CN100402748C - Multifunction reinforcing protection glue for paper historical documents - Google Patents
Multifunction reinforcing protection glue for paper historical documents Download PDFInfo
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- CN100402748C CN100402748C CNB200510095202XA CN200510095202A CN100402748C CN 100402748 C CN100402748 C CN 100402748C CN B200510095202X A CNB200510095202X A CN B200510095202XA CN 200510095202 A CN200510095202 A CN 200510095202A CN 100402748 C CN100402748 C CN 100402748C
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- 239000003292 glue Substances 0.000 title claims abstract description 22
- 230000003014 reinforcing effect Effects 0.000 title claims abstract description 15
- 229920001661 Chitosan Polymers 0.000 claims abstract description 13
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000012986 modification Methods 0.000 claims description 17
- 230000004048 modification Effects 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 4
- 230000001681 protective effect Effects 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 15
- 239000000463 material Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 8
- 239000010408 film Substances 0.000 description 7
- 230000002787 reinforcement Effects 0.000 description 6
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 5
- 238000006253 efflorescence Methods 0.000 description 5
- 206010037844 rash Diseases 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 229920005615 natural polymer Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000001857 anti-mycotic effect Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 239000002543 antimycotic Substances 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006074 cyclodimerization reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical group O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- -1 paraxylene free radical Chemical class 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000052 poly(p-xylylene) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The present invention relates to multifunctional glue solution for reinforcing and protecting paper historical documents, which belongs to glue solution for protecting paper historical documents. The protective glue solution comprises the components of the proportion by weight: 12 to 15% of FEVE fluororesin, 10 to 14% of hydroxy chitosan, 14 to 20% of HDI crosslinking agent, 4 to 8% of nanometer zinc oxide powder and 50 to 60% of N-methyl-pyrrolidone. The protective glue solution has the characteristics of transparency, absence of color, lackluster, no film formation and aging resistance, and has the functions of mildew prevention and sterilization.
Description
One, technical field
Multifunction reinforcing protection glue for paper historical documents of the present invention belongs to a kind of viscose of protecting paper historical documents.Paper historical documents comprises books in ancient times, calligraphy ﹠ painting, documents and materials, newspapers and periodicals etc.
Two, background technology
The main feature of multifunction reinforcing protection glue for paper historical documents is; can be under the prerequisite of basic maintenance paper historical documents original appearance; be exactly can be at the basic original color of paper historical documents, color and luster, the gloss of keeping; texture; under the prerequisite of thickness, the efflorescence part of paper historical documents is fixed, and fibrous fracture partly connects; fiber is increased slightly, thereby make paper historical documents obtain reinforcement protection.
The guard method of paper historical documents mainly contains holder and mounts method, silk net reinforcing method coating method, and synthetic fibre vacuum coating method, resin method for strengthening etc. draw in group.
The holder method of mounting is the traditional handicraft of paper historical documents protection; be the back side that the holder paper that will scribble paste is pasted on paper historical documents; paper historical documents to breakage is repaired, is reinforced, and damages by worms to repairing fracture, and the brown and crisp poor rotten paper historical documents that is printed on one side is effective.
The silk net reinforcing method is inventions such as why three coloured silk of Nanjing Museum; be to be woven into the silk screen of certain size through the silk of processed; by gluing hot pressing; with silk screen and paper historical documents applying carrying out reinforcement protection; web material is transparent, flexible, easy to operate; for the intrinsic obvious effects that adds of the paper historical documents of fragment shape, bulk strength difference, but because the persistence time of adhesive material has been grown silk screen can come off.
Coating method gets up damaged, fragile paper historical documents clamp by two layers of plastic thin films, and paper historical documents is isolated, and relies on film strength to protect paper, and coating method is actually a kind of method for preserving.
It is that paper historical documents is put in the vacuum equipment that the synthetic fibre coating method draws in group; paraxylene cyclodimerization body is vaporized, is cracked into active paraxylene gas aggradation in paper historical documents surface and crack; aggregate into parylene film (promptly the synthetic fibre film draws in group); the paraxylene free radical can infiltrate paper historical documents cavernous structure, penetrate the crack and carry out polymerization, on paper historical documents, form the reinforcement protection film.
Though it is effective that this method is protected, color, gloss etc. can keep the original appearance of paper historical documents basically, can obviously increase the thickness of paper historical documents, obviously change texture, even can make original soft crooked paper historical documents texture hardening be card.
The resin method for strengthening is that certain density resin adhesive liquid is sprayed, fills, permeates in paper historical documents surface and inner.This method can satisfy the requirement of historical relic's protection " restoring the old as the old " substantially, and easy, easy row is in recent years to the more a kind of method of paper historical documents protection research.Begin usually to reinforce paper historical documents from the forties in last century with acetate fiber.That uses at present has acrylic resin, polyvinyl butyral resin, N methoxymethyl nylon, an organic siliconresin etc.But these mostly are the synthetic resin material, the molecular weight height, and poor permeability, easy film forming, degradeds easy to change etc. can not be satisfactory.
Three, summary of the invention
The objective of the invention is to the problem that exists at prior art, a kind of have clear, colorless, tarnish, non-film forming, ageing-resistant, the multifunction reinforcing protection glue for paper historical documents that has function such as antimycotic antiseptic concurrently are provided.
The percentage by weight of multifunction reinforcing protection glue for paper historical documents of the present invention:
FEVE fluororesin 12～15%,
Modification of chitosan 10～14%,
HDI crosslinking agent 14～20%,
Zinc oxide nano-powder (treated) 4～8%,
N-methyl-pyrrolidones 60%.
Based on modified fluorin resin, added modification of chitosan and nano material etc. by above-mentioned prescription multifunction reinforcing protection glue for paper historical documents of the present invention as can be known, fundamental difference has been arranged with the protection of above-mentioned domestic and international paper historical documents.The fluorine material is owing to its superior weatherability, durability, chemical resistance, print resistance, and the reinforcement protection that it is applied to paper historical documents is not seen open report as yet.Have trial with shitosan protection paper historical documents in Brazil; but mainly be the antibiotic property protection that is used for paper; and employing fluorine material; modification of chitosan and usefulness, promptly synthetic resin and natural polymer and usefulness adopt high activity; ageing-resistant crosslinking agent; protective material and paper are combined, improved the integrated protection performance, this guard method does not still have report at home and abroad.In addition, also nano anti-biotic material is applied to paper historical documents protection aspect and does not also appear in the newspapers, this shows that the multifunction reinforcing protection glue for paper historical documents of development has novelty, originality.
Use reinforcing protection glue of the present invention have clear, colorless, tarnish, non-film forming, ageing-resistant, have functions such as antimycotic antiseptic concurrently.Paper historical documents intensity behind the reinforcement protection, elasticity are obviously improved, and change original texture, thickness, color and luster hardly, can satisfy the principle of historical relic's protection necessary " restoring the old as the old ", " maintenance original appearance "; Natural polymer, synthetic high polymer and function nano material three are integrated, to paper historical documents from fiber increase slightly, embrittlement reinforcing, fixed three aspects of efflorescence carry out reinforcement protection, guard method uniqueness, novelty simultaneously; And natural polymer, synthetic high polymer are carried out simultaneously suitably crosslinked, making existing chemical consolidation between protection glue and the paper historical documents has physical protection again.
Four, the specific embodiment
Paper historical documents multifunction reinforcing protection sol of the present invention adds modification of chitosan, HDI crosslinking agent and crosslinked the forming of modification zinc nano-powder based on the FEVE modified fluorin resin.
The FEVE modified fluorin resin is the product of fluororesin through modification, specifically is the copolymer of PVF and vinyl ethers, and this resin is an imported material.
Modification of chitosan, shitosan wherein also can be buied on the market by purifying voluntarily.Because the shitosan indissoluble is separated, therefore it is carried out graft modification, obtained modification of chitosan, improved its dissolubility.The concrete title of HDI crosslinking agent is hexamethylene-diisocyanate.
The modified zinc oxide nano-powder also can be buied now by synthetic voluntarily, but because nanometer is easy to reunite, can not be scattered in equably in the glue, just can not play its due performance and effect, therefore must carry out modification and handle.After the disposal methods with research voluntarily, obtain the modified nano zinc oxide powder body material, can be scattered in equably in the glue, played its due antimildew and antibacterial effect.
The modified crosslinking of its main material is as follows:
1, adopt the FEVE fluororesin of modification, its molecular structural formula to be,
X=F, CF
3, Cl R
1, R
2=alkyl R
3, R
4=alkylene base
2, the modified-reaction mechanism of shitosan is,
3, the reaction mechanism of HDI crosslinking agent and FEVE modified fluorin resin, modification of chitosan and paper fibre element is,
(R is respectively the basic structure of FEVE fluororesin, modification of chitosan and paper fibre element in the formula)
Instantiation:
Example (1) to intensity is still arranged but the paper that does not still have an efflorescence handle:
In the N-of 60g methyl-pyrrolidone solution, the FEVE fluororesin that adds 12g respectively successively, the modification of chitosan of 10g, 14g HDI crosslinking agent, the zinc oxide nano-powder of 4g, be put in after the stirring in the ultrasonic oscillator and handled about 20 minutes, after treating fully evenly, glue is sprayed on the paper equably, also can with special writing brush equably dipping on paper, solvent evaporates is clean about 60 minutes, and then hangs naturally 24 hours.
Example (2) is handled the paper that a small amount of efflorescence is arranged that does not almost have intensity:
In the solution of the N-of 60g methyl-pyrrolidones, the FEVE fluororesin that adds 14g respectively successively, the modification of chitosan of 12g, the zinc oxide nano-powder of 16g HDI crosslinking agent, 5g is put in after the stirring in the ultrasonic oscillator and handled about 25 minutes, treat fully evenly after, at special online spraying glue, glue is fallen on the paper equably, and solvent evaporates is clean about 60 minutes, hangs naturally 24 hours.
Be applied to immediately on the bonding plane, solvent evaporates is clean about 60 minutes, hangs naturally 24 hours again.
Example (3) is handled the paper that efflorescence seriously almost completely loses intensity:
In the N-of 60g methyl-pyrrolidone solution, the FEVE fluororesin that adds 15g respectively successively, the modification of chitosan of 14g, 20g HDI crosslinking agent, the zinc oxide nano-powder of 6g, be put in after stirring in the ultrasonic oscillator and handled about 30 minutes, after treating fully evenly,, make glue fall on the paper equably at special online spraying glue, solvent evaporates is clean about 60 minutes, hangs naturally 24 hours again.
Claims (1)
1. a multifunction reinforcing protection glue for paper historical documents is characterized in that, the percentage by weight of its composition is: FEVE fluororesin 12-15%; modification of chitosan 10-14%; HDI crosslinking agent 14-20%, zinc oxide nano-powder 4-8%, N-methyl-pyrrolidones 50-60%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510095202XA CN100402748C (en) | 2005-11-03 | 2005-11-03 | Multifunction reinforcing protection glue for paper historical documents |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200510095202XA CN100402748C (en) | 2005-11-03 | 2005-11-03 | Multifunction reinforcing protection glue for paper historical documents |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1773014A CN1773014A (en) | 2006-05-17 |
| CN100402748C true CN100402748C (en) | 2008-07-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200510095202XA Expired - Fee Related CN100402748C (en) | 2005-11-03 | 2005-11-03 | Multifunction reinforcing protection glue for paper historical documents |
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| Country | Link |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102418301B (en) * | 2011-10-10 | 2013-12-11 | 甘肃省博物馆 | Composition for protecting paper document as well as preparation method and application of composition |
| CN102504650B (en) * | 2011-10-26 | 2013-11-06 | 甘肃省博物馆 | Preparation method and application of composite material for protecting paper files |
| CN104532669A (en) * | 2014-12-05 | 2015-04-22 | 鲁继烈 | Water-tolerant light-resistant ozone-proof composition for protection of character image and cultural relics |
| CN108613852A (en) * | 2016-12-12 | 2018-10-02 | 中国石油天然气股份有限公司 | Solvent synthesis coating test method for hot-melt pressure-sensitive adhesive |
| CN110130152A (en) * | 2019-05-30 | 2019-08-16 | 方成 | A kind of Multifunctional paper historical relic reinforcement protection agent |
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2005
- 2005-11-03 CN CNB200510095202XA patent/CN100402748C/en not_active Expired - Fee Related
Non-Patent Citations (6)
| Title |
|---|
| HDI三聚体和偶联剂对纸质文物加固保护的研究. 毛科人，邱建辉，徐方圆，孙振乾，谢雷.南京航空航天大学学报，第36卷第5期. 2004 |
| HDI三聚体和偶联剂对纸质文物加固保护的研究. 毛科人，邱建辉，徐方圆，孙振乾，谢雷.南京航空航天大学学报，第36卷第5期. 2004 * |
| 含氟聚合物加固保护纸质文物研究. 徐方圆，邱建辉，孙振乾，毛科人.文物保护与考古科学，第16卷第4期. 2004 |
| 含氟聚合物加固保护纸质文物研究. 徐方圆，邱建辉，孙振乾，毛科人.文物保护与考古科学，第16卷第4期. 2004 * |
| 纸质文物保护研究. 龚德才，奚三彩，唐静娟.东南文化，第4期. 1997 |
| 纸质文物保护研究. 龚德才，奚三彩，唐静娟.东南文化，第4期. 1997 * |
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| Publication number | Publication date |
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| CN1773014A (en) | 2006-05-17 |
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