CN100457881C - Fabric care composition - Google Patents
Fabric care composition Download PDFInfo
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- CN100457881C CN100457881C CNB008169055A CN00816905A CN100457881C CN 100457881 C CN100457881 C CN 100457881C CN B008169055 A CNB008169055 A CN B008169055A CN 00816905 A CN00816905 A CN 00816905A CN 100457881 C CN100457881 C CN 100457881C
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- polymeric material
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
Abstract
A fabric care composition comprises a polymeric material which is capable of self cross-linking and/or of reacting with cellulose together with one or more textile compatible carriers, wherein the polymeric material comprises one or more poly(oxyalkylene) groups having an end group which comprises one or more amino groups or derivatives of said amino groups. The compositions may be used to treat fabric as part of a laundering process and improve the surface colour definition of the fabric following multiple washings.
Description
Technical field
The present invention relates to Fabrid care composition and utilize said composition or the method for the polymeric material processing fabric that they are contained.
Background and prior art
The laundry operation has some benefits to fabric usually, and the most common is removes crude removal and stain and in rinse cycle fabric is softened in washing process.Yet the repeated use of conventional laundry treatment compositions and/or existing clothes washing method has many defectives; One of them is to the quite coarse processing of fabric in laundry processes.
Multiple washing and wearing and tearing can cause the damage of fabric in a number of ways.Some FAQs that link with repeated washing are losses of fabric pilling and fabric face outward appearance, for example play fine hair, shrinkage (or expansion), the loss of fabric color or the race look (being commonly referred to dye transfer) of fabric.Only all can produce these problems with the multiple hand washing and with more violent machine washing method.In addition, also very important with fabric because of the long-term normal associated problem of damaging of using, as losing the wrinkling possibility of shape and increase.
The present invention relates to alleviate one or more above-mentioned problems.
The distinctiveness of the fabric face color that major advantage of the present invention relates to improvement after repeatedly washing and/or in washing process, give the fabric anti-pilling and/or resisted fine hair.The present invention has additional advantage aspect fabric treating.For example, can improve the others of fabric overall appearance, fabric creases and/or the corrugated tendency as reducing.
The scouring agent composition that contains polymeric amide-polyamine fabric-treating agent has been described in WO 98/29530.According to claim, as alleviating aspect balling-up/rise fine hair and anti-the fading, said composition is given the fabric that washs with this detergent composition overall appearance with improvement in the appearance performance.In WO 97/42287, told about the laundry composition of the polymeric amide-polyamine treatment agent that contains similar type.
Compare with other conventional laundry composition, the laundry composition that contains polymeric amide-polyamine fabric-treating agent has the performance that wipes out a blot of dyestuff absorptivity of raising (i.e. the dye transfer of Ti Gaoing) and difference.
US 5571286 people such as () Connell discloses some by polyoxyalkylene amine derived polymers and prepolymer and in anti-application of shrinking in the woolen knitwear processing.The woolen knitwear of this processing also can have more soft hand feeling than undressed woolen knitwear.This document is not mentioned the processing of cellulosic materials fabric or fabric face outward appearance that it may stand loss problem after washing.In addition, it all relates to plant-scale woolen knitwear handles, and does not mention the application on the fabric of said composition in laundry process.
The present invention is based on such accident and finds, comprises that promptly those some polymeric materials interior described in US 5571286 can give the appearance of cellulosic materials fabric to improve.Compare with some composition that contains polymeric amide-polyamine fabric-treating agent, aspect the soil release characteristics of dye transfer that for example increases and difference, described polymeric material has the further advantage that reduces disadvantageous side effect.
The invention definition
According to the invention provides a kind of Fabrid care composition, said composition contain can self-crosslinking and/or can with polymeric material and one or more carriers compatible of fibrin reaction with textiles, wherein, when the carrier compatible with textiles is water, then exist other to be applicable to the additive of laundry composition, wherein said polymeric material comprises one or more poly-(oxyalkylene) groups, and this poly-(oxyalkylene) group has the end group that contains one or more amino or derivative that should amino.
The present invention also provides the method as the processing fabric of the part of clothes washing method, and it comprises uses Fabrid care composition of the present invention or use polymeric material into the component of Fabrid care composition of the present invention fabric.
The present invention further provides in another aspect and has used Fabrid care composition of the present invention or be the polymeric material of the component of Fabrid care composition of the present invention, to improve the distinctiveness of the fabric face color after the repeatedly washing.
In another aspect, the invention provides and use Fabrid care composition of the present invention or be the polymeric material of the component of Fabrid care composition of the present invention, in laundry processes, to give the fabric anti-pilling and/or to have resisted fine hair.In addition, the present invention can give fabric other useful performance, as reduce in the laundry processes crease and/or wrinkling.
Detailed description of the Invention
Composition of the present invention contain can self-crosslinking and/or can with polymeric material and one or more carriers compatible of fibrin reaction with textiles, wherein, described polymeric material comprises one or more poly-(oxyalkylene) groups, and this poly-(oxyalkylene) group has the end group that contains one or more amino or derivative that should amino.
Composition of the present invention has surprising advantages, promptly gives fabric abrasion resistance, thereby and after the laundry, particularly repeatedly the washing after, make fabric have the distinctiveness of the surface color of improvement.
In addition, the polymeric material that contains in said composition can not cause dye transfer and/or the decontamination problem that is difficult to accept.
Can be used for polymeric material of the present invention and can be any polymkeric substance or prepolymer derived from the polyoxyalkylene amine described in US 5571286.The method for preparing described polymeric material is described among the US 5571286.Therefore, described polymeric material can be that for example the polymerization degree is 4 to 50 the diamines or reaction product or its mixture of triamine polyoxyalkylene polymers, and its Epicholorohydrin amount is an Epicholorohydrin to the ratio of amino nitrogen from 1: 1 to 3: 1.
Amino group in the polymeric material that the present invention uses can be the form of aminoderivative whole or in part.Derivative for example comprises by the adducts that forms at alkylation on the nitrogen-atoms or hydroxyalkylation or by form the adducts that amide group forms on nitrogen-atoms.Described derivative can be formed with the difunctionality bridging agent or with the linking agent reaction by amino.
Preferably, described polymeric material can be B (R) by formula
nPolymkeric substance and the reaction of linking agent obtain, n is 1 to 20 in the formula, B is the main chain group, each R is covalent bonding with it, and R is the group that contains poly-(oxyalkylene) chain, this chain contains amino end group, this polymkeric substance randomly forms the compound reaction with bridged bond.Therefore will understand the mixture that polymeric material of the present invention is a more complicated, and contain many different compounds, wherein some or all can be crosslinked.
Poly-(oxyalkylene) chain that constitutes a R group part can be for example poly-(oxygen ethene), poly-(oxygen butylene) or poly-(oxygen the third-1,2-alkene) chain.Chain length can change between 2 to 100 repeating units.
Advantageously n is 2 or 3.Be that containing formula at polymeric material of the present invention is B (R) with what recognize
nDifferent mixture of polymers the time, n can not be an integer.
Can be used for polymeric materials more of the present invention, B is
(that is, when m was 1, B was a glyceryl) and m equal n-2.
Yet B also can represent other meaning, as the residue of other ternary alcohol radical or dihydroxy compound, tetrahydroxy compound, pentahydroxyl compound or hexahydroxy-compound.Perhaps, B can represent the residue of diamines, triamine or polyamines.
Preferably, at least one R group has formula-(CH
2CH (R ') (CH
2)
aO)
p-A-NHR ", wherein: R ' is H or CH
3A is 0,1 or 2; P is by 5 to 30 integer; A is an alkylidene group; And R " is H or alkyl.More preferably, p is by 10 to 25.
Comprise C at this used term " alkyl "
1-C
6Alkyl randomly replaces on alkyl chain, and they can be branching or nonbranched, and for C
3-C
6Alkyl can be a cyclic.The definition of " alkylidene group " speech is similar, but is meant divalent radical.
Will be appreciated that term " end group " refer to or near the group of poly-(oxyalkylene) chain terminal, when the polymkeric substance formula is B (R)
nThe time, this terminal is at the other end of polymer chain with respect to the terminal that is attached to B.
Suitable formula is B (R)
nPolymkeric substance comprise that those have following array structure:
Wherein, R ' as defined above, p, q and r are can be identical or different and can be 5 to 30 integer, and A is branching or nonbranched low-grade alkylidene.
Other formula is B (R)
nSuitable polymers (wherein n equals 2) comprise that those have following array structure:
H
2N-(CH
2)
b-(O(CH
2)
4)
d-O(CH
2)
cO-((CH
2)
4O)
d2-(CH
2)
b-NH
2
Wherein: b is by 1 to 6 integer, is preferably 3; C is by 1 to 6 integer, is preferably 4; And d and d2 are identical or different and be by 10 to 15 integer.
Be used for preferably including epihalohydrin by forming the linking agent of the used polymeric material of the present invention or react polymkeric substance afterwards in advance with bridged bond formation compound with polymer reaction.Epicholorohydrin is a kind of suitable epihalohydrin.
Preferably, linking agent and formula are B (R)
nThe mol ratio of polymkeric substance be 0.5: 1 to 4: 1.Linking agent also can other amount be present in the used polymeric material of the present invention.
Suitable bridged bond forms compound and comprises two epoxies or hydroxy-acid group.This epoxy or hydroxy-acid group can connect by the linking agent that contains alkylene, arylidene, poly-(oxyalkylene) or siloxane groups or its combination.Therefore, bridged bond forms examples for compounds and comprises benzene-1,4-dioctyl phthalate, hexane-1, the 6-dioctyl phthalate and at the molecule two ends by end capped poly-(oxygen ethene) compound of epoxide group.Other bridged bond that is fit to forms compound and is disclosed among the US 5571286.
Compositions for use of the present invention can contain described polymeric material and other optional polymeric material.Said composition can further comprise can with the siloxanes of described polymeric material reaction.Suitable active siloxanes comprises that those have the siloxanes of amino and hydroxyl, and they are that those skilled in the art are well-known.
Preferably, when being 80g/m to be applied to weight based on paper weight 1% solid weight concentration with described polymeric material
2Paper on the time, with respect to undressed paper, it can improve at least 200% (according to testing method described later) with the wet tenacity of paper.
Be applicable to that polymeric material of the present invention can derive from Precision Processes Textiles (Ambergate, Derbyshire, Britain), trade mark is POLYMER AM and POLYMERMRSM.Polymeric material of the present invention is preferably with the form of the aqueous solution.
Polymer A M is the polymkeric substance with following array structure:
Polymkeric substance MRSM has the structure identical with polymer A M, but the siloxanes that is added in the polymeric blends is arranged.
The characteristic of the carrier compatible with textiles will be subjected to the present composition is used for the control in the stage of program for washing to a great extent, and in principle, said composition can be in program, and how the stage uses.For example, when described composition was used as main detergent ingredients, one or more carriers compatible with textiles comprised detergent active compound.When described composition was used in the rinse step of washing procedure, one or more carriers compatible with textiles can comprise fabric-softening and/or conditioning compound.
The present composition preferably contains perfume compound, is used for the kind of Fabrid care composition as routine.Said composition packing and mark can be used for the household laundry operation.
Described polymeric material preferably is present in the product with sufficient amount, on fabric, to obtain counting the amount of 0.0005 weight % to 5 weight % based on fabric weight, and more preferably 0.001 weight % to 2 weight % on fabric.In described composition, for the requirement that reaches at the polymeric material of the above-mentioned weight % on the fabric will be preferably 0.1 weight % to 13.5 weight % usually in the scope of 0.01 weight % to 35 weight %.
When being applied to fabric, the present composition can be of value to fabric when uncured.Yet they can comprise that flatiron and/or family expenses drum-type drying (preferred drum-type drying) solidify by the family expenses curing schedule.Solidify and preferably carry out more preferably 80 to 100 ℃ 50 to 100 ℃ scope.
Within the scope of the present invention, term " carrier compatible with textiles " is a kind of composition, and it helps the interaction of first composition and fabric.This carrier can provide the benefit that provides except that the first one-tenth branch for example softening, the benefit cleaning.Carrier can be water, the present composition will contain another additive that is applicable to laundry composition in this case, as perfume compound, perhaps carrier can be detergent active compound or fabric softener or conditioning compound or other suitable washing composition or fabric-treating agent.
If the present composition is used for a part such as the detergent ingredients of laundry operations as the fabrics in general treating product, then compatible with textiles carrier is detergent active compound normally.Yet if the fabric treating product is a rinse conditioner, the carrier compatible with textiles will be fabric-softening and/or conditioning compound.
If used the present composition before or after program for washing, it can be the form of spraying or frothed product.
The fabric that can handle in the present invention comprises those cellulose fibers, preferably contains 1% to 100% cellulosic fibre (more preferably 5% to 100% cellulosic fibre most preferably is 40% to 100% cellulosic fibre).Fabric can be the form of clothes, and in the case, the inventive method can be represented the method for laundry.When fabric contains when being less than 100% cellulosic fibre, rest part comprises other fiber or the fibre blend that is applicable to clothes, as polyester.Preferably, cellulosic fibre is from cotton or regenerated cellulose such as viscose.
Clothes washing method of the present invention comprises a large amount of of fabric and (for example family expenses) washing in a small amount.Preferably, described method is family expenses.
In the present invention, polymeric material of the present invention or composition can be in program for washing, and how the stage uses.Preferably, in the rinse cycle of program for washing, use said composition or polymeric material to handle fabric.Rinse cycle is preferably after handling fabric with detergent composition.
Detergent active compound
If composition of the present invention is the form with detergent ingredients, the carrier compatible with textiles can be selected from negatively charged ion, positively charged ion, nonionic, both sexes and zwitterionic detergent active compound of soap and non-soap and composition thereof.
Many suitable detergent active compounds are available, and detailed description is arranged in the literature, for example, and at Schwartz, in " Surface-ActiveAgents and Detergents " I of Perry and Berch volume and the II volume.
Can with, the preferred carrier compatible with textiles be soap class and synthetic non-soap anionic and non-ionic compound.
Aniorfic surfactant is well known to those skilled in the art.Example comprises alkylbenzene sulfonate, and particularly alkyl chain length is C
8-C
15The linear alkyl benzene sulfonate; Alkylsurfuric acid hydrogen salt and alkyl-sulphate, particularly C
8-C
15The alkylsurfuric acid hydrogen salt; Sulfated alkyl ether; Ethylenic sulfonate; Alkylxylene sulfonate; Dialkyl sulfosuccinates; And fatty sulfonate.Common particular certain cancers.
The available nonionic surface active agent comprises the ethoxylate of primary alconol and secondary alcohol, and especially every mol of alcohol is on average used the C of 1 to 20 moles of ethylene oxide ethoxylation
8-C
20Fatty alcohol, and more in particular be the C that every mol of alcohol is on average used 1 to 10 moles of ethylene oxide ethoxylation
10-C
15Primary aliphatic alcohols and aliphatic secondary alcohol.The nonionic surface active agent of ethoxylation does not comprise alkyl polyglycoside, glycerol monoethers and polyhydroxy amides (glucamide).
The available cationic surfactant comprises that general formula is R
1R
2R
3R
4N
+X
-Quaternary ammonium salt, wherein, the R group is that length is C independently
1-C
22Hydrocarbyl chain, the normally alkyl of alkyl, hydroxyalkyl or ethoxylation, and X is solubilising positively charged ion (for example such compound, wherein R
1Be C
8-C
22Alkyl, be preferably C
8-C
10Or C
12-C
14Alkyl, R
2Be methyl, and R
3And R
4(can be identical or different) be methyl or hydroxyethyl); And cationic ester (for example cholinesterase) and pyridinium salt.
In described composition, the total amount of detergent surfactant is suitably 0.1 to 60 weight %, and 0.5 to 55 weight % for example is as 5 to 50 weight %.
Preferably, the amount of aniorfic surfactant (when existing) is in 1 to 50% scope of total composition weight.More preferably, the amount of aniorfic surfactant is in the scope of 3 to 35 weight %, for example 5 to 30 weight %.
Preferably, when nonionic surface active agent existed, its amount was in the scope of 2 to 25 weight %, more preferably was 5 to 20 weight %.
Also can use amphoterics, for example amine oxide or trimethyl-glycine.
Described composition can suitably contain the detergency buider of 10 to 70 weight %, preferred 15 to 70 weight %.Preferably, the amount of buider is in the scope of 15 to 50 weight %.
Described detergent composition can contain crystalline aluminosilicate, preferred as alkali aluminosilicate, more preferably sodium aluminium silicate is as buider.
Aluminosilicate usually can 10 to 70 weight % (anhydrous benchmark), preferably mix with 25 to 50 weight %.Aluminosilicate is the material with following general formula:
0.8-1.5 M
2O·Al
2O
3·0.8-6 SiO
2
Wherein, M is a univalent cation, preferred sodium.These materials contain some combination water, and require to have the calcium ion-exchanged capacity that is at least 50mg CaO/g.Preferred sodium aluminium silicate contains 1.5-3.5 SiO in following formula
2The unit.Fully describe as institute in the literature, they can be by the prepared in reaction by water glass and sodium aluminate easily.
Fabric-softening and/or conditioning compound
If composition of the present invention is the form of fabric-conditioning compositions, the carrier compatible with textiles will be fabric-softening and/or conditioning compound (being called " fabric softening compound " at this), and it can be positively charged ion or non-ionic compound.
Softening and/or conditioning compound can be water-fast quaternary ammonium compound.This compound can exist by maximum 8 weight % (based on the total composition meter), and at this moment said composition is regarded as diluting; Or this compound concentration can be 8 weight % to about 50 weight %, and at this moment said composition is regarded as enriched material.
If in order to suitable form, the composition that is suitable for using in rinse cycle also can be applied to fabric in rotating drum type drying machine.Like this, another product form is a kind of composition (for example sticking with paste) that substrate (for example flexible flake or sponge or suitable divider) is gone up and discharged from it in the drum-type drying course that is suitable for being coated to.
Suitable cationic fabric softening compound mainly is the water-fast quaternary ammonium material that contains single alkyl or alkenyl long-chain, and its mean chain length is more than or equal to C
20, perhaps more preferably be the compound that contains polarity head end group and two alkyl or alkenyl chains, its mean chain length is more than or equal to C
14Preferably, fabric softening compound has two alkyl or alkenyl long-chains, and each chain mean chain length is more than or equal to C
16More preferably, at least 50% chain alkyl or alkenyl group have C
18Or longer chain length.If preferably the chain alkyl of fabric softening compound or alkenyl group mainly are straight chains.
Quaternary ammonium compound with two long-chain aliphatic group, for example VARISOFT TA100 and two (hard tallow alkyl) alkyl dimethyl ammonium chloride is widely used in the commercially available rinse conditioner composition.Other this cationoid examples for compounds sees Schwartz, in " Surface-Active Agents and Detergents " I volume and II volume of Perry and Berch.Any conventional kind of this compounds all can be used in the composition of the present invention.
Described fabric softening compound preferably provides the compound of excellent softening performance, and it is characterized in that chain fusing L β is higher than 25 ℃ to L α transition temperature, preferably is higher than 35 ℃, more preferably is higher than 45 ℃.This L β can detect by DSC to the transformation of L α, and is defined as " Handbook of Lipid Bilayers " (CRC Press, Boca Raton, Florida, 1990) the 137th to 337 page at D.Marsh.Substantially water-fast fabric softening compound is defined as in the time of 20 ℃ that solubleness is lower than 1 * 10 in softening water
-3The fabric softening compound of weight %.Preferably, fabric softening compound solubleness is lower than 1 * 10
-4Weight % is more preferably less than 1 * 10
-8To 1 * 10
-6Weight %.
Particularly preferably be the cationic fabric softening compound for water-fast quaternary ammonium material, it has two by at least one ester bond, preferably be connected to C on the molecule by two ester bonds
12-22The alkyl or alkenyl group.The quaternary ammonium material of particularly preferred ester linkage can be represented with formula II:
Wherein, each R
1Group independently is selected from C
1-4Alkyl or hydroxyalkyl or C
2-4Thiazolinyl; Each R
2Group independently is selected from C
8-28Alkyl or alkenyl; And R wherein
3Be the straight or branched alkylidene group that 1 to 5 carbon atom is arranged, T is
And p is 0 or is 1 to 5 integer.
Two (tallow oxygen base oxethyl) alkyl dimethyl ammonium chlorides and/or its hardened tallow analogue are particularly preferred formula (II) compounds.
Second kind of preferred kind of quaternary ammonium material can formula (III) be represented:
Wherein, R
1, p and R
2As defined above.
Useful is if the quaternary ammonium material is biological biodegradable.
Preferred substance in this class, as 1,2-two (sclerosis tallow base oxygen)-3-chlorination TMA (TriMethylAmine) propane, and preparation method thereof for example record and narrate in US 4 137 180 (Lever Brothers company).Preferably, these materials comprise the corresponding monoesters that resembles description in US 4 137 180 on a small quantity, for example 1-sclerosis tallow base oxygen-2-hydroxyl-3-chlorination TMA (TriMethylAmine) propane.
Other useful cationic tenderizer is the imidazolines of Fixanol and replacement.The also condensation product of primary amine, secondary amine and tertiary amine and lipid acid and alkyl polyamine usefully.
Described composition can or or comprise the water-soluble cationic fabric softener in addition, described at GB 2 039 556B (Unilever).
Described composition can comprise cationic fabric softening compound and oil, and is for example disclosed in EP-A-0829531.
Described composition can or or comprise the non-ionic type fabric softener in addition, as lanolin and derivative thereof.
Yelkin TTS also is suitable soften compound.
The non-ionic type tenderizer comprise form sugar ester (as M.Hato etc. at Langmuir 12,1659, described in 1666 (1996)) with such as the L β of related substanceses such as glyceryl monostearate or Isosorbide Dinitrate mutually.Usually these materials are used in combination with cationic material, to help deposition (referring to for example GB 2 202 244).In rinsing is handled,, use siloxanes as being total to tenderizer (participating in for example GB 1 549180) with similar mode with cationic tenderizer.
Described composition also can suitably contain non-ionic stabilizer.Suitable non-ionic stabilizer is with 10 to 20 moles of oxyalkylated straight chain C of alkylene oxide
8To C
22Alcohol, C
10To C
20Alcohol or its mixture.
Useful is that described non-ionic stabilizer is with 10 to 20 moles of oxyalkylated straight chain C of alkylene oxide
8To C
22Alcohol.Preferably, the concentration of non-ionic stabilizer is the scope at 0.1 to 10 weight %, more preferably 0.5 to 5 weight %, most preferably 1 to 4 weight %.The mol ratio of quaternary ammonium compound and/or other cationic tenderizer and non-ionic stabilizer suitably 40: 1 to about 1: 1 scope, preferably at 18: 1 to about 3: 1 scope.
Described composition also can contain lipid acid, for example C
8To C
24Alkyl or alkenyl monocarboxylic acid or its polymkeric substance.Preferably use saturated fatty acid, especially hardened tallow C
16To C
18Lipid acid.Preferably, lipid acid is non-saponified, and more preferably, lipid acid is free, for example oleic acid, lauric acid or tallow fatty acids.The content of fatty acid material preferably is higher than 0.1 weight %, more preferably is higher than 0.2 weight %.Concentrate composition can contain the lipid acid of 0.5 to 20 weight %, more preferably contains 1 to 10 weight %.The weight ratio of quaternary ammonium material and/or other cationic tenderizer and fatty acid material is preferably 10: 1 to 1: 10.
Fabric-conditioning compositions can comprise type siloxane, as is mainly the polydialkysiloxane class of straight chain, for example polydimethylsiloxane or contain the aminosiloxane of amine-functionalized side chain; Soil release polymer is as the segmented copolymer of polyethylene oxide and terephthalate; Amphoterics; The inorganic clay of montmorillonite type; The zwitter-ion quaternary ammonium compound; And nonionic surface active agent.
Fabric-conditioning compositions also can comprise a kind of reagent that produces the pearlescent outward appearance, for example organic pearly-lustre compound, and as diglycol stearate, or inorganic pearly-lustre pigment, as trickle mica or titanium dioxide (TiO
2) mica that applies.
Fabric-conditioning compositions can be the form of milk sap or its milk sap precursor.
Other optional member comprises emulsifying agent, be preferably the ionogen of 0.01 to 5 weight % (for example sodium-chlor or calcium chloride), pH buffer reagent and perfume compound (preferred 0.1 to 5 weight %).
Further optional member comprises non-aqueous solvent, perfume compound carrier, white dyes, tinting material, hydrotropic agent, antifoams, anti redeposition agent, enzyme, optics brightening agent, opalizer, dye transfer hold back agent, antishrinking agent, anti wrinkling agent, has resisted spot agent, sterilant, mycocide, antioxidant, ultraviolet absorbers (opalizer), heavy metal sequestering agent, chlorine scavenger, dye-fixing agent, resist, draping property imparting agent, static inhibitor and flatiron auxiliary agent.More than listedly do not mean exhaustive.
The fabric treating goods
The present composition can be the form of liquid, solid (for example powder or sheet), gel or paste, spraying, rod or foam or mousse.Example comprises that soaking goods, rinsing processing (for example amendment or retouching agent) or master washes goods.Described composition also can be applied to substrate for example on the flexible flake or be used for divider, and these can be used in washing process, rinse cycle or the drying course.
Only present invention is described with reference to following non-limiting examples now.
Embodiment
POLYMER AM (trade mark) and POLYMER MRSM (trade mark) are according to polymeric material of the present invention, and derive from Precision Processes Textiles (Ambergate, Derbyshire, Britain).
Testing method by wet-strength resins on the textiles strength assessment paper
The used test program is as follows:
The paper of selecting for use is 80gsm White Copier Bond, 210 * 297mm, UniversalOffice Supplies ref UCOP80.An A4 scraps of paper dry weight is 4.91g.Soaked 30 minutes and remove superfluous water after weight be 7.30g.Thereby absorbed dose is decided to be 50%.
For undressed standard substance, in tray, paper was soaked in deionized water 10 minutes.After this, paper is shifted out, and slowly pat with paper handkerchief and to be removed, to remove superfluous water until surface water.Then in the baking oven of fan is housed with paper 110 ℃ of dryings 10 minutes.
For the sample of handling, the POLYMER AM or POLYMER MRSM (trade mark) aqueous solution prepare with the 2g/l sodium bicarbonate, are the coating concentration of fabric weight 1% so that optical density to be provided.
As a reference, treated sample was soaked in above-mentioned solution 10 minutes, remove excessive moisture, as above carry out dried/cured then.
Make paper leave standstill at least 24 hours (mensuration because of tensile strength is carried out, so needn't limit this paper relative humidity 65%) then on saturated paper.
With shears sample is cut to 270mm * 67mm then, and is parallel to 35mm place setting-out in the minor face, with as the benchmark when sample is sandwiched the Testometric clamp.
Then sample was soaked in deionized water 30 minutes.
Subsequently, discharge most of water, paper is saturated when carrying out so that measure.Before test is carried out, remove superfluous water as preceding method.
The preparation of Testometric-25kgf load cell, speed 100mm/ branch, pretension 0.1kgf, sample length 200mm, sample width 67mm.
Test result is as follows:
Sample preparation wet tenacity (kgf)
Undressed paper 1.069
Polymer AM 4.920
Polymer MRSM 4.017
Embodiment 1
The prevention of dye migration
Disclosed as WO 97/42287, with domestic washing machine (Zanussi (trade mark) automatic washing machine, 40 ℃ of cotton fabric washing process, in washing process, add Persil (trade mark)) knit to white silk floss and singly use 5 0.2%Kenores 1440 (trade mark) polyamine-Epicholorohydrins (PAE) resin (a kind of polymkeric substance that does not belong to the scope of the invention, from Akzo Nobel), this is 1.0 weight %PAE, is based on the theoretical maximum applied amount of fabric weight.Carry out same processing with 0.2%Polymer AM (trade mark) and 0.2%Polymer MRSM (trade mark).Then treated fabric is washed with fabrics red 80 painted with substantive dyestuff, that be celebrated with the loss dyestuff.Use Spectroflash (trade mark) spectrometer that the fabric that obtains is measured then, to measure the dye migration degree.With blank fabric sample in contrast.
ΔL ΔE
0.2％Kenores 1440 -3.47 6.20
0.1％Kenores 1440 -1.05 2.32
Polymer AM 0.93 2.21
Polymer MRSM 0.28 1.47
Δ L=luminance brightness changes
Δ E=color change
Therefore, with the fabric of polymer treatment of the present invention less color change is arranged, so less dye migration is arranged.
Embodiment 2
The clothes care benefits
The Spectroflash (trade mark) of standard testing fabric that black and red color area are arranged measured show, the fabric of using Polymer AM (trade mark) and Polymer MRSM (trade mark) according to embodiment 1 to handle presents the damage of minimizing.
Black region:
ΔL ΔE
Unprocessed 9.94 10.07
Polymer AM 1.81 1.95
Polymer MRSM 3.00 3.09
Red area:
ΔL ΔE
Unprocessed 3.30 12.62
Polymer AM 1.20 5.39
Polymer MRSM 1.19 4.84
In above two kinds of situations, less Δ L and Δ E value show, compare with undressed sample, and the zone of handling shows less change on tone.
Embodiment 3
The removal of stain
According to the program of in embodiment 1, formulating, handle cotton fabric (5 times 0.2% rinsing is carried out in each washing) with the 1ml red wine.With Persil Performance Biological (trade mark) powder, in the time of 40 ℃, before washing and after the washing, stain is measured with Spectroflash (trade mark) spectrophotometer.Before washing, as follows with respect to the change of the stain color depth of sample:
ΔL ΔE
Unprocessed-17.93 22.10
Polymer AM -20.26 23.98
Polymer MRSM -23.36 26.37
Kenores 1440 -19.38 22.37
After the washing, the color measuring result is:
ΔL ΔE
Unprocessed-3.97 5.94
Polymer AM -3.65 5.10
Polymer MRSM -5.70 7.98
Kenores 1440 -8.42 10.45
Polymer AM (trade mark) shows and undressed fabric soil removability much at one, and Polymer MRSM (trade mark) is between Polymer AM (trade mark) and Kenores 1440 (trade mark).
Background area to fabric is also measured, to show any trend of the caused soil redeposition of this processing.The reading of spectrometer is more little, and the change of color is more little and soil redeposition is few more.
ΔL
Unprocessed-0.20
Polymer AM -0.02
Polymer MRSM -0.19
Kenores 1440 -0.27
Standard rinse conditioner *-0.05
* Comfort (trade mark) (Unilever plc, Britain)
Although difference is little, do not make the soil redeposition performance of fabric bring up to the same degree that PAE type polymkeric substance is reached still shown these polymkeric substance.For Polymer AM (trade mark), and compare with rinse conditioner, deposit less again.
Embodiment 4
The fabric-conditioning agent formulation
The fabric-conditioning agent formulation be by preparation contain following component 2-8 the standard fabric conditioner composition and under agitation make to wherein adding component 1.Composition is with dilution and the preparation of spissated form.
It is as follows to fill a prescription:
| Dilution | Concentrate | |
| 1.Polymer AM | 15.1％ | 48.7％ |
| 2. water | 80.04％ | 35.86％ |
| 3. antifoaming agent | 0.01％ | 0.03％ |
| 4.Genapol* | 0.25％ | 0.75％ |
| 5.HEQ | 4.20％ | 13.5％ |
| 6. sanitas | 0.03％ | 0.06％ |
| 7. dyestuff | 0.07％ | 0.15％ |
| 8. perfume compound | 0.30％ | 0.95％ |
* use the C of 20 moles of ethylene oxide ethoxylations
12Primary alconol.
Embodiment 5
The cotton poplin that Polymer AM filling is administered to 2% usefulness resin impregnated detect thing (40 * 40cm), be 0.5% optical density with generation on fabric based on fabric weight.To detect the thing drum-type drying then.This process is carried out 4 times, is 2% total concn based on fabric weight with generation.Polymer MRSM and Kenores 1440 are carried out same step.To detect thing and get, pulverize (wrinkle in the simulation washing process) wet, be placed in the family expenses roller dryer (Miele) with wet cotton single ballast (dry weight 1kg) then.With the weighting material oven dry, until finishing the crease-resistant program of dryer.To detect thing then and be divided into lath grid, to measure crease intensity by AATCC smoothness standard.Flatiron detects thing and repeats the wrinkle operation then.
| Polymkeric substance | 0.5% (based on fabric weight, before the flatiron) | 0.5% (based on fabric weight, the flatiron back) | 2% (based on fabric weight, before the flatiron) | 2% (based on fabric weight, the flatiron back) |
| The untreated control thing | 1.4 | 1.38 | 1.64 | 1.54 |
| PAE | 1.3 | 1.44 | 2.26 | 1.94 |
| Kenores 1440 | 2.28 | 2.06 | 2.3 | 2.52 |
| Polymer MRSE | 2.1 | 2.34 | 2.38 | 2.8 |
Compare with the untreated control thing, Polymer AM and the obvious wrinkle of Polymer MRSM are less.If comprise the flatiron step, then wrinkle are still less for the detection thing of handling with Polymer MRSM.
Compare with Kenores 1440, Polymer AM and the obvious wrinkle of Polymer MRSM are less, are being on 0.5% the concentration based on fabric weight especially.
Claims (19)
1. the application of Fabrid care composition, to improve the fabric face color clear degree after repeatedly washing and/or in laundry processes, to give the fabric anti-pilling and/or resisted fine hair, wherein, described composition comprise can self-crosslinking and/or with polymeric material and one or more carriers compatible of fibrin reaction with textiles, wherein, polymeric material comprises one or more poly-(oxyalkylene) groups, this group has the end group that contains one or more amino or derivative that should amino, and wherein when the carrier compatible with textiles is water, exist other to be applicable to the additive of laundry composition.
2. the application of claim 1, wherein, described polymeric material can pass through (i) formula B (R)
nPolymkeric substance obtain formula B (R) with the (ii) reaction of linking agent
nIn, n is 1 to 20, B is the main chain group, each R is covalent bonding with it, and R is the group that contains poly-(oxyalkylene) chain, this chain contains amino end group, with the linking agent reaction before, described polymkeric substance randomly forms the compound reaction with bridged bond.
3. the application of claim 2, wherein, n is 2 or 3.
4. claim 2 or 3 application, wherein, B is
And m equals n-2.
5. claim 2 or 3 application, wherein, the formula of at least one R group is-(CH
2CH (R ') (CH
2)
aO)
p-A-NHR ", wherein: R ' is H or CH
3A is 0,1 or 2; P is by 5 to 30 integer; A is an alkylidene group; And R " is H or alkyl.
6. the application of claim 5, wherein, p is 10 to 25.
7. claim 2 or 3 application, wherein, formula is B (R)
nPolymkeric substance be
Wherein, p, q and r are can be identical or different and 5 to 30 integer, and A is branching or nonbranched low-grade alkylidene.
8. claim 2 or 3 application, wherein, formula is B (R)
nPolymkeric substance be
H
2N-(CH
2)
b-(O(CH
2)
4)
d-O(CH
2)
cO-((CH
2)
4O)d
2-(CH
2)
b-NH
2
Wherein: b is by 1 to 6 integer; C is by 1 to 6 integer; And d and d2 are identical or different and be by 10 to 15 integer.
9. the application of claim 8, wherein, b be 3 and/or c be 4.
10. claim 2 or 3 application, wherein, linking agent comprises epihalohydrin.
11. the application of claim 2 or 3, wherein, linking agent and formula are B (R)
nThe mol ratio of polymkeric substance be 0.5: 1 to 4: 1.
12. the application of claim 2 or 3, wherein, bridged bond forms compound and contains two epoxies or hydroxy-acid group.
13. the application of claim 12, wherein, epoxy or hydroxy-acid group connect by the linking agent that contains alkylidene group, arylidene, poly-(oxyalkylene) or siloxane groups or its combination.
14. the application of claim 2 or 3, further comprise can with the siloxanes of described polymeric material reaction.
15. the application of claim 2 or 3, wherein, when with described polymeric material heavily being that to be administered to weight be 80g/m for the concentration of 1% solid weight based on paper
2Paper on the time, compare with undressed paper, the wet tenacity of paper can be improved at least 200%.
16. the application of claim 2 or 3, wherein, one or more carriers compatible with textiles comprise detergent active compound.
17. the application of claim 2 or 3, wherein, one or more carriers compatible with textiles comprise fabric-softening and/or conditioning compound.
18. the application of claim 2 or 3 also comprises perfume compound.
19. the application of claim 2 or 3, wherein, fabric contains cellulosic fibre.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9923921.2A GB9923921D0 (en) | 1999-10-08 | 1999-10-08 | Fabric care composition |
| GB9923921.2 | 1999-10-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1409753A CN1409753A (en) | 2003-04-09 |
| CN100457881C true CN100457881C (en) | 2009-02-04 |
Family
ID=10862432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008169055A Expired - Fee Related CN100457881C (en) | 1999-10-08 | 2000-09-26 | Fabric care composition |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP1218477B1 (en) |
| CN (1) | CN100457881C (en) |
| AR (1) | AR025970A1 (en) |
| AT (1) | ATE301703T1 (en) |
| AU (1) | AU7305000A (en) |
| BR (1) | BR0014560B1 (en) |
| CA (1) | CA2386553C (en) |
| CZ (1) | CZ20021239A3 (en) |
| DE (1) | DE60021903T2 (en) |
| ES (1) | ES2245647T3 (en) |
| GB (1) | GB9923921D0 (en) |
| HU (1) | HUP0203581A2 (en) |
| PL (1) | PL354930A1 (en) |
| TR (1) | TR200200925T2 (en) |
| WO (1) | WO2001027232A1 (en) |
| ZA (1) | ZA200202685B (en) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1387878B1 (en) * | 2001-05-17 | 2004-10-06 | Unilever Plc | Laundry composition |
| GB2378960A (en) * | 2001-08-22 | 2003-02-26 | Unilever Plc | Fabric care composition |
| GB0122825D0 (en) * | 2001-09-21 | 2001-11-14 | Unilever Plc | Fabric care composition |
| GB0201165D0 (en) | 2002-01-18 | 2002-03-06 | Unilever Plc | Azetidinium modidfied poymers and fabric treatment composition |
| WO2003078504A1 (en) | 2002-03-20 | 2003-09-25 | Ge Bayer Silicones Gmbh & Co. Kg | Branched polyorganosiloxane polymers |
| DE10316662A1 (en) | 2003-04-11 | 2004-11-11 | Ge Bayer Silicones Gmbh & Co. Kg | Reactive amino and / or ammonium polysiloxane compounds |
| WO2013032479A1 (en) * | 2011-09-01 | 2013-03-07 | Colgate-Palmolive Company | Method for providing fast dry to fabric |
| US9758927B2 (en) | 2011-09-01 | 2017-09-12 | Colgate-Palmolive Company | Method for ease of ironing |
| WO2013032481A1 (en) | 2011-09-01 | 2013-03-07 | Colgate-Palmolive Company | Method for increased fragrance release during ironing |
| WO2013032480A1 (en) * | 2011-09-01 | 2013-03-07 | Colgate-Palmolive Company | Method for ease of ironing |
| AU2014241193B2 (en) | 2013-03-28 | 2016-10-20 | The Procter And Gamble Company | Cleaning compositions containing a polyetheramine |
| CA2918838C (en) | 2013-08-26 | 2018-07-24 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| US9771547B2 (en) | 2014-03-27 | 2017-09-26 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| US9719052B2 (en) | 2014-03-27 | 2017-08-01 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| WO2016028257A1 (en) * | 2014-08-18 | 2016-02-25 | Colgate-Palmolive Company | Hair products containing polyetheramine |
| US9617502B2 (en) | 2014-09-15 | 2017-04-11 | The Procter & Gamble Company | Detergent compositions containing salts of polyetheramines and polymeric acid |
| US9631163B2 (en) | 2014-09-25 | 2017-04-25 | The Procter & Gamble Company | Liquid laundry detergent composition |
| US9752101B2 (en) | 2014-09-25 | 2017-09-05 | The Procter & Gamble Company | Liquid laundry detergent composition |
| US9487739B2 (en) | 2014-09-25 | 2016-11-08 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| US9850452B2 (en) | 2014-09-25 | 2017-12-26 | The Procter & Gamble Company | Fabric care compositions containing a polyetheramine |
| US9388368B2 (en) | 2014-09-26 | 2016-07-12 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| US20170275565A1 (en) | 2016-03-24 | 2017-09-28 | The Procter & Gamble Company | Compositions containing an etheramine |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3753931A (en) * | 1970-06-05 | 1973-08-21 | Sandoz Ltd | Polyether amines their production and use |
| US5571286A (en) * | 1989-07-24 | 1996-11-05 | Precision Processes (Textiles) Limited | Polymers and prepolymers and their use in a method for the treatment of wool |
| WO1998028530A1 (en) * | 1996-12-20 | 1998-07-02 | Lucas Industries Plc | Control system |
| US5858023A (en) * | 1990-10-15 | 1999-01-12 | Precision Processes Textiles | Softening agents |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9022305D0 (en) * | 1990-10-15 | 1990-11-28 | Precision Proc Textiles Ltd | Softening agents |
| JP2001507733A (en) * | 1996-12-31 | 2001-06-12 | ザ、プロクター、エンド、ギャンブル、カンパニー | Laundry detergent composition containing polyamide-polyamine to give good appearance to washed fabric |
-
1999
- 1999-10-08 GB GBGB9923921.2A patent/GB9923921D0/en not_active Ceased
-
2000
- 2000-09-26 WO PCT/GB2000/003695 patent/WO2001027232A1/en active IP Right Grant
- 2000-09-26 CN CNB008169055A patent/CN100457881C/en not_active Expired - Fee Related
- 2000-09-26 TR TR2002/00925T patent/TR200200925T2/en unknown
- 2000-09-26 AT AT00960893T patent/ATE301703T1/en not_active IP Right Cessation
- 2000-09-26 HU HU0203581A patent/HUP0203581A2/en unknown
- 2000-09-26 ES ES00960893T patent/ES2245647T3/en not_active Expired - Lifetime
- 2000-09-26 EP EP00960893A patent/EP1218477B1/en not_active Expired - Lifetime
- 2000-09-26 BR BRPI0014560-2A patent/BR0014560B1/en not_active IP Right Cessation
- 2000-09-26 DE DE60021903T patent/DE60021903T2/en not_active Expired - Lifetime
- 2000-09-26 PL PL00354930A patent/PL354930A1/en unknown
- 2000-09-26 AU AU73050/00A patent/AU7305000A/en not_active Abandoned
- 2000-09-26 CA CA2386553A patent/CA2386553C/en not_active Expired - Fee Related
- 2000-09-26 CZ CZ20021239A patent/CZ20021239A3/en unknown
- 2000-10-06 AR ARP000105268A patent/AR025970A1/en unknown
-
2002
- 2002-04-05 ZA ZA200202685A patent/ZA200202685B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3753931A (en) * | 1970-06-05 | 1973-08-21 | Sandoz Ltd | Polyether amines their production and use |
| US5571286A (en) * | 1989-07-24 | 1996-11-05 | Precision Processes (Textiles) Limited | Polymers and prepolymers and their use in a method for the treatment of wool |
| US5858023A (en) * | 1990-10-15 | 1999-01-12 | Precision Processes Textiles | Softening agents |
| WO1998028530A1 (en) * | 1996-12-20 | 1998-07-02 | Lucas Industries Plc | Control system |
Also Published As
| Publication number | Publication date |
|---|---|
| TR200200925T2 (en) | 2002-06-21 |
| EP1218477A1 (en) | 2002-07-03 |
| AR025970A1 (en) | 2002-12-26 |
| EP1218477B1 (en) | 2005-08-10 |
| CN1409753A (en) | 2003-04-09 |
| PL354930A1 (en) | 2004-03-22 |
| CA2386553A1 (en) | 2001-04-19 |
| AU7305000A (en) | 2001-04-23 |
| DE60021903T2 (en) | 2006-03-30 |
| ZA200202685B (en) | 2003-06-25 |
| CA2386553C (en) | 2010-02-16 |
| ATE301703T1 (en) | 2005-08-15 |
| BR0014560B1 (en) | 2010-08-24 |
| HUP0203581A2 (en) | 2003-03-28 |
| BR0014560A (en) | 2002-06-11 |
| WO2001027232A1 (en) | 2001-04-19 |
| DE60021903D1 (en) | 2005-09-15 |
| ES2245647T3 (en) | 2006-01-16 |
| CZ20021239A3 (en) | 2002-10-16 |
| GB9923921D0 (en) | 1999-12-08 |
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