[background technology]
Along with the quick growth of China's iron and steel output, the focus that the raising of the various quality of materials in stokehold has become refractories industry to pay close attention to.Skimmer is the main device of blast furnace steel-making stokehold slag iron treatment system, and skimmer is changed the length of time, directly has influence on the ordinary production order of blast furnace, has influence on the economic benefit of steel mill then.Existing skimmer all is to adopt the on-the-spot bulk cargo ramming of punching block to form, how much weight different steel mills account for and recently make skimmer and all have bigger randomness which uses plant bulk cargo and various bulk cargo, the antiscour of the skimmer of producing, anti-oxidant and anti-scour property is poor, just needed feed supplement once in every 10-15 days, have only 1-2 month general work-ing life, thereby influence is tapped a blast furnace on schedule, has prolonged molten iron and has deposited the stove time, brings potential safety hazard and has increased ton iron cost.The damage of skimmer material mainly is because the periodically chemical erosion of slag, molten iron, and the be full of cracks that thermal shocking causes is peeled off and washing away of slag iron reason such as deteriorate.With elder brother's steel iron work small furnace skimmer is example, uses traditional ramming mass, needs per week newly to make skimmer once.Life-span is shorter, repairs frequently, and labour intensity is big, severe operational environment; Because furrow bank dry slag iron phenomenon is serious etc., cause and make difficulty, it is consuming time that too much usually influence is tapped a blast furnace on schedule, causes the checking underproduction, and coke ratio raises, and has reduced labour productivity.
So, how to develop a kind of have good antiscour, anti-oxidant and anti-scour property, the high-performance skimmer of long service life has become the task of top priority.
[summary of the invention]
Purpose of the present invention solves the problems of the prior art exactly, proposes a kind of skimmer, has good antiscour, anti-oxidant and anti-scour property, long service life.
For achieving the above object, the present invention proposes a kind of skimmer, by compact alumina or brown corundum, silicon carbide, pelletted pitch, pure calcium aluminate cement, α-Al
2O
3Micro mist, uf-SiO
2Micro mist, metallic aluminium powder, metallic silicon power, composite additive and water cast form, the weight percent of said components is respectively: compact alumina or brown corundum: 43%-48%, silicon carbide: 29%-33%, pelletted pitch: 2%-3%, pure calcium aluminate cement: 2.5%-3%, α-Al
2O
3Micro mist: 8%-10%, uf-SiO
2Micro mist: 2%-2.5%, metallic aluminium powder: 0.5%-1.5%, metallic silicon power: 1%-3%, composite additive: 0.3%-0.5%, water: 3.5%-5.5%; Described composite additive is made up of water reducer, retardant, dispersant with high efficiency, antioxidant and anti-explosion agent, the weight percent of said components is respectively: water reducer: 18%-22%, retardant: 18%-22%, dispersant with high efficiency: 18%-22%, antioxidant: 18%-22%, anti-explosion agent: 18%-22%.
As preferably, the weight percent of each component is respectively: compact alumina or brown corundum: 45%, and silicon carbide: 31%, pelletted pitch: 2.5%, pure calcium aluminate cement: 3%, α-Al
2O
3Micro mist: 9%, uf-SiO
2Micro mist: 2%, metallic aluminium powder: 1%, metallic silicon power: 2%, composite additive: 0.5%, water: 4%.
Beneficial effect of the present invention: the present invention has added compound super-fine powder on the basis of compact alumina or brown corundum and two kinds of major ingredients of silicon carbide, wedding agent and composite additive, and to compound super-fine powder, the adding mechanism of wedding agent and composite additive and add-on have been carried out big quantity research and repeatedly experiment repeatedly, explored the zone of reasonableness of various component add-ons, the skimmer that adopts this prescription to produce has good antiscour, anti-oxidant and anti-scour property, prolonged the work-ing life of skimmer greatly, can reach 4-6 month the work-ing life of a skimmer, and do not need feed supplement in the use, greatly reduce stokehold labour intensity.Said components adopts cast to form the prefabricated skimmer, and under situation about reaching than original more excellent effect, its thickness is more a lot of than original little, has saved raw material resources.This skimmer cost is low, and long service life is easy for installation, greatly reduces stokehold hand labor intensity, has improved the stokehold Working environment, has improved labour productivity, has reduced ton iron cost.
[embodiment]
Embodiment one:
Compact alumina or brown corundum: 45%, silicon carbide: 31%, pelletted pitch: 2.5%, pure calcium aluminate cement: 3%, α-Al
2O
3Micro mist: 9%, uf-SiO
2Micro mist: 2%, metallic aluminium powder: 1%, metallic silicon power: 2%, composite additive: 0.5%, water: 4%.Directly be poured in the mould after preparing material according to the above ratio, fire, the prefabricated skimmer that formation can directly be used does not need to carry out the stokehold ramming again when the user uses.And under situation about reaching than original more excellent effect, its thickness is more a lot of than original little, has saved raw material resources.
The volume of blast furnace generally has 150m3,300m3,450m3, plurality of specifications such as 700m3, the volume of skimmer is mutually corresponding with the volume of blast furnace, and big volumetrical blast furnace will adopt big volumetrical skimmer, corresponding raw-material amount also will increase, but the weight percent of various components remains unchanged.
Wherein, compact alumina or brown corundum, silicon carbide are as bulk goods (aggregate) and powder-material.Allocate corundum material into to satisfy the use temperature of about 1500 ℃ of skimmers; The premium properties that utilizes carbofrax material is to satisfy the requirement of skimmer slag resistance, wear resistance, antiscour heat-shock resistance etc.; Utilize carbide fine powder can also play the effect that prevents oxidation of coal.Difference according to the skimmer size specification is controlled at 10-15mm with limit particle, and grain composition is the 3-4 level.Powder-material accounts for about 60% in compact alumina or the brown corundum, and powder-material accounts for about 60% in the silicon carbide.
Select α-Al
2O
3And uf-SiO
2Make compound super-fine powder.Purpose is to improve the slag corrosion resistance and the thermal shock resistance of skimmer; Improve the flowability of mould material, reduce water consumption; When temperature>800 ℃, can in matrix, form the mullite reticulated structure, the strength of materials is improved.But uf-SiO
2Adding surpass certain amount, will have influence on other performance of material, so with uf-SiO
2The amount of micro mist is about 2%.
Select pure calcium aluminate cement, pelletted pitch, Pure Silicon Metal and metallic aluminium powder to make wedding agent.Select for use the low calcium pure calcium aluminate cement of aquation wedding agent to guarantee the use temperature of about 1500 ℃ of skimmers; Select the organic bond pelletted pitch for use, utilize its higher carbon content to bring into play its good anti-scour property effect.Simultaneously, carbon content is high more in the wedding agent, and residual carbon element is also many more in bonded carbon element concentration and the hole on granular and powder-material surface, thereby makes the skimmer compact structure, and intensity increases; Select ceramic bond Pure Silicon Metal and metallic aluminium powder for use, be intended to interior in a big way hot strength (Si and C reaction generation β-SiC, Al and the C reaction generation Al at a certain temperature, that improves skimmer
4C
3).In addition, Al and Si can also play the effect that prevents that C is oxidized, also have the effect of doing anti-explosion agent.But because the response capacity of Al and Si is stronger, so the amount of metallic aluminium powder is controlled at about 1%, the amount of metallic silicon power is controlled at about 2%.
Select water reducer, retardant, dispersant with high efficiency, antioxidant, anti-explosion agent to form composite additive.The weight percent of said components is a water reducer in the composite additive: 20%, and retardant: 20%, dispersant with high efficiency: 20%, antioxidant: 20%, anti-explosion agent: 20%.Select for use tripoly phosphate sodium STPP to make water reducer, citric acid is made retardant, organic fibre is done anti-explosion agent, boron-containing compound is made antioxidant.
The prefabricated skimmer that adopts this prescription to make is whole for alkaline, environmentally safe.
The prefabricated skimmer that adopts this prescription to make, detecting station, Yixing through national light industry ceramic refractory quality surveillance detects, it reaches more than the 3.01g/cm3 in the volume density of baking after 24 hours under 110 ℃, strength at normal temperature reaches more than the 8.5MPa, and cold crushing strength reaches more than the 60.8MPa; Reach more than the 2.88g/cm3 in the volume density of baking after 3 hours under 1450 ℃, strength at normal temperature reaches more than the 11.6MPa, and cold crushing strength reaches more than the 60.6MPa.
Embodiment two:
Compact alumina or brown corundum: 43%, silicon carbide: 33%, pelletted pitch: 3%, pure calcium aluminate cement: 2.7%, α-Al
2O
3Micro mist: 9.8%, uf-SiO
2Micro mist: 2%, metallic aluminium powder: 0.5%, metallic silicon power: 1%, composite additive: 0.3%, water: 4.7%.Directly be poured in the mould after preparing material according to the above ratio, fire, the prefabricated skimmer that formation can directly be used does not need to carry out the stokehold ramming again when the user uses.And under situation about reaching than original more excellent effect, its thickness is more a lot of than original little, has saved raw material resources.
Embodiment three:
Compact alumina or brown corundum: 48%, silicon carbide: 29%, pelletted pitch: 2%, pure calcium aluminate cement: 2.5%, α-Al
2O
3Micro mist: 8%, uf-SiO
2Micro mist: 2.5%, metallic aluminium powder: 1.5%, metallic silicon power: 2.6%, composite additive: 0.4%, water: 3.5%.Directly be poured in the mould after preparing material according to the above ratio, fire, the prefabricated skimmer that formation can directly be used does not need to carry out the stokehold ramming again when the user uses.And under situation about reaching than original more excellent effect, its thickness is more a lot of than original little, has saved raw material resources.
Embodiment four:
Compact alumina or brown corundum: 46%, silicon carbide: 29%, pelletted pitch: 3%, pure calcium aluminate cement: 3%, α-Al
2O
3Micro mist: 8%, uf-SiO
2Micro mist: 2%, metallic aluminium powder: 1.5%, metallic silicon power: 1.5%, composite additive: 0.5%, water: 5.5%.Directly be poured in the mould after preparing material according to the above ratio, fire, the prefabricated skimmer that formation can directly be used does not need to carry out the stokehold ramming again when the user uses.And under situation about reaching than original more excellent effect, its thickness is more a lot of than original little, has saved raw material resources.
The foregoing description is to explanation of the present invention, is not limitation of the invention, any prescription after the simple transformation of the present invention is all belonged to protection scope of the present invention.