CN100451629C - Preparation of optical fiber humidity sensor sensing membrane - Google Patents
Preparation of optical fiber humidity sensor sensing membrane Download PDFInfo
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- CN100451629C CN100451629C CNB2006100685199A CN200610068519A CN100451629C CN 100451629 C CN100451629 C CN 100451629C CN B2006100685199 A CNB2006100685199 A CN B2006100685199A CN 200610068519 A CN200610068519 A CN 200610068519A CN 100451629 C CN100451629 C CN 100451629C
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Abstract
The related preparation method for sensitive film of an optical fiber moisture sensor comprises: selecting 30-50cm conventional fiber with inner and outer core diameter rate as 62.5/125mum, cutting 2-6cm segment on one end for sleeve and coating layer; corroding with HF to remove the package; activating the fiber core with 20-55% HNO3 for 10-60min to form active (OH)-; with PMMA as carrier, fixing the phenol red dyeing on fiber core. This invention is simple and reliable for remote detection.
Description
Technical field:
The invention belongs to the preparation method of preparation technology's method, particularly a kind of optical fiber humidity sensor sensing membrane of a kind of sensor humidity sensitive device in the Fibre Optical Sensor humidity detection technical field.
Background technology:
Optical fiber sensing technology is a new branch that forms along with the development of Fibre Optical Communication Technology.It has: volume is little, in light weight, shape is flexible, anti-electromagnetic interference (EMI), and is good to the adaptability of environment; Belong to noncontact, non-destroyed measurement.That optical fiber sensing technology can be applicable to is inflammable, explosive, the detection under narrow space and corrosive gas, liquid environment and the ray contamination environment, it be methods such as existing machinery, electromagnetism, electronics can't realize or incomparable detection technique.Traditional resistance-type and capacitance type humidity sensor are to be connected to collector by transmitter in the mode of voltage or electric current to detect humidity, so the response time is long, poor stability, and the matrix volume is big, be not suitable for microenvironment and remote online detection, the application of more difficult adaptation in rugged surroundings.The light fibre humidity sensing technology makes full use of the advantage of optical fiber sensing technology, and the fine variation of the relative humidity change by optical signalling is showed.At present, the key point of this technology is to modify humidity sensing film at optical fiber surface, and the method for modifying of sensitive membrane is general to adopt wet quick type macromolecular material to be fixed on the fiber core surface by the method for crosslinked film forming.
The key of light fibre humidity sensing technology is the preparation method of research fiber core surface moisture sensitive membrane, because selectable wet quick property macromolecular material kind is limited, sensing range is relevant with the characteristic of macromolecular material again, so choosing of humidity sensing film has certain degree of difficulty.
Summary of the invention:
The objective of the invention is to overcome the shortcoming that exists in the prior art, seek to design a kind of architectural feature of optic fibre carrier of utilizing of preparation and prepare optical fiber humidity sensor sensing membrane through chemistry and physical treatment method, this sensitive membrane can be used for remote detection humidity.The present invention is a carrier with common macromolecular material, adopts the method for physically trapping that the wet quick indicator of micromolecule is fixed on the fiber core surface, and prepared humidity sensing film has good response characteristic to the variation of relative humidity.
The preparation method of optical fiber humidity sensor sensing membrane, step is as follows:
1. get commercially available communication optical fiber 30-50cm, inside and outside core diameter is of a size of 62.5/125 μ m, and its inner structure is that fibre core is shaped on covering outward, and covering has overlay outward, and overlay is shaped on sheath outward.
2. cut optical fiber jacket and overlay respectively with blade, cutting length is 2-6cm.
3. exposed covering and core segment are corroded with 5%-40% hydrofluorite, to remove covering.Method is: corrode optical fiber in hydrofluoric acid solution, constantly monitor core diameter with spiral dial gauge (0-25mm range, resolution are 0.01mm), till reaching 50-60 μ m, etching time is 30 minutes to 330 minutes.
4. the fibre core of optical fiber is made by quartz material, and the fibre core after the corrosion activates 5 minutes with 5% nitric acid, makes the fibre core surface form the hydroxyl of activation.
5. adopting the method for physically trapping, is carrier with the polymethylmethacrylate, and humidity sensitive dyestuff phenol red is fixed on the fiber core surface.Method is: 5mg polymethylmethacrylate and 10mg phenol red are joined 1, in the 4-dioxane, place 20～80 ℃ stirred in water bath 60 minutes then, after treating to dissolve fully, be cooled to room temperature, will remove covering and activated optical fiber and impregnated in the solution 30 minutes, make it in the optical fiber surface film forming, in the dipping film forming procedure, drag optical fiber back and forth, guarantee the homogeneity of film.
The present invention compared with prior art, has many-sided technological merit, the optical fiber that at first will have humidity sensing film is placed in the closed container of adjustable humidity, the variation of optical output power in the record relative humidity variations process, optical output power increases gradually along with the increase of relative humidity, the process of relative humidity from 25% to 90%, optical output power becomes 7.19 μ W by 7.13 μ W, and the variation basic and relative humidity of its variation tendency is linear.The optical fiber that secondly will have humidity sensing film is placed in the closed container of adjustable humidity, record relative humidity is increased to 93% gradually from 43%, and then drop to gradually in 43% process, the situation of change of optical output power, when relative humidity is increased to 93% gradually from 43%, and then drop to gradually in 43% the process, the situation of change of positive and negative two curves overlaps substantially, and this light fibre humidity transducer that this method preparation is described has reversibility preferably.This method principle is reliable, and processing step is easy, and the operation preparation is easy, and product stability is good, long service life.
Embodiment:
Specific implementation process of the present invention and method can be further specified by the following example.
Embodiment:
1. get commercially available communication optical fiber 40cm, inside and outside core diameter is of a size of 62.5/125 μ m;
2. cut optical fiber jacket and overlay with blade, cutting length is 4cm;
3. exposed covering and core segment are corroded with 15% hydrofluorite, to remove covering.Method is: corrode optical fiber in hydrofluoric acid solution, constantly monitor core diameter with spiral dial gauge (0-25mm range, resolution are 0.01mm), till reaching 60 μ m, etching time is 4 hours.
4. the fibre core of optical fiber is made by quartz material, and the fibre core after the corrosion activates 5min with 5% nitric acid, makes the fibre core surface form the hydroxyl of activation.
5. 5mg polymethylmethacrylate and 10mg phenol red are joined 1, in the 4-dioxane, place 80 ℃ stirred in water bath 60 minutes then, after treating to dissolve fully, be cooled to room temperature, will remove covering and activated optical fiber and impregnated in the solution 30 minutes, make it in the optical fiber surface film forming, in the dipping film forming procedure, drag optical fiber back and forth, guarantee the homogeneity of film.
Prepared humidity sensor sensing membrane all adheres to specification through use and technical parameter test on the spot.
Claims (2)
1. the preparation method of an optical fiber humidity sensor sensing membrane, it is characterized in that choosing earlier inside and outside core diameter is the commercially available optical fiber 30-50cm of 62.5/125 μ m, going length in the one end-grain cutting is sheath and the overlay of 2-6cm; Use hydrofluorite erosion removal covering again; Fibre core after the corrosion activates 5 minutes with 5% nitric acid, makes the fibre core surface form the hydroxyl of activation; Then 5mg polymethylmethacrylate and 10mg phenol red are joined 1, in the 4-dioxane, place 20～80 ℃ stirred in water bath 60 minutes then, after treating to dissolve fully, be cooled to room temperature, will remove covering and activated optical fiber and impregnated in the solution 30 minutes, make it in the optical fiber surface film forming, in the dipping film forming procedure, drag optical fiber back and forth, guarantee the homogeneity of film.
2. the preparation method of optical fiber humidity sensor sensing membrane according to claim 1, it is characterized in that removing covering is to corrode optical fiber in the hydrofluoric acid solution, constantly monitor core diameter with the spiral dial gauge, till it reached 50-60 μ m, etching time was 30 minutes to 330 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100685199A CN100451629C (en) | 2006-08-17 | 2006-08-17 | Preparation of optical fiber humidity sensor sensing membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100685199A CN100451629C (en) | 2006-08-17 | 2006-08-17 | Preparation of optical fiber humidity sensor sensing membrane |
Publications (2)
| Publication Number | Publication Date |
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| CN1908634A CN1908634A (en) | 2007-02-07 |
| CN100451629C true CN100451629C (en) | 2009-01-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2006100685199A Expired - Fee Related CN100451629C (en) | 2006-08-17 | 2006-08-17 | Preparation of optical fiber humidity sensor sensing membrane |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101776493B (en) * | 2010-03-10 | 2011-09-07 | 华南理工大学 | Optical fiber temperature/humidity sensor inductive layer and preparation method and application thereof |
| CN103048269A (en) * | 2012-12-19 | 2013-04-17 | 南京师范大学 | Relative humidity sensor of optical fiber bundle modified by inverse opal film and preparation method thereof |
| CN103293137A (en) * | 2013-06-08 | 2013-09-11 | 中国船舶重工集团公司第七二五研究所 | Preparation method of optical fiber iron ion sensitive film |
| CN107389565A (en) * | 2017-08-11 | 2017-11-24 | 福建硅光通讯科技有限公司 | A kind of light fibre humidity transducer and preparation method thereof |
| CN110044823B (en) * | 2019-04-28 | 2022-06-03 | 北京航天控制仪器研究所 | Manufacturing method of fiber grating humidity sensor |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1018765B (en) * | 1988-03-28 | 1992-10-21 | 西屋电气公司 | Light fibre humidity transducer |
| CN1332371A (en) * | 2000-06-23 | 2002-01-23 | 梁传信 | Optical-fiber chemical sensor and its detection method and device |
| US20050105841A1 (en) * | 2002-10-04 | 2005-05-19 | Shufang Luo | Devices, systems, and methods for sensing moisture |
| WO2005090253A2 (en) * | 2004-03-17 | 2005-09-29 | Arcelik Anonim Sirketi | Coating material and a fiber optic sensor in which this coating material is used |
-
2006
- 2006-08-17 CN CNB2006100685199A patent/CN100451629C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1018765B (en) * | 1988-03-28 | 1992-10-21 | 西屋电气公司 | Light fibre humidity transducer |
| CN1332371A (en) * | 2000-06-23 | 2002-01-23 | 梁传信 | Optical-fiber chemical sensor and its detection method and device |
| US20050105841A1 (en) * | 2002-10-04 | 2005-05-19 | Shufang Luo | Devices, systems, and methods for sensing moisture |
| WO2005090253A2 (en) * | 2004-03-17 | 2005-09-29 | Arcelik Anonim Sirketi | Coating material and a fiber optic sensor in which this coating material is used |
Non-Patent Citations (8)
| Title |
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| 一种新型光纤湿度敏感元件. 姚岚等.传感器技术，第20卷第2期. 2001 |
| 一种新型光纤湿度敏感元件. 姚岚等.传感器技术，第20卷第2期. 2001 * |
| 光纤光栅型温湿度传感器的设计与实现. 张向东等.光子学报，第32卷第10期. 2003 |
| 光纤光栅型温湿度传感器的设计与实现. 张向东等.光子学报，第32卷第10期. 2003 * |
| 基于Nafion-结晶紫传感膜的光纤湿度传感器研究. 金兴良等.光谱学与光谱分析，第25卷第8期. 2005 |
| 基于Nafion-结晶紫传感膜的光纤湿度传感器研究. 金兴良等.光谱学与光谱分析，第25卷第8期. 2005 * |
| 布拉格光纤光栅测量湿蒸汽两相流温/湿度的理论数学模型. 黄雪峰等.中国电机工程学报，第26卷第7期. 2006 |
| 布拉格光纤光栅测量湿蒸汽两相流温/湿度的理论数学模型. 黄雪峰等.中国电机工程学报，第26卷第7期. 2006 * |
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| CN1908634A (en) | 2007-02-07 |
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