CN100403908C - Pollution-free tobacco mellowing and mildew-proof pesticide - Google Patents

Pollution-free tobacco mellowing and mildew-proof pesticide Download PDF

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CN100403908C
CN100403908C CNB200610041597XA CN200610041597A CN100403908C CN 100403908 C CN100403908 C CN 100403908C CN B200610041597X A CNB200610041597X A CN B200610041597XA CN 200610041597 A CN200610041597 A CN 200610041597A CN 100403908 C CN100403908 C CN 100403908C
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tobacco
water
iron powder
tobacco leaf
alcoholization
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CN1923005A (en
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王泽华
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Cca Changzhou Biochemical Co L
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Abstract

The invention discloses a pollution-free tobacco mellowing and mildew-proof insecticide, which comprises the following components in percentage by weight: 30 to 80 percent of reduced iron powder; 2 to 15 percent of active carbon; 3 to 30 percent of carbonized rice hulls; 1-15% of water-absorbent resin; 1.5 to 15 percent of chloride; 2.5 to 20 percent of calcium oxide; 1 to 5 percent of water. The reduced iron powder can thoroughly absorb oxygen, the calcium oxide can prevent the increase of the concentration of carbon dioxide in the alcoholization process, the water-absorbing resin can effectively control the humidity and the temperature in the sealed tobacco stack, the activated carbon can more thoroughly absorb the green and miscellaneous gases and the pungent smell in the tobacco leaves, the chloride and the water can control the oxygen absorption speed of the reduced iron powder, the tobacco insects can be effectively killed, the mildew can be prevented, the tobacco leaves are thoroughly alcoholized, the tobacco leaf alcoholization and mildew-proof pesticide is an ideal tobacco leaf alcoholization and mildew-proof pesticide, and the reduced iron powder is harmless to the tobacco leaves, the environment and operators and is a nuisanceless chemical composition.

Description

Nuisanceless tobacco leaf alcoholization, fungus-proof pesticide
Technical field:
The present invention relates to a kind of tobacco mellowing and handle the Chemical composition that of usefulness.
Background technology:
No matter the tobacco leaf that cigarette is used is flue-cured tobacco, air-curing of tobacco leaves, suncured tabacco, all must handle through alcoholization.But tobacco leaf is easy to produce in storage process and damages by worms, goes mouldy, charing, go rancid, defective such as color and luster is degenerated, alcoholization is not thorough, can cause a kind of peppery, excitant is strong sensation soon of choking when hearing and sucking smelling, and having to a certain degree living blue foreign smell, sucking quality is inferior.And become good through the tobacco leaf color and luster after fully alcoholization or the fermentation, the blue foreign smell flavor disappears, excitant reduces, it is pure and mild to inhale flavor, fragrance is better, quality be improved significantly.The quality of alcoholization quality directly has influence on the quality of cigarette.Improve the tobacco mellowing completeness, mildew-resistant, desinsection are the most key technical problems during tobacco leaf stores.
Desinsection in the tobacco leaf storage process, mildew-resistant, method for alcoholizing have controlled atmosphere method, chemical agent fumigating system, constant temperature and humidity+chemical method, present common use be qi-regulating technique.It is according to the gas content of ecological characteristic of storehouse worm, mould and the required environment of tobacco mellowing (oxygen, carbonic acid gas), temperature, damp condition, in airtight cigarette buttress, create one artificially and be unfavorable for cigarette worm, mould existence, and help the oxygen-free environment of tobacco mellowing, for guaranteeing that tobacco leaf does not have insect pest, do not go rancid in the alcoholization time limit, not charing, not having and go mouldy, guarantee that bad change does not take place the tobacco leaf interior quality, reach best alcoholization effect, to reach safe and effective, economic simple and direct integrated control purpose, this is that the requirement that must reach is handled in tobacco mellowing.The modern study achievement shows that the alcoholization process of tobacco leaf is a very complicated biochemistry change procedure.The course of reaction that the alcoholization of tobacco leaf (fermentation) is a tobacco leaf under self enzyme participates in, be the result of the organized enzyme effect that after ovennodulation processing, remains by tobacco leaf, the principal element that influences the tobacco leaf enzymic activity is temperature and moisture, irrelevant with oxygen, the tobacco enzyme all refines under the condition of aerobic and anaerobic, the intermediate product difference after just glucose is decomposed.The best alcoholization condition of tobacco leaf is: temperature is 20 ℃~29 ℃, and moisture value is 11%~13%, under suitable temperature and moisture condition, and tobacco enzyme active more intense, the alcoholization velocity ratio is balanced, and it is more abundant to refine time ratio.The mechanism of tobacco mellowing is:
Tobacco leaf aerobic alcoholization mechanism:
Figure C20061004159700041
Joule;
Tobacco leaf anaerobic alcoholization mechanism:
Figure C20061004159700042
Joule;
This shows that the tobacco mellowing process is an exothermic process, the anaerobic alcoholization is better than the aerobic alcoholization, and the too high alcoholization to tobacco leaf of temperature is disadvantageous.
Carry out in the process of tobacco leaf storage at the utilization qi-regulating technique, people have worked out many chemical fungus-proof pesticides that tobacco leaf stores that are used for, are purpose with the worm that kills generation all.Wang Meng is 02128083.5 openly to know clearly " nanometer double-suction deoxidation antistaling agent " homogeneous mixture that it is made up of nanometer iron powder, high-purity activity charcoal, chaff shell, basic anhydride, sodium chloride and water at application number; Wang Chunlu, Zou Xing are to have introduced " a kind of green multifunctional pesticidan anti-mildew agent for tobacco leaves " in 200510114810.0 at number of patent application, it is by oxygen absorbent (pyrite dust or reduced iron powder), humectant (crushed crude pearlite or bentonite), cathode material (powdered carbon, copper powder, mantoquita or lead salt), delayer (sulphite, ascorbic acid or hydroxylamine hydrochloride), salt (chloride or sulphate), the composition of water.They all claim they invention can both " effectively desinsection, mildew-resistant reach tobacco leaf and refine effect preferably, improve quality of tobacco, and nontoxic." but use checking through reality, they all have the oxygen uptake insecticidal effect, but tobacco mellowing, anti-mold effect are unsatisfactory, mainly are due to the content of humidity, carbonic acid gas in the sealing cigarette buttress can not effectively be controlled.
Summary of the invention:
Technical problem to be solved by this invention is to overcome existing tobacco mellowing to handle the deficiency that exists with Chemical composition that, a kind of Nuisanceless tobacco leaf alcoholization, fungus-proof pesticide are provided, it had both contained oxygen uptake function efficiently, have humidity and temperature in the control sealing tobacco bale storehouse again, thereby created the alcoholization environment of a relative ideal for tobacco mellowing, it can improve the alcoholization penetrability of tobacco leaf, has desirable mildew-resistant insecticidal effect again.
The component of Nuisanceless tobacco leaf alcoholization of the present invention, fungus-proof pesticide and percentage by weight are:
Reduced iron powder 30%~80%; Active carbon 2%~15%; Charring rice husk 3%~30%; Water-absorbing resin 1%~15%; Chlorate 1.5%~15%; Calcium oxide 2.5%~20%; Water 1%~5%.
Optimization proportioning of the present invention is: reduced iron powder 50%~60%; Active carbon 5%~15%; Charring rice husk 15%~30%; Water-absorbing resin 5%~10%; Chlorate 2%~5%; Calcium oxide 5%~10%, water 1%~5%.
Best proportioning of the present invention is: reduced iron powder 55%; Active carbon 8%; Charring rice husk 23%; Water-absorbing resin 5%; Chlorate 2%; Calcium oxide 5%, water 2%.
In the present invention, preferred sodium chloride of chlorate or potassium chloride.
In above-mentioned each component, reduced iron powder, active carbon, water-absorbing resin, chlorate, calcium oxide are routine and easily purchase chemicals; Charring rice husk is the product of rice husk after coking is handled; Preferred 50~100 orders of the particle diameter of described water-absorbing resin, water content is 3%~5%, it can regulate the humidity value of predetermined space, when humidity increases, it can suck the moisture content in the seal cavity, and when the humidity in the seal cavity was on the low side, water-absorbing resin can discharge moisture content wherein, the humidity in the seal cavity can be regulated, the temperature in the seal cavity can be regulated again.
In above-mentioned each component, reduced iron powder is the oxygen uptake component, and charring rice husk is the carrier of oxygen uptake component, and chlorate and water are that the oxygen uptake component is uniformly distributed in bonding agent on the charring rice husk, purpose is infected with on charring rice husk reduced iron powder equably, improves its oxygen uptake efficient; Wherein chlorate also is a reduced iron powder oxygen absorption rate adjusting control agent, and chlorate increases, and the oxygen absorption rate of reduced iron powder just slows down, otherwise then accelerates, and its effect is to reduce oxygen content in the sealing cigarette buttress, thereby reaches the purpose of harmful bacterial classifications such as killing cigarette worm, mould.The effect of active carbon is to absorb blue foreign smell in the tobacco leaf, excitant peculiar smell etc.Water-absorbing resin is a moisture regulator, and its effect is the humidity of regulating in the sealing cigarette buttress, for best damp condition is created in tobacco mellowing.Calcium oxide is the component that absorbs carbonic acid gas in the cigarette buttress, because tobacco leaf can produce carbonic acid gas in the oxygen free condition alcoholization, gas concentration lwevel increases can suppress tobacco mellowing, can generate slaked lime after the calcium oxide suction, slaked lime and carbon dioxide reaction can generate calcium carbonate and water, concentration of carbon dioxide in the cigarette buttress can be effectively reduced, the alcoholization of tobacco leaf can be promoted.
Carry out the tobacco leaf storage test with the present invention, in anaerobic environment by to desinsection, mildew-resistant, the charing that stores tobacco leaf, observation, test and the analysis of going rancid and hardening, in the tobacco leaf buttress of sealing, when concentration of oxygen is reduced to 5% left and right sides, climb in the tobacco bale buttress one after another around the film cover by the insect of oxygen existence in the buttress, insect vital movement after three days in the buttress is suppressed, and most insects are death by suffocation, whole deaths by suffocation after five days.Aerobic microorganisms such as mould also can't survive because of anoxic.To preservation life is half a year and the de-stacking inspection respectively of the tobacco leaf more than a year, and the storehouse worm is all withered in the cigarette buttress, no adult, larva and worm's ovum.The high sealing of 5 tobacco bales of pile buttress, though its bottom tobacco leaf is pressed very in fact, tobacco leaf is loose when getting rid of, does not have the phenomenon of going rancid, bond, tying plate and go mouldy.This explanation utilization the present invention is very good as the effect of sealing, refining fungus-proof pesticide up for safekeeping of tobacco leaf.
The alcoholization, the fungus-proof pesticide that use the present invention to store as tobacco leaf are simultaneously to " Malong, Yunnan C 4F ", " Fujian B 2F " and " Changting, Fujian C 3F " tobacco leaf in three kinds of different places of production carried out the check experiment that artificial ageing and natural alcoholization store; the tobacco leaf of getting is the tobacco leaf of same batch, same quality before the test; after the sealing alcoholization was handled through 12 months storage lifves, detect in the tobacco leaf main chemical result respectively and the exterior quality influence is compared, as following table:
Figure C20061004159700061
Can know from last table and to find out the unique effect of the present invention as the tobacco mellowing fungus-proof pesticide, wherein reduced iron powder can absorb the oxygen in the sealing cigarette buttress up hill and dale, calcium oxide can prevent the rising of gas concentration lwevel in the alcoholization process, water-absorbing resin can effectively be controlled humidity in the sealing cigarette buttress, active carbon can be absorbed blue foreign smell and the penetrating odor in the tobacco leaf comparatively up hill and dale, chlorate and water can be controlled the oxygen absorption rate of reduced iron powder, this tobacco mellowing, fungus-proof pesticide can effectively be killed the cigarette worm, prevent tobacco mildew, can also impel tobacco leaf thoroughly to refine, it is current ideal tobacco mellowing, fungus-proof pesticide, because the desinsection that it adopts, mildew-resistant, promote that the mechanism of alcoholization all is environmental protection, to tobacco leaf and environment and operating personnel all is harmless, thereby is a kind of non-harmful Chemical composition that.
Embodiment:
Illustrate the specific embodiment of the present invention below:
Example 1: the component of Nuisanceless tobacco leaf alcoholization of the present invention, fungus-proof pesticide and percentage by weight are:
Reduced iron powder 55%; Active carbon 8%; Charring rice husk 20%; Water-absorbing resin 5%; Sodium chloride 2%; Calcium oxide 6%, water 4%.
Its preparation method is:
1. take by weighing above-mentioned each component by above-mentioned percentage by weight;
2. sodium chloride is dissolved in the water, the water that will be dissolved with sodium chloride then splashes in the reduced iron powder, stirs while dripping, and makes the reduced iron powder surface have adhesive;
3. the reduced iron powder that more 2. step is obtained joins in the charring rice husk, stirs while adding, and reduced iron powder is evenly distributed on the charring rice husk;
4. the charring rice husk that is stained with reduced iron powder that 3. active carbon, water-absorbing resin, calcium oxide and step are obtained fully stirs and gets final product.
Using method of the present invention is as follows: the tobacco leaf in sealing stores in the storehouse, per four bags of tobacco leaf bag are piled a buttress, stack spaced reciprocally between buttress and the buttress, end face at every buttress tobacco bale is laid sackcloth, be sprinkling upon the present invention on the sackcloth equably, the amount of sowing is 1 kilogram of every bag, and sealed storage got final product in 1 year.
Example 2: the component of Nuisanceless tobacco leaf alcoholization of the present invention, fungus-proof pesticide and percentage by weight are:
Reduced iron powder 30%; Active carbon 10%; Charring rice husk 30%; Water-absorbing resin 10%; Sodium chloride 5%; Calcium oxide 10%, water 5%.
Example 3: the component of Nuisanceless tobacco leaf alcoholization of the present invention, fungus-proof pesticide and percentage by weight are: reduced iron powder 80%; Active carbon 5%; Charring rice husk 3%; Water-absorbing resin 5%; Potassium chloride 1%; Calcium oxide 3%, water 3%.
Its compound method is all identical with example 1 with using method.

Claims (4)

1. a Nuisanceless tobacco leaf alcoholization, fungus-proof pesticide, its component and percentage by weight are:
Reduced iron powder 30%~80%; Active carbon 2%~15%; Charring rice husk 3%~30%; Water-absorbing resin 1%~15%; Chlorate 1.5%~15%; Calcium oxide 2.5%~20%; Water 1%~5%.
2. according to the described Nuisanceless tobacco leaf alcoholization of claim 1, fungus-proof pesticide, its component and percentage by weight are:
Reduced iron powder 50%~60%; Active carbon 5%~15%; Charring rice husk 15%~30%; Water-absorbing resin 5%~10%; Chlorate 2%~5%; Calcium oxide 5%~10%, water 1%~5%.
3. according to the described Nuisanceless tobacco leaf alcoholization of claim 1, fungus-proof pesticide, its component and percentage by weight are:
Reduced iron powder 55%; Active carbon 8%; Charring rice husk 23%; Water-absorbing resin 5%; Chlorate 2%; Calcium oxide 5%, water 2%.
4. according to the described Nuisanceless tobacco leaf alcoholization of claim 1, fungus-proof pesticide, it is characterized in that: preferred 50~100 orders of the particle diameter of described water-absorbing resin, water content is 3%~5%.
CNB200610041597XA 2006-09-16 2006-09-16 Pollution-free tobacco mellowing and mildew-proof pesticide Ceased CN100403908C (en)

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101607631A (en) * 2009-05-11 2009-12-23 湖南华望熏蒸消毒有限公司 That the blanket gas of tobacco leaf storage is taken good care of and protected, controls is wet, mildew-resistant, pest control technology
CN102582975A (en) * 2011-01-10 2012-07-18 湖南华望熏蒸消毒有限公司 Storage method for storage substances through reducing oxygen to kill pests
CN102783707B (en) * 2011-05-16 2016-01-20 湖南华望熏蒸消毒有限公司 Controlled atmosphere sealing compound that a kind of tobacco leaf storage alcoholization process uses and preparation method thereof
CN103005698B (en) * 2012-12-06 2015-04-08 四川金叶生物防治有限公司 Environmental-friendly safety tobacco conservation agent
CN103404967A (en) * 2013-07-17 2013-11-27 湖南震宇天然生物科技有限责任公司 Deoxidizer and preparing method and application thereof
CN107810992B (en) * 2016-09-13 2020-11-03 德大生技有限公司 Method for manufacturing natural pesticide and water quenching device thereof
CN108378063A (en) * 2018-05-18 2018-08-10 中国农业科学院农业环境与可持续发展研究所 A kind of preparation method of muscardine granule
CN113892678B (en) * 2021-11-02 2023-03-24 江苏中烟工业有限责任公司 Curing agent for tobacco leaf storage and alcoholization process and use method thereof
CN114128916B (en) * 2021-11-22 2022-10-11 北京盈丰利泰科贸有限公司 Air regulating agent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0998762A (en) * 1995-10-05 1997-04-15 Daicel Chem Ind Ltd Cigarette filter and its production
CN1337273A (en) * 2001-06-26 2002-02-27 广州番禺凯德食品科技有限责任公司 Self-controlled oxygen absorbent and its prepn
CN1510105A (en) * 2002-12-25 2004-07-07 萌 王 Nanometer double-suction deoxidation antistaling agent
CN1759681A (en) * 2005-11-14 2006-04-19 王春录 Green multifunctional pesticidan anti-mildew agent for tobacco leaves

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0998762A (en) * 1995-10-05 1997-04-15 Daicel Chem Ind Ltd Cigarette filter and its production
CN1337273A (en) * 2001-06-26 2002-02-27 广州番禺凯德食品科技有限责任公司 Self-controlled oxygen absorbent and its prepn
CN1510105A (en) * 2002-12-25 2004-07-07 萌 王 Nanometer double-suction deoxidation antistaling agent
CN1759681A (en) * 2005-11-14 2006-04-19 王春录 Green multifunctional pesticidan anti-mildew agent for tobacco leaves

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