A kind of explosion protection for batteries
Technical field
The present invention relates to a kind of battery anti-explosion technology, particularly a kind of at the explosion-protection equipment that is provided with on the battery metal box hat that contains the electrolyte that flows.
Background technology
At the lithium battery that contains the electrolyte that flows, its electrolyte has severe corrosive, dissolves swellability by force, very responsive to airborne moisture, oxygen etc., need tight internal and external environment of isolating battery, particularly Nei Bu chemical substance is not good at because of manufacture process control or improper high temperature and a large amount of gas of producing of use, cause inside battery moment generation high pressure, break through metallic steel body (the metallic steel body is meant the metal box hat of steel, aluminium and alloy thereof) and produce blast, have very big danger.So this class battery all must have explosion precaution.Explosion-proof technology of the prior art has following several: 1, be a certain position mechanical score or line or the circle impression at the metallic steel body, accurate technical methods such as employing laser engraving, when in the steel body, producing certain pressure, there is the place of indentation or line or circle impression at first to break, thereby avoids the steel body under high pressure to explode.The disadvantage of this technology is that explosion-proof pressure is big, the explosion-proof pressure shakiness, and fluctuation range is bigger.The 2nd, adopt valve seal explosion-proof, such designs complicated, and it is big to take up room, the cost height, commercialization is worth very little.The 3rd, on battery cover board, have explosionproof hole, be stamped rupture pressure disc on the explosionproof hole, Chinese patent as CN200420094093.0, it is to utilize aluminum plastic film to be pasted on the explosionproof hole, its weak point is that electrolyte destroys the bonding plane on bonding plane and the middle aluminium foil of rupture pressure disc both sides easily, interlayer is separated, thereby do not have the function of tight seal, influence battery life, particularly the plastics on aluminium foil both sides have very big retractility, can cause explosion-proof pressure to strengthen, and unstable, reduce the reliability of its use greatly.Be direct or indirect weld metal paper tinsel on explosionproof hole in addition, in the patent as CN01109136.3, be to adopt soldering tech, adopt welding methods such as Laser Welding, supersonic welding in addition, its weak point is to be difficult to guarantee the consistency of the quality of welding, in welding process, can cause major injury to explosion-proof metal forming, thereby can't guarantee the stability of explosion-proof pressure.
Summary of the invention
The technical problem to be solved in the present invention is at the deficiencies in the prior art, and it is stable to have proposed a kind of explosion-proof pressure, safe and reliable explosion protection for batteries.
The technical problem to be solved in the present invention is achieved through the following technical solutions, a kind of explosion protection for batteries, it has explosionproof hole on the battery cover board matrix, be stamped explosion-proof aluminum-foil on the explosionproof hole, be characterized in: around the medial surface explosionproof hole of battery cover board matrix, handle the formation chromizing film layer through chromaking, between explosion-proof aluminum-foil and chromizing film layer, be provided with the hotmelt rete, explosion-proof aluminum-foil, hotmelt rete and battery cover board three are one by hot-press solidifying, and the hotmelt rete that is positioned at the explosionproof hole place is provided with the hole.
The technical problem to be solved in the present invention can also come by the following technical programs to realize that further described hotmelt rete is maleic anhydride modified polyhexene layer or maleic anhydride modified polypropylene layer that its thickness is 20~100 μ m.
The technical problem to be solved in the present invention can also come by the following technical programs further to realize that the chromizing film layer of handling formation through chromaking around the explosionproof hole is than the big at least 0.5mm of explosionproof hole periphery, and chromizing film layer thickness is 0.2~2 μ m.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, explosion-proof aluminum-foil, hotmelt rete and battery cover board three hot-press solidifying process: earlier the hotmelt rete is punched, the hole of hotmelt rete and the explosionproof hole of battery cover board are aligned, repave aluminium foil and carry out hot-forming.
The technical problem to be solved in the present invention can also come further to realize by the following technical programs, explosion-proof aluminum-foil, hotmelt rete and battery cover board three hot-press solidifying process: earlier with hotmelt rete and the pre-hot pressing of battery cover board, to cover again at the hotmelt film at battery cover board explosionproof hole place and go out the hole, and then hot-forming with aluminium foil.
The present invention compared with prior art, battery cover board is hot-forming by the hotmelt rete with aluminium foil again after chromaking is handled, it is bonding firmly, can guarantee the consistency of its quality in high volume production process.The hotmelt rete that is positioned at the explosionproof hole place in addition is provided with the hole, and its explosion-proof pressure is just decided by the material of employing aluminium foil and the thickness of aluminium foil like this, thereby realizes the stable of explosion-proof pressure, can control its explosion-proof pressure within ± 1kg scope.The present invention can significantly reduce the production cost of battery industry, guarantees safe and reliable in the use to promote the competitiveness of domestic battery industry in the international market.
Embodiment
A kind of explosion protection for batteries, it has explosionproof hole on the battery cover board matrix, be stamped explosion-proof aluminum-foil on the explosionproof hole, around the medial surface explosionproof hole of battery cover board matrix, handle the formation chromizing film layer through chromaking, the chromizing film layer of handling formation through chromaking around the explosionproof hole is than the big at least 0.5mm of explosionproof hole periphery, and chromizing film layer thickness is 0.2~2 μ m.Be provided with the hotmelt rete between explosion-proof aluminum-foil and chromizing film layer, explosion-proof aluminum-foil, hotmelt rete and battery cover board three are one by hot-press solidifying, and the hotmelt rete that is positioned at the explosionproof hole place is provided with the hole.Described hotmelt rete is maleic anhydride modified polyhexene layer or maleic anhydride modified polypropylene layer, and its thickness is 20~100 μ m.
Explosion-proof aluminum-foil, hotmelt rete and battery cover board three hot-press solidifying process: with the punching of hotmelt rete, the hole of hotmelt rete and the explosionproof hole of battery cover board are aligned earlier, repave aluminium foil and carry out hot-forming.
Explosion-proof aluminum-foil, hotmelt rete and battery cover board three hot-press solidifying process: first hotmelt rete and the pre-hot pressing of battery cover board, will cover again at the hotmelt film at battery cover board explosionproof hole place and go out the hole, and then hot-forming with aluminium foil.
The invention discloses two kinds of hot-press solidifying processes, also can adopt other method, but will guarantee that the explosion-proof aluminum-foil that is positioned at the explosionproof hole place is not covered by the hotmelt rete, leave the hole, its hole can be littler than explosionproof hole, also can be the same with explosionproof hole big.