CN100389226C - Metal rust-inhibiting liquid - Google Patents
Metal rust-inhibiting liquid Download PDFInfo
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- CN100389226C CN100389226C CNB2005100178452A CN200510017845A CN100389226C CN 100389226 C CN100389226 C CN 100389226C CN B2005100178452 A CNB2005100178452 A CN B2005100178452A CN 200510017845 A CN200510017845 A CN 200510017845A CN 100389226 C CN100389226 C CN 100389226C
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- metal
- rust
- water
- inhibiting liquid
- inhibiting
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Abstract
The present invention relates to a metal rust-inhibiting liquid for preprocessing the surfaces of metal materials and metal products, which is prepared from trisodium phosphate, sodium silicate, industrial sodium nitrite, methenamine, carbamide and water. The metal rust-inhibiting liquid for preprocessing the surfaces of metal materials and metal products can enhance anticorrosion capabilities of the surfaces of metals and improve moisture and air insulating capabilities of covering layers so that the metals have reliable long-term rust-inhibiting effects. The present invention can be repeatedly used, can not generate acid mist which can result in environmental pollution and burn skins when used and has the advantages of no waste liquid exhaust, no irritation to human bodies, no damage, high safety, reliability and easy operation.
Description
Technical field
The invention belongs to field of metal surface treatment technology, is that pretreated metal rust-inhibiting liquid is carried out on a kind of surface to metallic substance and metal products.
Background technology
In technique known; to metallic substance and metal products generally after carrying out chemically treated degreasing and rust removal; can there be layer protecting film in the metallic surface; though this layer protective membrane can play certain antirust corrosion inhibition to metal in a short time; but generally remained to 3～5 days, new corrosion forms under protective film and development gradually.Therefore, how to make the surface of metallic substance can realize the antirust of long period, become a major subjects of current research.
Goal of the invention
The purpose of this invention is to provide a kind ofly, can prolong the antirust time, improve the metal rust-inhibiting liquid of rust-proof effect metallic substance behind the degreasing and rust removal or metal products.
Realize that the technical scheme that purpose of the present invention is taked is: this rust protection liquid is by following raw materials by weight percent: tertiary sodium phosphate 10～40%, water glass 0.5～3%, industrial sodium nitrite 3～9%, urotropine 0.5～3%, urea 4～9% and 40～70% water are formulated.During preparation,, according to a back order with last item mixed preparing, be hybridly prepared into rust protection liquid successively then earlier with each raw material aqueous solution work in-process raw material of making soluble in water respectively.
The present invention selects for use tri-sodium phosphate, water glass, industrial sodium nitrite, urotropine and urea to make up, and makes each raw material effect produce synergy, thereby can effectively prolong the metal rust preventing time, improves the metal rust preventing effect.The function of each raw material is respectively:
Tertiary sodium phosphate: be slightly acidic, have phosphatization, rust inhibition.
Water glass: be slightly acidic, can form oxide film, have anti-oxidation function.
Industrial sodium nitrite: be slightly acidic, have rust inhibition.
Urotropine: in raw material, play complexing action.
Urea: neutrality after above-mentioned raw materials mixes, has rust inhibition.
According to the formulated metal rust-inhibiting liquid of above-mentioned raw materials; be primarily aimed at the metal behind the degreasing and rust removal; after the immersion treatment of rust protection liquid of the present invention; can improve the sticking power of corrosion protection tunic at connection metal; and in formed protective membrane; the metallic surface can be caused the potential risk of corrosion be reduced to bottom line; also make simultaneously protective layer itself fine and close more; improve the erosion resistance of metallic surface; improve the performance of protective layer damp proof insulation and secluding air, make it have the rust-proof effect of reliable long period.Its rust-proof effect: generally can keep 2～3 months or can keep no longer producing about 1 year the secondary oxidation corrosion indoor outdoor.There is not the acid mist that can cause environmental pollution in the use of this rust protection liquid, can not cause the hydrogen embrittlement of metal yet, can skin ambustion during use, and non-stimulated, harmless to human body, safe and reliable, easy handling.
Embodiment
Metal rust-inhibiting liquid of the present invention is by following raw materials by weight percent: tertiary sodium phosphate 10～40%, water glass 0.5～3%, industrial sodium nitrite 3～9%, urotropine 0.5～3%, urea 4～9% and 40～70% water are formulated.
In the present invention, the consumption of each raw material is also groped to sum up to draw through the contriver in a large number, and its consumption all has effect preferably in the following weight percentage range.
Embodiment one
The weight percent of described each raw material is: tertiary sodium phosphate 20%, water glass 1%, industrial sodium nitrite 6%, urotropine 1%, urea 7%, surplus are water.
Embodiment two
The weight percent of described each raw material is: tertiary sodium phosphate 35%, water glass 2%, industrial sodium nitrite 4%, urotropine 2%, urea 5%, surplus are water.
Embodiment three
The weight percent of described each raw material is: tertiary sodium phosphate 15%, water glass 3%, industrial sodium nitrite 8%, urotropine 3%, urea 8%, surplus are water.
Compound method of the present invention: raw material is contained in the acid-resistant container by getting dosage respectively, and again that raw material is soluble in water respectively, the consumption of water is as the criterion can melt raw material, makes half-finished aqueous feed solution, and the melting temperature of each raw material and water is:
(1) tertiary sodium phosphate stirs with dissolving in 80～90 ℃ the hot water, makes trisodium phosphate aqueous solution, waits to join;
(2) water glass stirs with dissolving in 30～40 ℃ of warm water, makes sodium silicate aqueous solution, waits to join;
(3) industrial sodium nitrite stirs with dissolving in 30～40 ℃ of warm water, makes the industrial sodium nitrite aqueous solution, waits to join;
(4) urotropine stirs with dissolving in 30～40 ℃ of warm water, makes the urotropine aqueous solution, waits to join;
(5) urea stirs with dissolving in 30～40 ℃ of warm water, makes aqueous solution of urea, waits to join.
With the above-mentioned work in-process raw material to be joined of making the aqueous solution, according to a back order with last mixed preparing, mix successively and fill up the water yield by proportioning, be mixed with the metal rust-inhibiting liquid finished product, be contained in the plastic tank stand-by then.
Using method of the present invention is: only need build the pond that can heat, be contained with antirust working fluid in the pond, metal works is immersed in 40～50 ℃ the antirust working fluid, take out workpiece after 8～20 minutes, at the ventilation airing, continue the nature phosphatization.This rust protection liquid can be recycled, and no discharging of waste liquid, its liquid ingredient be maintenance and control easily, and do not influence the metallic substance performance, and the phosphatize phosphate coat of formation does not have destruction to the application paint film.
Product of the present invention has good adaptive capacity and rust-proof effect, and easy to use, cost is low, Small investment, efficient height, simultaneously to environment without any pollution.
Claims (4)
1. metal rust-inhibiting liquid is characterized in that: by following raw materials by weight percent: tertiary sodium phosphate 10～40%, water glass 0.5～3%, industrial sodium nitrite 3～9%, urotropine 0.5～3%, urea 4～9% and 40～70% water are formulated.
2. metal rust-inhibiting liquid according to claim 1 is characterized in that: the weight percent of described each raw material is: tertiary sodium phosphate 20%, water glass 1%, industrial sodium nitrite 6%, urotropine 1%, urea 7%, surplus are water.
3. metal rust-inhibiting liquid according to claim 1 is characterized in that: the weight percent of described each raw material is: tertiary sodium phosphate 35%, water glass 2%, industrial sodium nitrite 4%, urotropine 2%, urea 5%, surplus are water.
4. metal rust-inhibiting liquid according to claim 1 is characterized in that: the weight percent of described each raw material is: tertiary sodium phosphate 15%, water glass 3%, industrial sodium nitrite 8%, urotropine 3%, urea 8%, surplus are water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100178452A CN100389226C (en) | 2005-08-03 | 2005-08-03 | Metal rust-inhibiting liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100178452A CN100389226C (en) | 2005-08-03 | 2005-08-03 | Metal rust-inhibiting liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1778988A CN1778988A (en) | 2006-05-31 |
| CN100389226C true CN100389226C (en) | 2008-05-21 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100178452A Expired - Fee Related CN100389226C (en) | 2005-08-03 | 2005-08-03 | Metal rust-inhibiting liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100389226C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105039994A (en) * | 2015-07-09 | 2015-11-11 | 江门市三清环境技术工程有限公司 | Novel black metal antirust agent and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102851662B (en) * | 2012-09-14 | 2014-06-11 | 江苏博铭威精密机械制造有限公司 | Metal anti-rust treatment liquid and application method thereof |
| CN110438481A (en) * | 2019-08-26 | 2019-11-12 | 浙江量泰标准件有限公司 | A kind for the treatment of process of antirust bolt |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85104742A (en) * | 1985-06-24 | 1985-12-20 | 淮北矿务局科研所 | Steel derusting, passivation novel process |
| WO1999046425A1 (en) * | 1998-03-13 | 1999-09-16 | Zakrytoe Aktsionernoe Obschestvo Firma Novye Sistemnye Teknologii | Agent for cleaning metal and metal-containing surfaces |
| CN1386907A (en) * | 2001-05-18 | 2002-12-25 | 天津市宇泰化工高科技有限公司 | Liquid for removing oil and rust from metal and its preparing process |
| CN1417379A (en) * | 2001-11-02 | 2003-05-14 | 王志刚 | Rust-eliminating and rust-preventing liquid |
| CN1492074A (en) * | 2002-10-27 | 2004-04-28 | 李天贵 | Novel rust-proof water |
-
2005
- 2005-08-03 CN CNB2005100178452A patent/CN100389226C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85104742A (en) * | 1985-06-24 | 1985-12-20 | 淮北矿务局科研所 | Steel derusting, passivation novel process |
| WO1999046425A1 (en) * | 1998-03-13 | 1999-09-16 | Zakrytoe Aktsionernoe Obschestvo Firma Novye Sistemnye Teknologii | Agent for cleaning metal and metal-containing surfaces |
| CN1386907A (en) * | 2001-05-18 | 2002-12-25 | 天津市宇泰化工高科技有限公司 | Liquid for removing oil and rust from metal and its preparing process |
| CN1417379A (en) * | 2001-11-02 | 2003-05-14 | 王志刚 | Rust-eliminating and rust-preventing liquid |
| CN1492074A (en) * | 2002-10-27 | 2004-04-28 | 李天贵 | Novel rust-proof water |
Non-Patent Citations (2)
| Title |
|---|
| 金属防锈剂研制的新进展. 赵二茹，尹伯生.现代涂料与涂装，第1期. 1997 |
| 金属防锈剂研制的新进展. 赵二茹，尹伯生.现代涂料与涂装，第1期. 1997 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105039994A (en) * | 2015-07-09 | 2015-11-11 | 江门市三清环境技术工程有限公司 | Novel black metal antirust agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1778988A (en) | 2006-05-31 |
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| C06 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Wuxi Putian Iron Core Co., Ltd. Assignor: Xia Guangfu Contract fulfillment period: 2009.7.25 to 2017.7.31 Contract record no.: 2009320001339 Denomination of invention: Metal rust-inhibiting liquid Granted publication date: 20080521 License type: Exclusive license Record date: 20090803 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.7.25 TO 2017.7.31; CHANGE OF CONTRACT Name of requester: WUXI PUTIAN IRON CORE CO., LTD. Effective date: 20090803 |
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| CF01 | Termination of patent right due to non-payment of annual fee |
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