CN100427382C - Heating to conatant temperature type equipment for reloading methanol - Google Patents

Heating to conatant temperature type equipment for reloading methanol Download PDF

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Publication number
CN100427382C
CN100427382C CNB2006100482688A CN200610048268A CN100427382C CN 100427382 C CN100427382 C CN 100427382C CN B2006100482688 A CNB2006100482688 A CN B2006100482688A CN 200610048268 A CN200610048268 A CN 200610048268A CN 100427382 C CN100427382 C CN 100427382C
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China
Prior art keywords
methanol
reforming
chamber
reformation
heating
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Expired - Fee Related
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CNB2006100482688A
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Chinese (zh)
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CN1915799A (en
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郑国璋
朱建军
王淑平
郭建玲
靳红玲
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  • Output Control And Ontrol Of Special Type Engine (AREA)

Abstract

This invention relates to a fuel-supply device for methanol engines. The constant-temperature-heating methanol reforming system comprises an electrically controlled methanol nozzle, a reforming chamber, and multiple reforming columns in the reforming chamber. Catalyst layers are set on the surface of the reforming columns as well as the inner wall of the reforming chamber for promoting methanol reforming. A PTC constant-temperature-heating element is set out of the reforming chamber, and connected with one end of a spring leaf. The other end of the spring leaf is connected with an electrode, which is fixed on the reforming chamber by an insulating block. This invention solves the problems of the difficulty of methanol cold-start as well as the emission of harmful formaldehyde intermediate during methanol combustion. In this invention, methanol is firstly introduced into the constant-temperature-heating reforming system to generate H2 and CO, which are then supplied to the engines for combustion. This invention thus has such advantages as no formaldehyde emission, better cold-start performance and little exhause pollution.

Description

Constant temperature heating-type methanolysis reformer
Technical field
The present invention relates to a kind of methanol engine fuel supply system, specifically is that a kind of utilization plays the methanolysis reintegration by the catalyzer that the constant temperature heating unit heats, the liquid methanol (CH for engine 3OH) be restructured as hydrogen (H 2) with the constant temperature heating-type methanolysis reformer of carbon monoxide (CO) geseous fuel.
Background technology
The motor car engine of prior art is a fuel with gasoline or diesel oil mostly, the deficient day by day and more and more strictness of automobile emission regulation along with petroleum resources, and the various alternative fuel of gasoline and diesel oil are all sought in countries in the world, and wherein methyl alcohol is alternative fuel preferably.Methyl alcohol can be produced by coal, Sweet natural gas and timber, adopts methyl alcohol to do motor spirit and can guarantee the secular energy security of China.There is the problem that methyl alcohol incendiary intermediate product formaldehyde nuisance is arranged in cold starting difficulty, the discharging in engine for combusting methyl alcohol at present.
Summary of the invention
Purpose of the present invention is exactly to be to provide a kind of the liquid methanol (CH for engine 3OH) be restructured as hydrogen (H 2) and the constant temperature heating-type methanolysis reformer of carbon monoxide (CO) geseous fuel, this device can improve the engine of burning methanol cold-start performance, avoid the formaldehyde emission pollutent.
The technical solution adopted for the present invention to solve the technical problems is: constant temperature heating-type methanolysis reformer comprises automatically controlled methyl alcohol nozzle, reformer chamber, reformation post.Reformer chamber is provided with multilayer reformation post, reformation post surface and reformer chamber surface are provided with and promote methanol recapitalization catalyst for reaction layer, reformation outdoor mounted PTC constant temperature heating unit, PTC constant temperature heating unit is connected with an end of spring piece, the other end of spring piece is connected with electrode, electrode is fixed on the reformer chamber by collets.
Reformer chamber of the present invention and reformation post adopt aluminium alloy to make, and reformation post surface and reformer chamber surface are provided with catalyzer such as cupric oxide (CuO) that one deck promotes the methanol recapitalization reaction, zinc oxide (ZnO), nickel oxide.Reformer chamber is fixed on the engine air inlet tube, electrode is connected with engine positive source electric wire 13 by terminal stud, automatically controlled methyl alcohol nozzle is fixed in the nozzle bore on the nozzle holder, and nozzle holder is fixed on the reformer chamber, and automatically controlled methyl alcohol nozzle links to each other with engine electronic control unit ECU through signal wire; Hydrogen (the H that reformer chamber produces 2) be connected with engine intake manifold through outlet with carbon monoxide (CO); Connect positive electrical wire and engine power supply during engine start, electric current from the engine positive source through positive electrical wire, terminal stud, electrode, spring piece, PTC constant temperature heating unit, reformer chamber, engine air inlet tube flow direction engine power cathode, PTC constant temperature heating unit heated reformate chamber, the reformation post, automatically controlled methyl alcohol nozzle sprayed into spray chamber with the middle pressure methyl alcohol in the middle pressure oil feed pipe of engine when reformer chamber and reformation column temperature reached 200 ℃-300 ℃, and the methyl alcohol of atomizing and the temperature on reformation post surface remain on 200 ℃-300 ℃ catalyzer and contact and reforming reaction takes place produce by hydrogen (H 2) with the reformed gas that carbon monoxide (CO) is formed, reformed gas enters engine intake manifold through the air outlet.
Beneficial effect of the present invention: the methyl alcohol (CH of supply engine 3OH) decompose reforming reaction and generate through the heating of Ben Dingwen electrothermic type methanolysis reformer, catalysis, generation by hydrogen (H 2) reformed gas formed with carbon monoxide (CO) supplies engine for combusting again; Hydrogen (H 2) flammability limit, ignition energy wideer than gasoline have only 1/10 of gasoline, easily light, flame propagation speed hydrogen (H 2) with carbon monoxide (CO) at engine chamber and oxygen (O 2) reactive combustion generation water (H 2O) with carbonic acid gas (CO 2) gas, do not produce in the combustion processes formaldehydeless in combustion intermediate product formaldehyde (HCHO), the discharging, do not have a unburned hydrocarbon polymer (HC); This constant temperature electrothermic type methanol recapitalization device can improve cold-start performance, the reduction exhaust pollution of methanol-fueled engine.
Description of drawings
Accompanying drawing 1 is the outside view of a kind of heating-type methanolysis reformer of the present invention
Accompanying drawing 2 be in the accompanying drawing 1 along D to view
Accompanying drawing 3 is the sectional view along the A-A line in the accompanying drawing 2
Accompanying drawing 4 is the sectional view along the C-C line in the accompanying drawing 3
Accompanying drawing 5 is the sectional view along the B-B line in the accompanying drawing 1
Among the figure: the automatically controlled methyl alcohol nozzle of 1-, 2-nozzle holder, 3-reformer chamber, 4-reformation post, 5-PTC constant temperature heating unit, 6-spring piece, the 7-bolt, 8-collets, 9-heat insulating mattress, the 10-bolt, 11-electrode, 12-terminal stud, the 13-positive electrical wire, 14-nozzle bore, 15-signal wire, press oil feed pipe among the 16-, 17-air outlet, 18-spray chamber.
Specific embodiments
In conjunction with the accompanying drawings the specific embodiment of the present invention is described further, embodiment is used for illustrating of the present invention, rather than it is imposed any restrictions.
As accompanying drawing 1, accompanying drawing 2, accompanying drawing 3, accompanying drawing 4, shown in, constant temperature electrothermic type methanolysis reformer comprises automatically controlled methyl alcohol nozzle 1, nozzle holder 2, reformer chamber 3, reformation post 4, PTC constant temperature heating unit 5, spring piece 6, bolt 7, collets 8, heat insulating mattress 9, electrode 11.Shown in accompanying drawing 2,3,4,5, be provided with a plurality of reformation posts 4 in the reformer chamber 3, reformer chamber 3 adopts aluminium alloys to make with reformation post 4, and reformation post 4 surfaces and reformer chamber 3 internal surfaces are provided with catalyzer such as cupric oxide (CuO) that one deck promotes the methanolysis reforming reaction, zinc oxide (ZnO), nickel oxide; As shown in Figure 2, reformer chamber 3 is connected with PTC constant temperature heating unit 5, and PTC constant temperature heating unit 5 is connected with an end of spring piece 6, the other end of spring piece 6 is connected with electrode 11, electrode 11 is fixed on the reformer chamber 3 by collets 8 shown in accompanying drawing 2, accompanying drawing 3; Electrode 11 is connected with engine positive source electric wire 13 by terminal stud 12, and automatically controlled methyl alcohol nozzle 1 is fixed in the nozzle bore 14 on the nozzle holder 2, and automatically controlled methyl alcohol nozzle links to each other with engine electronic control unit ECU through signal wire 15; Connect positive electrical wire 13 and engine power supply during engine start, electric current from the engine positive source through positive electrical wire 13, terminal stud 12, electrode 11, spring piece 6, bolt 7, PTC constant temperature heating unit 5, reformer chamber 3, engine air inlet tube flow direction engine power cathode, PTC constant temperature heating unit heated reformate chambers 35, reformation post 4, automatically controlled methyl alcohol nozzle sprayed into spray chamber 18 with the middle pressure methyl alcohol in the middle pressure oil feed pipe 16 of engine when reformer chamber 3 reached 200 ℃-300 ℃ with reformation post 4 temperature, the methyl alcohol of atomizing is through reformation post 4, and remains on 200 ℃-300 ℃ catalyzer with its surperficial temperature and contact and the reforming reaction generation takes place by hydrogen (H 2) with the reformed gas that carbon monoxide (CO) is formed, reformed gas enters engine intake manifold through air outlet 17.

Claims (1)

1, a kind of constant temperature heating-type methanolysis reformer, comprise automatically controlled methyl alcohol nozzle (1), reformer chamber (3), reformation post (4), it is characterized in that reformer chamber is provided with multilayer reformation post (4), reformation post (4) surface and reformer chamber (3) internal surface are provided with and promote methanol recapitalization catalyst for reaction layer, the outer PTC constant temperature heating unit (5) of installing of reformer chamber (3), PTC constant temperature heating unit (5) is connected with an end of spring piece (6), the other end of spring piece (6) is connected with electrode (11), electrode (11) is fixed on the reformer chamber (3) by collets (8).
CNB2006100482688A 2006-09-10 2006-09-10 Heating to conatant temperature type equipment for reloading methanol Expired - Fee Related CN100427382C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006100482688A CN100427382C (en) 2006-09-10 2006-09-10 Heating to conatant temperature type equipment for reloading methanol

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Application Number Priority Date Filing Date Title
CNB2006100482688A CN100427382C (en) 2006-09-10 2006-09-10 Heating to conatant temperature type equipment for reloading methanol

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CN1915799A CN1915799A (en) 2007-02-21
CN100427382C true CN100427382C (en) 2008-10-22

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101949347B (en) * 2010-09-14 2012-12-26 太原理工大学 Cold start device and cold start method of M100 methanol engine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1233584A (en) * 1998-04-27 1999-11-03 中国科学院山西煤炭化学研究所 Method for prodn. of hydrogen from methyl alcohol
EP1135326A1 (en) * 1998-10-30 2001-09-26 Siemens Aktiengesellschaft Reformer with dynamically adjustable reaction surface
CN1346786A (en) * 2001-11-27 2002-05-01 四川亚联高科技有限责任公司 Process and apparatus for preparing hihg-purity CO, hydrogen and their mixture by cracking methanol

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1233584A (en) * 1998-04-27 1999-11-03 中国科学院山西煤炭化学研究所 Method for prodn. of hydrogen from methyl alcohol
EP1135326A1 (en) * 1998-10-30 2001-09-26 Siemens Aktiengesellschaft Reformer with dynamically adjustable reaction surface
CN1346786A (en) * 2001-11-27 2002-05-01 四川亚联高科技有限责任公司 Process and apparatus for preparing hihg-purity CO, hydrogen and their mixture by cracking methanol

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Granted publication date: 20081022

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