three class functional additives with and the amount that adds, thereby improve the various aspects of performance of power-type lithium ion battery, obtained good effect.
The invention has the advantages that and improve high-temperature behavior when keeping this lithium-ion electrolyte cell high-capacity, solve the safety problem of battery, make battery have the good life-span that recycles.
Description of drawings
Fig. 1 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 1;
Fig. 2 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 2;
Fig. 3 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 3;
Fig. 4 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 4;
Fig. 5 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 5;
Fig. 6 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 6;
Fig. 7 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 7;
Fig. 8 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 8;
Fig. 9 is the figure line of the high temperature circulation discharge capacity of two batteries among the embodiment 9;
Figure 10 is the figure line of the high temperature circulation discharge capacity of two batteries in the Comparative Examples 2;
Figure 11 is the figure line of the high temperature circulation discharge capacity of two batteries in the Comparative Examples 2.
Embodiment
With the ethylene carbonate of carbonate solvent, propene carbonate, carbonic acid first propyl ester, dipropyl carbonate by account for total liquid heavy 26.43%, 11.32%, 12.94%, 24.81%, mix, in this solvent, add 12.5% LiPF then
6, average mark adds for three times, each 1.5～2.0 hours time intervals that add, fully shake up after the adding, the back adds the vinylene carbonate 1.0% and the propylene sulfite 2.0% of film for additive, anti-overcharge additive cyclohexyl benzene 7.0%, fire retardant trifluoromethyl phosphate 2.0%.The process for preparation of whole electrolyte is all operated in glove box, and glove box is an ar gas environment, and the temperature in the case is controlled in 25 ℃, and moisture is below 1ppm.
This electrolyte is injected in the battery, tests.
The battery that uses is:
Anodal preparation: active material LiCoO
2Content 94%, carbon black 3.0%, binding agent PVDF3.0%, aluminium foil are collector.Pole piece width 9.0cm, thickness 130 μ m.
The negative pole preparation: the content 90.0% of active material MCMB, the content 10.0% of binding agent PVDF, Copper Foil are collector, the wide 9.2cm of pole piece, thickness 158 μ m.
Barrier film is PE/PP/PE three strata compound films.The design capacity of battery is 10Ah.
Detection method:
Gained electrolyte is respectively annotated ten batteries, and after battery changed into, six batteries of detection computations are irreversible capacity first on average, wherein four batteries carry out 3C5V and overcharge, four are carried out 1C10V and overcharge, and four are carried out short-circuit test, in addition two batteries in 70 ℃ of environment with the 1C cycle charge-discharge.
Electrolyte prepares the multiplying power discharging characteristic detecting method of battery behind the battery:
1, with 1C electric current constant voltage charge to 4.2V, cut-off current is 20mA;
2, leave standstill 10 minutes, use secondary cell Performance Detection cabinet to detect battery capacity;
3, with the 1C current discharge to 3.0V;
4, leave standstill 10 minutes, use secondary cell Performance Detection cabinet to detect battery capacity.
Battery circulation discharge detection method: recycle the 1st to the 4th step of battery multiplying power discharging characteristic detecting method.
With the moisture in the coulomb Ka Shi method mensuration electrolyte, the acidity in the acid base titration test electrolyte, measure the conductivity of electrolyte with DJS-307 type electric conductivity instrument.
Embodiment 2-7
With embodiment 1, just each content of material is adjusted as shown in table 1 belowly, and do embodiment 1 described various tests with regard to the electrolyte of each embodiment gained.
Embodiment 8
With embodiment 1, just the cyclohexyl benzene with anti-overcharge additive changes terephthaldehyde's ether into, change the trifluoromethyl phosphate of fire retardant into 2,2,2-trifluoroethyl phosphate changes the vinylethylene carbonate in the film for additive into 1,3-sulfonic acid propiolactone, propylene sulfite changes ethylene sulfite into, LiPF
6Change Li (CF into
3SO
2)
2N also does embodiment 1 described various tests with regard to the electrolyte of gained.
Embodiment 9
With embodiment 1, just the cyclohexyl benzene with anti-overcharge additive changes adjacent benzene fluorine dimethyl ether into, change the trifluoromethyl phosphate of fire retardant into tributyl phosphate, and change vinylethylene carbonate in the film for additive and propylene sulfite into the chloroethylene carbonate ester, LiPF
6Change LiC (CF into
3SO
2)
3, and do embodiment 1 described various tests with regard to the electrolyte of gained.
Comparative Examples 1
Solvent ethylene carbonate, methyl ethyl carbonate, diethyl carbonate are mixed by mass ratio at 23.13%: 23.13%: 30.84%, and the back adds 12.9% LiPF
6, average mark three times adds, each 1.5～2.0 hours time intervals that add, stir, and the back adds 2.0% vinylene carbonate, 4.0% biphenyl, 4.0% cyclohexyl benzene, and does embodiment 1 described various tests with regard to the electrolyte of gained.
Comparative Examples 2
Solvent ethylene carbonate, dimethyl carbonate, diethyl carbonate are mixed by mass ratio at 23.55%: 23.55%: 31.4%, and the back adds 12.5% LiPF
6, average mark three times adds, each 1.5～2.0 hours time intervals that add, stir, add at last 2.0% vinylene carbonate, 7.0% 2,2,2-trifluoroethyl phosphate, and do embodiment 1 described various tests with regard to the electrolyte of gained.
Table 2 is the on average irreversible capacity loss first of battery in each example
| Example | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | |
Contrast 2 |
| Irreversible capacity loss (%) | 12.9 | 12.8 | 13.2 | 13.0 | 12.8 | 13.0 | 13.1 | 12.8 | 12.9 | 12.9 | 12.6 |
Table 3 is the experimental result that overcharges of battery in each example
| | 3C5V | 1C10V | |
| 1 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on fire | |
| 2 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on fire | |
| 3 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on fire | |
| 4 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on fire | |
| 5 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on fire | |
| 6 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on fire | |
| 7 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on fire | |
| 8 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on fire | |
| 9 | Do not explode, do not smolder, not on fire | Do not explode, do not smolder, not on | |
| Contrast | |||
| 1 | Do not explode, do not smolder, not on fire | 2 blasts are smoldered for 2 | |
| Contrast 2 | Battery explosion is smoldered, and is not on fire | Battery explosion is smoldered, and 1 on fire |
The short circuit experiment result of battery in each example of table 3
| Example | | Example | Phenomenon | |
| 1 | Do not explode, do not smolder, not on fire | 7 | Do not explode, do not smolder, not on fire | |
| 2 | Do not explode, do not smolder, not on fire | 8 | Do not explode, do not smolder, not on fire | |
| 3 | Do not explode, do not smolder, not on fire | 9 | Do not explode, do not smolder, not on fire | |
| 4 | Do not explode, do not smolder, not on | Contrast | 1 | 3 blasts, on fire |
| 5 | Do not explode, do not smolder, not on fire | Contrast 2 | 4 blasts are smoldered, and are not on fire | |
| 6 | Do not explode, do not smolder, not on fire |
Claims (2)
1, a kind of power-type lithium ion battery electrolyte is characterized in that electrolyte is made up of following various materials, and content of material is represented to account for the heavy w/w of total liquid:
A, carbonate solvent main component comprise that ethylene carbonate content is 26.43～40%, and the propylene carbonate ester content is not more than 20%, and carbonic acid first propyl ester content is not more than 40%, and dipropyl carbonate content is not more than 40% mixed liquor;
B, contain lithium salts 10～16%;
C, anti-overcharge additive main component comprise that cyclohexyl benzene, terephthaldehyde's ether or adjacent benzene fluorine dimethyl ether content are 6～12%;
D, fire retardant main component comprise tributyl phosphate, trifluoromethyl phosphate or 2,2,2-trifluoroethyl phosphate, and content is not more than 10%;
E, film for additive main component are halogenated ethylene carbonate, and content is 4～6%.
2, a kind of power-type lithium ion battery electrolyte according to claim 1 is characterized in that lithium salts is selected from LiPF
6, LiBOB, LiSO
3CF
3, LiBF
4, LiAsF
6, Li (CF
3SO
2)
2N, LiC (CF
3SO
2)
3In one or more, addition is 11～13%.
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| CNB2006101222620A CN100459277C (en) | 2006-09-20 | 2006-09-20 | Dynamic electrolyte for lithium ion battery |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101222620A CN100459277C (en) | 2006-09-20 | 2006-09-20 | Dynamic electrolyte for lithium ion battery |
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| CN100459277C true CN100459277C (en) | 2009-02-04 |
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Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101079504B (en) * | 2007-05-10 | 2010-05-26 | 武汉大学 | An electrolyte of efficient low-poison and combustion-resisting lithium cell and its lithium cell |
| CN101079505B (en) * | 2007-05-11 | 2010-05-26 | 武汉大学 | Combustion-resisting electrolyte of lithium secondary cell and its lithium cell |
| EP2526578B1 (en) * | 2007-08-16 | 2015-09-30 | LG Chem, Ltd. | Non-aqueous electrolyte lithium secondary battery |
| CN101593851B (en) * | 2008-05-29 | 2012-05-23 | 比亚迪股份有限公司 | Additive composition, electrolyte containing same and lithium ion secondary battery |
| CN101640288B (en) * | 2008-07-30 | 2012-03-07 | 比亚迪股份有限公司 | Lithium-ion battery electrolyte and lithium-ion battery containing same |
| CN102460817A (en) * | 2009-06-22 | 2012-05-16 | 日立车辆能源株式会社 | Lithium-ion secondary battery |
| CN101807720B (en) * | 2010-03-31 | 2012-08-15 | 张家港市国泰华荣化工新材料有限公司 | Flame-retardant electrolyte solution and application thereof |
| CN101826635A (en) * | 2010-04-09 | 2010-09-08 | 广州天赐高新材料股份有限公司 | Polymer electrolyte for lithium battery and manufacturing method of battery thereof |
| CN102237551B (en) * | 2010-04-30 | 2014-04-02 | 比亚迪股份有限公司 | Non-aqueous electrolyte, preparation method thereof and battery adopting electrolyte |
| CN101867065B (en) * | 2010-06-21 | 2013-07-10 | 张家港市国泰华荣化工新材料有限公司 | Flame-retardant electrolyte solution and application thereof |
| CN102544601A (en) * | 2010-12-17 | 2012-07-04 | 上海空间电源研究所 | Composite non-electrolyte additive for improving high-temperature safety performance of battery |
| CN102315484A (en) * | 2011-08-30 | 2012-01-11 | 珠海汉格能源科技有限公司 | Overcharge resistant electrolyte of polymer lithium ion battery |
| CN102496738A (en) * | 2011-12-31 | 2012-06-13 | 天津力神电池股份有限公司 | Non-aqueous electrolyte capable of improving safety performance of battery |
| CN102544581A (en) * | 2012-02-26 | 2012-07-04 | 河北工业大学 | Flame-retardant electrolyte for lithium iron phosphate power cell |
| CN102832408B (en) * | 2012-09-18 | 2015-04-08 | 广州天赐高新材料股份有限公司 | Electrolyte with high flame retardation performance and electrochemical performance and lithium ion battery |
| CN106340671B (en) * | 2015-07-08 | 2018-10-26 | 宁德时代新能源科技股份有限公司 | Lithium ion battery and electrolyte thereof |
| CN108242568A (en) * | 2016-12-26 | 2018-07-03 | 宁德时代新能源科技股份有限公司 | Electrolyte solution and secondary battery |
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