AU7305000A - Fabric care composition - Google Patents

Description

WO 01/27232 PCT/GB00/03695 FABRIC CARE COMPOSITION Technical Field 5 This invention relates to fabric care compositions and to methods of treating fabric using the compositions or the polymeric materials they contain. Background and Prior Art 10 The laundry process generally has several benefits for fabric, the most common being to remove dirt and stains from the fabric during the wash cycle and to soften the fabric during the rinse cycle. However, there are numerous 15 disadvantages associated with repeated use of conventional laundry treatment compositions and/or the actual laundry process; one of these being a fairly harsh treatment of fabric in the laundry process. 20 Fabrics can be damaged in several ways as a result of repeated laundering and/or wear. Fabric pilling and loss of fabric surface appearance e.g. fuzzing, shrinkage (or expansion), loss of colour from the fabric or running of colour on the fabric (usually termed dye transfer) are some 25 of the common problems associated with repeated laundering. These problems may occur merely from repeated hand washing as well as the more vigorous machine washing process. Furthermore, problems relating to damage of fabric over time through normal use, such as loss of shape and increased 30 likelihood of wrinkling are also significant.

WO01/27232 PCT/GBOO/03695 - 2 The present invention is directed towards alleviating one or more of the problems referred to hereinabove. The principal advantage of the present invention relates to 5 improving the surface colour definition of a fabric after multiple washings and/or to imparting pill and/or fuzz resistance to fabric during laundering. The invention can have further advantages in the treatment of fabric. For example, other aspects of the overall appearance of the 10 fabric can be improved, such as a reduction in the tendency of the fabric to become creased and/or wrinkled. Laundry detergent compositions containing polyamide polyamine fabric treatment agents are described in WO 15 98/29530. The compositions are claimed to impart improved overall appearance to fabrics laundered using the detergent compositions, in terms of surface appearance properties such as pill/fuzz reduction and antifading. Laundry compositions containing polyamide-polyamine treatment agents of similar 20 types are taught in WO 97/42287. Laundry compositions containing polyamide-polyamine fabric treatment agents can exhibit increased dye pick-up (ie, increased dye transfer) and poor stain removal properties 25 compared to other conventional laundry compositions. US 5571286 (Connell et al) discloses certain polymers and prepolymers derived from polyoxyalkyleneamines and their use in a process for shrink-proofing wool. The treated wool may 30 also have a softer handle than untreated wool. This document does not mention the treatment of cellulosic WO01/27232 PCT/GB00/03695 -3 fabrics or the problems of loss of fabric surface appearance that they can experience following laundering. Furthermore, it deals entirely with treatment of wool on an industrial scale and does not mention the application of the 5 compositions to fabric in the context of laundering processes. The present invention is based on the surprising finding that certain polymeric materials, including those described 10 in US 5571286, can impart improved surface appearance to cellulosic fabrics. The polymeric materials can have the further advantage of reduced adverse side-effects, in terms of increased dye transfer and poor stain removal, for example, compared to certain compositions containing 15 polyamide-polyamine fabric treatment agents. Definition of the Invention According to the present invention, there is provided a 20 fabric care composition comprising a polymeric material which is capable of self cross-linking and/or of reacting with cellulose together with one or more textile compatible carriers, in which when the textile compatible carrier is water a further additive suitable for use in laundry 25 compositions is present, wherein the polymeric material comprises one or more poly(oxyalkylene) groups having an end group which comprises one or more amino groups or derivatives of said amino groups. 30 The invention also provides a method of treating fabric, as part of a laundering process, which comprises applying to WO01/27232 PCT/GBOO/03695 -4 the fabric a fabric care composition of the invention or a polymeric material which is a component of the fabric care composition of the invention. 5 Further provided by the invention in another aspect is the use of a fabric care composition of the invention or a polymeric material which is a component of the fabric care composition of the invention to improve the surface colour definition of a fabric after multiple washings. 10 In another aspect, the invention provides the use of a fabric care composition of the invention or a polymeric material which is a component of the fabric care composition of the invention to impart pill and/or fuzz resistance to 15 fabric during laundering. In addition, the invention can impart other beneficial properties to the fabric, such as reduced creasing and/or wrinkling of the fabric during laundering. 20 Detailed Description of the Invention The compositions of the present invention comprise a polymeric material which is capable of self cross linking and/or of reacting with cellulose together with 25 one or more textile compatible carriers, wherein the polymeric material comprises one or more poly(oxyalkylene) groups having an end group which comprises one or more amino groups or derivatives of said amino groups. 30 WO01/27232 PCT/GBOO/03695 5 The compositions of the invention have the surprising advantage of imparting wear resistance to fabrics, and thereby causing improved surface colour definition of the fabric after laundering, particularly after multiple 5 washings. Furthermore, the polymeric materials contained in the compositions need not cause unacceptable dye transfer and/or stain removal problems. The polymeric material which can be used in the present 10 invention can be any of the polymers or prepolymers derived from polyoxyalkyleneamines that are described in US 5571286, the contents of which are incorporated herein by reference. Methods for preparing the polymeric materials are described in US 5571286. Hence the polymeric material can be, for 15 example, the reaction product of a diamine or triamine polyoxyalkylene polymer having a polymerisation degree of from 4 to 50 or a mixture thereof with epichlorohydrin in a ratio of epichlorohydrin to amino nitrogen of from 1:1 to 3:1. 20 The amino groups in the polymeric material of the invention may wholly or partly in the form of derivatives of amino groups. Derivatives include, for example, adducts formed by alkylation or hydroxyalkylation at the nitrogen atom or by 25 the formation of an amide group at the nitrogen atom. The derivatives may be formed by the reaction of the amino groups with a bifunctional bridging agent or with a cross linking agent. 30 Preferably, the polymeric material is obtainable by the reaction of a polymer of formula B(R)n, wherein n is from 1 WO 01/27232 PCT/GB00/03695 - 6 to 20, B is a backbone group to which each R is covalently bonded and R is a group comprising a poly(oxyalkylene) chain, which chain comprises an amino end group, the polymer being optionally reacted with a bridging compound, with a 5 cross-linking agent. It will thus be appreciated that the polymeric material of the invention is a relatively complex mixture comprising a number of different compounds, some or all of which may be cross-linked. 10 The poly(oxyalkylene) chain which forms a part of the R group may be, for example, a poly(oxyethylene), poly(oxybutylene) or poly(oxyprop-1,2-ylene) chain. The length of the chain can vary from 2 to 100 repeat units. 15 Conveniently,n is 2 or 3. It will be appreciated that n may not be a whole number where the polymeric material of the invention comprises a mixture of different polymers of formula B(R)n. 20 In some of the polymeric materials which may be used in the invention,B is

-O-CH

2 (CH) m-CH 2 -O- (ie, B is the residue of glycerol when m is 1) and m is equal 1 25 O to n-2. However, B can also represent other values such as , for 30 example, the residue of other triols or the residue of a di , tetra-, penta- or hexa- hydroxy compound. Alternatively, B can represent the residue of a di-, tri- or poly- amine.

WO01/27232 PCT/GB00/03695 - 7 Preferably, at least one R group has the formula (CH 2 CH(R') (CH 2 )aO)p-A-NHR'', wherein: R' is H or CH 3 ; a is 0, 1 or 2; p is an integer from 5 to 30; A is an alkylene 5 group; and R'' is H or alkyl. More preferably, p is from 10 to 25. The term "alkyl", as used herein, includes C1 to C6 alkyl, optionally substituted on the alkyl chain, which may be 10 branched or unbranched and, for C3 to C6 alkyl, may be cyclic. The term "alkylene" is defined similarly but refers to a divalent radical. It will be appreciated that the term "end group" refers to 15 the group at or near to the end of the poly(oxyalkylene) chain, which end, when the polymer is of formula B(R)n, is at the other end of the polymer chain from the end which is attached to B. 20 Suitable polymers of formula B(R)n include those having the following structure: H2C-O (CH 2 CH (R') 0) p-A-NH 2 I

HC-O(CH

2 CH(R')O)q-A-NH2 25

H

2

C-O(CH

2 CH(R' ) 0) -A-NH 2 wherein R' is as defined herein before, p, q and r are integers which may be the same or different and may be from 30 5 to 30 and A is branched or unbranched lower alkylene.

WO 01/27232 PCT/GB00/03695 - 8 Other suitable polymers of formula B(R)n, in which n is equal to 2, include those having the following formula:

H

2 N- (CH 2 ) b- (0 (CH 2 ) 4) d-O (CH 2 ) cO- ((CH 2 ) 40) d2- (CH 2 ) b-NH 2 wherein: b is an integer from 1 to 6, preferably 3; c is an 5 integer from 1 to 6, preferably 4; and d and d2 are the same or different and are integers from 10 to 15. The cross-linking agent which is used to form the polymeric material of the invention by reaction with the polymer, or 10 the polymer after prior reaction with the bridging compound, preferably comprises an epihalohydrin. Epichlorohydrin is a suitable epihalohydrin. Preferably the molar ratio of cross-linking agent to polymer 15 of formula B(R)n is from 0.5:1 to 4:1. Other amounts of cross-linking agent may be present in the polymeric material of the invention. Suitable bridging compounds comprise two epoxide or 20 carboxylic acid groups. The epoxide or carboxylic acid groups may be linked by a linker comprising alkylene, arylene, poly(oxyalkylene) or siloxane groups or combinations thereof. Examples of bridging compounds therefore include benzene-1,4-dicarboxylic acid, hexane-1,6 25 dicarboxylic acid and poly(oxyethylene) compounds terminated at both ends of the molecule by an epoxide group. Other suitable bridging compounds are disclosed in US 5571286. The composition of the invention can contain the polymeric 30 material, optionally together with other polymeric materials. The compositions may further comprise a silicone WO01/27232 PCT/GB00/03695 -9 which is capable of reacting with the polymeric material. Suitable reactive silicones include those having amino or hydroxyl groups which are well-known to those skilled in the art. 5 Preferably, the polymeric material is capable of increasing the wet strength of paper by at least 200% compared to untreated paper when applied to paper having a weight of 80 g/m 2 at a level of 1% solids by weight based on weight of 10 paper, according to the test method described hereinafter. Polymeric materials which are suitable for use in the present invention are available from Precision Processes Textiles (Ambergate, Derbyshire, UK) under the trade marks 15 POLYMER AM and POLYMER MRSM. The polymeric materials of the invention are preferably in the form of aqueous solutions. Polymer AM is a polymer having the following structure: 20

C

2 H C 2 H C 2 Hs HO N O O N CH 2 25

CH

2 CI OH HO OH

CH

2 CI

CH

2 CI POLYMER AM WO01/27232 PCTIGB00/03695 - 10 Polymer MRSM has the same structures as polymer AM but has silicone added to the polymer mixture. 5 The nature of the textile compatible carrier will be dictated to a large extent by the stage at which the composition of the invention is used in a laundering process, the compositions being capable of being used, in 10 principle, at any stage of the process. For example, where the compositions are for use as main wash detergent compositions, the one or more textile compatible carriers comprise a detergent active compound. Where the compositions are for use in the rinsing step of a laundering 15 process, the one or more textile compatible carriers may comprise a fabric softening and/or conditioning compound. The compositions of the invention preferably comprise a perfume, such as of the type which is conventionally used in 20 fabric care compositions. The compositions may be packaged and labelled for use in a domestic laundering process. The polymeric material is preferably present in the product in a sufficient quantity to give an amount of 0.0005% to 5% 25 by weight on the fabric based on the weight of the fabric, more preferably 0.001% to 2% by weight on fabric. The amount of the polymeric material in the composition required to achieve the above % by weight on fabric will typically be in the range 0.01% to 35% by weight, preferably 0.1 to 13.5% 30 by weight.

WO01/27232 PCT/GB00/03695 - 11 The compositions of the invention, when applied to a fabric, can impart benefits to the fabric when uncured. However, they may be cured by a domestic curing step including ironing and/or domestic tumble drying, preferably tumble 5 drying. The curing is preferably carried out at a temperature in the range of from 50 to 100 0 C, more preferably from 80 to 100 0 C. In the context of the present invention the term "textile 10 compatible carrier" is a component which can assist in the interaction of the first component with the fabric. The carrier can also provide benefits in addition to those provided by the first component e.g. softening, cleaning etc. The carrier may be water, in which case the 15 composition of the invention will contain another additive, suitable for use in laundry compositions such as perfume, for example, or the carrier may be a detergent-active compound or a fabric softener or conditioning compound or other suitable detergent or fabric treatment agent. 20 If the composition of the invention is to be used in a laundry process as part of a conventional fabric treatment product, such as a detergent composition, the textile compatible carrier will typically be a detergent-active 25 compound. Whereas, if the fabric treatment product is a rinse conditioner, the textile-compatible carrier will be a fabric softening and/or conditioning compound. If the composition of the invention is to be used before, or 30 after, the laundry process it may be in the form of a spray or foaming product.

WO01/27232 PCT/GB00/03695 - 12 The fabrics which may be treated in the present invention include those which comprise cellulosic fibres, preferably from 1% to 100% cellulosic fibres (more preferably 5% to 5 100% cellulosic fibres, most preferably 40% to 100%). The fabric may be in the form of a garment, in which case the method of the invention may represent a method of laundering a garment. When the fabric contains less than 100% cellulosic fibres, the balance comprises other fibres or 10 blends of fibres suitable for use in garments such as polyester, for example. Preferably, the cellulosic fibres are of cotton or regenerated cellulose such as viscose. The laundering processes of the present invention include 15 the large scale and small scale (eg domestic) cleaning of fabrics. Preferably, the processes are domestic. In the invention, the polymeric material or the composition of the invention may be used at any stage of the laundering 20 process. Preferably, the composition or the polymeric material is used to treat the fabric in the rinse cycle of a laundering process. The rinse cycle preferably follows the treatment of the fabric with a detergent composition.

WO01/27232 PCT/GB00/03695 - 13 Detergent Active Compounds If the composition of the present invention is in the form 5 of a detergent composition, the textile-compatible carrier may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof. 10 Many suitable detergent active compounds are available and are fully described in the literature, for example, in "Surface-Active Agents and Detergents", Volumes I and II, by Schwartz, Perry and Berch. 15 The preferred textile-compatible carriers that can be used are soaps and synthetic non-soap anionic and nonionic compounds. Anionic surfactants are well-known to those skilled in the 20 art. Examples include alkylbenzene sulphonates, particularly linear alkylbenzene sulphonates having an alkyl chain length of C 8

-C

15 ; primary and secondary alkylsulphates, particularly C 8

-C

15 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; 25 dialkyl sulphosuccinates; and fatty acid ester sulphonates. Sodium salts are generally preferred. Nonionic surfactants that may be used include the primary and secondary alcohol ethoxylates, especially the C 8

-C

20 30 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more WO01/27232 PCT/GB00/03695 - 14 especially the CI0o-C15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol. Non-ethoxylated nonionic surfactants include alkylpolyglycosides, glycerol 5 monoethers, and polyhydroxyamides (glucamide). Cationic surfactants that may be used include quaternary ammonium salts of the general formula RiR 2

R

3

R

4

N

+ X wherein the R groups are independently hydrocarbyl chains of CI-C 22 10 length, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups, and X is a solubilising cation (for example, compounds in which RI is a C 8

-C

22 alkyl group, preferably a C8-C10 or 012-014 alkyl group, R 2 is a methyl group, and R 3 and

R

4 , which may be the same or different, are methyl or 15 hydroxyethyl groups); and cationic esters (for example, choline esters) and pyridinium salts. The total quantity of detergent surfactant in the composition is suitably from 0.1 to 60 wt% e.g. 0.5-55 wt%, 20 such as 5-50wt%. Preferably, the quantity of anionic surfactant (when present) is in the range of from 1 to 50% by weight of the total composition. More preferably, the quantity of anionic 25 surfactant is in the range of from 3 to 35% by weight, e.g. 5 to 30% by weight. Preferably, the quantity of nonionic surfactant when present is in the range of from 2 to 25% by weight, more preferably 30 from 5 to 20% by weight.

WO01/27232 PCT/GB00/03695 - 15 Amphoteric surfactants may also be used, for example amine oxides or betaines. The compositions may suitably contain from 10 to 70%, 5 preferably from 15 to 70% by weight, of detergency builder. Preferably, the quantity of builder is in the range of from 15 to 50% by weight. The detergent composition may contain as builder a 10 crystalline aluminosilicate, preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate. The aluminosilicate may generally be incorporated in amounts of from 10 to 70% by weight (anhydrous basis), preferably 15 from 25 to 50%. Aluminosilicates are materials having the general formula: 0.8-1.5 M 2 0. A1 2 0 3 . 0.8-6 SiO 2 20 where M is a monovalent cation, preferably sodium. These materials contain some bound water and are required to have a calcium ion exchange capacity of at least 50 mg CaO/g. The preferred sodium aluminosilicates contain 1.5-3.5 SiO 2 units in the formula above. They can be prepared readily by 25 reaction between sodium silicate and sodium aluminate, as amply described in the literature. Fabric Softening and/or Conditioner Compounds 30 If the composition of the present invention is in the form of a fabric conditioner composition, the textile-compatible WO01/27232 PCT/GB00/03695 - 16 carrier will be a fabric softening and/or conditioning compound (hereinafter referred to as "fabric softening compound"), which may be a cationic or nonionic compound. 5 The softening and/or conditioning compounds may be water insoluble quaternary ammonium compounds. The compounds may be present in amounts of up to 8% by weight (based on the total amount of the composition) in which case the compositions are considered dilute, or at levels from 8% to 10 about 50% by weight, in which case the compositions are considered concentrates. Compositions suitable for delivery during the rinse cycle may also be delivered to the fabric in the tumble dryer if 15 used in a suitable form. Thus, another product form is a composition (for example, a paste) suitable for coating onto, and delivery from, a substrate e.g. a flexible sheet or sponge or a suitable dispenser during a tumble dryer cycle. 20 Suitable cationic fabric softening compounds are substantially water-insoluble quaternary ammonium materials comprising a single alkyl or alkenyl long chain having an average chain length greater than or equal to C 20 or, more 25 preferably, compounds comprising a polar head group and two alkyl or alkenyl chains having an average chain length greater than or equal to C 14 . Preferably the fabric softening compounds have two long chain alkyl or alkenyl chains each having an average chain length greater than or 30 equal to C16. Most preferably at least 50% of the long chain alkyl or alkenyl groups have a chain length of C 18 or above.

WO01/27232 PCT/GBOO/03695 - 17 It is preferred if the long chain alkyl or alkenyl groups of the fabric softening compound are predominantly linear. Quaternary ammonium compounds having two long-chain 5 aliphatic groups, for example, distearyldimethyl ammonium chloride and di(hardened tallow alkyl) dimethyl ammonium chloride, are widely used in commercially available rinse conditioner compositions. Other examples of these cationic compounds are to be found in "Surface-Active Agents and 10 Detergents", Volumes I and II, by Schwartz, Perry and Berch. Any of the conventional types of such compounds may be used in the compositions of the present invention. The fabric softening compounds are preferably compounds that 15 provide excellent softening, and are characterised by a chain melting LP to Lx transition temperature greater than 25 0 C, preferably greater than 35 0 C, most preferably greater than 450C. This LP to La transition can be measured by DSC as defined in "Handbook of Lipid Bilayers", D Marsh, CRC 20 Press, Boca Raton, Florida, 1990 (pages 137 and 337). Substantially water-insoluble fabric softening compounds are defined as fabric softening compounds having a solubility of less than 1 x 10 -3 wt % in demineralised water at 20 0 C. Preferably the fabric softening compounds have a solubility 25 of less than 1 x 10 -4 wt%, more preferably less than 1 x 10-8 to 1 x 10 -6 wt%. Especially preferred are cationic fabric softening compounds that are water-insoluble quaternary ammonium materials 30 having two C12-22 alkyl or alkenyl groups connected to the molecule via at least one ester link, preferably two ester WO 01/27232 PCT/GB00/03695 - 18 links. An especially preferred ester-linked quaternary ammonium material can be represented by the formula II: RI 5 RI N +

R

3

-T-R

2 (II) 10

(CH

2 ) p-T-R 2 15 wherein each RI group is independently selected from C 1 -4 alkyl or hydroxyalkyl groups or C2-4 alkenyl groups; each R 2 group is independently selected from C8-28 alkyl or alkenyl groups; and wherein R 3 is a linear or branched alkylene group of 1 to 5 carbon atoms, T is 20 0 0 II II -O-C- or -C-O-; 25 and p is 0 or is an integer from 1 to 5. Di(tallowoxyloxyethyl) dimethyl ammonium chloride and/or its hardened tallow analogue is especially preferred of the 30 compounds of formula (II). A second preferred type of quaternary ammonium material can be represented by the formula (III): 35 WO01/27232 PCT/GBOO/03695 - 19 OOCR 2 5 (R 1 ) 3 N -

(CH

2 ) p H (III)

CH

2 0OCR 2 10 wherein R 1 , p and R 2 are as defined above. It is advantageous if the quaternary ammonium material is biologically biodegradable. 15 Preferred materials of this class such as 1,2-bis(hardened tallowoyloxy)-3-trimethylammonium propane chloride and their methods of preparation are, for example, described in US 4 137 180 (Lever Brothers Co). Preferably these materials comprise small amounts of the corresponding 20 monoester as described in US 4 137 180, for example, 1-hardened tallowoyloxy- 2 -hydroxy-3-trimethylammonium propane chloride. Other useful cationic softening agents are alkyl pyridinium 25 salts and substituted imidazoline species. Also useful are primary, secondary and tertiary amines and the condensation products of fatty acids with alkylpolyamines. The compositions may alternatively or additionally contain 30 water-soluble cationic fabric softeners, as described in GB 2 039 556B (Unilever).

WO01/27232 PCT/GBOO/03695 - 20 The compositions may comprise a cationic fabric softening compound and an oil, for example as disclosed in EP-A 0829531. 5 The compositions may alternatively or additionally contain nonionic fabric softening agents such as lanolin and derivatives thereof. Lecithins are also suitable softening compounds. 10 Nonionic softeners include LP phase forming sugar esters (as described in M Hato et al Langmuir 12, 1659, 1666, (1996)) and related materials such as glycerol monostearate or sorbitan esters. Often these materials are used in 15 conjunction with cationic materials to assist deposition (see, for example, GB 2 202 244). Silicones are used in a similar way as a co-softener with a cationic softener in rinse treatments (see, for example, GB 1 549 180) 20 The compositions may also suitably contain a nonionic stabilising agent. Suitable nonionic stabilising agents are linear C8 to C22 alcohols alkoxylated with 10 to 20 moles of alkylene oxide, Ci0 to C20 alcohols, or mixtures thereof. 25 Advantageously the nonionic stabilising agent is a linear C8 to C22 alcohol alkoxylated with 10 to 20 moles of alkylene oxide. Preferably, the level of nonionic stabiliser is within the range from 0.1 to 10% by weight, more preferably from 0.5 to 5% by weight, most preferably from 1 to 4% by 30 weight. The mole ratio of the quaternary ammonium compound and/or other cationic softening agent to the nonionic WO01/27232 PCT/GBOO/03695 - 21 stabilising agent is suitably within the range from 40:1 to about 1:1, preferably within the range from 18:1 to about 3:1. 5 The composition can also contain fatty acids, for example C8 to C24 alkyl or alkenyl monocarboxylic acids or polymers thereof. Preferably saturated fatty acids are used, in particular, hardened tallow C1 to C18 fatty acids. Preferably the fatty acid is non-saponified, more preferably 10 the fatty acid is free, for example oleic acid, lauric acid or tallow fatty acid. The level of fatty acid material is preferably more than 0.1% by weight, more preferably more than 0.2% by weight. Concentrated compositions may comprise from 0.5 to 20% by weight of fatty acid, more preferably 1% 15 to 10% by weight. The weight ratio of quaternary ammonium material or other cationic softening agent to fatty acid material is preferably from 10:1 to 1:10. The fabric conditioning compositions may include silicones, 20 such as predominately linear polydialkylsiloxanes, e.g. polydimethylsiloxanes or aminosilicones containing amine functionalised side chains; soil release polymers such as block copolymers of polyethylene oxide and terephthalate; amphoteric surfactants; smectite type inorganic clays; 25 zwitterionic quaternary ammonium compounds; and nonionic surfactants. The fabric conditioning compositions may also include an agent which produces a pearlescent appearance, e.g. an 30 organic pearlising compound such as ethylene glycol WO01/27232 PCT/GB00/03695 - 22 distearate, or inorganic pearlising pigments such as microfine mica or titanium dioxide (TiO 2 ) coated mica. The fabric conditioning compositions may be in the form of 5 emulsions or emulsion precursors thereof. Other optional ingredients include emulsifiers, electrolytes (for example, sodium chloride or calcium chloride) preferably in the range from 0.01 to 5% by weight, pH 10 buffering agents, and perfumes (preferably from 0.1 to 5% by weight). Further optional ingredients include non-aqueous solvents, perfume carriers, fluorescers, colourants, hydrotropes, 15 antifoaming agents, antiredeposition agents, enzymes, optical brightening agents, opacifiers, dye transfer inhibitors, anti-shrinking agents, anti-wrinkle agents, anti-spotting agents, germicides, fungicides, anti-oxidants, UV absorbers (sunscreens), heavy metal sequestrants, 20 chlorine scavengers, dye fixatives, anti-corrosion agents, drape imparting agents, antistatic agents and ironing aids. This list is not intended to be exhaustive. Fabric Treatment Products 25 The composition of the invention may be in the form of a liquid, solid (e.g. powder or tablet), a gel or paste, spray, stick or a foam or mousse. Examples including a soaking product, a rinse treatment (e.g. conditioner or 30 finisher) or a mainwash product. The composition may also be applied to a substrate e.g. a flexible sheet or used in a WO01/27232 PCT/GB00/03695 - 23 dispenser which can be used in the wash cycle, rinse cycle or during the dryer cycle. The invention will now be described by way of example only 5 and with reference to the following non-limiting examples. EXAMPLES 10 POLYMER AM (trade mark) and POLYMER MRSM (trade mark) are polymeric materials according to the invention and were obtained from Precision Processes Textiles of Ambergate, Derbyshire, UK. 15 Test method for assessing wet-strength resins on paper by tensile strength The test procedure used was as follows: 20 Paper selected = 80 gsm White Copier Bond, 210 x 297 mm, Universal Office Supplies ref UCOP80. Dry weight of one A4 sheet = 4.91 g. Weight after 30 minute soak and removal of excess water = 7.30 g. Pick-up therefore set as 50%. 25 For the untreated standard, the paper was soaked in deionised water for 10 minutes in a shallow tray. After this time, sheets were removed and the excess water removed by gently patting with paper towels until all surface water had been removed. The paper was then dried at 110 0 C for 10 30 minutes in a fan-assisted oven.

WO01/27232 PCT/GB00/03695 - 24 For the treated sample, a solution of Polymer AM or Polymer MRSM (trade mark) with water was prepared along with 2 g/l of sodium bicarbonate to provide an application level by pick-up of 1% o.w.f. 5 As with the reference, the treated samples are soaked for 10 minutes in the solution, the excess water removed and then dried/cured as above. 10 The paper is then allowed to stand for at least 24 hours (as the tensile strength measurements are carried out on saturated paper, it is not necessary to condition the paper at 65% RH). 15 The samples are cut using a guillotine to 270 mm by 67 mm, and lines are drawn parallel to the smaller length 35 mm in to act as a guide when clamping the sample into the Testometric jaws. 20 The samples are then soaked in deionised water for 30 minutes. After this time, the majority of the water is drained away to leave the paper saturated while measurements are made. 25 Prior to the test being performed, the excess water is removed as before. Testometric set-up - 25 kgf load cell, 100 mm/min speed, pre-tension 0.1 kgf, sample length 200 mm, sample width 67 30 mm.

WO01/27232 PCT/GB00/03695 - 25 The results of the tests were as follows: Sample treatment Wet strength (kgf) Untreated paper 1.069 Polymer AM 4.920 Polymer MRSM 4.017 Example 1 5 Dye transfer inhibition Five applications of 0.2% Kenores 1440 (trade mark) polyamine-epichlorohydrin (PAE) resin (Akzo Nobel) as disclosed in WO 97/42287 (a polymer outside the scope of 10 this invention) were made via a domestic washing machine (Zanussi (trade mark) automatic washing machine, 40 0 C cotton wash cycle, Persil (trade mark) applied during the wash cycle) to white woven cotton sheeting, a theoretical maximum application of 1.0% by weight PAE on weight of fabric (owf). 15 A similar process was carried out using 0.2% Polymer AN (trade mark) and 0.2% Polymer MRSM (trade mark). The treated fabrics were then washed with Direct Red 80 dyed fabric which is known to lose dye. The resulting fabrics were then measured on a Spectroflash (trade mark) 20 spectrometer to determine the degree of dye transfer. A blank fabric sample was used as reference. 25 WO01/27232 PCT/GB00/03695 - 26 AL AE 0.2% Kenores 1440 -3.47 6.20 0.1% Kenores 1440 -1.05 2.32 Polymer AM 0.93 2.21 Polymer MRSM 0.28 1.47 AL = change in lightness AE = change in colour 5 Thus, there is less change in colour for the fabric treated with a polymer according to the invention and, therefore, less dye transfer. Example 2 10 Garment Care Properties Spectroflash (trade mark) measurements on a standard test fabric having black and red regions show that the fabrics treated with Polymer AM (trade mark) and Polymer MRSM (trade 15 mark) according to Example 1 display reduced damage. Black area: AL AE Untreated 9.94 10.07 Polymer AM 1.81 1.95 Polymer MRSM 3.00 3.09 WO01/27232 PCT/GB00/03695 - 27 Red area: AL AE Untreated 3.30 12.62 Polymer AM 1.20 5.39 Polymer MRSM 1.19 4.84 In both cases, the treated areas show less change in shade 5 than the untreated sample, indicated by the smaller AL and AE values. Example 3 Stain removal 10 1 ml of red wine was applied to treated cotton according to the procedure set out in Example 1 (5 rinse applications of 0.2% per wash). The stain was measured on a Spectroflash (trade mark) spectrophotometer prior to washing and after 15 washing at 40 0 C using Persil Performance Biological (trade mark) powder. The change in depth of colour on the stains relative to the sample before washing was: AL AE Untreated -17.93 22.10 Polymer AM -20.26 23.98 Polymer MRSM -23.36 26.37 Kenores 1440 -19.38 22.37 20 After washing, the colour measurements were: WO01/27232 PCT/GB00/03695 - 28 AL AE Untreated -3.97 5.94 Polymer AM -3.65 5.10 Polymer MRSM -5.70 7.98 Kenores 1440 -8.42 10.45 Polymer AM (trade mark) shows almost identical stain release properties to untreated fabric, whereas Polymer MRSM (trade mark) falls between Polymer Am (trade mark) and Kenores 1440 5 (trade mark). The background area of the fabric was also measured to provide an indication of any tendency of the treatments to cause soil redeposition. The smaller the spectrometer 10 reading, the less the change in colour and the less soil redeposition. AL Untreated -0.20 Polymer AM -0.02 Polymer MRSM -0.19 Kenores 1440 -0.27 Standard rinse conditioner* -0.05 *Comfort (trade mark) (Unilever plc, UK) 15 Although the differences are small, there are still indications that these polymers do not increase the soil redeposition properties of the fabric to the same extent that PAE-type polymers do. In the case of Polymer AM (trade WO01/27232 PCT/GB00/03695 - 29 mark), there is less redeposition than with the rinse conditioner. Example 4 5 Fabric Conditioner Formulation Fabric conditioner formulations were made by preparing a standard fabric conditioner composition containing components 2 to 8 below and adding component 1 to it, with 10 stirring. Compositions were prepared in both dilute and concentrated forms. The formulations were as follows: Dilute Concentrate 1. Polymer AM 15.1% 48.7% 2. Water 80.04% 35.86% 3. Antifoam 0.01% 0.03% 4. Genapol* 0.25% 0.75% 5. HEQ 4.20% 13.5% 6. Preservative 0.03% 0.06% 7. Dye 0.07% 0.15% 8. Perfume 0.30% 0.95% 15 *a C 12 primary alcohol ethoxylated with 20 moles of ethylene oxide Example 5 20 Polymer AM was pad applied to 2% resinated cotton poplin monitors (40x40cm) to give a pick-up lever of 0.5% owf on the fabric. The monitors were then tumble dried. This was WO01/27232 PCT/GB00/03695 - 30 carried our four times to give a total level of 2% owf. A similar procedure was carried out for Polymer MRSM and Kenores 1440. The monitors were wetted, scrunched (to simulate creasing in the wash process) then placed in a 5 domestic tumble drier (Miele) with wetted cotton sheeting ballast (1 Kg when dry). The load was then dried until the anti-crease setting on the drier was attained. The monitors were then panelled against AATCC smoothness standards to determine the level of creasing. The monitors were then 10 ironed and the crease process repeated Polymer 0.5% owf 0.5% owf 2% owf 2% owf (before (after (before (after ironing) ironing) ironing) ironing) Untreated control 1.4 1.38 1.64 1.54 PAE 1.3 1.44 2.26 1.94 Kenores 1440 2.28 2.06 2.3 2.52 Polymer MRSM 2.1 2.34 2.38 2.8 Polymer AM and Polymer MRSM are considerably less creased than the untreated control. Polymer MRSM treated monitors 15 become even less creased if an ironing step is included. Polymer AM and Polymer MRSM are considerably less creased than Kenores 1440 especially at the 0.5% owf level.

Claims (25)

1. Fabric care composition comprising a polymeric material which is capable of self cross-linking and/or of reacting 5 with cellulose together with one or more textile compatible carriers, wherein the polymeric material comprises one or more poly(oxyalkylene) groups having an end group which comprises one or more amino groups or derivatives of said amino groups, wherein when the textile compatible carrier is 10 water a further additive suitable for use in laundry compositions is present.

2. Composition as claimed in Claim 1, wherein the polymeric material is obtainable by the reaction of a 15 polymer of formula B(R)n, wherein n is from 1 to 20, B is a backbone group to which each R is covalently bonded and R is a group comprising a poly(oxyalkylene) chain, which chain comprises an amino end group, the polymer being optionally reacted with a bridging compound, with a cross-linking 20 agent.

3. Composition as claimed in Claim 2, wherein n is 2 or 3.

4. Composition as claimed in Claim 2 or Claim 3, wherein B 25 is -O-CH 2 (CH) m-CH 2 -O- and m is equal to n-2. I 0 30 5. Composition as claimed in any one of Claims 2 to 4, wherein at least one R group has the formula (CH 2 CH(R') (CH 2 )aO)p-A-NHR' ', wherein: R' is H or CH 3 ; a is 0, WO01/27232 PCT/GB00/03695 - 32 1 or 2; p is an integer from 5 to 30; A is an alkylene group; and R'' is H or alkyl.

5

6. Composition as claimed in any one of Claims 2 to 5, wherein p is from 10 to 25.

7. Composition as claimed in any one of Claims 2 to 6, wherein the polymer of formula B(R)n is 10 H 2 C-O (CH 2 CH(R') )p-A-NH 2 HC-O (CH 2 CH (R') 0) q-A-NH 2 I H 2 C-O (CH 2 CH (R') 0) r-A-NH 2 15 wherein p, q and r are integers which may be the same or different and may be from 5 to 30 and A is branched or unbranched lower alkylene. 20

8. Composition as claimed in any one of Claims 2 to 6, wherein the polymer of formula B(R)n is H 2 N- (CH 2 ) b- (0 (CH 2 ) 4) d-O (CH 2 ) CO- ((CH 2 ) 40) d2 (CH 2 ) b-NH 2 wherein: b is an integer from 1 to 6; c is an integer from 1 to 6; and d and d2 are the same or different and are 25 integers from 10 to 15.

9. Composition as claimed in Claim 8, wherein b is 3 and/or c is 4. 30

10. Composition as claimed in any one of Claims 2 to 9, wherein the cross-linking agent comprises an epihalohydrin. WO01/27232 PCT/GB00/03695 - 33

11. Composition as claimed in any one of Claims 2 to 10 wherein the molar ratio of cross-linking agent to polymer of formula B(R)n is from 0.5:1 to 4:1. 5

12. Composition as claimed in any one of Claims 2 to 11, wherein the bridging compound comprises two epoxide or carboxylic acid groups.

13. Composition as claimed in Claim 11, wherein the epoxide 10 or carboxylic acid groups are linked by a linker comprising alkylene, arylene, poly(oxyalkylene) or siloxane groups or combinations thereof.

14. Composition as claimed in any one of Claims 1 to 13 15 further comprising a silicone which is capable of reacting with the polymeric material.

15. Composition as claimed in any one of Claims 1 to 14, wherein the polymeric material is capable of increasing the 20 wet strength of paper by at least 200% compared to untreated paper when applied to paper having a weight of 80 g/m 2 at a level of 1% solids by weight based on weight of paper.

16. Composition as claimed in any one of Claims 1 to 15, 25 wherein the one or more textile compatible carriers comprise a detergent active compound.

17. Composition as claimed in any one of Claims 1 to 15, wherein the one or more textile compatible carriers comprise 30 a fabric softening and/or conditioning compound. WO01/27232 PCT/GBOO/03695 - 34

18. Composition as claimed in any one of Claims 1 to 17, further comprising a perfume.

19. A method of treating fabric, as part of a laundering 5 process, which comprises applying to the fabric a fabric care composition according to any one of Claims 1 to 18.

20. A method of treating fabric, as part of a laundering process, which comprises applying to the fabric a polymeric 10 material as defined in any one of Claims 1 to 18.

21. A method as claimed in Claim 19 or Claim 20 wherein the composition is applied to the fabric during a wash cycle. 15

22. A method as claimed in Claim 19, or Claim 20, wherein the composition is applied to the fabric during a rinse cycle.

23. Use of a fabric care composition according to any one 20 of Claims 1 to 18 or a polymeric material as defined in any one of Claims 1 to 18 to improve the surface colour definition of a fabric after multiple washings.

24. Use of a fabric care composition according to any one 25 of Claims 1 to 18 or a polymeric material as defined in any one of Claims 1 to 18 to impart pill and/or fuzz resistance to fabric during laundering.

25. Use as claimed in Claim 23 or Claim 24, wherein the 30 fabric comprises cellulosic fibres.